Search Results (58)

Lime-based stabilization of clayey soils remains a cornerstone of ground improvement, yet the high carbon footprint of lime production drives the search for sustainable supplementary binders derived from industrial and quarrying wastes. Volcanic tuff waste (VTW), a fine powder by-product of wet cutting of ignimbritic tuff blocks, is an underutilized quarrying residue, already fine enough to use directly without grinding or thermal processing, yet its use as a supplementary binder in lime-stabilized clays has not been systematically investigated. This study evaluates VTW sourced from Ahlat (Bitlis, Türkiye) in kaolin clay stabilized with 6% lime, with VTW added at 0%, 10%, 15%, and 20% by dry weight. Mixtures were characterized through Atterberg limits, compaction, unconfined compressive strength (UCS) at 1–28 days, California Bearing Ratio (CBR), XRD, SEM, and FTIR. VTW reduced plasticity index, increased maximum dry density, and lowered optimum moisture content. The 15% VTW mixture achieved the highest 28-day UCS of 4296 kPa, a 17.2% improvement over the lime-only control, and the highest CBR of 80%. XRD revealed Tobermorite 9 Å formation, while SEM and FTIR confirmed cementitious gel phases consistent with pozzolanic reactions. The findings demonstrate that ignimbritic VTW, used directly without processing, is an effective supplementary binder that partially replaces carbon-intensive lime, supporting low-carbon, cost-effective stabilization and the valorization of quarrying waste within a circular economy framework. Full article

In porous ignimbrites, porosity defines the first-order control on elastic trend, but rocks with similar porosity can still behave differently because their pore networks are arranged differently. We analyzed 50 specimens from seven ignimbrite units in Mexico using density and porosity measurements, permeability tests, mercury intrusion porosimetry, image-based pore descriptors, and ultrasonic P- and S-wave velocities. At the unit scale averages, total porosity ranges from 31.4% in Tl to 42.9%, but elastic properties and permeability vary widely, showing that porosity alone does not define a unique physical state. Two end-member pore-network tendencies can be recognized: crack-linked, throat-restricted systems and more equant or intergranular systems. At similar porosity, crack-dominated networks are generally less stiff and less permeable, whereas more equant networks show higher permeability and stiffer behavior under dry conditions. Effective-medium models indicate that most samples are consistent with KT aspect ratios of 0.15–0.20 and a critical-porosity range of 40–60%. Overall, porosity defines the first-order elastic trend, whereas pore-network architecture explains much of the remaining hydraulic variability and part of the residual elastic spread. Full article

Ultrasound propagation velocity was investigated as a non-destructive predictor of open porosity (${\rho }_0$) and water absorption ($A_w$) in volcanic rocks (two ignimbrites, a trachyte, and a basalt). Six velocity measurements were obtained under dry and saturated conditions along three orthogonal directions, and the dry Z-axis velocity was selected as the reference univariate predictor because it provided the highest explanatory power and the best cross-validated performance among the tested ultrasound variables. Four univariate regressions (linear, exponential, power law, and second-order polynomial), parametric multivariable linear regression, and five machine learning regressors were compared using lithology-stratified 5-fold cross-validation, grouping both ignimbrites as a single lithology. Univariate models showed moderate predictive capability for ${\rho }_0$ (cross-validated coefficient of determination $R^2\approx$ 0.506 to 0.580), whereas $A_w$ was captured more accurately, with the power law model reaching 0.923 ± 0.008. Multivariable linear regression improved ${\rho }_0$ when lithology was included (0.803 ± 0.084), while changes for $A_w$ were small. The highest accuracy was achieved by ensemble tree methods: extremely randomized trees with lithology yielded 0.949 ± 0.015 for ${\rho }_0$ (root mean square error 2.16 ± 0.38 percentage points), and Gradient Boosting with lithology yielded 0.976 ± 0.006 for $A_w$ (0.80 ± 0.12 percentage points). Full article

Continental rift lacustrine basins typically feature multiple sediment sources under the combined controls of volcanism, tectonics, water balance and sediment supply, resulting in complex stratigraphic successions. This complexity is particularly pronounced in fine-grained successions, which are of high interest for their potential to generate and accumulate hydrocarbons. Nevertheless, the mechanisms governing the sedimentary transition from volcaniclastic to siliciclastic-dominated fills within a rift cycle remain poorly constrained. The Lower Cretaceous Xiguayuan Formation in the Luanping Basin accumulated in a lacustrine setting influenced by explosive volcanism, providing an excellent archive of siliciclastic–volcaniclastic interaction. Based on field observations, core descriptions, and petrographic analysis, sixteen lithofacies have been grouped into seven facies associations, including subaqueous ignimbrite, volcanically sourced turbidites, subaqueous volcanic ridge, central-lake sedimentation, shallow-lacustrine margin deposits, low-density turbidites, and high-density turbidites. Their spatial relationships reveal two volcanic pulses and document the lake’s environmental evolution, with deep-water background sediments overlying volcaniclastics and a marked increase in siliciclastic input upsection, reflecting a transition from an underfilled, volcaniclastic-dominated underfilled lake to a siliciclastic-dominated lake. Notably, the fine-grained sediments associated with volcanism exhibit excellent hydrocarbon potential. Organic-rich claystones and carbonate laminae form a microscopic source–reservoir system, in which volcanic inputs appear to enhance organic matter preservation and promote the development of reservoir-quality layers. This study elucidates how volcanic activity modulates sedimentation and sediment supply in a deep-lacustrine rift, offering new insights into volcano-sedimentary interactions and related hydrocarbon systems in continental rift basins. Full article

The Tuzla area, located in the Ayvacık district of Çanakkale (Biga Peninsula, northwestern Türkiye), hosts a Oligocene-Miocene volcanic system comprising andesitic, dacitic, rhyolitic lavas, trachyandesite, pyroclastics, and ignimbrites, and the Kestanbol Pluton. Petrographic and X-ray diffraction (XRD) analyses indicate that the altered volcanic units are dominated by porphyritic dacitic/rhyodacitic and trachyandesitic rocks, with silicification, iron oxide formation, and opacification. XRD results reveal smectite, smectite–illite/mica, illite–mica, kaolinite, cristobalite–opal, K-feldspar, plagioclase, dolomite, hematite, and quartz as the principal mineral phases. Geochemical data, including rare earth elements (REEs), suggest that fractional crystallization of primary mineral phases played a major role in controlling magmatic evolution. Chondrite-normalized REE patterns display enrichment in light REEs relative to heavy REEs, indicating derivation from a common magma source. K₂O–Na₂O and (Na₂O + K₂O)–FeOᵗ–MgO (AFM) diagrams show high-K calc-alkaline, calc-alkaline, and tholeiitic affinities, with most rhyodacite/dacite and all trachyandesite samples plotting in the tholeiitic field. Tectonic discrimination diagrams indicate formation in both volcanic arc and intraplate tectonic settings. Moderate enrichments in Ba and Sr reflect magmatic evolution and source characteristics, whereas the highest concentrations are attributed to post-magmatic fluid–rock interaction. Overall, the Tuzla volcanic rocks originated from a collision-related enriched lithospheric mantle source and subsequently evolved through fractional crystallization and assimilation processes, accompanied by crustal contamination and variable hydrothermal overprint. Full article

This study investigates how external insulation materials used for energy efficiency affect indoor radon accumulation, using a scale model room built with ignimbrite, a highly radon-emitting volcanic rock. Two insulation materials—mineral wool (open-cell, 98% porosity) and extruded polystyrene (XPS, closed-cell, >95%)—were applied to the outer walls of the model room. Their effects were tested in combination with three internal radon barriers (silane-terminated membrane, silicone sealant, bitumen membrane) and under varying ventilation rates (0.11 h⁻¹ and 0.44 h⁻¹). Radon concentrations were measured using calibrated detectors over five experimental phases. Without ventilation, XPS increased indoor radon by up to +351%, while mineral wool showed a milder effect (+26%). The silicone sealant reduced radon by up to 90%, outperforming other barriers. Ventilation significantly lowered radon levels, simulating the “flushing” effect of wind. The combination of impermeable insulation and lack of air exchange led to the highest radon accumulation. High-performance insulation can compromise indoor air quality by trapping radon, especially in buildings with high geogenic radon potential. Effective mitigation requires pairing insulation with high-performing radon barriers and adequate ventilation. These findings highlight the need to balance energy efficiency with indoor environmental safety. Full article

Different composites of polyethylene and two fillers (ignimbrite dust and Arundo donax fibers) were obtained by rotational molding. Both fillers were also combined among them to produce hybrid composites. The blends, prepared by dry-blending, were later rotomolded to determine the effect of such fillers into the tensile properties of the materials, before and after subjecting them to accelerated weathering on a UV chamber for up to 500 h. No significant differences are observed in the mechanical behavior of the different sample series, regardless their type or ratio of filler (5 or 10% by weight), due to the modifications only taking place on the sample surface and the rotomolded items having a thickness of nominally 4 mm. The carbonyl index was obtained from the FTIR spectra, determining an increase in this parameter with irradiation time. The samples with the Arundo fibers exhibit a lower carbonyl index, showing the potential stabilization effect of this lignocellulosic filler against UV, while the composites with the mineral powder tend to increase the oxidation of the samples when included at high loadings (10%). Full article

The present study investigates post-emplacement zeolitization processes in two widespread pyroclastic units from Central Italy: the Cimina Ignimbrite and the Sorano Ignimbrite. A total of seventy-five samples from ten outcrops were analyzed using optical and environmental scanning electron microscopy, electron probe microanalysis, X-ray powder diffraction, and inductively coupled plasma optical emission spectrometry. Analytical results allow the mineral distribution, zeolite composition, textural relationships, and geochemical features of the zeolite-bearing rocks to be defined. In the Cimina Ignimbrite, zeolitization affects the glassy portion of the groundmass, where the glass transforms into a medium- to high-temperature mineral assemblage dominated by clinoptilolite-Ca and cristobalite. This transformation is restricted to the innermost parts of the deposit. In contrast, zeolitization in the Sorano Ignimbrite involves the entire glassy fraction of pumice clasts, with extensive alteration of the glass into medium- to low-temperature zeolites such as chabazite-K and phillipsite-K. The results reveal a significant correlation between the chemical composition of the juvenile material and that of the newly formed zeolites in both types of ignimbrites, particularly in the Sorano Ignimbrite. Zeolitization in Central Italy ignimbrites likely occurs in a natural autoclave-like setting, where hot fluids remain trapped in the deposit for a long time. Full article

The Mazenod Lake region of the southern Great Bear Magmatic Zone (GBMZ) of the Northwest Territories, Canada, comprises the north-central portion of the Faber volcano-plutonic belt. Widespread and abundant surface exposure of several coalescing hydrothermal systems enables this paper to document, without ambiguity, the relationships between geology, structure, alteration, and mineralization in this well exposed iron-oxide–copper–gold (IOCG) mineral system. Mazenod geology comprises rhyodacite to basaltic-andesite ignimbrite sheets with interlayered volcaniclastic sedimentary rocks dominated by fine-grained laminated tuff sequences. Much of the intermediate to mafic nature of volcanic rocks is masked by low-intensity but pervasive metasomatism. The region is affected by a series of coalescing magmatic–hydrothermal systems that host the Sue–Dianne magnetite–hematite IOCG deposit and several related showings including magnetite, skarn, and iron oxide apatite (IOA) styles of alteration ± mineralization. The mid to upper levels of these systems are exposed at surface, with underlying batholith, pluton and stocks exposed along the periphery, as well as locally within volcanic rocks associated with more intense alteration and mineralization. Widespread alteration includes potassic and sodic metasomatism, and silicification with structurally controlled giant quartz complexes. Localized tourmaline, skarn, magnetite–actinolite, and iron-oxide alteration occur within structural breccias, and where most intense formed the Sue–Dianne Cu-Ag-Au diatreme-like breccia deposit. Magmatism, volcanism, hydrothermal alteration, and mineralization formed during a negative tectonic inversion within the Wopmay Orogen. This generated a series of oblique offset rifted basins with continental style arc magmatism and extensional structures unique to GBMZ rifting. All significant hydrothermal centers in the Mazenod region occur along and at the intersections of crustal faults either unique to or put under tension during the GBMZ inversion. Full article

The Aghbar-Bou Azzer East mining district (ABED) is located between the Bou Azzer East and Aghbar deposits. It is an area of approximately 7 km long towards ENE–WSW and 2 km wide towards N–S. In this barren area, volcano-sedimentary rocks are attributed to the Ouarzazate group outcrop (Ediacarian age): they are composed of volcanic rocks (ignimbrite, andesite, rhyolite, dacite, etc.) covered by the Adoudou detritic formation in angular unconformity. Given the absence of serpentinite outcrops, exploration investigation in this area has been very limited. This paper aims to use ionic leach geochemistry (on samples of soil) to detect the presence of Co-bearing arsenides above hidden ore deposits in this unexplored area of the Bou Azzer inlier. In addition, a detailed structural analysis allowed the identification of four families of faults and fractures with or without filling. Three directional major fault systems of several kilometers in length and variable orientation in both the Cryogenian basement and the Ediacaran cover have been identified: (i) ENE–WSW, (ii) NE–SW, and (iii) NW–SE. Several geochemical anomalies for Co, As, Ni, Ag, and Cu are aligned along three main directions, including NE–SW, NW–SE, and ENE–WSW. They are particularly well-defined in the western zone but are only minor in the central and eastern zones. Some of these anomalies correlate with the primary structural features observed in the studied area. These trends are consistent with those known under mining exploitation in nearby ore deposits, supporting the potential for similar mineralization in the ABED. Based on structural analysis and ionic leach geochemistry, drilling programs were conducted in the study area, confirming the continuity of serpentinites at depth beneath the Ediacaran cover and the presence of Co–Fe-bearing arsenide ores. This validates the ionic geochemistry technique as a reliable method for exploring buried ore deposits. Full article

The construction industry generates large amounts of waste and high CO₂ emissions, especially from cement production. Sustainable alternatives, such as geopolymers, help reduce these impacts by promoting eco-friendly materials. This study aimed to develop geopolymer mortar using ignimbrite (IG) residues from the Arequipa region, Peru, combined with metakaolin (MK). The raw materials were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS) to assess the chemical composition, structure, and morphology. Geopolymeric mortars were synthesized with varying MK/IG ratios while maintaining a fixed fine sand proportion. An activating solution of 9 mol/L NaOH was used with different liquid-to-solid ratios. Geopolymers cured at room temperature for 28 days exhibited lower compressive strength than those dried at 50 °C for 48 h or sequentially at 50 °C for 48 h followed by 90 °C for 12 h. The highest IG-content mixture achieved a compressive strength of 18 MPa, while the MK-based geopolymer reached 12 MPa, both under high-temperature curing. An increase in the SiO₂/Al₂O₃ molar ratio was also associated with improved mechanical performance, reinforcing the influence of precursor composition on geopolymerization. These results highlight the potential of regional ignimbrite for the production of geopolymer mortar, promoting sustainable and innovative building materials. Full article

This study aims to synthesize sustainable zeolite catalysts by taking advantage of the great abundance of natural precursors, such as pozzolana, ignimbrite, and pumice, found in the southern zone of Peru. Different methodologies were selected. On the one hand, an alkaline fusion/hydrothermal reaction with NaOH processes was utilized and, on the other hand, the hydrothermal method was employed. The characteristics of these catalysts and their application in the catalytic pyrolysis of polypropylene were evaluated. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) were employed to investigate the structure and properties of the obtained catalysts. Catalytic pyrolysis experiments of polypropylene were carried out at 450 °C for 30 min with a 6% w/w zeolite catalyst. It was possible to synthesize zeolites similar to commercial zeolites such as ZSM-5 and zeolite X, with a BET surface area of up to 451.3 m²/g⁻¹, offering the possibility of obtaining commercial products from natural materials. According to the results obtained in the pyrolytic process, method 1 (alkaline fusion/hydrothermal reaction with NaOH) presents the best results, with 94% in liquid and gaseous products. The zeolite synthesized with the pozzolan precursor was the most successful, followed by pumice. Full article

Groundwater resources from the volcanic aquifers of northern Latium (central Italy) are widely used to supply local water needs and are mainly captured through wells. Nevertheless, despite the detailed hydrogeological knowledge of these aquifers, not enough information is available on the long-term pumping yield necessary to define the sustainable yield of a well. In this study, data from about 230 pumping tests (mainly step-drawdown and a few constant-flow-rate tests) performed in the volcanic aquifers of the Latium region were analyzed. Specifically, the aquifer formations intercepted by the wells are the fall and flow pyroclastic deposits of the Vico, Vulsini, and Sabatini volcanic districts; lava from the Vico, Cimino, and Vulsini volcanic districts; and Ignimbrite Cimina, one of the main pyroclastic products of the Cimino eruptions. These aquifers were grouped and analyzed by considering the type of permeability, hydrostratigraphic succession, and frequency and thickness of the aquifer horizons intercepted by wells. The results obtained in terms of specific capacity and transmissivity values are comparable among the identified different aquifer formations, showing a good correlation between the two parameters, a strong hydraulic heterogeneity (variability within five orders of magnitude), and variable responses regarding drawdown to pumping. This study highlights that the analysis of drawdown over time at a constant flow is fundamental in heterogeneous hydrogeological environments such as volcanic ones, where the trend in drawdown is often affected by the reduced spatial continuity of the most productive aquifer formations. Knowledge of the trend in drawdown over time, the thickness of the aquifer intercepted by the well, and the operating time of the well is an essential element in defining the sustainable yield of a well. Full article

Post-collisional volcanism provides valuable insights into mantle dynamics, crustal processes, and mechanisms driving orogen uplift and collapse. This study presents geological, geochemical, and geochronological data for Ediacaran effusive and pyroclastic units from the Taghdout Volcanic Field (TVF) in the Siroua Window, Anti-Atlas Belt. Two eruptive cycles are identified based on volcanological and geochemical signatures. The first cycle comprises a diverse volcanic succession of basalts, basaltic andesites, andesites, dacites, and rhyolitic crystal-rich tuffs and ignimbrites, exhibiting arc calc-alkaline affinities. These mafic magmas were derived from a lithospheric mantle metasomatized by subduction-related fluids and are associated with the gravitational collapse of the Pan-African Orogen. The second cycle is marked by bimodal volcanism, featuring tholeiitic basalts sourced from the asthenospheric mantle and felsic intraplate magmas. These units display volcanological characteristics typical of facies models for continental basaltsuccessions and continental felsic volcanoes. Precise CA-ID-TIMS U-Pb zircon dating constrains the volcanic activity to 575–557 Ma, reflecting an 18-million-year period of lithospheric thinning, delamination, and asthenospheric upwelling. This progression marks the transition from orogen collapse to continental rifting, culminating in the breakup of the Rodinia supercontinent and the opening of the Iapetus Ocean. The TVF exemplifies the dynamic interplay between lithospheric and asthenospheric processes during post-collisional tectonic evolution. Full article

Upper Cretaceous volcaniclastic deposits of the Haţeg Basin (VDHB) (Southern Carpathians, Romania) consist of relatively poorly exposed products of multiple phreatomagmatic volcanic eruptions of andesitic to rhyolitic composition and crop out around Densuş, Răchitova, Peşteniţa, and Ciula Mică localities. These deposits are commonly associated with the Late Cretaceous Neotethyan magmatic activity that developed in Central-Eastern Europe, forming the Apuseni–Banat–Timok–Srednogorie (ABTS) belt. Since the geochemistry of these deposits has been investigated very little so far, this study provides petrographic and whole-rock geochemical analysis for twenty new different volcaniclastic rock samples, out of which sixteen samples represent lava clasts and the other four are samples of pyroclastic flow deposits. According to our geochemical data, the VDHB have a calc-alkaline and high-K calc-alkaline character, similar to the majority of rock samples from all sectors of the ABTS belt. A comparison between the Haţeg rock samples and Banat and Apuseni samples reveals comparable major and trace element abundances and REE patterns, supporting the idea that they originate from similar magmas. Trace element patterns suggest that the parental magmas were mostly derived from the melting of a metasomatized lithospheric mantle source, previously modified by an earlier subduction event. A combination of crystal fractionation and variable degrees of crustal assimilation during storage at higher and lower pressures was the principal mechanism driving calc-alkaline differentiation. Our geochemical analyses indicate that the VDHB were produced by magmas generated during two different magmatic events. Older, silica-rich melts produced the Peştenita and Răchitova ignimbrite deposits, while the Densuş and Răchitova andesitic–dacitic–rhyolitic rock suite was generated by younger, intermediate magmas. The individual melt production episodes are evidenced by the emergence of two different crystal fractionation trends: an amphibole-controlled trend at mid-crustal levels and an upper-crust plagioclase-dominated trend. The hydrous, calc-alkaline magmas arguably occurred in a post-collisional setting, in agreement with the orogenic collapse model, among others, proposed for the origin of the ABTS magmatic activity. Full article