Search Results (568)

Reactive transport in porous media exists ubiquitously in natural and industrial systems—reformation of geological energy repository, carbon dioxide (CO${}_2$) sequestration, CO${}_2$ storage via mineralization, and soil remediation are just some examples where geo-/bio-chemical reactions play a key role. Reactive transport models are expected to provide assessments of (1) the effective property variation and (2) the reaction capability. However, the synergy among flow, solute transport, and reaction undermines the predictability of the existing model. In recent decades, the Micro-Continuum Approach (MCA) has demonstrated advantages for modeling pore-scale reactive transport and high accuracy compared with experiments. In this study, we present an MCA-based numerical framework that simulates dissolution/erosion or precipitation in digital rocks. The framework imports two- or three-dimensional digital rock samples, conducts reactive transport simulations, and evaluates dynamic changes in porosity, surface area, permeability tensor, tortuosity, mass change, and reaction rate. The results show that samples with similar effective properties, e.g., porosity or permeability, may exhibit different reaction abilities, suggesting that the pore-scale geometry has a strong impact on reactive transport. Additionally, the numerical framework demonstrates the advantage of conducting multiple reaction studies on the same sample, in contrast to reality, where there is often only one physical experiment. This advantage enables the identification of the optimal condition, quantified by the dimensionless P$\acute{\mathrm{e}}$clet number and Damk$\ddot{\mathrm{o}}$hler number, to reach the maximum reaction. We believe that the newly developed framework serves as a toolbox for evaluating reactivity capacity and predicting effective properties of digital samples. Full article

This study examines whether twisted tape inserts in a pipe system can reduce pipe erosion under a liquid–solid flow regime. Three different twisted tape configurations were designed using 3D printing technology: tapes with one twist, four twists, and four twists with perforations. Experiments were performed using a PVC pipe with a carbon steel plate as the material under investigation. Slurries of water and silica sand were prepared with varying sand concentrations—1%, 3%, and 5%—to induce different erosion rates. The experimental results were backed by Computational Fluid Dynamics (CFD) using the discrete phase model (DPM) to predict particle flow and erosion attributes. Erosion trends were also tested through mass loss and paint loss tests. The analysis outcomes demonstrated that the one-twist, four-twist, and perforated four-twist tapes reduced the erosion rate by 18%, 39%, and 45%, respectively. Among the different configurations, the four-twist tape with holes reduced erosion the most. These results suggest that twisted tape inserts can control erosion, thereby increasing the service life of pipes that handle abrasive flows. Full article

Multiphase flow in porous media is ubiquitous in physical processes, yet modeling it consistently remains difficult, and sometimes it can be coupled with solid-phase decomposition and phase change, such as in hydrate dissociation or internal erosion processes. Recent code comparison studies have highlighted this difficulty, revealing clear inconsistencies in numerical results across different research groups for the same benchmark problem. This paper presents a new, reliable benchmark test and a hybrid explicit-implicit finite element method adaptable to various scenarios. In our mathematical framework, the solid decomposition is described by a rate equation for porosity that depends on the fluid pressure, and the phase change is modeled via mass source terms. The hybrid explicit-implicit finite element method features a novel three-stage updating strategy, which incorporates an artificial diffusion term and carefully selects the transport equation for the final saturation update. Validation results demonstrate that our proposed method achieves substantial agreement with those of the fully implicit finite volume method, confirming its reliability. Furthermore, our analysis confirms that the saturation update must use the transport equation of the incompressible fluid phase, and that the artificial diffusion term is critical for capturing physically correct saturation profiles, even when advection is not dominant. Overall, this work provides a consistent and effective tool for simulating complex multiphase flow scenarios and serves as a valuable complement to future benchmark studies. Full article

Polyester fibers are extensively used in textiles, packaging, and industrial applications due to their durability and excellent mechanical properties. However, high-crystallinity polyester fibers represent a major challenge in plastic waste management due to their resistance to biodegradation. This study evaluated the biodegradation potential of environmental Bacillus isolates, obtained from mold-contaminated black bean plastic bags, toward polyethylene terephthalate (PET) and industrial-grade polyester fibers under mesophilic conditions. Among thirteen isolates, five (Bacillus altitudinis N5, Bacillus subtilis N6, and others) exhibited measurable degradation within 30 days, with mass losses up to 5–6% and corresponding rate constants of 0.04–0.05 day⁻¹. A combination of complementary characterization techniques, including mass loss analysis, scanning electron microscopy (SEM), gel permeation chromatography (GPC), and gas chromatography/mass spectrometry (GC/MS), together with Fourier-transform infrared spectroscopy (FTIR), thermogravimetric/differential scanning calorimetry (TGA/DSC), and water contact angle (WCA) analysis, was employed to evaluate the biodegradation behavior of polyester fibers. Cross-analysis of mass loss, surface morphology, molecular weight reduction, and degradation products suggests a surface erosion-dominated degradation process, accompanied by ester-bond hydrolysis and preferential degradation of amorphous regions. FTIR, TGA/DSC, and WCA analyses further reflected chemical, thermal, and surface property changes induced by biodegradation rather than directly defining the degradation mechanism. The findings highlight the capacity of mesophilic Bacillus species to partially depolymerize polyester fibers under mild environmental conditions, providing strain resources and mechanistic insight for developing low-energy bioprocesses for polyester fiber waste management. Full article

Rainfall erosivity is a key driver of soil erosion and sediment delivery in the Lancang River Basin, but its spatiotemporal variations and relationship with sediment delivery changes remain unquantified. Based on the daily precipitation data from meteorological stations and the annual sediment delivery data from the Yunjinghong hydrologic station, the spatial and temporal variations in rainfall erosivity and how rainfall erosivity changes contribute to the sediment delivery changes were examined in this study. The results showed that the annual average rainfall erosivity varied from 202.6 to 15,946.6 MJ mm ha⁻¹ h⁻¹ a⁻¹ among stations. The rainfall erosivity increased from the upstream to the downstream as elevation decreased. Basin-wide average rainfall erosivity declined by about ten percent from 1958 to 2019, with a decreasing rate of −6.3 MJ mm ha⁻¹ h⁻¹ a⁻¹ per year. Summer rainfall erosivity accounted for the largest portion of the rainfall erosivity throughout the whole year. The sediment delivery increased from 1963 to 2000 but has sharply decreased since 2001. Double mass curve analysis revealed that rainfall erosivity reduction accounted for 32% of the sediment delivery decrease after 2001, with human activities (vegetation restoration and dam operations) contributing the remaining 68%. Full article

Background and Objectives: Lacrimal sac/nasolacrimal duct (LS/NLD) tumors may present as primary acquired nasolacrimal duct obstruction (PANDO), raising debate over routine versus selective dacryocystorhinostomy (DCR) biopsy. We systematically reviewed (i) biopsy yields in routine versus selective strategies, (ii) clinical/imaging red flags for neoplasia, and (iii) outcomes of malignant LS/NLD tumors. Materials and Methods: Following a preregistered PRISMA 2020-compliant protocol, we searched PubMed/MEDLINE, Web of Science, and Scopus (1970–2025) for adult cohorts reporting histopathology, imaging, or oncologic outcomes in PANDO/DCR or LS/NLD tumors. Eligible designs included comparative, cohort, cross-sectional, and diagnostic accuracy studies with histology as a reference. Results: Across 16 cohorts, routine DCR series reported “any specific pathology” in 0–7.91% of specimens and malignant yields generally ≤0.73%. In Anderson, 7.91% of 316 patients had significant pathology and 4.43% neoplasia, with 2.53% unsuspected pre-/intra-operatively. Selective biopsy or tumor-enriched cohorts showed higher malignant burdens; pooled modern data yielded ~72.8% squamous cell carcinoma and ~21.4% lymphoma among malignancies. Imaging red flags included bone erosion (50% malignant vs. 11% benign) and infiltrative patterns (63% vs. 0%), while sac masses were present in 88% of tumors in one recent series. In LSSCC-only cohorts, contemporary multimodal therapy achieved 5-year overall survival of 87.6% and progression-free survival of 76.3%. Conclusions: Malignancy is rare in unselected PANDO but clinically significant when present. A tiered strategy combining bedside red flags, targeted CT/MRI, and selective biopsy appears to balance oncologic safety with resource stewardship and supports histology-directed epithelial versus lymphoma care pathways. Full article

This study investigates the wear characteristics and optimization of a centrifugal pump (Q = 25 m³/h, H = 50 m, n = 2900 r/min) applied in sediment-laden waters of Southern Xinjiang irrigation systems. A numerical framework integrating the Realizable $k-\epsilon$ turbulence model, Discrete Phase Model (DPM), and Oka erosion model was established to analyze wear patterns under varying parameters (particle size, density, and mass flow rate). Results indicate that the average erosion rate peaks at 0.92 kg/s mass flow rate. Subsequently, a Response Surface Methodology (RSM)-based optimization was implemented: (1) Plackett–Burman (PB) screening identified the inlet placement angle (A), inlet diameter (C), and outlet width (E) as dominant factors; (2) Full factorial design (FFD) revealed significant interactions (e.g., A × C, C × E); (3) Box–Behnken Design (BBD) generated quadratic regression models for head, efficiency, shaft power, and wear rate (R² > 0.94). Optimization reduced the average erosion rate by 31.35% (from 1.550 × 10⁻⁴ to 1.064 × 10⁻⁴ kg·m⁻²·s⁻¹). Experimental validation confirmed the numerical model’s accuracy in predicting wear localization (e.g., impeller outlet). This work provides a robust methodology for enhancing the wear resistance of centrifugal pumps for agricultural irrigation in water with high fine sediment concentration environments. Full article

To address the engineering challenge of durability deterioration in concrete structures in the cold and saline regions in northern China, this study investigated PVA fiber-reinforced concrete under combined sulfate attack and freeze–thaw cycles using PVA fiber volume fractions (0%, 0.1%, 0.3%, 0.5%) and salt-freeze cycles (0, 25, 50, 75, 100, 125, 150 cycles) as key variables. By testing the mechanical and microscopic properties of the specimens after salt-freeze, the degradation law of macroscopic performance and the evolution mechanism of microscopic structure of PVA fiber concrete under different volume fractions are analyzed, and the salt-freeze damage evolution equation is established based on the loss rate of relative dynamic elastic modulus. The results show that the addition of PVA fibers has no significant inhibitory effect on the surface erosion of concrete, and the degree of surface spalling of concrete still increases with the increase in the number of salt-freeze cycles. With the increase in the number of salt-freezing cycles, the mass, relative dynamic elastic modulus and cube compressive strength of the specimens first increase and then decrease, while the splitting tensile strength continuously decreases. The volume fraction of 0.3% PVA fibers has the most significant effect on improving the cube compressive strength and splitting tensile strength of concrete, and at the same time, it allows concrete to reach its best salt-freezing resistance. PVA fibers contribute to a denser microstructure, inhibit the development of micro-cracks, delay the formation of erosion products, and enhance the salt-freezing resistance of concrete. The damage degree D of relative dynamic elastic modulus for PVA fiber concrete exhibits a cubic functional relationship with the number of salt-freeze cycles N, and the correlation coefficient R² is greater than 0.88. The equation can accurately describe the damage and deterioration law of PVA fiber concrete in the salt-freeze coupling environment. In contrast to numerous studies on single-factor exposures, this work provides new insights into the degradation mechanisms and optimal fiber dose for PVA fiber concrete under the synergistic effect of combined sulfate and freeze-thaw attacks, a critical scenario for infrastructure in cold saline regions. This study can provide theoretical guidance for the durability assessment and engineering application of PVA fiber concrete in cold and saline regions. Full article

Soil erosion in the purple soil region presents severe challenges with complex driving mechanisms. At the same time, evaluation and prediction of runoff and sediment dynamics are lacking for natural vegetation restoration in bare areas. The Mann–Kendall and Pettitt tests were employed to identify abrupt shift points in runoff and sediment dynamics, utilizing monitoring data from the Suining Soil and Water Conservation Experimental Station over the period from 1984 to 2018. Therefore, the research periods were divided into a baseline period (1984–1992) and an evaluation period (1993–2018). Subsequently, encompassing rainfall, runoff, sediment, topography, soil properties, and vegetation parameters, a Water Erosion Prediction Project (WEPP) model was established to quantify the reduction benefits of runoff and sediment during the period of forest restoration. We found that the calibrated WEPP model demonstrated satisfactory performance based on Nash–Sutcliffe efficiency coefficients (NSE > 0.5) and determination coefficients (R² > 0.5) for runoff and sediment simulations. The WEPP model and double-mass curve analysis method revealed that forest restoration reduced runoff and sediment by more than 80%. It is recommended to implement artificial vegetation restoration before reaching the threshold for natural vegetation restoration to achieve soil and water conservation goals. Full article

This study focuses on the core issue of sustainably utilizing shells to enhance the performance of cement mortar. The influence of shell powder on the slump flow, setting time, mechanical strengths, drying shrinkage rate and carbonation depth of cement mortar is investigated. The flexural and compressive strengths of cement mortar incorporating calcium formate after 12 h, 3-day and 28-day curing periods are examined. The effect of basalt fibers on the attenuation of cement mortar’s mechanical properties (flexural and compressive strengths) after NaCl freeze–thaw cycles is also studied. Scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) is employed to elucidate the underlying mechanisms. Results show that the slump flow, setting time and mechanical strengths have cubic function relationships with the shell powder’s mass ratio, while the drying shrinkage rate and carbonation depth follow quadratic function changes. Cement mortar with 15% shell powder by mass of the total binder materials demonstrates the highest slump flow and mechanical strengths. At this shell powder mass ratio, cement mortar shows the lowest drying shrinkage rate and carbonation depth. Calcium formate positively influences the 12-h mechanical strengths. After 3 days of curing, the mechanical strengths of cement mortar with 0.3% calcium formate are the highest. The calcium carbonate powder reduces the drying shrinkage rate of mortar and increases the content of Ca and C elements. The mass ratio of calcium formate exhibits a negative correlation with the cement mortar’s mechanical strengths after being cured for 28 days. The addition of basalt fibers enhances resistance to chloride salt freeze–thaw and dry-wet alternations erosion performance. These findings will provide a sustainable and effective strategy for utilizing agricultural by-products in concrete structures. Full article

Glacier mass loss driven by climate change has increased glacier-related hazards, including glacier debris flows, and poses growing threats to downstream communities. The Badswat Basin in northern Karakoram has experienced repeated glacier debris flows in recent years but lacks systematic disaster analysis and detailed monitoring. This study reconstructs and analyzes three glacier debris flows from 2015, 2018, and 2021 using multi-source remote sensing data and high-resolution DEMs. Results show that three events were triggered by tributary glaciers, with the 2015 event creating the initial dammed lake, and the 2018 and 2021 events further enlarging it (up to 0.72 km² and 40 million m³). These events transported glacier mass downstream, expanded alluvial fans, and caused net glacier erosion. The 2018 event was the most destructive, damaging 75 buildings, flooding 0.28 km² of farmland, and destroying 4.95 km of roads. Analysis suggests that topography influences environmental vulnerability and glacier stability. High temperatures, which accelerate glacier melting, are the primary drivers of the hazard. The bidirectional link between glacier movement and debris flows is a key factor in triggering or intensifying events. Under future climate scenarios, both tributary and main glaciers are expected to continue losing mass, further increasing downstream risks. This study details the evolutionary process of recurring periodic debris flows in the Badswat Basin, providing scientific insights into glacier–landform interactions and hazard management in high-mountain socio-ecological systems. Full article

Saline archaeological artifacts are highly susceptible to deterioration caused by salt crystallization and moisture–material interactions, particularly in coastal archaeological contexts affected by saline water intrusion. This persistent challenge necessitates the development of temporary, low-impact protective materials capable of limiting saline ingress. The present study reports on a preliminary assessment of modified polycaprolactone (PCL) films containing graphene oxide (GO) at 0.1%, 0.25%, and 0.5% to evaluate their potential as temporary barrier layers under saline stress conditions. Free-standing PCL/GO films were fabricated via solvent casting and exposed to natural Ionian seawater in a controlled laboratory incubation environment at 15 °C for up to 90 days, simulating early-stage saline exposure while controlling environmental variability and physical stress. Film behavior was evaluated through complementary surface, structural, mechanical, and permeability analyses. The findings indicate that GO content significantly influences surface wettability, microstructural evolution, and water transport properties. Low GO content (0.1%) enhanced barrier performance while maintaining structural integrity and controlled hydrolytic softening. In contrast, higher GO contents (0.25–0.5%) resulted in increased hydrophilicity, accelerated surface erosion, and greater mechanical degradation due to enhanced water uptake. Observed mass loss is attributed to early-stage hydrolysis rather than long-term biodegradation. This investigation is a material-level screening and does not represent a direct validation for conservation application. With superior stability and enhanced barrier properties, the optimized PCL/GO 0.1% film suggests significant potential for the protection of saline-affected archaeological materials. Full article

This study numerically investigates pavement damage caused by explosions in buried leaking natural gas pipelines using a coupled Lagrangian–Eulerian (CLE) framework in LS-DYNA. The gas phase is described by a Jones–Wilkins–Lee-based equation of state, while soil and pavement are modeled using a pressure-dependent soil model and the Riedel–Hiermaier–Thoma concrete model with strain-based erosion, respectively. The approach is validated against benchmark underground explosion tests in sand and blast tests on reinforced concrete slabs, demonstrating accurate prediction of pressure histories, ejecta evolution, and crater or damage patterns. Parametric analyses are then conducted for different leaked gas masses and pipeline burial depths to quantify shock transmission, soil heave, pavement deflection, and damage evolution. The results indicate that the dynamic response of the pavement structure is most pronounced directly above the detonation point and intensifies significantly with increasing total leaked gas mass. For a total leaked gas mass of 36 kg, the maximum vertical deflection, the peak kinetic energy, and the peak pressure at the bottom interface at this location reach 148.46 mm, 14.64 kJ, and 10.82 MPa, respectively. Moreover, a deflection-based index is introduced to classify pavement response into slight (<20 mm), moderate (20–40 mm), severe (40–80 mm), and collapse (>80 mm) states, and empirical curves are derived to predict damage level from leakage mass and burial depth. Finally, the effectiveness of carbon fiber reinforced polymer (CFRP) strengthening schemes is assessed, showing that top and bottom surface reinforcement with a total CFRP thickness of 2.67 mm could reduce vertical deflection by up to 37.93% and significantly mitigates longitudinal cracking. The results provide a rational basis for safety assessment and blast resistant design of pavement structures above buried gas pipelines. Full article

To promote the sustainable utilization of desert sand as a regional resource in the infrastructure construction of saline-alkali areas, this paper proposes an accelerated test method based on the coupling of an external electric field (60 V) and a 2% Na₂SO₄ solution for rapid evaluation of its sulfate erosion resistance. The optimal mix proportion (FA 10%, water-to-binder ratio 0.33, cement-to-sand ratio 1:1.5, SF 10%) was determined through orthogonal experiments. By employing multi-scale analytical techniques including electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), X-ray diffraction (XRD) and thermal analysis (TG-DTG), the differentiated deterioration mechanisms driven by the electric field were systematically revealed. The results show that the charge-transfer resistance (Rct) decreased by about 95% within 28 d, demonstrating the characteristic of “micro-scale deterioration preceding macro-scale strength loss.” The anode region was dominated by dissolution of hydration products (porosity 5.1%), while the cathode region, due to enrichment of sulfate ions (S content 3.37 wt.%), generated a large amount of expansive products, leading to more pronounced structural damage (porosity 8.3%) and greater mass loss (cathode 12.56% > anode 9.85%). This study not only elucidates the deterioration mechanisms of desert sand concrete under coupled environmental action, but also provides a mechanism-explicit, rapid and efficient laboratory evaluation method for its sulfate resistance, offering practical guidance for durability design and prevention in engineering structures exposed to saline-alkali conditions. Full article

Rigid pavements in marine airports are subjected to severe surface degradation due to the combined effects of salt erosion and repeated aircraft impact loading, which significantly reduces service life and operational safety. This study investigates the degradation behavior and underlying mechanisms governing the surface wear resistance of C40 concrete under simulated marine environmental and mechanical conditions. Specimens were first subjected to repeated drop-weight impact loading, after which abrasion tests were performed to quantify surface wear resistance. Microstructural evolution and corrosion products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses. The results show that repeated impact loading significantly accelerates surface deterioration: after 60 abrasion cycles, cumulative mass loss increased by up to 23.6 g for specimens subjected to 80 impacts, while long-term water absorption rose by up to 7.52% due to impact-induced microcracking. In contrast, moderate salt-fog exposure initially enhanced wear resistance, as cumulative mass loss decreased from 18.1 g (unexposed) to 9.4 g after 30 cycles, attributable to pore filling by CaCO₃ and Friedel’s salt. However, prolonged exposure (40 cycles) reversed this trend, leading to strength loss. Under combined impact of salt-fog conditions, the wear resistance deteriorated more rapidly, and the transition from strengthening to weakening occurred earlier than under salt exposure alone, indicating a coupled degradation effect. These findings clarify the coupled chemical–mechanical deterioration mechanism of marine airport pavements and provide a scientific basis for durability design and maintenance optimization. Full article