Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (51)

Search Parameters:
Keywords = neutron diffusion model

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
24 pages, 3937 KB  
Article
Probing the Density Dependence of Nuclear Symmetry Energy Through Isospin Transport in Heavy-Ion Reactions
by S. Mallik, F. Gulminelli, C. Ciampi and D. Gruyer
Universe 2026, 12(7), 202; https://doi.org/10.3390/universe12070202 - 6 Jul 2026
Viewed by 235
Abstract
The density dependence of nuclear symmetry energy remains one of the key uncertainties in contemporary nuclear physics, with significant implications for the structure of exotic nuclei, the dynamics of heavy-ion collisions, and the properties of astrophysical objects such as neutron stars and core-collapse [...] Read more.
The density dependence of nuclear symmetry energy remains one of the key uncertainties in contemporary nuclear physics, with significant implications for the structure of exotic nuclei, the dynamics of heavy-ion collisions, and the properties of astrophysical objects such as neutron stars and core-collapse supernovae. However, extracting robust constraints requires observables that are minimally affected by final-state interactions and are reliably predicted by transport models. This review synthesizes recent theoretical and experimental advancements in constraining the symmetry energy by leveraging isospin diffusion in heavy-ion reactions within the Fermi energy domain. Recent results from the INDRA-FAZIA collaboration, including isospin transport ratio data and Boltzmann–Uehling–Uhlenbeck (BUU) transport model calculations, are highlighted. Confidence regions for the symmetry energy are extracted from isospin transport ratios and isospin diffusion currents by utilizing state-of-the-art nuclear functionals, including both ab initio and phenomenological approaches, with a particular focus on the density regions probed by these experiments. The resulting constraints will aid future Bayesian studies of the nuclear equation of state and contribute to a more unified understanding of dense matter in both terrestrial experiments and astrophysical environments. Full article
Show Figures

Figure 1

42 pages, 9170 KB  
Review
Advanced Characterization of Biphasic Ceramic Tritium Breeder Pebbles for Fusion Energy
by Viktor Dolin, Rosa Lo Frano, Antonio Bulgheroni and Salvatore A. Cancemi
Eng 2026, 7(7), 316; https://doi.org/10.3390/eng7070316 - 30 Jun 2026
Viewed by 584
Abstract
Tritium breeding blanket is a key component of future fusion power plants, and its performance depends on the selection, fabrication, and qualification of lithium-based ceramic material. Among the proposed lithium ceramics materials, the main candidates for ceramic breeders are lithium orthosilicate (Li4 [...] Read more.
Tritium breeding blanket is a key component of future fusion power plants, and its performance depends on the selection, fabrication, and qualification of lithium-based ceramic material. Among the proposed lithium ceramics materials, the main candidates for ceramic breeders are lithium orthosilicate (Li4SiO4) and lithium metatitanate (Li2TiO3). These advanced ceramics and their biphasic composites are the leading candidates due to their high lithium density, favorable tritium breeding ratio (TBR ≈ 1.15–1.25 with Be12Ti multiplier and 90% 6Li enrichment), and robust thermo-mechanical behavior within the 200–900 °C operational window of helium-cooled pebble bed (HCPB) blankets. This review provides an engineering-oriented assessment covering fabrication routes (solid-state, hydrothermal, melt-based, drip casting, powder injection molding, microwave sintering, and digital light processing additive manufacturing); microstructure–property relationships and performance under neutron irradiation; and tritium generation, retention, and release as functions of chemical composition, defect structure, and operating temperature. Induced radioactivity of Li-based ceramics and key impurity elements is quantified using activation formalisms applied to WWR-K reactor conditions, providing guidance for raw-material selection and waste-management assessment. Authors’ original contributions include (i) an empirical model of pebble crush load vs. biphasic composition (R2 > 0.99); (ii) two universal semi-empirical kinetic models (exponential growth and non-linear strength degradation, R2 = 0.97–0.99) for nine structural and mechanical parameters of Li2TiO3 under He2+ and H+ irradiation; (iii) a consolidated table of Arrhenius tritium diffusion parameters from reactor experiments and DFT; and (iv) an induced radioactivity calculation for the biphasic system with two-exponential post-irradiation decay analysis. The review identifies biphasic Li4SiO4–Li2TiO3 composites with ~30 ± 5 mol.% Li2TiO3 as particularly promising and formulates specific data gaps and modeling needs for the reliable deployment of ceramic breeder pebbles in helium-cooled fusion blanket systems. It should be specifically noted that Li4SiO4 pebbles fabricated via the melt method, as an example, typically exhibit exceptionally high densities, generally exceeding 90% of the theoretical density (TD). Building on the calculation of induced radioactivity, it is crucial to consider the microstructural distribution of highly radioactive nuclides (e.g., Co, Mn) within the ceramic matrix. If these impurities segregate at grain boundaries rather than being homogeneously distributed, there is a potential pathway to develop targeted wet-chemical methods, such as selective acid leaching, to remove these impurities post-irradiation, thereby lowering the waste disposal classification. Full article
(This article belongs to the Section Materials Engineering)
Show Figures

Figure 1

47 pages, 3969 KB  
Review
Fast Radio Bursts as Sources of Ultra-High-Energy Cosmic Rays: A Multi-Messenger Review
by Luiz Augusto Stuani Pereira
Universe 2026, 12(7), 190; https://doi.org/10.3390/universe12070190 - 24 Jun 2026
Viewed by 267
Abstract
Fast radio bursts (FRBs) are millisecond-duration radio transients of extragalactic origin, while ultra-high-energy cosmic rays (UHECRs; E1018 eV) remain among the most important unresolved problems in astroparticle physics. This review examines the viability of FRBs and their central engines as [...] Read more.
Fast radio bursts (FRBs) are millisecond-duration radio transients of extragalactic origin, while ultra-high-energy cosmic rays (UHECRs; E1018 eV) remain among the most important unresolved problems in astroparticle physics. This review examines the viability of FRBs and their central engines as sources of UHECRs within a comprehensive multi-messenger framework. We summarize the observational constraints on UHECR source populations imposed by the energy spectrum, nuclear composition, anisotropy measurements, diffuse γ-ray background, and high-energy neutrino observations, which, together, favor source classes capable of accelerating heavy nuclei with hard injection spectra, modest cosmological evolution, and sufficiently high source densities. We then review the current landscape of FRB progenitor and engine models, including magnetars, supramassive neutron stars, compact-object mergers, and accretion-powered systems, emphasizing their energetics, environments, and particle-acceleration capabilities through relativistic shocks, magnetic reconnection, magnetar wind nebulae, and direct electromagnetic acceleration by ultra-relativistic FRB pulses. We discuss how these scenarios are constrained by neutrino and γ-ray observations from IceCube, KM3NeT, and Fermi-LAT, as well as by large-scale UHECR anisotropy measurements from the Pierre Auger Observatory and Telescope Array. Finally, we examine the observational tests that will become possible in the coming decade through large samples of localized FRBs, composition-resolved UHECR measurements, next-generation neutrino observatories, and wide-field γ-ray facilities. We emphasize that FRB dispersion and rotation measures provide unique probes of the baryonic and magnetic environments relevant for UHECR acceleration and propagation, enabling a new form of multi-messenger tomography of cosmic-ray source environments and allowing the FRB–UHECR connection to become a quantitatively testable astrophysical framework. Full article
(This article belongs to the Special Issue Fast Radio Bursts in the Era of Multi-Messenger Astrophysics)
Show Figures

Figure 1

37 pages, 4406 KB  
Article
The ‘Forgotten’ Neutrons: Implications for the Propagation of High-Energy Cosmic Rays in Magnetized Astrophysical and Cosmological Structures
by Ellis R. Owen, Kinwah Wu, Yoshiyuki Inoue, Tatsuki Fujiwara, Qin Han and Hayden P. H. Ng
Universe 2026, 12(4), 94; https://doi.org/10.3390/universe12040094 - 26 Mar 2026
Viewed by 888
Abstract
Cosmological filaments, galaxy clusters, and galaxies are magnetized reservoirs of cosmic rays (CRs). The exchange of CRs across these structures is usually modeled assuming that they remain charged and magnetically confined. At high energies, hadronic interactions can convert CR protons to neutrons. This [...] Read more.
Cosmological filaments, galaxy clusters, and galaxies are magnetized reservoirs of cosmic rays (CRs). The exchange of CRs across these structures is usually modeled assuming that they remain charged and magnetically confined. At high energies, hadronic interactions can convert CR protons to neutrons. This physics is routinely included in air-shower and ultra-high-energy (UHE) CR propagation Monte Carlo simulations used for composition studies but is rarely treated explicitly in propagation models of CR transport and exchange between magnetized reservoirs. CR neutrons are not affected by magnetic fields and can propagate ballistically over kpc-Mpc distances before decaying back into protons, with relativistic time dilation extending their effective decay length. We show how such charged–neutral switching modifies CR confinement and escape in four representative environments: a Milky Way-like galaxy, a starburst galaxy, a galaxy cluster, and a cosmological filament. By solving the transport of a confined CR proton population in each structure using a diffusion/streaming propagation approach with hadronic pp and pγ interactions, and treating neutron production and decay as a stochastic Poisson “jump” process, we find that neutron-mediated steps can allow additional CR escape from large-scale cosmological structures at energies where charged-particle transport alone would predict strong CR confinement and attenuation in ambient radiation fields. These effects imply a qualitative shift in how ultra-high-energy CRs are transferred from embedded sources into filaments and voids once intermediate neutron propagation is considered, with consequences for the partitioning of CRs across the large-scale structure of the Universe. Full article
(This article belongs to the Special Issue Studying Astrophysics with High-Energy Cosmic Particles)
Show Figures

Figure 1

13 pages, 2413 KB  
Article
A Small-Angle Neutron Scattering Methodology for Quantitative Characterization of Channel Width in Gamma Matrix Phase
by Zhong Chen, Tianfu Li, Erdong Wu, Xiaoming Du, Shaohua Zhang, Shibo Yan, Zijun Wang, Kai Sun and Dongfeng Chen
Nanomaterials 2025, 15(20), 1581; https://doi.org/10.3390/nano15201581 - 16 Oct 2025
Viewed by 860
Abstract
This study establishes a robust small-angle neutron scattering (SANS) methodology for the quantitative characterization of γ matrix channel widths in the nickel-based single-crystal superalloy DD10. By combining SANS with TEM analyses and modeling the one-dimensional SANS data via a polydisperse lamellar model, we [...] Read more.
This study establishes a robust small-angle neutron scattering (SANS) methodology for the quantitative characterization of γ matrix channel widths in the nickel-based single-crystal superalloy DD10. By combining SANS with TEM analyses and modeling the one-dimensional SANS data via a polydisperse lamellar model, we accurately determined the channel width distribution across macroscopic sample volumes. In the virgin state, the mean channel widths were nearly isotropic, measuring 17.8 ± 0.1 nm along [002] and 20.5 ± 0.1 nm along [020]. After standard heat treatment (solution and two-step aging), significant anisotropic coarsening was observed, with widths increasing to 36.8 ± 0.2 nm along [002] and 28.0 ± 0.1 nm along [020], indicating stress-free rafting. Elemental mapping revealed substantial redistribution of key alloying elements: Al content in γ′ precipitates increased by 2.6 at.%, while Cr in the γ channels rose by 5.9 at.%. These quantitative results demonstrate that SANS provides reliable, bulk-statistical insights into nanoscale channel geometry, highlighting its critical role in influencing elemental diffusion kinetics and microstructural evolution during thermal exposure. Full article
(This article belongs to the Section Theory and Simulation of Nanostructures)
Show Figures

Figure 1

15 pages, 6509 KB  
Article
Abundance Analysis of the Spectroscopic Binary α Equulei
by Anna Romanovskaya and Sergey Zvyagintsev
Galaxies 2025, 13(4), 88; https://doi.org/10.3390/galaxies13040088 - 6 Aug 2025
Viewed by 1749
Abstract
We present the results of a detailed spectroscopic analysis of the double-lined spectroscopic binary system α Equulei. High-resolution spectra obtained with the SOPHIE spectrograph at various orbital phases were used to disentangle the composite spectra into individual components using the spectral line deconvolution [...] Read more.
We present the results of a detailed spectroscopic analysis of the double-lined spectroscopic binary system α Equulei. High-resolution spectra obtained with the SOPHIE spectrograph at various orbital phases were used to disentangle the composite spectra into individual components using the spectral line deconvolution (SLD) iterative technique. The atmospheric parameters of each component were refined with the SME (spectroscopy made easy) package and further validated by following methods: SED (spectral energy distribution), the independence of the abundance of individual Fe iii lines on the reduced equivalent width and ionisation potential, and fitting with the hydrogen line profiles. Our accurate abundance analysis uses a hybrid technique for spectrum synthesis. This is based on classical model atmospheres that are calculated under the assumption of local thermodynamic equilibrium (LTE), together with non-LTE (NLTE) line formation. This is used for 15 out of the 25 species from C to Nd that were investigated. The primary giant component (G7-type) exhibits a typical abundance pattern for normal stars, with elements from He to Fe matching solar values and neutron-capture elements showing overabundances up to 0.5 dex. In contrast, the secondary dwarf component displays characteristics of an early stage Am star. The observed abundance differences imply distinct diffusion processes in their atmospheres. Our results support the scenario in which chemical peculiarities in Am stars develop during the main sequence and may decrease as the stars evolve toward the subgiant branch. Full article
(This article belongs to the Special Issue Stellar Spectroscopy, Molecular Astronomy and Atomic Astronomy)
Show Figures

Figure 1

16 pages, 1496 KB  
Article
Annealing of Oxygen-Related Frenkel Defects in Corundum Single Crystals Irradiated with Energetic Xenon Ions
by Kotomin A. Eugene, Ruslan Assylbayev, Guldar Baubekova, Irina Kudryavtseva, Vladimir N. Kuzovkov, Alise Podelinska, Viktor Seeman, Evgeni Shablonin and Aleksandr Lushchik
Crystals 2025, 15(6), 573; https://doi.org/10.3390/cryst15060573 - 18 Jun 2025
Cited by 4 | Viewed by 1207
Abstract
The recovery of radiation damage induced by 231-MeV xenon ions with varying fluence (from 5 × 1011 to 2 × 1014 cm−2) in α-Al2O3 (corundum) single crystals has been studied by means of isochronal thermal annealing [...] Read more.
The recovery of radiation damage induced by 231-MeV xenon ions with varying fluence (from 5 × 1011 to 2 × 1014 cm−2) in α-Al2O3 (corundum) single crystals has been studied by means of isochronal thermal annealing of radiation-induced optical absorption (RIOA). The integral of elementary Gaussians (product of RIOA spectrum decomposition) OK has been considered as a concentration measure of relevant oxygen-related Frenkel defects (neutral and charged interstitial-vacancy pairs, F-H, F+-H). The annealing kinetics of these four ion-induced point lattice defects has been modelled in terms of diffusion-controlled bimolecular recombination reactions and compared with those carried out earlier for the case of corundum irradiation by fast neutrons. The changes in the parameters of interstitial (mobile component in the recombination process) annealing kinetics—activation energy E and pre-exponential factor X—in ion-irradiated crystals are considered. Full article
(This article belongs to the Section Materials for Energy Applications)
Show Figures

Figure 1

22 pages, 8160 KB  
Article
Design and Characterization of the Modified Purdue Subcritical Pile for Nuclear Research Applications
by Matthew Niichel, Vasileios Theos, Riley Madden, Hannah Pike, True Miller, Brian Jowers and Stylianos Chatzidakis
Instruments 2025, 9(2), 13; https://doi.org/10.3390/instruments9020013 - 6 Jun 2025
Cited by 1 | Viewed by 3089
Abstract
First demonstrated in 1942, subcritical and zero-power critical assemblies, also known as piles, are a fundamental tool for research and education at universities. Traditionally, their role has been primarily instructional and for measuring the fundamental properties of neutron diffusion and transport. However, these [...] Read more.
First demonstrated in 1942, subcritical and zero-power critical assemblies, also known as piles, are a fundamental tool for research and education at universities. Traditionally, their role has been primarily instructional and for measuring the fundamental properties of neutron diffusion and transport. However, these assemblies could hold potential for modern applications and nuclear research. The Purdue University subcritical pile previously lacked a substantial testing volume, limiting its utility to simple neutron activation experiments for the purpose of undergraduate education. Following the design and addition of a mechanical and electrical testbed, this paper aims to provide an overview of the testbed design and characterize the neutron flux of the rearranged Purdue subcritical pile, justifying its use as a modern scientific instrument. The newly installed 1.5 × 105 cubic-centimeter volume testbed enables a systematic investigation of neutron and gamma effects on materials and the generation of a comprehensive data set with the potential for machine learning applications. The neutron flux throughout the pile is measured using gold-197 and indium-115 foil activation alongside cadmium-covered foils for two-group neutron energy classification. The neutron flux measurements are then used to benchmark a detailed geometrically and materialistically accurate Monte Carlo model using OpenMC 0.15.0 and MCNP 6.3. The experimental measurements reveal that the testbed has a neutron environment with a total neutron flux approaching 9.5 × 103 n/cm2 × s and a thermal flux of 6.5 × 103 n/cm2 × s. This work establishes that the modified Purdue subcritical pile can provide fair neutron and gamma fluxes within a large volume to enable the radiation testing of integral electronic components and can be a versatile research instrument with the potential to support material testing and limited isotope activation, while generating valuable training data sets for machine learning algorithms in nuclear applications. Full article
Show Figures

Figure 1

11 pages, 1268 KB  
Article
Study of Average Characteristic Parameters of Isotopes, Isotones and Isobars by Electron and Proton Scattering
by Mirteimour Mirabutalybov and Mina Aliyeva
Quantum Beam Sci. 2025, 9(2), 18; https://doi.org/10.3390/qubs9020018 - 6 May 2025
Viewed by 1516
Abstract
By way of studying the difference of the proton and neutron distributions in isotopes, isotones and isobars, we used the results of theoretical calculations obtained from the scattering of protons and electrons on nuclei. To calculate the differential cross section of proton scattering, [...] Read more.
By way of studying the difference of the proton and neutron distributions in isotopes, isotones and isobars, we used the results of theoretical calculations obtained from the scattering of protons and electrons on nuclei. To calculate the differential cross section of proton scattering, an expression was obtained for the distorted-wave formfactor of the nucleus, which, using the mathematical method proposed by us, is expressed through the plane-wave Born formfactor. In addition, using the data for elastic scattering of electrons on nuclei, the average characteristic parameters of C2040a, C2048a, C2452r, C2454r, F2654e, N2858i, N2860i nuclei were determined. In this work, for calculating the differential cross section of the elastic scattering of electrons on spherical nuclei, the Fermi function was chosen as a trial function of the proton density distribution. In the calculations, the pole method was used to solve the Born integral of the target nucleus formfactor. Based on an analysis of the calculations of the differential cross section of the elastic scattering of electrons and the calculations of the differential cross section of the scattering of protons on the same nuclei, the main patterns of behavior of the general characteristics of nuclei, such as the root mean square radius (RMS), diffuseness, and the isotopic and isotonic shifts of parameters, were determined. For the C2048a nucleus, the radial dependence of the nucleon density distribution on the center of the nucleus, as well as the ratio of proton to neutron densities, have been studied. Changes in the distribution of densities of protons and neutrons with the addition of two neutrons to nucleus C2452r as well as changes in the distributions of densities of protons and neutrons when two neutrons are replaced by protons in isobars F2654eC2454r have been studied. The results of changes in the distribution of densities of protons and neutrons were justified on the basis of the shell model of the nucleus, using characteristic parameters determined for these nuclei from elastic electron scattering. A joint analysis of experimental work on the elastic scattering of electrons and protons on spherical nuclei leads to the conclusion that the distribution patterns of protons and neutrons differ from each other. In particular, this follows from calculations of the RMS of proton, neutron and nucleon distributions. Full article
Show Figures

Figure 1

10 pages, 5511 KB  
Review
Multimessenger Studies with the Pierre Auger Observatory
by Jon Paul Lundquist and the Pierre Auger Collaboration
Particles 2025, 8(2), 45; https://doi.org/10.3390/particles8020045 - 22 Apr 2025
Viewed by 1647
Abstract
The Pierre Auger Observatory, the world’s largest ultra-high-energy (UHE) cosmic ray (CR) detector, plays a crucial role in multi-messenger astroparticle physics with its high sensitivity to UHE photons and neutrinos. Recent Auger Observatory studies have set stringent limits on the diffuse and point-like [...] Read more.
The Pierre Auger Observatory, the world’s largest ultra-high-energy (UHE) cosmic ray (CR) detector, plays a crucial role in multi-messenger astroparticle physics with its high sensitivity to UHE photons and neutrinos. Recent Auger Observatory studies have set stringent limits on the diffuse and point-like fluxes of these particles, enhancing constraints on dark-matter models and UHECR sources. Although no temporal coincidences of neutrinos or photons with LIGO/Virgo gravitational wave events have been observed, competitive limits on the energy radiated in these particles have been established, particularly from the GW170817 binary neutron star merger. Additionally, correlations between the arrival directions of UHECRs and high-energy neutrinos have been explored using data from the IceCube Neutrino Observatory, ANTARES, and the Auger Observatory, providing additional neutrino flux constraints. Efforts to correlate UHE neutron fluxes with gamma-ray sources within our galaxy continue, although no significant excesses have been found. These collaborative and multi-faceted efforts underscore the pivotal role of the Auger Observatory in advancing multi-messenger astrophysics and probing the most extreme environments of the Universe. Full article
Show Figures

Figure 1

9 pages, 253 KB  
Article
Revisiting the Influence of Neutron Transfer Coupling on Surface Diffuseness Parameters for Carbon-Induced Fusion Reactions
by Rakesh Dubey
Atoms 2025, 13(4), 33; https://doi.org/10.3390/atoms13040033 - 9 Apr 2025
Cited by 1 | Viewed by 930
Abstract
The influence of neutron transfer coupling on surface diffuseness has been thoroughly investigated in the study of carbon-induced fusion reactions. Through analysis of experimental measurements using advanced coupled-channel computational frameworks, we have examined how neutron exchange processes modify nuclear interaction potentials with a [...] Read more.
The influence of neutron transfer coupling on surface diffuseness has been thoroughly investigated in the study of carbon-induced fusion reactions. Through analysis of experimental measurements using advanced coupled-channel computational frameworks, we have examined how neutron exchange processes modify nuclear interaction potentials with a particular focus on surface diffuseness parameters. The findings reveal that neutron transfer mechanisms substantially contribute to reducing surface diffuseness values, with this effect being particularly pronounced in reactions involving neutron-rich isotopic combinations. This research highlights the critical importance of incorporating neutron transfer pathways when modeling fusion cross-sections, offering valuable perspectives for subsequent investigations of nuclear reaction dynamics. Full article
Show Figures

Figure 1

18 pages, 5702 KB  
Article
Applicability Analysis of Reduced-Order Methods with Proper Orthogonal Decomposition for Neutron Diffusion in Molten Salt Reactor
by Zhengyang Zhou, Ming Lin, Maosong Cheng, Yuqing Dai and Xiandi Zuo
Energies 2025, 18(8), 1893; https://doi.org/10.3390/en18081893 - 8 Apr 2025
Cited by 5 | Viewed by 1349
Abstract
The high-dimensional integral–differential nature of the neutron transport equation and the complexity of nuclear reactors result in high computational costs. A set of reduced-order modeling frameworks based on Proper Orthogonal Decomposition (POD) is developed to improve the computational efficiency for neutron diffusion calculations [...] Read more.
The high-dimensional integral–differential nature of the neutron transport equation and the complexity of nuclear reactors result in high computational costs. A set of reduced-order modeling frameworks based on Proper Orthogonal Decomposition (POD) is developed to improve the computational efficiency for neutron diffusion calculations while maintaining accuracy, especially for small samples. For modal coefficient calculations, three methods—Galerkin, radial basis function (RBF), and Deep Neural Network (DNN)—are introduced and analyzed for molten salt reactors. The results show that all three reduced-order models achieve sufficient accuracy, with neutron flux L2 errors below 1% and delayed neutron precursor (DNP) L2 errors below 2.4%, while the acceleration ratios exceed 800. Among these, the POD–Galerkin model demonstrates superior performance, achieving average L2 errors of less than 0.00658% for neutron flux and 1.01% for DNP concentration, with an acceleration ratio of approximately 1800 and excellent extrapolation ability. The POD–Galerkin reduced-order model significantly enhances the computational efficiency for solving neutron multi-group diffusion equations and DNP conservation equations in molten salt reactors while preserving the solution accuracy, making it ideal for a liquid fuel molten salt reactor in the case of small samples. Full article
(This article belongs to the Special Issue Nuclear Engineering and Nuclear Fuel Safety)
Show Figures

Figure 1

16 pages, 4164 KB  
Article
Hydrogenolysis of Benzyl Phenyl Ether Using Nickel–Molybdenum Clay Catalysts—A Model for Cleaving Ether Linkages in Lignin
by Indri B. Adilina, Muhammad A. Fitriady, Ferensa Oemry, Fauzan Aulia, Nino Rinaldi, Gagus K. Sunnardianto, Ian P. Silverwood and Stewart F. Parker
Catalysts 2024, 14(12), 953; https://doi.org/10.3390/catal14120953 - 23 Dec 2024
Cited by 1 | Viewed by 2914
Abstract
The solvent-free hydrogenolysis (HDL) of benzyl phenyl ether (BPE), a model for the C–O (α-O-4) linkage in lignin, was investigated using NiMo-pillared clay catalysts in their reduced (NiMoPR) and sulfided (NiMoPS) forms. NiMoPS show higher activity and selectivity to give an equimolar mixture [...] Read more.
The solvent-free hydrogenolysis (HDL) of benzyl phenyl ether (BPE), a model for the C–O (α-O-4) linkage in lignin, was investigated using NiMo-pillared clay catalysts in their reduced (NiMoPR) and sulfided (NiMoPS) forms. NiMoPS show higher activity and selectivity to give an equimolar mixture of toluene and phenol, demonstrating selective cleavage of the Caliphatic–O of BPE, while non-equimolar amounts were found for NiMoPR. Strong acid sites are dominant in NiMoPS, giving a higher total acidity compared to NiMoPR, which explains the higher selectivity of the sulfided catalyst towards the HDL products and monomeric aromatics. To understand the interaction of BPE on the catalyst surface, we carried out a comprehensive investigation of the 2D potential energy surface (PES) of BPE and the vibrational spectra using neutron scattering and computational studies. The results suggest that BPE is weakly adsorbed on NiMoPS and the pillared clay support (PILC) via a van der Waals or H-bonding interaction, but they are strongly chemisorbed on the NiMoPR due to covalent bonding. Weakly adsorbed BPE allows higher mobility during diffusion to the catalytic site, which promotes the higher activity of NiMoPS for the HDL. This work demonstrates the potential use of clay-supported NiMo catalysts for lignin valorization and the future circular economy. Full article
(This article belongs to the Section Biomass Catalysis)
Show Figures

Figure 1

16 pages, 2344 KB  
Article
Effect of Carbon on Void Nucleation in Iron
by Lin Shao
Materials 2024, 17(13), 3375; https://doi.org/10.3390/ma17133375 - 8 Jul 2024
Cited by 6 | Viewed by 1888
Abstract
The study reports the significance of carbon presence in affecting void nucleation in Fe. Without carbon, void nucleation rates decrease gradually at high temperatures but remain significantly high and almost saturated at low temperatures. With carbon present, even at 1 atomic parts per [...] Read more.
The study reports the significance of carbon presence in affecting void nucleation in Fe. Without carbon, void nucleation rates decrease gradually at high temperatures but remain significantly high and almost saturated at low temperatures. With carbon present, even at 1 atomic parts per million, void nucleation rates show a low-temperature cutoff. With higher carbon levels, the nucleation temperature window becomes narrower, the maximum nucleation rate becomes lower, and the temperature of maximum void nucleation shifts to a higher temperature. Fundamentally, this is caused by the change in effective vacancy diffusivity due to the formation of carbon-vacancy complexes. The high sensitivity of void nucleation to carbon comes from the high sensitivity of void nucleation to the vacancy arrival rate in a void. The void nucleation is calculated by first obtaining the effective vacancy diffusivity considering the carbon effect, then calculating the defect concentration and defect flux change considering both carbon effects and pre-existing dislocations, and finally calculating the void nucleation rate based on the recently corrected homogeneous void nucleation theory. The study is important not only in the fundamental understanding of impurity effects in ion/neutron irradiation but also in alloy engineering for judiciously introducing impurities to increase swelling resistance, as well as in the development of simulation and modeling methodologies applicable to other metals. Full article
Show Figures

Graphical abstract

18 pages, 12761 KB  
Article
Research on the Effect of Fracture Angle on Neutron Logging Results of Shale Gas Reservoirs
by Xueang Zhang, Zhichao Yang and Xiaoyan Li
Energies 2024, 17(13), 3342; https://doi.org/10.3390/en17133342 - 8 Jul 2024
Cited by 1 | Viewed by 1808
Abstract
Fracture structures are important natural gas transport spaces in shale gas reservoirs, and their storage state in shale gas reservoirs seriously affects gas production and extraction efficiency. This work uses numerical modeling techniques to investigate the logging response law of the thermal and [...] Read more.
Fracture structures are important natural gas transport spaces in shale gas reservoirs, and their storage state in shale gas reservoirs seriously affects gas production and extraction efficiency. This work uses numerical modeling techniques to investigate the logging response law of the thermal and epithermal neutrons in the gas-containing fracture environment at various angles, applying neutron logging as a technical method. To increase the precision of the evaluation of the natural gas storage condition in shale gas reservoirs, the angle of the fractures’ neutron logging data is analyzed. It is found that even in an environment with the same porosity of the fractures, there are significant differences in the logging results due to the different angles of the fracture alignment: 1. the neutron counts in the high-angle (70–90°) fracture environment are 2.25 times higher than in the low-angle (0–20°), but the diffusion area of the neutrons is only 10.58% of that in the low-angle (0–20°); 2. in the neutron energy spectrum, neutron counts are spreading to the high-energy region (7–13 MeV) along with the increase in the angle of the fracture, and the feature is especially prominent in the approximately vertical (60–90°) fracture environment, which is an increase of 528.12% in comparison with the counts in the approximately horizontal angle (0–30°) environment. The main reason for these differences is the variation in the volume of the fracture within the source radiation. This volumetric difference results from the variation in fracture angles (even though the fracture porosity is the same). In view of the above phenomenon, this paper proposes the concept of “effective fracture volume”, which can intuitively reflect the degree of influence of fracture angle on neutron logging results. Further, based on the unique characteristics of shale gas reservoirs and neutrons, this paper provides important theoretical support for the modification of the porosity of the field operation, the evaluation of the physical characteristics of the gas endowment space, and the assessment. Full article
(This article belongs to the Section H: Geo-Energy)
Show Figures

Figure 1

Back to TopTop