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Keywords = high-speed photodetectors

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19 pages, 4368 KB  
Article
Comparative Investigation of LG and HG Modes for a QKD-Assisted High-Capacity and Secure LiFi/MDM System
by Meet Kumari, Satyendra K. Mishra and Jyoteesh Malhotra
Photonics 2026, 13(8), 794; https://doi.org/10.3390/photonics13080794 - 21 Aug 2026
Viewed by 202
Abstract
Light fidelity (LiFi) is progressively evolving as a highly promising communication technology because of its unique benefits, available spectrum, low implementation costs, and adaptive beamforming capabilities. Despite their advantages, existing LiFi networks remain constrained by limited data rates, coverage area, and information security [...] Read more.
Light fidelity (LiFi) is progressively evolving as a highly promising communication technology because of its unique benefits, available spectrum, low implementation costs, and adaptive beamforming capabilities. Despite their advantages, existing LiFi networks remain constrained by limited data rates, coverage area, and information security in practical environments. Therefore, a high-speed, high-capacity, and secure quantum key distribution (QKD)-assisted integrated multi-wavelengths (450/532/620 nm) LiFi system using mode division multiplexing (MDM) is proposed. The results demonstrate that the proposed system achieves maximum transmission distances of 20.5–22 m and 19–22 m using different Laguerre–Gaussian (LG) and Hermite–Gaussian (HG) mode indices {[0,0], [0,10], [0,20], [0,30]}, at an aggregate data rate of 40 Gbps. Furthermore, the minimum acceptable transmitter angles of 30–90° for irradiance angles of 20–80° are required to maintain the target bit error rate (BER) of 10−9. The minimum photodetector detection areas required at transmission distances of 20–30 m are 1–2 cm2 at the minimum BER limit. Moreover, the proposed system exhibits optimum performance, achieving an optical loss of −39.47 dB, −49.03 dBm received power, and 45.39 dB signal-to-noise ratio for 1–10 photons/pulse. Compared with existing studies, the proposed system demonstrates enhanced overall performance across various communication metrics. Full article
(This article belongs to the Special Issue Recent Progress in Optical Quantum Information and Communication)
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27 pages, 3972 KB  
Review
AI-Driven Photonic Front-Ends for 6G Visible Light Communication: From Micro-LEDs and Reconfigurable Optics to Energy-Autonomous Receivers
by Amjad Ali, Syed Raza Mehdi, Shulan Lin, Ying Xu, Pablo Palacios Jativa, Waseem Ur Rahman, Baseerat Bibi, Ameen Alkasem, Mehboob Hussain and Zeeshan Shafiq
Photonics 2026, 13(8), 779; https://doi.org/10.3390/photonics13080779 - 17 Aug 2026
Viewed by 332
Abstract
Visible light communication (VLC) has emerged as a transformative optical wireless technology for sixth-generation (6G) networks, offering license-free spectrum access, inherent electromagnetic-interference immunity, high spatial confinement, and the unique ability to combine high-speed wireless connectivity with solid-state lighting infrastructure. However, the transition from [...] Read more.
Visible light communication (VLC) has emerged as a transformative optical wireless technology for sixth-generation (6G) networks, offering license-free spectrum access, inherent electromagnetic-interference immunity, high spatial confinement, and the unique ability to combine high-speed wireless connectivity with solid-state lighting infrastructure. However, the transition from conventional VLC links to practical 6G optical wireless systems requires far more than advanced modulation and signal processing. Future VLC performance will be strongly determined by the co-design of photonic front-ends, including high-speed transmitters, spectrally engineered emitters, reconfigurable optical interfaces, intelligent receivers, and energy-autonomous detection units. This article provides a comprehensive, device-centered review of photonic hardware and artificial intelligence (AI) enablers for next-generation 6G VLC systems. Particular attention is given to micro-LEDs, laser diodes, color-conversion materials, including perovskite quantum dots, advanced photodetectors, imaging receivers, wavelength-shifting fiber receivers, solar-cell-based receivers, optical reconfigurable intelligent surfaces (RISs), metasurfaces, beam-steering components, and optical wireless power transfer. This review discusses how AI can support inverse photonic design, transmitter and receiver calibration, nonlinear impairment mitigation, channel-aware beam control, and energy-aware resource management. Unlike broader VLC surveys that mainly emphasize network architecture, this article provides a device-centered perspective on AI-enabled photonic integration for 6G VLC, supported by a comprehensive survey of recent experimental demonstrations. Key challenges related to bandwidth, optical efficiency, receiver field of view, mobility, safety, standardization, and practical deployment are summarized, followed by a research roadmap for 2025–2032. Full article
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23 pages, 1699 KB  
Review
Underwater Optical Communications: From Photodiodes to Single-Photon Detectors
by Zbigniew Bielecki and Janusz Mikołajczyk
Photonics 2026, 13(8), 752; https://doi.org/10.3390/photonics13080752 - 10 Aug 2026
Viewed by 272
Abstract
Underwater wireless optical communication (UWOC) has emerged as a key technology for high-speed, low-latency data transmission in aquatic environments, enabling applications in autonomous underwater vehicles (AUVs), remotely operated vehicles (ROVs), subsea sensor networks, and the Internet of Underwater Things (IoUT). This paper reviews [...] Read more.
Underwater wireless optical communication (UWOC) has emerged as a key technology for high-speed, low-latency data transmission in aquatic environments, enabling applications in autonomous underwater vehicles (AUVs), remotely operated vehicles (ROVs), subsea sensor networks, and the Internet of Underwater Things (IoUT). This paper reviews photodetector technologies that shape UWOC system performance, covering both mature and emerging detector classes. We discuss the operating principles, key parameters, and practical trade-offs of photomultiplier tubes (PMTs), p-i-n photodiodes (PINs), avalanche photodiodes (APDs), single-photon avalanche diodes (SPADs), and silicon photomultipliers (SiPMs/MPPCs). We also present emerging photodetector technologies, including perovskite-based structures, SiC photoelectrochemical devices, scintillating optical fibers, and photovoltaic solar cells. A comparative analysis of reported UWOC experiments reveals a clear sensitivity–bandwidth trade-off among detector technologies: PIN-based receivers achieve the highest data rates (up to 25 Gbps) but are generally restricted to short-range links, whereas SPAD- and SiPM-based receivers provide sensitivities below −80 dBm and support transmission distances exceeding 200 m, at the cost of moderate data rates. The findings indicate that SiPM/MPPC arrays currently offer the most promising compromise between sensitivity and data rate for long-range UWOC applications. Full article
(This article belongs to the Special Issue Free-Space Optical Communication and Networking Technology)
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18 pages, 10224 KB  
Article
Balancing Conductive Network Continuity and Out-of-Plane Transport Barrier in PEDOT:PSS/Ga2O3 Self-Powered Solar-Blind Photoelectrochemical Photodetectors
by Jintao Xu, Rihui Yao, Haoyan Chen, Dongxiang Luo, Chi Yuan, Haitao Zhu, Xu Zhou, Xiaojie Li, Weiguang Xie, Honglong Ning and Junbiao Peng
Inorganics 2026, 14(8), 209; https://doi.org/10.3390/inorganics14080209 - 6 Aug 2026
Viewed by 327
Abstract
To realize self-powered solar-blind ultraviolet (UV) photodetectors with high stability, high efficiency, and low cost, a self-powered photoelectrochemical (PEC)-type hybrid UV photodetector was constructed based on a poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS)/Ga2O3 organic–inorganic heterojunction. The PEDOT:PSS layer serves not only as a [...] Read more.
To realize self-powered solar-blind ultraviolet (UV) photodetectors with high stability, high efficiency, and low cost, a self-powered photoelectrochemical (PEC)-type hybrid UV photodetector was constructed based on a poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS)/Ga2O3 organic–inorganic heterojunction. The PEDOT:PSS layer serves not only as a p-type hole transport layer but also as an interface modification layer to modulate charge separation and surface recombination in Ga2O3. As the spin-coating speed decreases, the PEDOT:PSS film thickness increases monotonically from 33.27 to 44.18 nm. Thicker films develop a more continuous conductive network, which favors hole transport. However, additional insulating PSS lamellae also accumulate in the vertical direction, creating a higher out-of-plane transport barrier that counteracts this improvement. The device with an intermediate film thickness of 36.50 nm achieves the optimal balance between these two competing factors, delivering a responsivity of 20.6 mA/W and a specific detectivity of 1.36 × 1010 Jones under 267 nm illumination at zero bias, along with a high UV/visible rejection ratio of 3.18 × 105 and fast rise/decay times of 26/10 ms. This work provides a facile interface engineering strategy for low-cost, high-performance self-powered solar-blind UV photodetectors. Full article
(This article belongs to the Special Issue Advanced Inorganic Semiconductor Materials, 4th Edition)
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19 pages, 2367 KB  
Review
Recent Advances and Critical Review on Two-Dimensional Black Phosphorus: Preparation and Optoelectronic Applications
by Jialu Zheng, Zeying Zhou, Danghui Wang, Yan Li and Zhao Li
Materials 2026, 19(13), 2691; https://doi.org/10.3390/ma19132691 - 23 Jun 2026
Viewed by 469
Abstract
Two-dimensional black phosphorus (2D BP) has emerged as one of the most promising two-dimensional semiconductors for next-generation micro and nanoelectronics beyond Moore’s Law. It is distinguished by its unique combination of a layer dependent direct bandgap, broadband photoresponse, and pronounced in-plane anisotropy, addressing [...] Read more.
Two-dimensional black phosphorus (2D BP) has emerged as one of the most promising two-dimensional semiconductors for next-generation micro and nanoelectronics beyond Moore’s Law. It is distinguished by its unique combination of a layer dependent direct bandgap, broadband photoresponse, and pronounced in-plane anisotropy, addressing key intrinsic limitations that have hindered the widespread application of graphene and conventional transition metal dichalcogenides (TMDCs). This review provides a systematic and comprehensive overview of recent advances in the controllable fabrication of 2D BP and its applications in transistors and photodetectors. We first elucidate its crystal lattice structure and fundamental physical properties, then categorize and summarize synthesis strategies based on production scale ranging from small scale methods (e.g., mechanical exfoliation and solution based exfoliation) to large scale methods (e.g., Chemical Vapor Deposition (CVD) and Pulsed Laser Deposition (PLD)), with a particular focus on recent advances in high-speed field-effect transistors and broadband photodetectors. In summary, the key to achieving large-scale controllable synthesis lies in addressing the challenges of high-temperature oxidation of black phosphorus and the uncontrollable diffusion of phosphorus sources. In the future, industrial applications are expected to be realized through CVD based regulation of phosphorus sources, low-temperature growth by PLD, and deep integration with silicon-based processes. Full article
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40 pages, 742 KB  
Review
Cross-Platform Neuromorphic Photodetectors: From Organic and Oxide to Perovskite, Wide-Bandgap, and Si-CMOS
by Martin Weis
Photonics 2026, 13(6), 589; https://doi.org/10.3390/photonics13060589 - 17 Jun 2026
Cited by 2 | Viewed by 779
Abstract
Conventional photodetectors and image sensors deliver high-fidelity digital outputs but face a growing data-movement bottleneck: the energy and latency cost of transferring raw pixel streams to off-chip memory and processors increasingly dominates over both sensing and computation in modern machine-vision pipelines. An emerging [...] Read more.
Conventional photodetectors and image sensors deliver high-fidelity digital outputs but face a growing data-movement bottleneck: the energy and latency cost of transferring raw pixel streams to off-chip memory and processors increasingly dominates over both sensing and computation in modern machine-vision pipelines. An emerging response is the neuromorphic photodetector, a class of optoelectronic device that converts incident light into an electrical signal while simultaneously storing, modulating, and pre-processing that signal in a manner inspired by biological synapses and retinas. Over the past decade, demonstrations have spanned at least eight material platforms—organic semiconductors, organic–carbon-nanotube hybrids, perovskite and perovskite hybrids, metal oxides (including ultra-wide-bandgap and printable variants), wide-bandgap III-nitrides and 4H-SiC, two-dimensional materials, photo-memristors, and silicon CMOS in-sensor compute architectures—and have been realised through four distinct architectural families: phototransistor synapses, photo-memristors, heterojunction in-sensor compute, and linear photovoltaic neural networks. Here, we provide a quantitative cross-platform benchmark across forty in-scope articles, identify persistent photoconductivity as a near-universal device-physical substrate underlying synaptic functionality, characterise the responsivity–speed–energy trade-off structure observed across platforms, and present a critical assessment of energy-reporting practice in the field. We further identify three best-practice exemplars from three independent material platforms that converge on operating biases of 0.01–0.1 V and energies of 0.07–0.8 fJ per event, and we propose a unified reporting framework to enable meaningful cross-platform benchmarking of next-generation neuromorphic photodetectors. Full article
(This article belongs to the Special Issue New Perspectives in Photodetectors)
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10 pages, 2400 KB  
Article
Boosting the Performance of Visible/Near-Infrared Organic Photodetectors via Hole Interface Engineering
by Yijing Fan, Junquan Luo, Lan Liu, Qiao He, Jiahui Lu, Zhimin Shao, Zhensheng Xu, Zhe Liu, Yun Xia, Xuanye Li and Lintao Hou
Nanomaterials 2026, 16(11), 644; https://doi.org/10.3390/nano16110644 - 22 May 2026
Viewed by 457
Abstract
When poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) is employed as the hole transport layer in visible/near-infrared photodetectors, the extraction and transport of holes are hindered by the accumulation of the PSS insulating phase at the interface. This accumulation results in an increase in contact resistance [...] Read more.
When poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) is employed as the hole transport layer in visible/near-infrared photodetectors, the extraction and transport of holes are hindered by the accumulation of the PSS insulating phase at the interface. This accumulation results in an increase in contact resistance and creates a potential barrier for hole injection. This study introduces a self-assembled monolayer, (2-(9H-carbazol-9-yl)ethyl)phosphonic acid (2PACz), to modify PEDOT:PSS, effectively optimizing the interface of the hole transport layer. Such improvements lead to a reduction in recombination losses during charge transfer, a lower dark current, and improved energy level alignment in the device, thereby boosting the performance of visible/near-infrared photodetectors. The fabricated double hole layer photodetector exhibits a low dark current of (1.4 ± 0.6) × 10−5 A at −1 V bias and a switching ratio of up to 7.62 × 105 at 0 V bias. The device achieves a responsivity of 0.31 A/W and a high specific detection rate of 3.23 × 1012 Jones at a wavelength of 780 nm, which corresponds to the peak responsivity, showcasing enhanced detection capabilities. In comparison to a reference device based on PEDOT:PSS, the response speed, cutoff frequency, and linear dynamic range of the double hole layer device have been enhanced by 400%, 213%, and 81%, respectively, thereby better aligning with practical application requirements. This research presents a novel approach for the development of high-performance organic visible/near-infrared photodetectors. Full article
(This article belongs to the Section Nanophotonics Materials and Devices)
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12 pages, 1484 KB  
Article
High-Performance Terahertz Photodetectors Based on Spiral Structure-Regulated Graphene
by Lei Yang, Bohan Zhang, Yingdong Wei, Hongfei Wu, Zhiyuan Zhou, Zhaowen Bao, Huichuan Fan, Xiaoyun Wang, Lin Wang and Xiaoshuang Chen
Sensors 2026, 26(9), 2633; https://doi.org/10.3390/s26092633 - 24 Apr 2026
Viewed by 732
Abstract
Terahertz technology has demonstrated immense potential across a wide range of applications, particularly in the realm of THz photodetection. However, state-of-the-art detectors typically face fundamental trade-offs among sensitivity, response speed, operating temperature, and spectral bandwidth. While previous studies have shown that graphene field-effect [...] Read more.
Terahertz technology has demonstrated immense potential across a wide range of applications, particularly in the realm of THz photodetection. However, state-of-the-art detectors typically face fundamental trade-offs among sensitivity, response speed, operating temperature, and spectral bandwidth. While previous studies have shown that graphene field-effect transistors (GFETs) exhibit a broadband, room-temperature photoresponse to THz radiation—often attributed to photothermoelectric (PTE) and plasma-wave rectification effects—the similar functional dependence of these mechanisms on the gate voltage has historically made it challenging to disentangle their individual contributions. In this study, we leverage monolayer graphene as the photoactive material to overcome these limitations within a single device architecture. We present a novel THz photodetector driven predominantly by the PTE effect, facilitated by a precisely designed counterclockwise spiral antenna. The demonstrated device achieves exceptional room-temperature sensitivity, featuring a minimum noise equivalent power (NEP) of 80.7 pW/Hz alongside a rapid response time of less than 11 μs. Furthermore, by systematically analyzing the temporal response dynamics, we unambiguously identify the PTE effect as the dominant operating mechanism. These results provide a robust strategy for the development of high-performance, room-temperature THz optoelectronics, paving the way for advanced practical applications in high-capacity wireless communications and real-time THz imaging. Full article
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13 pages, 2761 KB  
Article
Design of High-Speed MUTC-PD Under High Input Optical Power Utilizing Combined Analytical and Numerical Methods
by Xiyue Zhang and Xiaofeng Duan
Photonics 2026, 13(4), 370; https://doi.org/10.3390/photonics13040370 - 13 Apr 2026
Cited by 1 | Viewed by 971
Abstract
High-speed photodetectors with extended dynamic ranges are critical for emerging optical systems like LiDAR. This paper presents a design methodology for a modified uni-traveling-carrier photodetector (MUTC-PD) that integrates a physics-based analytical model with numerical simulations. The existing analytical models for MUTC-PDs rely on [...] Read more.
High-speed photodetectors with extended dynamic ranges are critical for emerging optical systems like LiDAR. This paper presents a design methodology for a modified uni-traveling-carrier photodetector (MUTC-PD) that integrates a physics-based analytical model with numerical simulations. The existing analytical models for MUTC-PDs rely on approximations that may not hold under high injection levels and high frequencies, leading to discrepancies between theoretical predictions and practical observations. To address this limitation, we re-examine the governing equations and derive a corrected frequency response analytical model based on drift–diffusion theory by decomposing the device into distinct transport regions, enabling a physically meaningful optimization of the epitaxial layer structure to maximize theoretical intrinsic bandwidth. The calculated results closely match the simulated bandwidth (maximum error less than 6%), demonstrating consistent peak positions and trends. Subsequently, numerical simulations reveal the dynamic evolution of the device’s bandwidth under varying incident optical intensities. The results demonstrate that the intrinsic bandwidth initially increases to a peak of 325.82 GHz at 7×104W/cm2 under −3.5 V, attributed to the drift-enhancement effect driven by the self-induced quasielectric field. Beyond this optimal regime, the space charge effect causes internal field collapse and significant bandwidth degradation. This study establishes bandwidth maintenance capability under high injection as a key metric for linearity, offering a transparent theoretical and practical framework for designing a high-speed MUTC-PD. Full article
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13 pages, 2158 KB  
Article
A Broad-Band Self-Powered Photodetector Based on a MoTe2/Bi2Te3 Heterojunction for Optical Imaging and Bias-Controlled Signal Modulation
by Shaoxiong Du, Kunle Li, Weijie Li, Jiahui Feng, Yunwei Sheng, Lili Tao, Zhaoqiang Zheng, Wei Song and Yu Zhao
Materials 2026, 19(6), 1270; https://doi.org/10.3390/ma19061270 - 23 Mar 2026
Cited by 1 | Viewed by 771
Abstract
Self-powered photodetectors are highly demanded in applications but often suffer from limited spectral absorption, slow response speed, and high dark currents. Two-dimensional van der Waals heterostructures have emerged as promising candidates owing to their designable structures and excellent performance. Herein, we construct a [...] Read more.
Self-powered photodetectors are highly demanded in applications but often suffer from limited spectral absorption, slow response speed, and high dark currents. Two-dimensional van der Waals heterostructures have emerged as promising candidates owing to their designable structures and excellent performance. Herein, we construct a MoTe2/Bi2Te3 heterostructure and investigate its photoelectric properties. At zero bias, it exhibits a broad photovoltaic response ranging from 405 to 1550 nm. Benefiting from the interfacial built-in electric field, it achieves a responsivity of 1.38 A/W and a detectivity of 1.90 × 1012 Jones at 532 nm and retains 174.56 mA/W and 2.4 × 1011 Jones at 1060 nm, together with a low dark current of 1.6 × 10−12 A. Upon a reverse bias of −1 V and 532 nm laser illumination at an intensity of 19.0 W/m2, the responsivity is further boosted to 36.22 A/W, accompanied by rise and decay times of 32 ms and 33 ms, respectively. Taking advantage of the distinct optical switching ratios at zero/non-zero biases, application in optical imaging and bias-controlled signal modulation is realized, highlighting the heterojunction’s potential as a broadband self-powered photodetector. Full article
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11 pages, 2565 KB  
Article
Germanium-on-Silicon Waveguide-Integrated Photodiode with Dual Optical Inputs for Datacenter Applications
by Itamar-Mano Priel, Shai Cohen, Liron Gantz and Yael Nemirovsky
Micromachines 2026, 17(3), 386; https://doi.org/10.3390/mi17030386 - 23 Mar 2026
Cited by 1 | Viewed by 903
Abstract
As the exponential growth in advanced compute workloads drives intra-datacenter interconnects to ever increasing bitrates, optical networking equipment has risen to the challenge by shifting from NRZ signaling to bandwidth efficient modulation methods such as PAM4. As these modulation schemes introduce an inherent [...] Read more.
As the exponential growth in advanced compute workloads drives intra-datacenter interconnects to ever increasing bitrates, optical networking equipment has risen to the challenge by shifting from NRZ signaling to bandwidth efficient modulation methods such as PAM4. As these modulation schemes introduce an inherent SNR penalty, maintaining low bit error rates (BER) forces optical links to operate at significantly higher optical powers. However, increasing the optical power leads to photodetectors reaching one of their fundamental bottlenecks caused by the space-charge effect, limiting their ability to provide a high-speed response under high-power illumination. This work presents the design, fabrication, and characterization of a waveguide-integrated photodiode with dual optical inputs (DIPD) designed to overcome this limitation. Specifically, we demonstrate that combining a dual-fed architecture with targeted cross-sectional geometric optimizations effectively distributes the photocurrent density to delay the onset of space-charge saturation. Experimental validation demonstrates a high responsivity of ≈0.91 [A/W] (for O-band wavelengths) and a large electro-optic bandwidth (EOBW) of ≈58 [GHz], all under high-power illumination and CMOS driving voltages. Full article
(This article belongs to the Section A:Physics)
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13 pages, 3782 KB  
Article
A Self-Powered, High-Performance Photodetector Based on a g-C3N4/Textured Si n-n Heterojunction
by Xiwei Zhang, Junshuai Li, Jiale Sang, Jiabao Luo, Jiayi Shi, Huijuan Geng and Zhenjie Tang
Inorganics 2026, 14(3), 77; https://doi.org/10.3390/inorganics14030077 - 6 Mar 2026
Viewed by 1122
Abstract
g-C3N4 has emerged as a promising metal-free semiconductor for optoelectronic applications due to its suitable bandgap, excellent stability, and low cost. However, enhancing its photoresponse efficiency in practical devices remains a challenge. In this work, a high-performance self-powered photodetector was [...] Read more.
g-C3N4 has emerged as a promising metal-free semiconductor for optoelectronic applications due to its suitable bandgap, excellent stability, and low cost. However, enhancing its photoresponse efficiency in practical devices remains a challenge. In this work, a high-performance self-powered photodetector was developed using a g-C3N4/textured Si n-n heterojunction fabricated via a simple solution process. The device exhibits excellent diode characteristics with a rectification ratio of ~4.9 × 102 and an ideality factor of 1.41. It achieves broadband detection from 405 to 980 nm, a high responsivity of 3.2 A/W, a specific detectivity of 1.9 × 1014 Jones, and fast response speeds of 44/36 ms at 650 nm under zero bias. Significantly, the textured Si-based device shows approximately tenfold higher performance than its planar Si counterpart, owing to enhanced light absorption from the textured surface. The combination of excellent photoresponse and simple fabrication makes the g-C3N4/textured Si n-n heterojunction a promising candidate for low-cost, high-performance optoelectronic applications. Full article
(This article belongs to the Section Inorganic Materials)
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30 pages, 23783 KB  
Review
Recent Progress in Silicon-Based On-Chip Integrated Infrared Photodetectors
by Yu He, Hongling Peng, Peng Cao, Zeyu Wang, Jiaqi Wei, Chunxu Song, Wanhua Zheng and Qiandong Zhuang
Sensors 2026, 26(4), 1125; https://doi.org/10.3390/s26041125 - 9 Feb 2026
Cited by 4 | Viewed by 2441
Abstract
Infrared (IR) photodetectors are indispensable to modern optoelectronic systems, ranging from night vision imaging, surveillance, and industrial process control to environmental monitoring and medical diagnostics. However, traditional detectors based on bulk semiconductors are constrained by prohibitive fabrication costs and the stringent requirement for [...] Read more.
Infrared (IR) photodetectors are indispensable to modern optoelectronic systems, ranging from night vision imaging, surveillance, and industrial process control to environmental monitoring and medical diagnostics. However, traditional detectors based on bulk semiconductors are constrained by prohibitive fabrication costs and the stringent requirement for bulky cryogenic cooling, which severely hinders their widespread deployment in Size, Weight, and Power (SWaP)-sensitive scenarios. Silicon-based on-chip integration, leveraging compatibility with mature CMOS processes, has emerged as a transformative paradigm. It enables the realization of fully functional photonic integrated circuits (PICs) capable of on-chip sensing and high-speed data transmission, offering a pathway toward miniaturized and cost-effective architectures. This article provides a review of recent progress in silicon-based infrared photodetectors across three core material systems: Group IV (Ge/GeSn), III–V compounds, and two-dimensional (2D) materials. In the end, we offer an outlook on the development trends of next-generation intelligent sensing systems driven by optoelectronic convergence. Full article
(This article belongs to the Special Issue Feature Papers in Optical Sensors 2026)
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24 pages, 3258 KB  
Review
Progress in Charge Transfer in 2D Metal Halide Perovskite Heterojunctions: A Review
by Chenjing Quan, Jiahe Yan, Xiaofeng Liu, Qing Lin, Beibei Xu and Jianrong Qiu
Materials 2025, 18(24), 5690; https://doi.org/10.3390/ma18245690 - 18 Dec 2025
Cited by 3 | Viewed by 1043
Abstract
Metal halide perovskite (MHP)-based heterojunctions have become a forefront area in the research of optoelectronic functional materials due to their unique layered crystal structure, tunable band gaps, and exceptional optoelectronic properties. Recent studies have demonstrated that interface charge transfer is a crucial factor [...] Read more.
Metal halide perovskite (MHP)-based heterojunctions have become a forefront area in the research of optoelectronic functional materials due to their unique layered crystal structure, tunable band gaps, and exceptional optoelectronic properties. Recent studies have demonstrated that interface charge transfer is a crucial factor in determining the optoelectronic performance of the heterojunction devices. By constructing heterojunctions between MHPs and two-dimensional (2D) materials such as graphene, MoS2, and WS2, efficient electron–hole separation and transport can be achieved, significantly extending carrier lifetimes and suppressing non-radiative recombination. This results in enhanced response speed and energy conversion efficiency in photodetectors, photovoltaic devices, and light-emitting devices (LEDs). In these heterojunctions, the thickness of the MHP layer, interface defect density, and band alignment significantly influence carrier dynamics. Furthermore, techniques such as interface engineering, molecular passivation, and band engineering can effectively optimize charge separation efficiency and improve device stability. The integration of multilayer heterojunctions and flexible designs also presents new opportunities for expanding the functionality of high-performance optoelectronic devices. In this review, we systematically summarize the charge transfer mechanisms in MHP-based heterojunctions and highlight recent advances in their optoelectronic applications. Particular emphasis is placed on the influence of interfacial coupling on carrier generation, transport, and recombination dynamics. Furthermore, the ultrafast dynamic behaviors and band-engineering strategies in representative heterojunctions are elaborated, together with key factors and approaches for enhancing charge transfer efficiency. Finally, the potential of MHP heterojunctions for high-performance optoelectronic devices and emerging photonic systems is discussed. This review aims to provide a comprehensive theoretical and experimental reference for future research and to offer new insights into the rational design and application of flexible optoelectronics, photovoltaics, light-emitting devices, and quantum photonic technologies. Full article
(This article belongs to the Section Energy Materials)
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22 pages, 4062 KB  
Article
Laser Truncation of Silicon Nanowires Fabricated by Ag-Assisted Chemical Etching for Reliable Electrode Deposition in Solar Cells
by Grażyna Kulesza-Matlak, Ewa Sarna, Tomasz Kukulski, Anna Sypień, Mariusz Kuglarz and Kazimierz Drabczyk
Appl. Sci. 2025, 15(24), 12873; https://doi.org/10.3390/app152412873 - 5 Dec 2025
Viewed by 757
Abstract
Silicon nanowires (SiNWs) fabricated by Ag-assisted metal-assisted chemical etching (MACE) exhibit excellent light-trapping performance, yet their fragile high-aspect-ratio morphology severely limits reliable metallization in photovoltaic devices. Conventional electrode deposition methods often fail on dense SiNW arrays due to poor mechanical stability of the [...] Read more.
Silicon nanowires (SiNWs) fabricated by Ag-assisted metal-assisted chemical etching (MACE) exhibit excellent light-trapping performance, yet their fragile high-aspect-ratio morphology severely limits reliable metallization in photovoltaic devices. Conventional electrode deposition methods often fail on dense SiNW arrays due to poor mechanical stability of the nanowire tips, leading to delamination, inhomogeneous coverage, and high contact resistance. In this work, we introduce a maskless laser-based truncation technique that selectively shortens MACE-derived SiNWs to controlled residual heights of 300–500 nm exclusively within the regions intended for electrode formation, while preserving the full nanowire morphology in active areas. A detailed parametric study of laser power, scanning speed, and pulse repetition frequency allowed the identification of an optimal processing window enabling controlled tip melting without damaging the nanowire roots or the crystalline silicon substrate. High-resolution SEM imaging confirms uniform planarization, well-preserved structural integrity, and the absence of subsurface defects in the laser-processed tracks. Optical reflectance measurements further demonstrate that introducing 2% and 5% truncated surface fractions—corresponding to the minimum and maximum metallized front-grid coverage in industrial Si solar cells—results in only a minimal reflectance increase, preserving the advantageous the light-trapping behavior of the SiNW texture. The proposed laser truncation approach provides a clean, scalable, and industrially compatible route toward creating electrode-ready surfaces on nanostructured silicon, enabling reliable metallization while maintaining optical performance. This method offers strong potential for integration into silicon photovoltaics, photodetectors, and nanoscale electronic and sensing devices. Full article
(This article belongs to the Special Issue Advances in Manufacturing and Machining Processes)
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