Search Results (999)

This research paper employed novel sustainable alternative materials to reduce the environmental impact of thermoset/synthetic fibre composites. The effect of seawater hydrothermal ageing at 45 °C for 45 and 90 days on the physical and interlaminar fracture toughness (mode I and mode II) of a semi-unidirectional non-crimp basalt fibre (BF)-reinforced acrylic matrix and epoxy matrix composites was investigated. Optical and scanning electron microscopes were used to describe the fracture and interfacial failure mechanisms. The results show that the BF/Elium composite exhibited higher fracture toughness properties compared to the BF/Epoxy composite. The results of the mode I and mode II interlaminar fracture toughness values for the BF/Elium composite were 1280 J/m² and 2100 J/m², which are 14% and 56% higher, respectively, than those of the BF/Epoxy composite. The result values for both composites were normalised with respect to the density of each composite laminate. The saturated moisture content and diffusion coefficient values of seawater-aged samples at 45 °C and room temperature for the BF/Elium and BF/Epoxy composites were analysed. Both composites exhibited signs of polymer matrix decomposition and fibre surface degradation under the influence of seawater hydrothermal ageing, resulting in a reduction in the mode II interlaminar fracture toughness values. Enhancement was observed in mode I fracture toughness under hydrothermal ageing, particularly for the BF/Epoxy composite, due to matrix plasticisation and fibre bridging. Full article

In comparison to shallow coal seams, deep coal seams exhibit characteristics of high temperature, pressure, and in-situ stress, leading to significant differences in reservoir properties that constrain the effective development of deep coalbed methane (CBM). This study takes the Carboniferous deep 8# coal seam in the Yulin area of Ordos basin as the research subject. Based on the test results from core drilling wells, a comprehensive analysis of the characteristics and variation patterns of coal reservoir properties and a comparative analysis of the exploration and development potential of deep CBM are conducted, aiming to provide guidance for the development of deep CBM in the Ordos basin. The research results indicate that the coal seams are primarily composed of primary structure coal, with semi-bright to bright being the dominant macroscopic coal types. The maximum vitrinite reflectance (R_o,max) ranges between 1.99% and 2.24%, the organic is type III, and the high Vitrinite content provides a substantial material basis for the generation of CBM. Longitudinally, influenced by sedimentary environment and plant types, the lower part of the coal seam exhibits higher Vitrinite content and fixed carbon (FC_ad). The pore morphology is mainly characterized by wedge-shaped/parallel plate-shaped pores and open ventilation pores, with good connectivity, which is favorable for the storage and output of CBM. Micropores (<2 nm) have the highest volume proportion, showing an increasing trend with burial depth, and due to interlayer sliding and capillary condensation, the pore size (<2 nm) distribution follows an N shape. The full-scale pore heterogeneity (fractal dimension) gradually increases with increasing buried depth. Macroscopic fractures are mostly found in bright coal bands, while microscopic fractures are more developed in Vitrinite, showing a positive correlation between fracture density and Vitrinite content. The porosity and permeability conditions of reservoirs are comparable to the Daning–Jixian block, mostly constituting oversaturated gas reservoirs with a critical depth of 2400–2600 m and a high proportion of free gas, exhibiting promising development prospects, and the middle and upper coal seams are favorable intervals. In terms of resource conditions, preservation conditions, and reservoir alterability, the development potential of CBM from the Carboniferous deep 8# coal seam is comparable to the Linxing block but inferior to the Daning–Jixian block and Baijiahai uplift. Full article

In order to investigate the influence of graphene/rubber powder compound modified asphalt on the low-temperature cracking resistance of drainage asphalt mixtures, graphene/rubber powder compound modified asphalt mixtures were prepared using graphene/rubber powder compound modified asphalt for drainage asphalt mixtures, and compared with SBS-modified asphalt and rubber powder-modified asphalt, and the low-temperature cracking resistance of graphene/rubber powder compound modification asphalt mixtures was investigated through the Marshall Stability Test, Semi-circular Bending Test (SCB), and Freeze–Thaw Split Test. Research was carried out. At the same time, a scanning electric microscope (SEM) was adopted to analyze the micro-mechanism of the graphene/rubber powder compound modified asphalt mixtures under the microscopic condition. The findings showed that graphene dispersed the aggregation of rubber powder effectively in the microscopic state and improved the stability of the composite modified asphalt. The addition of graphene improved the fracture energy of rubber powder composite modified asphalt by 15.68% under the condition of −15 °C to 0 °C, which effectively slowed down the decrease of fracture energy; at −15 °C and −10 °C, the largest stresses were improved by 7.50% and 26.71%, respectively, compared to the drainage asphalt mixtures prepared as rubber powder-modified asphalt and SBS-modified asphalt. After a freeze–thaw cycle, the maximum stress decrease of graphene/rubber powder compound modified asphalt was 21.51% and 10.37% at −15 °C and 0 °C, respectively. When compared to rubber powder-modified asphalt, graphene/rubber powder compound modified asphalt significantly improved the low-intensity cracking resistance of drainage asphalt mixtures at low temperatures, slowed down the decrease of the maximum stress, and its low-temperature cracking resistance was more stable. Full article

The aim of translucency-enhancing liquids (TEL) is to locally influence the phase composition of zirconia in order to increase its translucency. This study aimed to determine the influence of TEL on 3Y- and 4Y-TZP zirconia concerning roughness, hardness, wear, flexural strength, dynamic stability and fracture force of fixed dental prostheses after thermal cycling and mechanical loading. Two zirconia materials (4Y-TZP; 3Y-TZP-LA, n = 8 per material and test) were investigated with and without prior application of TEL. Two-body wear tests were performed in a pneumatic pin-on-block design (50 N, 120,000 cycles, 1.6 Hz) with steatite balls (r = 1.5 mm) as antagonists. Mean and maximum vertical loss as well as roughness (Ra, Rz) were measured with a 3D laser-scanning microscope (KJ 3D, Keyence, J). Antagonist wear was determined as percent area of the projected antagonist area. Martens hardness (HM; ISO 14577-1) and biaxial flexural strength (BFS; ISO 6872) were investigated. The flexural fatigue limit BFSdyn was determined under cyclic loading in a staircase approach with a piston-on-three-ball-test. Thermal cycling and mechanical loading (TCML: 2 × 3000 × 5 °C/55 °C, 2 min/cycle, H₂O dist., 1.2 × 10⁶ force á 50 N) was performed on four-unit fixed dental prostheses (FDPs) (n = 8 per group) and the fracture force after TCML was determined. Statistics: ANOVA, Bonferroni test, Kaplan–Meier survival, Pearson correlation; α = 0.05. TEL application significantly influences roughness, hardness, biaxial flexural strength, dynamic performance, as well as fracture force after TCML in 3Y-TZP. For 4Y-TZP, a distinct influence of TEL was only identified for BFS. The application of TEL on 3Y- or 4Y-TZP did not affect wear. TEL application has a strong effect on the mechanical properties of 3Y-TZP and minor effects on 4Y-TZP. All effects of the TEL application are of a magnitude that is unlikely to restrict clinical application. Full article

Lateritic soils in tropical regions feature cohesive textures and high specific resistance, driving up energy demands for tillage and harvesting machinery. However, current equipment designs lack discrete element models that account for soil moisture variations, and the microscopic effects of water content on lateritic soil deformation remain poorly understood. This study aims to calibrate and validate discrete element method (DEM) models of lateritic soil at varying moisture contents of 20.51%, 22.39%, 24.53%, 26.28%, and 28.04% by integrating the Hertz–Mindlin contact mechanics with bonding and JKR cohesion models. Key parameters in the simulations were calibrated through systematic experimentation. Using Plackett–Burman design, critical factors significantly affecting axial compressive force—including surface energy, normal bond stiffness, and tangential bond stiffness—were identified. Subsequently, Box–Behnken response surface methodology was employed to optimize these parameters by minimizing deviations between simulated and experimental maximum axial compressive forces under each moisture condition. The calibrated models demonstrated high fidelity, with average relative errors of 4.53%, 3.36%, 3.05%, 3.32%, and 7.60% for uniaxial compression simulations across the five moisture levels. Stress–strain analysis under axial loading revealed that at a given surface displacement, both fracture dimensions and stress transfer rates decreased progressively with increasing moisture content. These findings elucidate the moisture-dependent micromechanical behavior of lateritic soil and provide critical data support for DEM-based design optimization of soil-engaging agricultural implements in tropical environments. Full article

This research paper employed the recently developed Elium thermoplastic resin and basalt fabrics as an alternative to thermoset/synthetic fibre composites to reduce their environmental impact. Elium^® 191 XO/SA and Epoxy Prime^TM 37 resin were reinforced with mineral-based semi-unidirectional basalt fibre (BF). Physical, chemical, tensile, and flexural performance was investigated under the effect of hydrothermal seawater ageing at 45 °C for 45 and 90 days. The results show that the BF/Elium composite exhibited superior tensile and flexural strength, as well as good stiffness, compared with the BF/Epoxy composite. Digital images and scanning electron microscope images were used to describe the fracture and failure mechanisms. The tensile and flexural strength values of the BF/Elium composite were 1165 MPa and 1128 MPa, greater than those of the BF/Epoxy composite by 33% and 71%, respectively. The tensile and flexural modulus values of the BF/Elium composite were 44.1 GPa and 38.2 GPa, which are 30% and 12% greater than those of the BF/Epoxy composite. The result values for both composites were normalised with respect to the density of each composite laminate. Both composites exhibited signs of resin decomposition and fibre surface degradation under the influence of seawater ageing, resulting in a more recognisable reduction in flexural properties than in tensile properties. Full article

Chemically strengthened glass is widely used for its remarkable fracture strength, mechanical performance, and scratch resistance. Assessing its hardness is crucial to evaluating improvements from chemical tempering. However, conventional methods like Vickers hardness tests are destructive, altering the sample surface. This study presents a novel, rapid, and nondestructive testing (NDT) approach by correlating the nonlinear refractive index (n₂) with surface hardness. Using ultrafast laser pulses, we measured the n₂ cross-section via the nonlinear ellipse rotation (NER) signal in Gorilla^®-type glass subjected to ion exchange (Na⁺ by K⁺). A microscope objective lens provided a penetration resolution of ≈5.5 μm, enabling a localized NER signal analysis. We demonstrate a correlation between the NER signal and hardness, offering a promising pathway for advanced, noninvasive characterization. This approach provides a reliable alternative to traditional destructive techniques, with potential applications in industrial quality control and material science research. Full article

This study is based on the laser-induced thermal-crack propagation (LITP) technology, focusing on the issues of deviation and thermal damage during the transverse crack propagation process, with the aim of achieving high-purity, non-destructive, and high-precision cutting of glass. A 50 W, 1064 nm fiber laser is used for S-pattern scanning cutting of soda–lime glass. A moving heat source model is established and analyzed via MATLAB R2022a numerical simulation. Combined with the ABAQUS 2019 software, the relationships among temperature field, stress field, crack propagation, and deviation during laser-induced thermal crack cutting are deeply explored. Meanwhile, laser thermal fracture experiments are also carried out. A confocal microscope detects glass surface morphology, cross-sectional roughness and hardness under different heat flux densities (HFLs), determining the heat flux density threshold affecting the glass surface quality. Through a comprehensive study of theory, simulation, and experiments, it is found that with an increase in the HFL value of the material, the laser-induced thermal crack propagation can be divided into four stages. When the heat flux density value is in the range of 47.2 to 472 W/m², the glass substrate has good cross-sectional characteristics. There is no ablation phenomenon, and the surface roughness of the cross-section is lower than 0.15 mm. The hardness decreases by 9.19% compared with the reference value. Full article

The coal reservoir in the Ordos Mizhi block is buried at a depth of over 2000 m. This study aims to obtain the characteristics of the coal reservoir in the Mizhi block through various experimental methods and combine the gas-bearing characteristics obtained from on-site desorption experiments to analyze the gas content and logging response characteristics of the study area. On this basis, a reservoir parameter interpretation model for the study area is established. This provides a reference for the exploration and development of coal-rock gas in the Mizhi block. The research results show that: (1) The study area is characterized by the development of the No. 8 coal reservoirs of the Benxi Formation, with a thickness ranging from 2 to 11.6 m, averaging 7.2 m. The thicker coal reservoirs provide favorable conditions for the formation and storage of coal-rock gas. The lithotypes are mainly semi-bright and semi-dark. The coal maceral is dominated by the content of the vitrinite, followed by the inertinite, and the exinite is the least. The degree of metamorphism is high, making it a high-grade coal. In the proximate analysis, the moisture ranges from 0.36 to 1.09%, averaging 0.65%. The ash ranges from 2.34 to 42.17%, averaging 16.57%. The volatile ranges from 9.18 to 15.7%, averaging 11.50%. The fixed carbon ranges from 45.24 to 87.51%, averaging 71.28%. (2) According to the results of scanning electron microscopy (SEM), the coal samples in the Mizhi block have developed fractures and pores. Based on the results of the carbon dioxide adsorption experiment, the micropore adsorption capacity is 7.8728–20.3395 cm³/g, with an average of 15.2621 cm³/g. The pore volume is 0.02492–0.063 cm³/g, with an average of 0.04799 cm³/g. The specific surface area of micropores is 79.514–202.3744 m²/g, with an average of 153.5118 m²/g. The micropore parameters are of great significance for the occurrence of coal-rock gas. Based on the results of the desorption experiment, the gas content of the coal rock samples in the study area is 12.97–33.96 m³/t, with an average of 21.8229 m³/t, which is relatively high. (3) Through the correlation analysis of the logging parameters of the coal reservoir, the main logging response parameters of the reservoir are obtained. Based on the results of the logging sensitivity analysis of the coal reservoir, the interpretation model of the reservoir parameters is constructed and verified. Logging interpretation models for parameters such as industrial components, microscopic components, micropore pore parameters, and gas content are obtained. The interpretation models have interpretation effects on the reservoir parameters in the study area. Full article

This study investigates the acoustic and mechanical performance of three types of 3D-printed polylactic acid (PLA) panels with varying infill densities (5–100%) and structural configurations. Using fused filament fabrication (FFF), panels were designed as follows: Type 1 (core infill only), Type 2 (core infill + 1.6 mm shell), and Type 3 (core infill + multi-layer shells). Acoustic testing via impedance tube revealed that Type 2 panels with a 65% infill density achieved the highest sound absorption coefficient (α = 0.99), while Type 1 panels exhibited superior sound transmission loss (TLn = 53.3 dB at 60% infill). Mechanical testing demonstrated that shell layers improved tensile and bending resistance by 25.7% and 36.9%, respectively, but reduced compressive strength by 23.6%. Microscopic analysis highlighted ductile failure in Type 2 and brittle fracture in Type 3. The optimal panel thickness for acoustic performance was identified as 4 mm, balancing material efficiency and sound absorption. These findings underscore the potential of tailored infill parameters in sustainable noise-control applications. Full article

The pressing issue of global warming has prompted industries to seek sustainable and renewable materials that can reduce the use of petroleum-based products. Natural fibers, as bio-based and environmentally friendly materials, offer a promising solution. In this study, ramie fiber, which is one of the strongest natural fibers, is used as reinforcement, and the mechanical properties of natural rubber composites are evaluated. The composites were fabricated using a vulcanizing technique at 150 °C, and the fibers were cut into different lengths (5 mm, 10 m, and 15 mm) and weights (15 g, 30 g, and 60 g). Mechanical performance tests, including tensile and tear strength and hardness, were conducted. The results showed that as fiber concentration increased, so did the curing time. Moreover, the composites with higher fiber concentration had higher strength. The composite with a 10 mm fiber length and 60 g weight showed the highest tensile strength (10.35 MPa). Maximum tear strength (52.51 kN/m) was achieved with 5 mm fiber length and 60 g weight. Hardness values reached up to 88 Shore A (10 mm fiber length and 60 g weight), indicating excellent wear resistance. The specimen with the highest tensile strength was subjected to scanning electron microscope analysis. The SEM analysis revealed that the composite had a ductile type of fracture with appreciable plastic deformation, confirming good fiber–matrix interaction. These findings underscore the potential of ramie fiber–reinforced natural rubber composites as sustainable, high-performance alternatives to petroleum-based materials in structural and vibration-damping applications. Full article

The selection of grinding media significantly impacts the resulting mineral’s liberation degree and grinding quality; this is particularly impactful for granite pegmatite-type quartz. Accordingly, in this study, we investigate the effects of different grinding media on the breakage characteristics of muscovite granite pegmatite-type quartz, focusing also on quartz mineral flotation. An analysis of scanning electron microscope images reveals distinct fracture characteristics among different minerals. Notably, the fractal dimension of mineral fracture roughness in ball-milled products is larger compared to that of rod-milled products, which exhibit a smaller fractal dimension. This fractal dimension serves as a quantitative measure of the microscopic morphology of mineral fractures in the grinding products, establishing a relationship between the roughness of the fractures and the type of grinding medium used. Further analysis of particle size distribution and mineral dissociation indicates that the rod mill produces a higher yield of coarse fractions compared to both ceramic and steel balls, while the fine fraction yield is significantly lower than that of the rod mill and steel balls. Importantly, the rod mill enhances the dissociation degree of quartz, suggesting that it can improve the liberation of mineral monomers and increase the yield of qualified fractions during the grinding process while effectively reducing the phenomenon of overgrinding. Our flotation experiments demonstrate that the recovery rate of quartz using the rod mill is 2.59% and 5.07% higher than that achieved with the ball mill and ceramic mill, respectively. These findings provide theoretical support for the optimization of grinding media and enhancement of mineral flotation recovery. Full article

For over five decades, blending hydrogen into existing natural gas pipelines has been explored as a potential solution to reduce greenhouse gas emissions. Despite its promise, implementing this approach has been slow due to concerns about hydrogen embrittlement (HE) and its interactions with various metals. Stainless steel alloys like 316L are commonly used in hydrogen service due to their superior resistance to HE. However, the impact of additive manufacturing (AM) on 316L’s susceptibility to HE when subjected to gas charging has not been thoroughly investigated. To fill this knowledge gap, we created conventionally manufactured and AM 316L tensile bars and solubility specimens, which were then exposed to hydrogen-blended natural gas at 10 MPa with a 50% blend and 100% pure H₂. Both conventionally manufactured and additively manufactured specimens had as-received/printed samples that were used as controls. The samples underwent mechanical evaluation through tensile testing and hot chemical extraction to assess hydrogen solubility. Further analysis revealed significant changes in the microstructure near the fracture area of the soaked samples using scanning electron microscope fractography and metallography. These findings were compared with our previous work on traditionally produced 316L bar stock, which demonstrated that AM processing conditions can yield superior performance in terms of resistance to HE. Notably, this study provides valuable insights into the effects of AM on 316L’s susceptibility to HE when subjected to gas charging. The results have significant implications for the development and implementation of AM 316L for hydrogen/natural gas applications in pressure regulators when AM processing conditions are well-controlled. This article is a revised and expanded version of a paper entitled “Effect of Hydrogen-Blended Natural Gas on Additive Manufactured 316L Stainless Steel in Pressure Regulator Environments”, which was presented at TMS in Las Vegas, March 2025. Full article

To mitigate the influence of wellbore heat transfer on the physicochemical properties of water-based fracturing fluids in the high-temperature environments of low-permeability shale reservoirs, this study investigates the fluid filtration behavior of water-based fracturing fluids within the wellbore under such reservoir conditions. A wellbore heat-transfer model based on solid–liquid coupling was constructed in order to analyse the effects of different reservoir and wellbore factors on fluid properties (viscosity and filtration volume) in the water-based fracturing fluids. Concurrently, boundary conditions and control equations were established for the numerical model, thereby delineating the heat-transfer conditions extant between the water-based fracturing fluid and the wellbore. Furthermore, molecular dynamics theory and microgrid theory were utilised to elucidate the mechanisms of the alterations of the fluid properties of the water-based fracturing fluids due to wellbore heat transfer in low-permeability shale reservoirs. The findings demonstrated that wellbore heat transfer in low-permeability shale reservoirs exerts a pronounced influence on the fluid viscosity and filtration volume of the water-based fracturing fluids. Parameters such as wellbore wall thickness, heat-transfer coefficient, radius, and pressure differential introduce distinct variation trends in these fluid properties. At the microscopic scale, the disruption of intermolecular hydrogen bonds and the consequent increase in free molecular content induced by thermal effects are the fundamental mechanisms driving the observed changes in viscosity and fluid filtration. These findings may offer theoretical guidance for improving the thermal stability of water-based fracturing fluids under wellbore heat-transfer conditions. Full article

Background: Forensic investigation of child homicides presents unique challenges due to the vulnerability of children and the complexity of distinguishing between natural, accidental, and intentional manner of death. A multidisciplinary approach integrating traditional forensic methods with emerging technologies is crucial to ensure accurate diagnosis and effective legal outcomes. Methods: This review examines current and emerging forensic techniques used in neonate, infant, and older child homicide investigations. It highlights advancements in postmortem imaging, histological examination, microbiological analysis, toxicology, and molecular autopsy. Results: Traditional forensic autopsy remains the cornerstone of child homicide investigations, providing critical insights into external and internal injuries. Histological examination enhances diagnostic accuracy by detecting microscopic evidence of trauma and infectious diseases. Postmortem imaging techniques are complementary for better identifying fractures, soft tissue injuries, and vascular abnormalities. Forensic toxicology plays a key role in detecting poisoning, while postmortem microbiology aids in identifying infectious causes of death. Furthermore, advancements in molecular autopsy and genetic testing have significantly enhanced the identification of hereditary conditions linked to sudden unexplained deaths in children, especially in cases involving multiple child fatalities within the same family, where forensic investigations are needed to accurately differentiate between natural causes and potential criminal involvement. Conclusions: A multidisciplinary approach incorporating traditional autopsy with postmortem imaging, histological examination, toxicology, postmortem microbiology, and molecular autopsy is essential for comprehensive forensic analysis, promoting both justice and prevention of fatal child abuse/homicide. Future research should focus on standardizing forensic protocols and exploring the potential of artificial intelligence (AI) in forensic investigations. Full article