Search Results (52)

This study focuses on the structural and electrochemical behavior of the compound ZnLaFeO₄ as a negative electrode material for nickel–metal hydride (Ni-MH) batteries. The material was synthesized by a sol–gel hydrothermal method to assess the influence of lanthanum doping on the ZnFe₂O₄ spinel structure. X-ray diffraction revealed the formation of a dominant LaFeO₃ perovskite phase, with ZnFe₂O₄ and La₂O₃ as secondary phases. SEM analysis showed agglomerated grains with an irregular morphology. Electrochemical characterization at room temperature and a discharge rate of C/10 (full charge in 10 h) revealed a maximum discharge capacity of 106 mAhg⁻¹. Although La³⁺ doping modified the microstructure and slowed the activation process, the electrode exhibited stable cycling with moderate polarization behavior. The decrease in capacity during cycling is due mainly to higher internal resistance. These results highlight the potential and limitations of La-doped spinel ferrites as alternative negative electrodes for Ni-MH systems. Full article

There is a high demand for nickel hydroxide as an engineering material used in the positive electrode of nickel metal hydride (Ni-MH) rechargeable batteries. These batteries are extensively used in various small instruments, disposable batteries, and electric vehicles. The structure of nickel hydroxide significantly influences the discharge capacity and energy density, key properties of Ni-MH batteries, and this structure is primarily determined by the synthesis method used. In this study, nickel hydroxide was synthesized using an electrochemical precipitation method, with current density acting as a parameter to control the desired phase of the product, whether α-nickel hydroxide, β-nickel hydroxide, or a combination of both. At a current density of 50 A/m², the synthesized nickel hydroxide demonstrated a smaller particle size and a superior discharge electrochemical property in comparison to that generated at 500 A/m². The effect of agitation in catholyte was also investigated to examine the change in discharge property of the precipitated material. The product synthesized at 500 A/m² from an agitated catholyte exhibited a tap density of 1.24 g/cc and an improved discharge capacity of 254 mAh per gram of Ni(OH)₂. Full article

In the ongoing shift toward electric vehicles (EVs) primarily utilizing lithium-ion battery technology, a significant population of hybrid electric vehicles (HEVs) remains operational, which are reliant on established NiMH battery systems. Over the last twenty years, these HEVs have generated a substantial number of NiMH batteries that are either inoperable, experiencing performance degradation, or approaching the end of their service life. This situation results in a twofold challenge: (i) a growing volume of environmentally hazardous waste due to the difficulty of NiMH battery reclamation and (ii) escalating maintenance costs for HEV owners necessitated by replacement battery purchases. To overcome this scenario, patent WO2015092107A1, published in 2015, proposed a ‘Method for regenerating NiMH batteries.’ This method claimed the ability to restore NiMH batteries to their original functionality based on a non-intrusive approach. However, a comprehensive review of the relevant scientific literature fails to identify any empirical evidence supporting the efficacy of this regeneration technique. Within this context, this study provides a detailed analysis and evaluation of the regeneration process based on an unsupervised and non-intrusive prototype. The proposed prototype can be used not only to implement and evaluate the previous patent, but also to test any other process or methodology based on controlled charging/discharging periods under certain current conditions. NiMH battery cells from a Toyota Prius were included in this work as a real case study. The experimental results from this prototype demonstrate the reduced potential for battery regeneration using the proposed method. Future contributions should offer a promising solution for mitigating the challenges associated with NiMH battery disposal, maintenance within the HEV domain, and other second-life alternative options. Full article

Mg-based alloy anodes suffer from severe corrosion in alkaline electrolytes, which substantially impedes their cycle life and thereby limits their suitability as anode materials for nickel–metal hydride (Ni-MH) batteries. This work modifies the conventional 6 M KOH electrolyte by adding 0.1 M Al₂(SO₄)₃·18H₂O. The electrochemical hydrogen storage properties of Mg_0.45Ti_0.05Ni_0.50 alloy in this electrolyte and its microstructural evolution during cycling are studied. In the 6 M KOH + 0.1 M Al₂(SO₄)₃·18H₂O electrolyte, a protective layer consisting of Mg₂Al(OH)₇ is formed on the surface of the Mg_0.45Ti_0.05Ni_0.50 alloy anode during charge/discharge cycling instead of Mg(OH)₂, effectively preventing further corrosion and improving its cycle life. The Mg_0.45Ti_0.05Ni_0.50 alloy anode delivers a maximum discharge capacity of 479.0 mAh g⁻¹ and maintains 318.4 mAh g⁻¹ after 30 cycles in the 6 M KOH + 0.1 M Al₂(SO₄)₃·18H₂O electrolyte, which is significantly superior to that achieved in the 6 M KOH electrolyte (471.1 mAh g⁻¹ and 201.8 mAh g⁻¹, respectively). This work provides a new strategy for improving the cycle stability of Mg-based alloy anodes. Full article

Metallic glasses (MGs) are a type of multicomponent non-crystalline metallic alloys obtained by rapid cooling, which possess several physical, mechanical, and chemical advantages against their crystalline counterparts. In this work, an Fe-based MG is explored as a hydrogen storage material, especially, due to the evidence in previous studies about the capability of some amorphous metals to store hydrogen. The evaluation of an Fe-based MG as a novel negative electrode material for nickel/metal hydride (Ni-MH) batteries was carried out through cyclic voltammetry and galvanostatic charge–discharge tests. A conventional LaNi₅ electrode was also evaluated for comparative purposes. The electrochemical results obtained by cyclic voltammetry showed the formation of three peaks, which are associated with the formation of Fe oxides/oxyhydroxides and hydroxides. Cycling charge/discharge tests revealed activation of the MG electrode. The highest discharge capacity value was 173.88 mAh/g, but a decay in its capacity was observed after 25 cycles, contrary to the LaNi₅, which presents an increment of the discharge capacity for all the current density values evaluated, reached its value maximum at 183 mAh/g. Characterization analyses performed by X-ray diffraction, Scanning Electron Microscopy and Raman Spectroscopy revealed the presence of corrosion products and porosity on the surface of the Fe-based MG electrodes. Overall, the Fe-based MG composition is potentially able to work as a negative electrode material, but degradation and little information about storage mechanisms means that it requires further investigation. Full article

This article investigates the impact of loading on the hybrid powertrain of the FCAT-30 model, equipped with a proton-exchange-membrane fuel cell (PEMFC) and a nickel–metal hydride (NiMH) battery. This study involves analyzing structural component performance based on voltage and current measurements of the fuel cell, battery, and powertrain. Tests conducted under different load conditions reveal significant differences in battery current and fuel-cell voltage, highlighting the crucial role of the battery in the powertrain. External loading induces cyclic operation of the fuel cell, generating peak power. The energy balance analysis demonstrates that, under no-load conditions, the vehicle consumes 37.3% of its energy from the fuel cell, with a total energy consumption of 3597 J. Under load, the energy from the battery is significantly utilized, resulting in a constant fuel-cell share of approximately 19%, regardless of the vehicle’s load. This study concludes that the battery predominantly drives the powertrain, with the fuel cell acting as a secondary energy source. These findings provide valuable insights into the power distribution and energy balance in the hybrid powertrain. Using a load driving profile reduced the fuel-cell-stack energy contribution by 6.85% relative to driving without an external load. Full article

The state of charge of a battery depends on many magnitudes, but only voltage and intensity are included in mathematical equations because other variables are complex to integrate into. The contribution of this work was to obtain a model to determine the state of charge with these complex variables. This method was developed considering four models, the multilayer feed-forward backpropagation models of two and three input variables used supervised training, with the variable-learning-rate backpropagation training function, five and seven neurons in the hidden layer, respectively, achieving an optimal training. Meanwhile, the radial basis neural network models of two and three input variables were trained with the hybrid method, the propagation constant with a value of 1 and 80 neurons in the hidden layer. As a result, the radial basis neural network with the variable-learning-rate training function, considering the discharge temperature, was the one with the best performance, with a correlation coefficient of 0.99182 and a confidence interval of 95% (0.98849; 0.99516). It is then concluded that artificial neural networks have high performance when modeling nonlinear systems, whose parameters are difficult to measure with time variation, so estimating them in formulas where they are omitted is no longer necessary, which means an accurate SOC. Full article

Back-scattered electron imaging and X-ray elemental mapping were combined in a tabletop scanning electron microscope (SEM) to investigate cross-sections of three AA-type (mignon) nickel–metal hydride (NiMH) batteries from different manufacturers. All batteries underwent 500–800 charge/discharge cycles and reached their end of lifetime after several years as they could no longer hold any significant electric charge (less than 20% of nominal charge capacity), but none showed any short-circuiting. The types of degradation observed in this field study included electrode swelling, metallic nickel formation and carbon incorporation into pores in the positive electrodes and, in the negative electrodes, metal alloy segregation of different elements such as nickel, lanthanum and, in one case, sodium, as well as grain break-up and pore formation. All these phenomena could readily be observed at rather small magnifications. This will be important for the improvement of NiMH batteries, for which new generations with nominally slightly increased charge capacities are being marketed all the time. Full article

Rare earth elements (REEs) are essential for permanent magnets that are vital for wind turbines and electric vehicles motors (EV), and are also used in a range of high-tech devices such as smartphones, digital cameras, and electronic displays. Nickel metal hydride (NiMH) batteries have been identified as a potential source due to their short lifespans and an anticipated boom in the production of EV. The aim of this study was to investigate the effect of mesomixing on crystal quality in a non-confined impinging jet mixer (NCIJM) during antisolvent crystallization of 3.2 g/L Nd₂(SO₄)₃ from a synthetic leach solution of NiMH battery using ethanol at an O/A ratio of 1.1. The jet streams were supplied at a Reynolds number (Re) between 7500 and 15,000. The product slurry was allowed to further crystallize in a stirred batch crystallizer at a Re of 13,000 for 45 s. An average yield of 90% was achieved. Laser diffraction and scanning electron microscopy (SEM) were used for size analysis. The initial results were inconclusive due to the secondary mixing effect in the stirred batch crystallizer. Therefore, the experiments were repeated, and samples were collected immediately after mixing in the NCIJM onto a porous grid placed on a high absorbance filter paper to abruptly halt crystallization. The samples were analysed using a transmission electron microscope (TEM), and the acquired images were processed using ImageJ to obtain crystal size distributions (CSDs). It was found that the enhanced mesomixing conditions resulted in smaller crystal sizes and narrower CSDs. This was because the nucleation rate was found to be mass-transfer-limited, such that higher mesomixing intensities promoted the nucleation rate from 6 × 10¹² to 5 × 10¹³ m⁻³ s⁻¹ and, therefore, favoured the formation of smaller crystals. In parallel, intensified mesomixing resulted in uniform distribution of the supersaturation and, hence, narrowed the CSDs. Full article

The recycling of REEs from the end of life (EoL) products, such as nickel metal hydride batteries (NiMH), offers great opportunities for their supply in Europe. In the presented paper, the application of ‘green’ extractants such as citric (CA), metatartaric (TA), and ethylenediaminedisuccinic acid (EDDS) (also with H₂O₂ addition) for the recovery of REEs was studied. The studies were conducted considering the effects of the phase contact time, the initial concentration of CA, TA, and EDDS, as well as H₂O₂, pH, and temperature. It was found that the addition of TA to the CA solution meant that higher rates of metal ion binding and, thus, leaching was observed. The optimal conditions were obtained in the system: CA-TA and H₂O₂ for the concentration 0.6M-0.3 M-2%. Full article

Considering how important rare earth elements (REEs) are for many different industries, it is important to separate them from other elements. An extractant that binds to REEs inexpensively and selectively even in the presence of interfering ions can be used to develop a useful separation method. This work was designed to recover REEs from spent nickel–metal hydride batteries using ammonium sulfate. The chemical composition of the Ni–MH batteries was examined. The operating leaching conditions of REE extraction from black powder were experimentally optimized. The optimal conditions for the dissolution of approximately 99.98% of REEs and almost all zinc were attained through use of a 300 g/L (NH₄)₂SO₄ concentration after 180 min of leaching time and a 1:3 solid/liquid phase ratio at 120 °C. The kinetic data fit the chemical control model. The separation of total REEs and zinc was conducted under traditional conditions to produce both metal values in marketable forms. The work then shifted to separate cerium as an individual REE through acid baking with HCl, thus leaving pure cerium behind. Full article

The treatment of spent nickel metal hydride batteries (NiMHs) of Lexus vehicles to recover nickel (Ni) and cobalt (Co) as well as rare earth elements (REEs) including La, Ce, Nd and Y was investigated. Co-extraction of Al, Fe, Cr and Cu has also been examined. Following batteries’ manual dismantling to remove metallic cases, outer plastics and current collectors, the remaining parts including cathodes of black coloured nickel (oxy)hydroxides, anodes consisting of a nickel-containing alloy (AB5 mischmetal type), and separators were simultaneously ground down to −5 mm using a hammer mill equipped with sieves. The fine (−1 mm) fraction of this product was further subjected to sulphuric acid leaching to recover the high-value elements contained. Acid consumption of 14 mol H₂SO₄ per kg of this fraction was found to be sufficient to decrease pH to less than 1. Leaching experiments were performed using 0.5, 1 and 2 M sulphuric acid solution at 5% pulp density and temperature 50, 75 or 95 °C. The optimum conditions for the extraction of all elements were 2M H₂SO₄ concentration and temperature of 75 °C with the exception of Ni extraction, which reached its highest value at 95 °C and 2M H₂SO₄ concentration. Extractions of 93.34% of Ni, 99.03% of Co and 100% of REEs were achieved at these conditions. Full article

Nickel metal hydride (NiMH) batteries are extensively used in the manufacturing of portable electronic devices as well as electric vehicles due to their specific properties including high energy density, precise volume, resistance to overcharge, etc. These NiMH batteries contain significant amounts of rare earth metals (REMs) along with Co and Ni which are discarded due to illegal dumping and improper recycling practices. In view of their strategic, economic, and industrial importance, and to mitigate the demand and supply gap of REMs and the limited availability of natural resources, it is necessary to explore secondary resources of REMs. Therefore, the present paper reports a feasible hydrometallurgical process flowsheet for the recovery of REMs and valuable metals from spent NiMH batteries. More than 90% dissolution of REMs (Nd, Ce and La) was achieved using 2 M H₂SO₄ at 75 °C in 60 min in the presence of 10% H₂O₂ (v/v). From the obtained leach liquor, the REMs, such as Nd and Ce, were recovered using 10% PC88A diluted in kerosene at eq. pH 1.5 and O/A ratio 1/1 in two stages of counter current extraction. La of 99% purity was selectively precipitated from the leach liquor in the pH range of 1.5 to 2.0, leaving Cu, Ni and Co in the filtrate. Further, Cu and Ni were extracted with LIX 84 at equilibrium pH 2.5 and 5, leaving Co in the raffinate. The developed process flow sheet is feasible and has potential for industrial exploitation after scale-up/pilot trails. Full article

As the automotive industry progresses, electric vehicles (EV) grow with increasing demand throughout the world. Nickel-metal hydride (NiMH) battery and lithium-ion (Li-ion) are widely used in EV due to their advantages such as impressive energy density, good power density, and low self-discharge. However, the batteries must be operated within their optimum range for safety and good thermal management to enable a longer lifespan, lower costs, and improve safety for EV batteries. The need for a liquid cold plate (LCP) to be used in EV batteries is now highly reliable on the distribution of the required temperature rather than only standard cooling systems. The fins arrangement in the LCP would likewise impact the cooling efficiency of the EV battery. The main objective of this paper is to determine the heat transfer enhancement of liquid cold plate systems with the oblique fin and different types of liquid coolants. In the experimental test, two liquid types are used namely G13 ethylene glycol and distilled water in five steps, 10% ethylene glycol, 100% distilled water, 75% ethylene glycol + 25% distilled water, 50% ethylene glycol + 50% distilled water, and 25% ethylene glycol + 75% distilled water. Three different flow rates have been utilized which are 0.3, 0.5, and 0.7 GPM to maximize the productivity of flowing fluid and heat transferring with the gate door valve. The LCP encompasses the inline configuration of the oblique fin, which is able to enhance the heat transfer rate from the heater to the liquid cold plate. A GPM of 0.7 reached the least surface temperature for the battery in the three different flow levels. The LCP is capable of sustaining the ambient surface temperatures of the batteries just under the permissible 50 °C operating temperature, which indicates that the developed LCP with the oblique fin may perhaps become an effective option for the thermal control of EV batteries. Full article

Batteries in energy storage systems are exposed to electrical noise, such as alternating current (AC) harmonics. While there have been many studies investigating whether Lithium-ion batteries are affected by AC harmonics, such studies on Nickel Metal Hydride (NiMH) batteries are scarce. In this study a 10 Ah, 12 V NiMH battery was tested with three different harmonic current frequency overlays during a single charge/discharge cycle: 50 Hz, 100 Hz, and 1000 Hz. No effect on battery internal temperature or gas pressure was found, indicating that NiMH battery aging is not affected by the tested harmonic AC frequencies. This can reduce the cost of energy storage systems, as no extra filters are needed to safeguard the batteries. Instead, the capacitive properties of the batteries give the possibility to use the battery bank itself as a high pass filter, further reducing system complexity and cost. Full article