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Keywords = iron metallurgy

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21 pages, 1113 KiB  
Article
Research on High-Frequency Modification Method of Industrial-Frequency Smelting Transformer Based on Parallel Connection of Multiple Windings
by Huiqin Zhou, Xiaobin Yu, Wei Xu and Weibo Li
Energies 2025, 18(15), 4196; https://doi.org/10.3390/en18154196 - 7 Aug 2025
Abstract
Under the background of “dual-carbon” strategy and global energy transition, the metallurgical industry, which accounts for 15–20% of industrial energy consumption, urgently needs to reduce the energy consumption and emission of DC power supply of electric furnaces. Aiming at the existing 400–800 V/≥3000 [...] Read more.
Under the background of “dual-carbon” strategy and global energy transition, the metallurgical industry, which accounts for 15–20% of industrial energy consumption, urgently needs to reduce the energy consumption and emission of DC power supply of electric furnaces. Aiming at the existing 400–800 V/≥3000 A industrial-frequency transformer-rectifier system with low efficiency, large volume, heat dissipation difficulties and other bottlenecks, this thesis proposes and realizes a high-frequency integrated DC power supply scheme for high-power electric furnaces: high-frequency transformer core and rectifier circuit are deeply integrated, which breaks through and reduces the volume of the system by more than 40%, and significantly reduces the iron consumption; multiple cores and three windings in parallel are used for the system. The topology of multiple cores and three windings in parallel enables several independent secondary stages to share the large current of 3000 A level uniformly, eliminating the local overheating and current imbalance; the combination of high-frequency rectification and phase-shift control strategy enhances the input power factor to more than 0.95 and cuts down the grid-side harmonics remarkably. The authors have completed the design of 100 kW prototype, magneto-electric joint simulation, thermal structure coupling analysis, control algorithm development and field comparison test, and the results show that the program compared with the traditional industrial-frequency system efficiency increased by 12–15%, the system temperature rise reduced by 20 K, electrode voltage increased by 10–15%, the input power of furnace increased by 12%, and the harmonic index meets the requirements of the traditional industrial-frequency system. The results show that the efficiency of this scheme is 12–15% higher than the traditional IF system, the temperature rise in the system is 20 K lower, the voltage at the electrode end is 10–15% higher, the input power of the furnace is increased by 12%, and the harmonic indexes meet the requirements of GB/T 14549, which verifies the value of the scheme for realizing high efficiency, miniaturization, and reliable DC power supply in metallurgy. Full article
(This article belongs to the Section F3: Power Electronics)
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14 pages, 10994 KiB  
Article
Novel Cemented Carbide Inserts for Metal Grooving Applications
by Janusz Konstanty, Albir Layyous and Łukasz Furtak
Materials 2025, 18(15), 3674; https://doi.org/10.3390/ma18153674 - 5 Aug 2025
Abstract
Although cemented carbides have been manufactured by the powder metallurgy (P/M) technology for over a century now, systematic developmental efforts are still underway. In the present study, tool life improvements in metal grooving applications are the key objective. Four PVD-coated cemented carbides compositions, [...] Read more.
Although cemented carbides have been manufactured by the powder metallurgy (P/M) technology for over a century now, systematic developmental efforts are still underway. In the present study, tool life improvements in metal grooving applications are the key objective. Four PVD-coated cemented carbides compositions, dedicated to groove steel, stainless steel, cast iron, and aluminium alloys, have been newly designed, along with their manufacturing conditions. Physical, mechanical and chemical characteristics—such as sintered density, modulus of elasticity, hardness, fracture toughness, WC grain size, and the chemical composition of the substrate material, as well as the chemical composition, microhardness, structure, and thickness of the coatings—have been studied. A series of grooving tests have also been conducted to assess whether modifications to the thus far marketed tool materials, tool geometries, and coatings can improve cutting performance. In order to compare the laboratory and application properties of the investigated materials with currently produced by reputable companies, commercial inserts have also been tested. The experimental results obtained indicate that the newly developed grooving inserts exhibit excellent microstructural characteristics, high hardness, fracture toughness, and wear resistance and that they show slightly longer tool life compared to the commercial ones. Full article
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20 pages, 10502 KiB  
Article
Strengthening Mechanism of Char in Thermal Reduction Process of Silicon Dioxide
by Xiuli Xu, Peng Yu, Jinxiao Dou and Jianglong Yu
Materials 2025, 18(15), 3651; https://doi.org/10.3390/ma18153651 - 3 Aug 2025
Viewed by 253
Abstract
This study investigates the strengthening mechanisms of char in silicon dioxide thermal reduction through systematic high-temperature experiments using three char types (YQ1, CW1, HY1) characterized by X-ray diffraction, Raman spectroscopy, transmission electron microscopy, and scanning electron microscopy. HY1 char demonstrated superior reactivity due [...] Read more.
This study investigates the strengthening mechanisms of char in silicon dioxide thermal reduction through systematic high-temperature experiments using three char types (YQ1, CW1, HY1) characterized by X-ray diffraction, Raman spectroscopy, transmission electron microscopy, and scanning electron microscopy. HY1 char demonstrated superior reactivity due to its highly ordered microcrystalline structure, characterized by the largest aromatic cluster size (La) and lowest defect ratio (ID/IG = 0.37), which directly correlated with enhanced reaction completeness. The carbon–silicon reaction reactivity increased progressively with temperature, achieving optimal performance at 1550 °C. Addition of Fe and Fe2O3 significantly accelerated the reduction process, with Fe2O3 exhibiting superior catalytic performance by reducing activation energy and optimizing reaction kinetics. The ferrosilicon formation mechanism proceeds through a two-stage pathway: initial char-SiO2 reaction producing SiC and CO, followed by SiC–iron interaction generating FeSi, which catalytically promotes further reduction. These findings establish critical structure–performance relationships for char selection in industrial silicon production, where microcrystalline ordering emerges as the primary performance determinant. The identification of optimal temperature and additive conditions provides practical pathways to enhance energy efficiency and product quality in silicon metallurgy, enabling informed raw material selection and process optimization to reduce energy consumption and improve operational stability. Full article
(This article belongs to the Section Carbon Materials)
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15 pages, 4359 KiB  
Article
Phase Transformations During Heat Treatment of a CPM AISI M4 Steel
by Maribel L. Saucedo-Muñoz, Valeria Miranda-Lopez, Felipe Hernandez-Santiago, Carlos Ferreira-Palma and Victor M. Lopez-Hirata
Metals 2025, 15(7), 818; https://doi.org/10.3390/met15070818 - 21 Jul 2025
Viewed by 233
Abstract
The phase transformations of Crucible Particle Metallurgy (CPM) American Iron and Steel Institute (AISI) M4 steel were studied during heat treatments using a CALPHAD-based method. The calculated results were compared with experimental observations. The optimum austenitizing temperature was determined to be about 1120 [...] Read more.
The phase transformations of Crucible Particle Metallurgy (CPM) American Iron and Steel Institute (AISI) M4 steel were studied during heat treatments using a CALPHAD-based method. The calculated results were compared with experimental observations. The optimum austenitizing temperature was determined to be about 1120 °C using Thermo-Calc software (2024b). Air-cooling and quenching treatments led to the formation of martensite with a hardness of 63–65 Rockwell C (HRC). The annealing treatment promoted the formation of the equilibrium ferrite and carbide phases and resulted in a hardness of 24 HRC. These findings with regard to phases and microconstituents are in agreement with the predictions derived from a Thermo-Calc-calculated time–temperature–transformation diagram at 1120 °C. Additionally, the primary carbides, MC and M6C, which formed prior to the heat treatment and had a minor influence on the quenched hardness. In contrast, the tempering process primarily led to the formation of fine secondary M6C carbides, which hardened the tempered martensite to 57 HRC. The present work demonstrates the application of a CALPHAD-based methodology to the design and microstructural analysis of tool steels. Full article
(This article belongs to the Special Issue Advances in Steels: Heat Treatment, Microstructure and Properties)
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34 pages, 5960 KiB  
Article
Motor Temperature Observer for Four-Mass Thermal Model Based Rolling Mills
by Boris M. Loginov, Stanislav S. Voronin, Roman A. Lisovskiy, Vadim R. Khramshin and Liudmila V. Radionova
Sensors 2025, 25(14), 4458; https://doi.org/10.3390/s25144458 - 17 Jul 2025
Viewed by 231
Abstract
Thermal control in rolling mills motors is gaining importance as more and more hard-to-deform steel grades are rolled. The capabilities of diagnostics monitoring also expand as digital IIoT-based technologies are adopted. Electrical drives in modern rolling mills are based on synchronous motors with [...] Read more.
Thermal control in rolling mills motors is gaining importance as more and more hard-to-deform steel grades are rolled. The capabilities of diagnostics monitoring also expand as digital IIoT-based technologies are adopted. Electrical drives in modern rolling mills are based on synchronous motors with frequency regulation. Such motors are expensive, while their reliability impacts the metallurgical plant output. Hence, developing the on-line temperature monitoring systems for such motors is extremely urgent. This paper presents a solution applying to synchronous motors of the upper and lower rolls in the horizontal roll stand of plate mill 5000. The installed capacity of each motor is 12 MW. According to the digitalization tendency, on-line monitoring systems should be based on digital shadows (coordinate observers) that are similar to digital twins, widely introduced at metallurgical plants. Modern reliability requirements set the continuous temperature monitoring for stator and rotor windings and iron core. This article is the first to describe a method for calculating thermal loads based on the data sets created during rolling. The authors have developed a thermal state observer based on four-mass model of motor heating built using the Simscape Thermal Models library domains that is part of the MATLAB Simulink. Virtual adjustment of the observer and of the thermal model was performed using hardware-in-the-loop (HIL) simulation. The authors have validated the results by comparing the observer’s values with the actual values measured at control points. The discrete masses heating was studied during the rolling cycle. The stator and rotor winding temperature was analysed at different periods. The authors have concluded that the motors of the upper and lower rolls are in a satisfactory condition. The results of the study conducted generally develop the idea of using object-oriented digital shadows for the industrial electrical equipment. The authors have introduced technologies that improve the reliability of the rolling mills electrical drives which accounts for the innovative development in metallurgy. The authors have also provided recommendations on expanded industrial applications of the research results. Full article
(This article belongs to the Section Industrial Sensors)
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19 pages, 4517 KiB  
Article
Early Medieval Iron Metallurgy in the Lučenec Basin, Slovakia
by Jozef Petrík, Peter Futáš, Beatrice Plešingerová, Peter Blaško, Alena Pribulová and Pavol Vadasz
Processes 2025, 13(7), 2104; https://doi.org/10.3390/pr13072104 - 2 Jul 2025
Viewed by 333
Abstract
Archeological structures connected with iron metallurgy were identified in the outskirts of the town Lučenec, Slovakia. Based on the shapes and decoration of the ceramic fragments, it was possible to date them to the 9th or 10th century. The first group of discovered [...] Read more.
Archeological structures connected with iron metallurgy were identified in the outskirts of the town Lučenec, Slovakia. Based on the shapes and decoration of the ceramic fragments, it was possible to date them to the 9th or 10th century. The first group of discovered metallurgical materials included slags with low wüstite content, which looks like slag from younger higher-shaft furnaces. The second group included slags which could be attributed to the technology common at the time of the site’s existence: iron smelting in lower free-standing shaft furnaces with average efficiency. The third group were slags from the forging of iron blooms to remove pores and slag particles. The fourth group consisted of ceramics fragments (tuyeres and refractory material). Bog ore was probably smelted using principally oak wood charcoal. Full article
(This article belongs to the Section Chemical Processes and Systems)
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12 pages, 1004 KiB  
Review
Causes and Demonstration of Thermal Stress in Castings Made from Gray Iron
by Peter Futas, Alena Pribulova, Jozef Petrik, Peter Blasko, Marek Solc and Marcin Brzezinski
Thermo 2025, 5(3), 21; https://doi.org/10.3390/thermo5030021 - 27 Jun 2025
Viewed by 366
Abstract
Cast iron is a longtime reliable material for the production of heat-treated stressed castings, i.e., those that are long, are cyclically heated, and heat-stressed. The durability of thermally stressed castings used in practice is dependent on the choice of the optimum chemical composition, [...] Read more.
Cast iron is a longtime reliable material for the production of heat-treated stressed castings, i.e., those that are long, are cyclically heated, and heat-stressed. The durability of thermally stressed castings used in practice is dependent on the choice of the optimum chemical composition, metallurgy of production, macro- and microstructures, construction, and the way of exploitation. Today, the successful solution of this problem is dominated by simulation programs. The comprehensive analysis of heat stress is very important, i.e., the impacts of various physical quantities on its rise, progress, and size. This paper provides a comprehensive analysis of thermal stress mechanisms in gray iron castings, with a particular emphasis on the relationships between the material properties, microstructural characteristics, and component performance under thermal loading conditions. The theoretical foundations are complemented by experimental data, establishing practical guidelines for optimizing cast iron compositions and processing parameters for thermal applications. Full article
(This article belongs to the Special Issue Thermal Science and Metallurgy)
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27 pages, 6313 KiB  
Review
Experimental and Simulation Research Progress on the Solidification Structure Evolution of High Chromium Cast Iron
by Longxiao Huang, Yang Liu and Hanguang Fu
Metals 2025, 15(6), 663; https://doi.org/10.3390/met15060663 - 13 Jun 2025
Viewed by 419
Abstract
High-chromium cast irons (HCCIs) have emerged as preferred materials for critical wear-resistant components operating under extreme conditions, owing to their excellent wear resistance, low cost, and good castability. They are widely used in metallurgy, energy, and mechanical engineering industries. The evolution of solidification [...] Read more.
High-chromium cast irons (HCCIs) have emerged as preferred materials for critical wear-resistant components operating under extreme conditions, owing to their excellent wear resistance, low cost, and good castability. They are widely used in metallurgy, energy, and mechanical engineering industries. The evolution of solidification microstructure directly governs the final properties of HCCIs, making the in-depth investigation of their solidification behavior of great significance. This paper provides a comprehensive review of recent experimental and simulation-based advances in understanding the solidification microstructure evolution of HCCIs. The effects of alloy composition, cooling rate, and inoculation treatments on microstructure development and phase distribution during solidification are critically analyzed. Furthermore, the application of simulation techniques—including thermodynamic modeling, phase-field method, cellular automata, and finite element analysis—is discussed in detail, highlighting their roles in revealing the mechanisms of microstructural evolution. Finally, the current challenges and potential future research directions in the study of the solidification behavior of high-chromium cast irons are outlined. Full article
(This article belongs to the Special Issue Calphad Tools for the Metallurgy of Solidification)
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12 pages, 7645 KiB  
Article
Searching Optimum Self-Brazing Powder Mixtures Intended for Use in Powder Metallurgy Diamond Tools—A Statistical Approach
by Andrzej Romański, Piotr Matusiewicz and Elżbieta Cygan-Bączek
Materials 2025, 18(12), 2726; https://doi.org/10.3390/ma18122726 - 10 Jun 2025
Viewed by 391
Abstract
This paper presents a study on optimising self-brazing powder mixtures for powder metallurgy diamond tools, specifically focusing on wire saws used in cutting natural stone. The research aimed to understand the relationship between the chemical composition of powder mixtures and the hardness of [...] Read more.
This paper presents a study on optimising self-brazing powder mixtures for powder metallurgy diamond tools, specifically focusing on wire saws used in cutting natural stone. The research aimed to understand the relationship between the chemical composition of powder mixtures and the hardness of the sintered matrix. The experimental process involved the use of various commercially available powders, including carbonyl iron, carbonyl nickel, atomised bronze, atomised copper, and ferrophosphorus. The samples made of different powder mixtures were compacted and sintered and then characterised by dimensional change, density, porosity, and hardness. The obtained results were statistically analysed using an analysis of variance (ANOVA) tool to create linear regression models that relate the material properties to their chemical composition. The investigated materials exhibited excellent sintering behaviour and very low porosity, which are beneficial for diamond retention. Very good sinterability of powder mixtures can be achieved by tin bronze addition, which provides a sufficient content of the liquid phase and promotes the shrinkage during sintering. Statistical analysis revealed that hardness was primarily affected by phosphorous content, with nickel having a lesser but still significant impact. The statistical model can predict the hardness of the matrix based on its chemical composition. This model, with a determination coefficient of approximately 80%, can be valuable for developing new metal matrices for diamond-impregnated tools, particularly for wire saw beads production. Full article
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17 pages, 879 KiB  
Article
The Impact of Self-Sufficiency in Basic Raw Materials of Metallurgical Companies on Required Return and Capitalization: The Case of Russia
by Sergey Galevskiy, Tatyana Ponomarenko and Pavel Tsiglianu
J. Risk Financial Manag. 2025, 18(6), 318; https://doi.org/10.3390/jrfm18060318 - 10 Jun 2025
Viewed by 1280
Abstract
This article considers the impact of self-sufficiency in basic raw materials on the level of systematic risk, required return and capitalization on the example of Russian ferrous metallurgy companies. The methods applied include classical approaches to determining beta coefficient, required return and capitalization, [...] Read more.
This article considers the impact of self-sufficiency in basic raw materials on the level of systematic risk, required return and capitalization on the example of Russian ferrous metallurgy companies. The methods applied include classical approaches to determining beta coefficient, required return and capitalization, as well as correlation–regression analysis performed in the Python programming language (version 3.0, libraries: Numpy, Pandas, Matplotlib, Datetime, Statistics, Scipy, Bambi). The study revealed an inverse relationship between the self-sufficiency of ferrous metallurgy companies in iron ore and coking coal and their systematic risk. That was confirmed by the developed regression model. The presence of this dependence directly indicates the need to consider self-sufficiency when assessing a company’s required return and capitalization. The acquisition of the Tikhov coal mine by PJSC Magnitogorsk Iron and Steel Works (MMK) led to an increase in capitalization not only due to additional profit from the new asset, but also due to a decrease in the required return caused by the growth of the company’s self-sufficiency in coking coal. The proposed approach contributes to a more accurate assessment of the company’s capitalization and creates additional incentives for vertical integration transactions. Full article
(This article belongs to the Special Issue Corporate Finance: Financial Management of the Firm)
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14 pages, 4846 KiB  
Article
Study of Corrosion, Power Consumption, and Wear Characteristics of Herringbone-Grooved Fan Bearings in High-Temperature and High-Humidity Environments
by Jim-Chwen Yeh, Yu-Chang Lee, Chun-Hsiang Huang, Ming-Yuan Li and Chin-Chung Wei
Lubricants 2025, 13(6), 245; https://doi.org/10.3390/lubricants13060245 - 28 May 2025
Viewed by 554
Abstract
Fans are essential electronic components for heat dissipation in electronic systems, with fan bearings being critical parts that determine fan performance and lifespan. This paper investigates the corrosion, wear, power consumption, temperature, and vibration characteristics of a newly designed and manufactured powder metallurgy [...] Read more.
Fans are essential electronic components for heat dissipation in electronic systems, with fan bearings being critical parts that determine fan performance and lifespan. This paper investigates the corrosion, wear, power consumption, temperature, and vibration characteristics of a newly designed and manufactured powder metallurgy bearing with herringbone oil grooves for fans under high-humidity and high-temperature conditions. Corrosion experiments on iron–copper powder metallurgy bearings show that a higher environmental temperature and humidity result in greater corrosion current and reduced corrosion resistance. Bearings operated under high humidity (85% RH) and a high temperature (80 °C) for 0, 3, and 8 days, respectively, revealed that wear and corrosion occur simultaneously. The longer the operating time, the more significant the wear and corrosion. After 3 and 8 days, the lubricating oil flow in the oil grooves decreased by 9.8% and 51.5%, respectively. When bearings subjected to varying degrees of corrosion were tested under the same standard operating conditions, it was found that the bearings corroded for 3 and 8 days, resulting in a significant increase in the number of wear debris particles, higher RMS vibration values, and a power consumption increase of 6.9% and 7.8%, respectively. The percentage of iron elements on the surface gradually decreased, with the copper elements being the primary wear particles during the wear process. However, due to the increased clearance between the rotating shaft and the bearing caused by wear, the fan temperature slightly decreased with increased surface wear. Full article
(This article belongs to the Special Issue Recent Advances in Tribological Properties of Machine Tools)
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30 pages, 10047 KiB  
Article
An Investigation into the Effects of Coke Dry Quenching Waste Heat Production on the Cost of the Steel Manufacturing Process
by Lin Lu, Zhipeng Yan, Xilong Yao and Yunfei Han
Sustainability 2025, 17(10), 4402; https://doi.org/10.3390/su17104402 - 12 May 2025
Viewed by 514
Abstract
It is essential to evaluate the prospective development trends of coke dry quenching (CDQ) waste heat power generation, to reduce the comprehensive cost of the steelmaking system. Based on TIMES energy system optimization model, this study develops a model of China’s iron and [...] Read more.
It is essential to evaluate the prospective development trends of coke dry quenching (CDQ) waste heat power generation, to reduce the comprehensive cost of the steelmaking system. Based on TIMES energy system optimization model, this study develops a model of China’s iron and steel production. Three scenarios are established, predictions and comparisons are conducted regarding the iron and steel production structure, total CDQ quantity, CO2 and pollutant emissions under these scenarios. The findings indicate that: (1) The advancement of hydrogen metallurgy and EAF scrap smelting facilitates a reduction in the quantity of BF-BOF steelmaking and total CDQ consumption. (2) The decreasing demand for CDQ shows that the shift to clean production alters process pathways and compels the energy system from scale-driven to flexibility-focused. (3) The marginal value of the CDQ system is contingent upon the targeted policy support for multi-energy co-generation systems and their deep integration with hydrogen infrastructure. Accordingly, the utilization of CDQ waste heat power generation should be considered as a transitional strategy, it will be imperative to implement a reduction in capacity. Full article
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26 pages, 1729 KiB  
Review
Research Progress on Energy-Saving Technologies and Methods for Steel Metallurgy Process Systems—A Review
by Jiacheng Cui, Gang Meng, Kaiqiang Zhang, Zongliang Zuo, Xiangyu Song, Yuhan Zhao and Siyi Luo
Energies 2025, 18(10), 2473; https://doi.org/10.3390/en18102473 - 12 May 2025
Cited by 1 | Viewed by 854
Abstract
Against the backdrop of global energy crises and climate change, the iron and steel industry, as a typical high energy consumption and high-emission sector, faces rigid constraints for energy conservation and emission reduction. This paper systematically reviews the research progress and application effects [...] Read more.
Against the backdrop of global energy crises and climate change, the iron and steel industry, as a typical high energy consumption and high-emission sector, faces rigid constraints for energy conservation and emission reduction. This paper systematically reviews the research progress and application effects of energy-saving technologies across the entire steel production chain, including coking, sintering, ironmaking, steelmaking, continuous casting, and rolling processes. Studies reveal that technologies such as coal moisture control (CMC) and coke dry quenching (CDQ) significantly improve energy utilization efficiency in the coking process. In sintering, thick-layer sintering and flue gas recirculation (FGR) technologies reduce fuel consumption while enhancing sintered ore performance. In ironmaking, high-efficiency pulverized coal injection (PCI) and hydrogen-based fuel injection effectively lower coke ratios and carbon emissions. Integrated and intelligent innovations in continuous casting and rolling processes (e.g., endless strip production, ESP) substantially reduce energy consumption. Furthermore, the system energy conservation theory, through energy cascade utilization and full-process optimization, drives dual reductions in comprehensive energy consumption and carbon emission intensity. The study emphasizes that future advancements must integrate hydrogen metallurgy, digitalization, and multi-energy synergy to steer the industry toward green, high-efficiency, and low-carbon transformation, providing technical support for China’s “Dual Carbon” goals. Full article
(This article belongs to the Section A: Sustainable Energy)
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17 pages, 5754 KiB  
Article
Study of Stress and Wear Behavior of Internal Components in Hydrogen-Based Shaft Furnaces Based on the Discrete Element Method (DEM) Model
by Hongzhi Ling, Yan Jin, Zhengchao Huang, Ziyu Liu and Peng Lin
Processes 2025, 13(3), 857; https://doi.org/10.3390/pr13030857 - 14 Mar 2025
Viewed by 557
Abstract
In the context of the “carbon peaking and carbon neutrality” era, China’s steel industry, as one of the pillars of the national economy, must accelerate the exploration and adoption of innovative production processes to effectively reduce its carbon footprint. The numerical simulation of [...] Read more.
In the context of the “carbon peaking and carbon neutrality” era, China’s steel industry, as one of the pillars of the national economy, must accelerate the exploration and adoption of innovative production processes to effectively reduce its carbon footprint. The numerical simulation of hydrogen-based shaft furnaces is an important method for studying the internal characteristics of steelmaking processes. Its objective is to set reasonable furnace parameters to significantly enhance production efficiency and environmental friendliness, ensuring that sustainability and economic benefits coexist in the steel manufacturing process. In order to develop a new shaft furnace, which simplifies the cooling parts, the mathematical model was used to conduct a numerical simulation analysis of hydrogen-based shaft furnaces. The Discrete Element Method (DEM) was employed to focus on the stress and wear behavior of internal components within the hydrogen-based shaft furnace. The results indicated that during the charging of iron ore pellets, the outlet area experienced friction and compression from Direct Reduced Iron (DRI), resulting in a maximum stress of 47,422.1 Pa at the output section. The stresses on the loosening roller were locally concentrated due to its clockwise rotational motion, with a maximum shear stress of 219,896.1 Pa. By applying the Archard wear theory and the moving bed model, the theoretical wear degrees of the refractory materials in the reduction section and the steel shell in the cooling section were obtained; the monthly wear rate of the loosening roller was approximately 0.601 mm. Reasonably setting the parameters and feeding speed of the hydrogen-based shaft furnace can optimize the force and wear conditions of internal components, achieving optimal operating conditions. This provides a reference for factories to effectively extend the service life of hydrogen-based shaft furnaces and offers reasonable suggestions for the future industrial application of hydrogen metallurgy. Full article
(This article belongs to the Section Materials Processes)
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28 pages, 9191 KiB  
Review
Research Progress on Alloying of High Chromium Cast Iron—Austenite Stabilizing Elements and Modifying Elements
by Shiqiu Liu and Li Liang
Crystals 2025, 15(3), 210; https://doi.org/10.3390/cryst15030210 - 22 Feb 2025
Cited by 2 | Viewed by 974
Abstract
High chromium cast iron (HCCI) is widely used in the manufacturing of equipment parts in the fields of mining, cement, electric power, metallurgy, the chemical industry, and paper-making because of its excellent wear and corrosion resistance. Although the microstructure and properties of HCCI [...] Read more.
High chromium cast iron (HCCI) is widely used in the manufacturing of equipment parts in the fields of mining, cement, electric power, metallurgy, the chemical industry, and paper-making because of its excellent wear and corrosion resistance. Although the microstructure and properties of HCCI can be modified by controlling the casting and heat treatment process, alloying is still the most basic and important method to improve the properties of HCCI. There are about 14 common alloying elements in HCCI, among which nickel, copper, and manganese are typical austenite stabilizing elements, which can increase austenite content and matrix electrode potential. The addition of elements such as silicon, nitrogen, boron, and rare earth (RE) is often small, but it has a significant effect on tailoring the microstructure, thereby improving wear resistance and impact toughness. It was thought that after years of development, the research on the role of the above elements in HCCI was relatively complete, but in the past 5 to 10 years, there has been a lot of new research progress. Moreover, the current development situation of HCCI is still relatively extensive, and there are still many problems regarding the alloying of HCCI to be further studied and solved. In this paper, the research results of austenitic stabilizing elements and modifying elements in HCCI are reviewed. The existing forms, distribution law of these elements in HCCI, and their effects on the microstructure, hardness, wear resistance, and corrosion resistance of HCCI are summarized. Combined with the current research situation, the future research and development direction of HCCI alloying is prospected. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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