Search Results (112)

Studying carbonate breccias enhances our understanding of various geological processes. Fieldwork in the vicinity of the Sakhray Massif in the Western Caucasus (western edge of the Caucasus Mountains) allowed us to discover a peculiar layer of carbonate breccia in the monotonous succession of Lower Triassic platy limestones. The lithological peculiarities of this breccia and the hosting rocks were examined in the field, as well as in polished slabs and thin sections. The results show that the breccia consists of a chaotic mass of chiefly angular clasts of entirely different limestones with abundant fossil debris and a micritic matrix similar to the hosting rocks but bearing siliciclastic debris. The age of the carbonate breccia is the same as that of the hosting rocks, i.e., it is late Induan–early Olenekian (Early Triassic), but the clasts are attributed to upper Changhsingian (Upper Permian) limestones (also reefal). It is proposed that these clasts were created by erosion in a subaerial environment, after which they were transported from a land mass to a deep sea. Apparently, extraordinary geological events (e.g., severe storms, earthquakes, or tsunamis) triggered submarine debris flows on a steep slope. From a practical point of view, the reported discovery extends the vision of the geological heritage of this part of the Western Caucasus. Full article

In the surface protection of stone and brick cultural heritage, a primary challenge is that traditional polymeric coatings are prone to photooxidative degradation under ultraviolet (UV) irradiation, and the resulting aged fragments readily block the substrate micropores, leading to a loss of “breathability”. To address the performance conflict among waterproofing, breathability, and weather resistance, this study prepared few-layer Ti₃C₂T_X MXene using a minimally intensive layer delamination (MILD) method. The poor compatibility between MXene and the fluorosilicone (FPS) resin matrix was effectively resolved through covalent modification with a silane coupling agent (KH-550). Results demonstrate that at an ultralow loading (0.5 wt%), the functionalized f-MXene is uniformly dispersed within the resin. This structure not only spontaneously constructs a hierarchical rough architecture on the surface that imparts high hydrophobicity (water contact angle of 131.6°), but its internal “labyrinth effect” also effectively blocks corrosive media. Simultaneously, the intrinsic water vapor transmission rate of the substrate is effectively maintained (with a reduction of less than 3%), and no visually perceptible color difference is generated (∆E = 1.2). Mechanically, f-MXene relies on interfacial interactions to act as a “nano-skeleton” for stress transfer, thereby increasing the uniaxial compressive strength of fragile limestone by 32.4%. Optical and spectroscopic characterizations further elucidate its anti-aging mechanism: f-MXene not only provides broadband UV shielding but also exhibits highly efficient radical scavenging activity during long-term UV aging. After 400 h of aging, the concentrations of hydroxyl and superoxide anion radicals within the system are significantly reduced, blocking the photooxidative chain reaction from the source. This work develops a composite protective material system for stone cultural heritage that simultaneously integrates high moisture permeability, minimal visual intervention, and long-term antioxidant performance. Full article

Synthetic polymers are widely used in stone conservation, yet their long-term biological stability remains insufficiently evaluated. This study investigates the microbial susceptibility of three commonly used acrylic consolidants, Paraloid B-72, B-66, and B-44, applied to deteriorated limestone. Bacteria, fungi, and actinomycetes were isolated from a deteriorated limestone false door and screened for acid production. From each microbial group, only the strong acid-producing isolates were selected for further investigation, including evaluation of their ability to utilize the three Paraloid resins as sole carbon sources and their deterioration potential on limestone cubes before and after consolidation. Deterioration was assessed by weight loss, compressive strength testing, stereomicroscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). All selected strong acid-producing isolates demonstrated the ability to grow on the tested polymers, confirming their biodegradation potential. Mixed microbial cultures caused greater weight loss and compressive strength reduction than single isolates, attributed to synergistic metabolic interactions. Among the consolidants, Paraloid B-72 showed the highest susceptibility to microbial attack, while Paraloid B-66 exhibited comparatively greater resistance, attributed to the steric hindrance of its isobutyl side groups and higher surface hydrophobicity. FTIR and XRD analyses confirmed ester bond hydrolysis, progressive gypsum formation, and structural alteration of the limestone substrate. These findings demonstrate that acrylic consolidants commonly used in stone conservation are not biologically inert and may actively contribute to biodeterioration under microbial colonization, highlighting the need for developing bio-resistant conservation materials. Full article

Compact carbonate stones are widely used in architectural heritage for their aesthetic value and cultural significance, yet their long-term durability in saline environments remains insufficiently understood, particularly when assessed using standard salt crystallization tests developed primarily for porous lithotypes. This study investigates salt-induced deterioration in Portoro limestone, a compact ornamental carbonate extensively employed in historic architecture, considering four commercial varieties representative of heritage applications. Salt crystallization tests were performed using saturated sodium sulphate (Na₂SO₄) and sodium chloride (NaCl) solutions following the relevant European standard procedure, with the protocol extended to 45 cycles to capture delayed deterioration processes. Both untreated specimens and samples subjected to controlled thermal pre-conditioning at 300 °C and 500 °C were tested to activate latent microstructural weaknesses. Material decay was assessed through mass variation, porosity changes, surface observations, Leeb rebound hardness and ultrasonic pulse velocity measurements. Results demonstrate that deterioration is primarily controlled by salt type and microstructural characteristics rather than by total porosity. Sodium sulphate induced severe internal damage and abrupt structural failure associated with mirabilite crystallization, often following a prolonged phase of apparent stability. In contrast, sodium chloride causes mainly superficial effects with negligible mechanical impact. Thermal pre-conditioning accelerated damage development, while non-destructive techniques revealed internal deterioration well before visible damage occurred. These findings indicate that standard crystallization tests may be inadequate for low-porosity stones and that extended-cycle approaches provide a more reliable framework for durability assessment in saline environments. Full article

Superhydrophobic materials have clear potential for mitigating rain/humidity-induced damage to cultural heritage. In the present study, the wetting properties of Paraloid B72 were tailored to achieve superhydrophobicity by incorporating modified calcium carbonate (CaCO₃) nanoparticles (NPs). B72 is a well-established conservation product while CaCO₃ is chemically compatible with calcareous materials commonly found in cultural heritage buildings and objects. Initially, the wettabilities of CaCO₃ NPs, functionalised with caproic (C6), caprylic (C8), lauric (C12), myristic (C14), palmitic (C16), and stearic (C18) acid, were evaluated by measuring water contact angles (CAs) on NP pellets. For NPs with short hydrocarbon chains, CA increased with chain length, from 66.3° for CaCO₃-C6 to 118.0° for CaCO₃-C12 NPs. For NPs with longer chains, CA remained stable and around 118°. Based on these results, CaCO₃-C12 NPs were selected for further investigation and subjected to transmission electron microscopy analysis, which revealed chain-like agglomerates of aggregated nanocrystallites (5–10 nm) forming 40–150 nm polycrystalline NPs. Scanning transmission electron microscopy combined with elemental mapping revealed a homogeneous distribution of Ca, C, and O within the NPs. Next, CaCO₃-C12 NPs were dispersed in B72 solutions and sprayed onto limestone, which was employed as a model calcite-rich substrate. At optimal NP concentration, the resulting composite coating exhibited superhydrophobicity (CA > 150°), while it induced minimal colour alteration to limestone and effective resistance to capillary water absorption. The fluorine-free coating also demonstrated good durability against UV exposure, drop impact, salt attack, freeze–thaw cycles, tape peeling, drop pH variations, and thermal treatment. Full article

Jordan’s masonry archaeology across limestone, sandstone, and basalt faces escalating threats from a disconnect between conservation and architectural education. Though Jordanian archaeology has evolved into a multidisciplinary field, architecture curricula prioritize technical training over the engineering complexities of endangered sites. This study argues that engaging future architects with ancient engineering as recoverable technical knowledge, rather than as objects for specialist intervention, is essential for cultivating advocates of archaeology. It aims to develop a constructivist framework for architectural archaeology that reorients education from mere intervention toward knowledge transfer through reverse engineering. A mixed-methods experiment with architecture students at Hashemite University engaged participants in deconstructing ancient techniques through digital documentation and structural simulation and then reconstructing this knowledge for contemporary applications. A four-domain framework operationalized object-laden epistemology (technical acquisition) and value-laden ontology (constructed advocacy). Findings revealed four transformative outcomes: science-making (recovering ancient engineering as legitimate knowledge); heritage-making (sites becoming living practice); temporality-making (past–present dialogue within presentism and futurism); and advocacy-making (students as ‘custodian-transmitters’ assuming professional stewardship). By integrating architectural archaeology into core curricula, this framework reaches future architects beyond specialized programs, addressing regional gaps in community support for endangered heritage while maintaining critical reflexivity regarding power and selection in archaeological discourse. Full article

This research establishes a high-fidelity documentation framework utilizing multi-sensor 3D data to support critical decisions regarding the conservation and preservation of monuments in urban environments. Focus is placed on the Morosini Fountain, Heraklion, Crete, a 17th-century monument facing significant deterioration due to environmental stressors, material-specific decay of limestone and marble, and cumulative historical interventions. Placed within the context of contemporary cultural heritage management, the research establishes a high-fidelity 3D digital representative to support interdisciplinary documentation and a decision-support framework for restoration. The methodology employs handheld structured light scanning for high geometric accuracy with close-range digital photogrammetry to ensure high-fidelity color acquisition. Strategic semantic segmentation of the monument into architectural components—such as lobes, lions, and basins—facilitated large scale dataset management and optimized alignment procedures under challenging urban conditions, including intense direct sunlight and active water flow. Results include the delivery of metrically accurate multi-resolution models and 2D orthographic products. Quantitative pathology mapping successfully identified extensive affected surface areas on specific panels, while multi-scale geometric morphological analysis effectively identified high-complexity surface areas, which were subsequently classified as either intentional artistic form or active decay through expert visual assessment between intentional artistic form and active alveolar erosion or exogenous accretions. The study concludes that this enhanced digital model serves as an indispensable tool for sustainable management, transforming passive records into active predictive simulations. The implementation of multi-sensor 3D data provides the essential evidentiary basis for high-stakes conservation decisions, demonstrating that comprehensive digital recording is vital for the resilience of urban heritage landmarks. Full article

Masonry retaining walls constitute an essential component of historic and urban infrastructure in seismic regions; however, their seismic performance remains insufficiently quantified due to material heterogeneity, limited tensile capacity, and complex soil–structure interaction. This study investigates the seismic response of historic stone masonry retaining walls using a finite element-based anisotropic macro-modeling approach. The analysis focuses on the perimeter retaining walls of Emirgan Grove in Istanbul, which represent culturally significant heritage structures constructed from natural limestone and cement–lime mortar. Material properties were defined based on experimental test results and representative values reported in the literature, while composite anisotropic behavior was incorporated into the numerical models. Static loads, earth pressures, and seismic actions were applied in accordance with the Turkish Building Earthquake Code (TBEC-2018) using the equivalent static earthquake load method. Representative wall segments with heights of 2.5 m, 3.5 m, 4.0 m, and 6.30 m were analyzed. The numerical results show that maximum compressive stresses reached approximately 0.48 MPa, remaining well below the allowable limit of 4.50 MPa, while maximum tensile stresses of about 0.28 MPa did not exceed the allowable tensile limit of 1.00 MPa. In contrast, shear stresses locally reached approximately 0.25 MPa, exceeding the allowable shear limit of 0.10 MPa, particularly along the soil–wall interface in taller walls. Sliding stability was satisfied in all cases, whereas overturning and shear behavior governed seismic vulnerability. These findings confirm that wall height is the primary parameter controlling seismic response and demonstrate the effectiveness of the proposed framework for preservation-oriented seismic safety assessment of historic masonry retaining walls. Full article

The detection of underground cavities and dissolution features is a critical component in assessing geohazards within karst terrains, particularly where natural processes interact with long-term human occupation. This study investigates two contrasting sites in the Sefrou region of northern Morocco: Binna, a rural travertine-dolomite system shaped by Quaternary karstification, and the urban Old Medina of Bhalil, where traditional cave dwellings are carved into carbonate formations. A combined geophysical and geological approach was applied to characterize subsurface heterogeneities and assess the extent of near-surface void development. Vertical electrical soundings (VES) at Binna site delineated high-resistivity anomalies consistent with air-filled cavities, dissolution conduits, and brecciated limestone horizons, all indicative of an active karst system. In the Bhalil old Medina site, ground-penetrating radar (GPR) with low-frequency antennas revealed strong reflection contrasts and localized signal attenuation zones corresponding to shallow natural cavities and potential anthropogenic excavations beneath densely constructed areas. Geological observations, including lithostratigraphic logging and structural cross-sections, provided additional constraints on cavity geometry, depth, and spatial distribution. The integrated results highlight a high degree of subsurface karstification across both sites and underscore the associated geotechnical risks for infrastructure, cultural heritage, and land-use stability. This work demonstrates the value of combining electrical and radar methods with geological analysis for mapping hazardous subsurface voids in cavity-prone Quaternary landscapes, offering essential insights for risk mitigation and sustainable urban and rural planning. Full article

The bell tower of Murcia Cathedral (1521–1793) exhibits a documented inclination whose origin and structural significance have never been examined through an integrated geotechnical–structural approach. This study aims to identify the causes, quantify the magnitude, and assess the safety implications of the tower’s long-term differential settlement. A multidisciplinary methodology is adopted, combining historical construction records, geological and geotechnical data from the Segura alluvial plain, non-destructive testing of masonry, and classical analytical modelling based on Heyman’s masonry theory, consolidation mechanics, and elastic column behaviour. This approach is selected in place of finite element modelling because the tower’s geometry, construction sequence, and material parameters are sufficiently constrained to allow a non-invasive and verifiable assessment suited to heritage structures. Results indicate a total horizontal displacement of approximately 0.56 m toward the northwest, produced by the slow consolidation of compressible silty–clayey deposits influenced by groundwater fluctuations and by historical eccentric load redistributions during the eighteenth-century construction phase. The calculated working compressive stresses (0.83–1.02 N/mm²) remain far below the estimated strength of the limestone masonry, and the bearing capacity analysis suggests a safety factor of about 1.5 against foundation failure. These findings confirm that the tower’s deformation reflects the long-term geotechnical response of the subsoil rather than structural instability. The study provides a non-destructive analytical framework for interpreting settlement mechanisms in historic masonry towers and contributes a quantitatively grounded explanation of the Murcia Cathedral tower’s inclination, offering guidance for future assessment of similar heritage structures. Full article

In assessing the strength properties of stone materials, especially in historic structures, ultrasonic measurements are widely used as a non-destructive testing (NDT) method. Actual stone degradation in situ is estimated based on various laboratory tests which allow researchers to correlate the number of artificial ageing cycles of stone specimens with ultrasonic wave velocity measured on these specimens. This paper presents the results obtained for granite, marble, limestone, travertine and sandstone which underwent various cyclic ageing tests including freezing and thawing, high temperature and salt crystallization. Analysis of the obtained results shows that, independent of the stone type tested and independent of the ageing test applied, a rate of change in the stone elastic properties is described by an ordinary differential equation whose solution is an exponential law analogue to the Newton’s law of cooling. The degradation function model can be used for further research on expected residual strength and dynamics of the heritage materials degradation processes. Full article

Jerusalem’s prominent building material of limestone and dolostone, which is commonly known as “Jerusalem stone”, characterizes the city’s architecture and built environment. The distinctive stone was quarried from the Jerusalem landscape, prepared as building stone, and transported to building sites, a process referred to in this paper as the “lithic journey”. While these ancient quarries have been identified in previous studies, new evidence identifies the characteristics and the spatial distribution of these quarries and the connections between them. This study examined over one hundred archeological reports resulting from mainly salvage excavations conducted in the last decade (2012–2024), which has enabled the creation of updated mapping. Data collected from the Hadashot Arkheologiyot: Excavations and Surveys in Israel (HA-ESI), are included in a database that classifies quarry types, building material provenance, and specific characteristics of the ancient quarries that supplied Jerusalem’s building stones. The resulting expanded dataset of this open-access, online resource broadens our understanding of the quarry landscape and the continuous use of stone in the city’s building culture, while also offering an understanding of Jerusalem’s urban development and the design of Jerusalem’s cityscape from antiquity to the present day, as well as contribute to the city’s heritage management. Full article

The conservation of heritage buildings requires non-invasive tools that can predict material performance while maintaining historical integrity and structural safety. This study introduces a multivariate statistical framework that integrates regression analysis, Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA) to classify seven traditional materials adobe, lime mortar, limestone, sandstone, marble, volcanic stone, and wood based on their mechanical, thermal, and moisture-related properties. This study aims to develop a validated multivariate framework for classifying traditional heritage materials based on their mechanical, thermal, and moisture-related properties to support sustainable restoration and retrofit design for classifying traditional materials based on their mechanical, thermal, and moisture-related properties to support sustainable restoration and retrofit design. Unlike prior research limited to single-material assessments, this study standardizes and analyzes data from fourteen peer-reviewed sources using regression models, Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA), Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA), complemented by pilot non-destructive validation tests on lime mortar, sandstone, limestone, and marble. The framework compiles and standardizes datasets from fourteen peer-reviewed sources into a unified predictive model. The framework was validated through pilot testing using non-invasive methods (density, ultrasonic pulse velocity, rebound hardness), which confirmed the statistical predictions of robustness versus moisture vulnerability. Advanced cluster solutions identified conservation-relevant subgroups, enabling engineers to distinguish between moisture-sensitive low-density materials and durable lithic stones, with direct implications for sustainable restoration and retrofit practices. The originality of this study lies in transforming fragmented datasets into a validated, decision-support tool that can be embedded into Historic Building Information Modeling (HBIM) platforms for predictive diagnostics, compatibility assessment, and energy-efficient retrofit planning in heritage structures. This study provides the first validated cross-material statistical framework linking traditional conservation materials with predictive digital-modeling tools. This framework further demonstrates that the application of regression, Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA) enables quantitative prediction of material performance through non-destructive parameters. The integration of these techniques provides interpretive value beyond descriptive classification, facilitating preventive diagnostics, compatibility assessments, and energy-oriented retrofit planning within HBIM systems. Full article

Karstic dolines are unique geomorphological and ecological features of limestone landscapes, characterised by strong microclimatic and edaphic gradients. These concave landforms form natural microrefugia that harbour a variety of plant species. In this study, dolines in the northern Dinarides on the Kras Plateau were investigated to assess the horticultural potential of their flora. Vegetation surveys along edge-to-bottom transects revealed a pronounced species turnover and differentiation of functional traits. Shade-tolerant geophytes and early-flowering perennials dominate the bottoms of the dolines, while the edges harbour drought-tolerant aromatic herbs. Not only do dolines serve biodiversity conservation by acting as microrefugia, but they also preserve cultural heritage through ethnobotanical species and provide a species pool for the selection of plants with horticultural potential. We selected horticultural important plants (HPs) and analysed them within the dolines. Depending on their morphology and seasonal occurrence, they can be divided into woody species, early and late spring flowering species, orchids, and structural species. By linking biodiversity conservation with applied horticulture, this study emphasises the multifunctional role of dolines as small natural features of disproportionate ecological and horticultural importance. We suggest that integrating doline species into horticultural utilisation could improve sustainability, diversify plantings, and strengthen climate adaptation strategies. Full article

Hybrid hydrophobic coatings (HHCs), which combine organic and inorganic materials, have demonstrated superior weathering resistance compared to conventional organic coatings in conserving stone heritage structures. Among the inorganic components of HHCs, nanosilica is especially promising because of its ability to form durable, weathering-resistant and hydrophobic silane-based structures. This overview examined recent studies, advances, and emerging trends about nanosilica-based HHCs from 2020 to 2024 using the “Boolean strategy” and search terms “stone”, “heritage”, “hydrophobic”, and “coating”, capturing 5244 articles. After screening for titles containing “nanosilica” (470 items remained), excluding works related to “consolidants” and “cement” (171 items remained), and requiring quantitative data on formulations, methods, and performance of nanosilica-based HHCs in stone heritage structures, 16 relevant works were identified. China and Italy dominated research works on nanosilica-based HHC development, which was applied to stone heritage structures composed of carbonate materials (e.g., limestone, dolomite, and Palazzolo carbonates) and silica-rich materials (e.g., Qingshi stone, Hedishi stone, and red sandstone). Key evaluation metrics reported by multiple authors to evaluate HHC efficacy included water contact angle (WCA), total color difference (TCD), and solution pH. Moreover, ultraviolet light (UV) durability, thermomechanical stability, biocidal efficiency, and graffiti protection were achieved when nanosilica was combined with other nanomaterials. Integrating emerging technologies, such as artificial intelligence (AI), internet-of-things (IoT), and smartphones with colorimeter apps could improve accessibility, real-time monitoring and reliability of HHC testing, while adherence to standardized testing protocols would further enhance comparability and practical application across studies. Overall, this overview provides valuable insights into nanosilica-based HHCs for researchers and restorers/conservators of stone heritage structures. Full article