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Keywords = heat flux measurements

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23 pages, 3831 KiB  
Article
Estimating Planetary Boundary Layer Height over Central Amazonia Using Random Forest
by Paulo Renato P. Silva, Rayonil G. Carneiro, Alison O. Moraes, Cleo Quaresma Dias-Junior and Gilberto Fisch
Atmosphere 2025, 16(8), 941; https://doi.org/10.3390/atmos16080941 - 5 Aug 2025
Abstract
This study investigates the use of a Random Forest (RF), an artificial intelligence (AI) model, to estimate the planetary boundary layer height (PBLH) over Central Amazonia from climatic elements data collected during the GoAmazon experiment, held in 2014 and 2015, as it is [...] Read more.
This study investigates the use of a Random Forest (RF), an artificial intelligence (AI) model, to estimate the planetary boundary layer height (PBLH) over Central Amazonia from climatic elements data collected during the GoAmazon experiment, held in 2014 and 2015, as it is a key metric for air quality, weather forecasting, and climate modeling. The novelty of this study lies in estimating PBLH using only surface-based meteorological observations. This approach is validated against remote sensing measurements (e.g., LIDAR, ceilometer, and wind profilers), which are seldom available in the Amazon region. The dataset includes various meteorological features, though substantial missing data for the latent heat flux (LE) and net radiation (Rn) measurements posed challenges. We addressed these gaps through different data-cleaning strategies, such as feature exclusion, row removal, and imputation techniques, assessing their impact on model performance using the Root Mean Square Error (RMSE), Mean Absolute Error (MAE), and r2 metrics. The best-performing strategy achieved an RMSE of 375.9 m. In addition to the RF model, we benchmarked its performance against Linear Regression, Support Vector Regression, LightGBM, XGBoost, and a Deep Neural Network. While all models showed moderate correlation with observed PBLH, the RF model outperformed all others with statistically significant differences confirmed by paired t-tests. SHAP (SHapley Additive exPlanations) values were used to enhance model interpretability, revealing hour of the day, air temperature, and relative humidity as the most influential predictors for PBLH, underscoring their critical role in atmospheric dynamics in Central Amazonia. Despite these optimizations, the model underestimates the PBLH values—by an average of 197 m, particularly in the spring and early summer austral seasons when atmospheric conditions are more variable. These findings emphasize the importance of robust data preprocessing and higtextight the potential of ML models for improving PBLH estimation in data-scarce tropical environments. Full article
(This article belongs to the Special Issue Applications of Artificial Intelligence in Atmospheric Sciences)
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23 pages, 5064 KiB  
Article
Study on Reasonable Well Spacing for Geothermal Development of Sandstone Geothermal Reservoir—A Case Study of Dezhou, Shandong Province, China
by Shuai Liu, Yan Yan, Lanxin Zhang, Weihua Song, Ying Feng, Guanhong Feng and Jingpeng Chen
Energies 2025, 18(15), 4149; https://doi.org/10.3390/en18154149 - 5 Aug 2025
Abstract
Shandong Province is rich in geothermal resources, mainly stored in sandstone reservoirs. The setting of reasonable well spacing in the early stage of large-scale recharge has not attracted enough attention. The problem of small well spacing in geothermal engineering is particularly prominent in [...] Read more.
Shandong Province is rich in geothermal resources, mainly stored in sandstone reservoirs. The setting of reasonable well spacing in the early stage of large-scale recharge has not attracted enough attention. The problem of small well spacing in geothermal engineering is particularly prominent in the sandstone thermal reservoir production area represented by Dezhou. Based on the measured data of temperature, flow, and water level, this paper constructs a typical engineering numerical model by using TOUGH2 software. It is found that when the distance between production and recharge wells is 180 m, the amount of production and recharge is 60 m3/h, and the temperature of reinjection is 30 °C, the temperature of the production well will decrease rapidly after 10 years of production and recharge. In order to solve the problem of thermal breakthrough, three optimization schemes are assumed: reducing the reinjection temperature to reduce the amount of re-injection when the amount of heat is the same, reducing the amount of production and injection when the temperature of production and injection is constant, and stopping production after the temperature of the production well decreases. However, the results show that the three schemes cannot solve the problem of thermal breakthrough or meet production demand. Therefore, it is necessary to set reasonable well spacing. Therefore, based on the strata near the Hydrological Homeland in Decheng District, the reasonable spacing of production and recharge wells is achieved by numerical simulation. Under a volumetric flux scenario ranging from 60 to 80 m3/h, the well spacing should exceed 400 m. For a volumetric flux between 80 and 140 m3/h, it is recommended that the well spacing be greater than 600 m. Full article
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25 pages, 3590 KiB  
Article
Effectiveness of Firefighter Training for Indoor Intervention: Analysis of Temperature Profiles and Extinguishing Effectiveness
by Jan Hora
Fire 2025, 8(8), 304; https://doi.org/10.3390/fire8080304 - 1 Aug 2025
Viewed by 228
Abstract
This study assessed the effectiveness of stress-based cognitive-behavioral training compared to standard training in firefighters, emphasizing their ability to distribute extinguishing water and cool environments evenly during enclosure fires. Experiments took place at the Zbiroh training facility with two firefighter teams (Team A [...] Read more.
This study assessed the effectiveness of stress-based cognitive-behavioral training compared to standard training in firefighters, emphasizing their ability to distribute extinguishing water and cool environments evenly during enclosure fires. Experiments took place at the Zbiroh training facility with two firefighter teams (Team A with stress-based training and Team B with standard training) under realistic conditions. Using 58 thermocouples and 4 radiometers, temperature distribution and radiant heat flux were measured to evaluate water distribution efficiency and cooling performance during interventions. Team A consistently achieved temperature reductions of approximately 320 °C in the upper layers and 250–400 °C in the middle layers, maintaining stable conditions, whereas Team B only achieved partial cooling, with upper-layer temperatures remaining at 750–800 °C. Additionally, Team A recorded lower radiant heat flux densities (e.g., 20.74 kW/m2 at 0°) compared to Team B (21.81 kW/m2), indicating more effective water application and adaptability. The findings confirm that stress-based training enhances firefighters’ operational readiness and their ability to distribute water effectively during interventions. This skill is essential for safer and effective management of indoor fires under extreme conditions. This study supports the inclusion of stress-based and scenario-based training in firefighter education to enhance safety and operational performance. Full article
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27 pages, 10397 KiB  
Article
Methods for Measuring and Computing the Reference Temperature in Newton’s Law of Cooling for External Flows
by James Peck, Tom I-P. Shih, K. Mark Bryden and John M. Crane
Energies 2025, 18(15), 4074; https://doi.org/10.3390/en18154074 - 31 Jul 2025
Viewed by 267
Abstract
Newton’s law of cooling requires a reference temperature (Tref) to define the heat-transfer coefficient (h). For external flows with multiple temperatures in the freestream, obtaining Tref is a challenge. One widely used method, [...] Read more.
Newton’s law of cooling requires a reference temperature (Tref) to define the heat-transfer coefficient (h). For external flows with multiple temperatures in the freestream, obtaining Tref is a challenge. One widely used method, referred to as the adiabatic-wall (AW) method, obtains Tref by requiring the surface of the solid exposed to convective heat transfer to be adiabatic. Another widely used method, referred to as the linear-extrapolation (LE) method, obtains Tref by measuring/computing the heat flux (qs) on the solid surface at two different surface temperatures (Ts) and then linearly extrapolating to qs=0. A third recently developed method, referred to as the state-space (SS) method, obtains Tref by probing the temperature space between the highest and lowest in the flow to account for the effects of Ts or qs on Tref. This study examines the foundation and accuracy of these methods via a test problem involving film cooling of a flat plate where qs switches signs on the plate’s surface. Results obtained show that only the SS method could guarantee a unique and physically meaningful Tref where Ts=Tref on a nonadiabatic surface qs=0. The AW and LE methods both assume Tref to be independent of Ts, which the SS method shows to be incorrect. Though this study also showed the adiabatic-wall temperature, TAW, to be a good approximation of Tref (<10% relative error), huge errors can occur in h about the solid surface where |TsTAW| is near zero because where Ts=TAW, qs0. Full article
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22 pages, 7102 KiB  
Article
Electrolytic Plasma Hardening of 20GL Steel: Thermal Modeling and Experimental Characterization of Surface Modification
by Bauyrzhan Rakhadilov, Rinat Kurmangaliyev, Yerzhan Shayakhmetov, Rinat Kussainov, Almasbek Maulit and Nurlat Kadyrbolat
Appl. Sci. 2025, 15(15), 8288; https://doi.org/10.3390/app15158288 - 25 Jul 2025
Viewed by 125
Abstract
This study investigates the thermal response and surface modification of low-carbon manganese-alloyed 20GL steel during electrolytic plasma hardening. The objective was to evaluate the feasibility of surface hardening 20GL steel—traditionally considered difficult to quench—by combining high-rate surface heating with rapid cooling in an [...] Read more.
This study investigates the thermal response and surface modification of low-carbon manganese-alloyed 20GL steel during electrolytic plasma hardening. The objective was to evaluate the feasibility of surface hardening 20GL steel—traditionally considered difficult to quench—by combining high-rate surface heating with rapid cooling in an electrolyte medium. To achieve this, a transient two-dimensional heat conduction model was developed to simulate temperature evolution in the steel sample under three voltage regimes. The model accounted for dynamic thermal properties and non-linear boundary conditions, focusing on temperature gradients across the thickness. Experimental temperature measurements were obtained using a K-type thermocouple embedded at a depth of 2 mm, with corrections for sensor inertia based on exponential response behavior. A comparison between simulation and experiment was conducted, focusing on peak temperatures, heating and cooling rates, and the effective thermal penetration depth. Microhardness profiling and metallographic examination confirmed surface strengthening and structural refinement, which intensified with increasing voltage. Importantly, the study identified a critical cooling rate threshold of approximately 50 °C/s required to initiate martensitic transformation in 20GL steel. These findings provide a foundation for future optimization of quenching strategies for low-carbon steels by offering insight into the interplay between thermal fluxes, surface kinetics, and process parameters. Full article
(This article belongs to the Section Materials Science and Engineering)
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13 pages, 1895 KiB  
Article
Class-Dependent Solar Flare Effects on Mars’ Upper Atmosphere: MAVEN NGIMS Observations of X8.2 and M6.0 from September 2017
by Junaid Haleem and Shican Qiu
Universe 2025, 11(8), 245; https://doi.org/10.3390/universe11080245 - 25 Jul 2025
Viewed by 249
Abstract
Transient increments of X-ray radiation and extreme ultraviolet (EUV) during solar flares are strong drivers of thermospheric dynamics on Mars, yet their class-dependent impacts remain poorly measured. This work provides the first direct, side-by-side study of Martian thermospheric reactions to flares X8.2 on [...] Read more.
Transient increments of X-ray radiation and extreme ultraviolet (EUV) during solar flares are strong drivers of thermospheric dynamics on Mars, yet their class-dependent impacts remain poorly measured. This work provides the first direct, side-by-side study of Martian thermospheric reactions to flares X8.2 on 10 September 2017 and M6.0 on 17 September 2017. This study shows nonlinear, class-dependent effects, compositional changes, and recovery processes not recorded in previous investigations. Species-specific responses deviated significantly from irradiance proportionality, even though the soft X-ray flux in the X8.2 flare was 13 times greater. Argon (Ar) concentrations rose 3.28× (compared to 1.13× for M6.0), and radiative cooling led CO2 heating to approach a halt at ΔT = +40 K (X8.2) against +19 K (M6.0) at exobase altitudes (196–259 km). N2 showed the largest class difference, where temperatures rose by +126 K (X8.2) instead of +19 K (M6.0), therefore displaying flare-magnitude dependent thermal sensitivity. The 1.95× increase in O concentrations during X8.2 and the subsequent decrease following M6.0 (−39 K cooling) illustrate the contradiction between photochemical production and radiative loss. The O/CO2 ratio at 225 km dropped 46% during X8.2, revealing compositional gradients boosted by flares. Recovery timeframes varied by class; CO2 quickly re-equilibrated because of effective cooling, whereas inert species (Ar, N2) stabilized within 1–2 orbits after M6.0 but needed >10 orbits of the MAVEN satellite after the X8.2 flare. The observations of the X8.2 flare came from the western limb of the Sun, but the M6.0 flare happened on the far side. The CME shock was the primary driver of Mars’ EUV reaction. These findings provide additional information on atmospheric loss and planetary habitability by indicating that Mars’ thermosphere has a saturation threshold where strong flares induce nonlinear energy partitioning that encourages the departure of lighter species. Full article
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29 pages, 6649 KiB  
Article
Optimizing Kang-to-Room Area Ratios for Thermal Comfort in Traditional Chinese Architecture: An Empirical and Simulation-Based Approach
by Ning Li, Zhihua Zhao, Dongxu Wang, Qian Zhang and Lin Li
Buildings 2025, 15(15), 2593; https://doi.org/10.3390/buildings15152593 - 22 Jul 2025
Viewed by 223
Abstract
Traditional Chinese Kang heating systems have been used for over two millennia in northern China, yet their thermal efficiency and optimal design parameters lack scientific validation. This study aims to establish evidence-based guidelines for Kang-to-room area ratios to enhance thermal comfort and energy [...] Read more.
Traditional Chinese Kang heating systems have been used for over two millennia in northern China, yet their thermal efficiency and optimal design parameters lack scientific validation. This study aims to establish evidence-based guidelines for Kang-to-room area ratios to enhance thermal comfort and energy efficiency in rural architecture. We conducted direct measurements in a controlled experimental house (24 m2) in Huludao City, collecting temperature and humidity data from Kang surfaces and interior spaces over five-day periods. A benchmark curve for heat flux density was developed based on specific fuelwood consumption rates (1 kg/m2). TRNSYS simulations were employed to validate experimental data and analyze thermal performance in the historical Qingning Palace (352 m2) at Shenyang Imperial Palace. The benchmark curve demonstrated high accuracy with a Mean Absolute Error of 0.46 °C and Root Mean Square Error of 0.53 °C when compared to measured temperatures over the 48 h validation period; these values are well within acceptable ranges for calibrated thermal models. Simulations revealed optimal thermal comfort conditions when heat dissipation parameters were scaled appropriately for building size. The optimal Kang-to-room area ratio ranges from 0.28 to 0.69, with the existing Qingning Palace ratio (0.34) falling within this range, validating traditional design wisdom. This research provides a scientific foundation for sustainable architectural practices, bridging traditional knowledge with contemporary thermal engineering principles for both heritage preservation and modern rural construction applications. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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21 pages, 5135 KiB  
Article
Assessing the Heat Transfer Modeling Capabilities of CFD Software for Involute-Shaped Plate Research Reactors
by Cezary Bojanowski, Ronja Schönecker, Katarzyna Borowiec, Kaltrina Shehu, Julius Mercz, Frederic Thomas, Yoann Calzavara, Aurelien Bergeron, Prashant Jain, Christian Reiter and Jeremy Licht
Energies 2025, 18(14), 3692; https://doi.org/10.3390/en18143692 - 12 Jul 2025
Viewed by 348
Abstract
The ongoing efforts to convert High-Performance Research Reactors (HPRRs) using Highly Enriched Uranium (HEU) to Low-Enriched Uranium (LEU) fuel require reliable thermal–hydraulic assessments of modified core designs. The involute-shaped fuel plates used in several major HPRRs present unique modeling challenges due to their [...] Read more.
The ongoing efforts to convert High-Performance Research Reactors (HPRRs) using Highly Enriched Uranium (HEU) to Low-Enriched Uranium (LEU) fuel require reliable thermal–hydraulic assessments of modified core designs. The involute-shaped fuel plates used in several major HPRRs present unique modeling challenges due to their compact core geometries and high heat flux conditions. This study evaluates the capability of three commercial CFD tools, STAR-CCM+, COMSOL, and ANSYS CFX, to predict cladding-to-coolant heat transfer using Reynolds-Averaged Navier–Stokes (RANS) methods within the thermal–hydraulic regimes of involute-shaped plate reactors. Broad sensitivity analysis was conducted across a range of reactor-relevant parameters using two turbulence models (kϵ and kω SST) and different near-wall treatment strategies. The results were benchmarked against the Sieder–Tate correlation and experimental data from historic studies. The codes produced consistent results, showing good agreement with the empirical correlation of Sieder–Tate and the experimental measurements. The findings support the use of these commercial CFD codes as effective tools for assessing the thermal–hydraulic performance of involute-shaped plate HPRRs and guide future LEU core development. Full article
(This article belongs to the Section B4: Nuclear Energy)
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20 pages, 3918 KiB  
Article
Crop Evapotranspiration Dynamics in Morocco’s Climate-Vulnerable Saiss Plain
by Abdellah Oumou, Ali Essahlaoui, Mohammed El Hafyani, Abdennabi Alitane, Narjisse Essahlaoui, Abdelali Khrabcha, Ann Van Griensven, Anton Van Rompaey and Anne Gobin
Remote Sens. 2025, 17(14), 2412; https://doi.org/10.3390/rs17142412 - 12 Jul 2025
Viewed by 703
Abstract
The Saiss plain in northern Morocco covers an area of 2300 km2 and is one of the main agricultural contributors to the national economy. However, climate change and water scarcity reduce the region’s agricultural yields. Conventional methods of estimating evapotranspiration (ET) provide [...] Read more.
The Saiss plain in northern Morocco covers an area of 2300 km2 and is one of the main agricultural contributors to the national economy. However, climate change and water scarcity reduce the region’s agricultural yields. Conventional methods of estimating evapotranspiration (ET) provide localized results but cannot capture regional-scale variations. This study aims to estimate the spatiotemporal evolution of daily crop ET (olives, fruit trees, cereals, and vegetables) across the Saiss plain. The METRIC model was adapted for the region using Landsat 8 data and was calibrated and validated using in situ flux tower measurements. The methodology employed an energy balance approach to calculate ET as a residual of net radiation, soil heat flux, and sensible heat flux by using hot and cold pixels for calibration. METRIC-ET ranged from 0.1 to 11 mm/day, demonstrating strong agreement with reference ET (R2 = 0.76, RMSE = 1, MAE = 0.78) and outperforming MODIS-ET in accuracy and spatial resolution. Olives and fruit trees showed higher ET values compared to vegetables and cereals. The results indicated a significant impact of ET on water availability, with spatiotemporal patterns being influenced by vegetation cover, climate, and water resources. This study could support the development of adaptive agricultural strategies. Full article
(This article belongs to the Section Remote Sensing in Agriculture and Vegetation)
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15 pages, 4738 KiB  
Article
Mechanical Performance of Ceria-Coated 3D-Printed Black Zirconia Cellular Structures After Solar Thermochemical CO/H2 Fuel Production Cycles
by Fernando A. Costa Oliveira, Manuel Sardinha, Joaquim M. Justino Netto, Miguel Farinha, Marco Leite, M. Alexandra Barreiros, Stéphane Abanades and Jorge Cruz Fernandes
Crystals 2025, 15(7), 629; https://doi.org/10.3390/cryst15070629 - 8 Jul 2025
Viewed by 359
Abstract
Solar fuels production requires developing redox active materials with porous structures able to withstand thermochemical cycles with enhanced thermal stability under concentrated solar irradiation conditions. The mechanical performance of 3D-printed, macroporous black zirconia gyroid structures, coated with redox-active ceria, was assessed for their [...] Read more.
Solar fuels production requires developing redox active materials with porous structures able to withstand thermochemical cycles with enhanced thermal stability under concentrated solar irradiation conditions. The mechanical performance of 3D-printed, macroporous black zirconia gyroid structures, coated with redox-active ceria, was assessed for their suitability in solar thermochemical cycles for CO2 and H2O splitting. Experiments were conducted using a 1.5 kW solar furnace to supply the high-temperature concentrated heat to a windowed reaction chamber to carry out thermal redox cycling under realistic on-sun conditions. The ceria coating on ceramic structures improved the thermal stability and redox efficiency while minimizing the quantity of the redox material involved. Crushing strength measurements showed that samples not directly exposed to the concentrated solar flux retained their mechanical performance after thermal cycling (~10 MPa), while those near the concentrated solar beam focus exhibited significant degradation due to thermal stresses and the formation of CexZr1−xO2 solid solutions (~1.5 MPa). A Weibull modulus of 8.5 was estimated, marking the first report of such a parameter for fused filament fabrication (FFF)-manufactured black zirconia with gyroid architecture. Failure occurred via a damage accumulation mechanism at both micro- and macro-scales. These findings support the viability of ceria-coated cellular ceramics for scalable solar fuel production and highlight the need for optimized reactor designs. Full article
(This article belongs to the Section Materials for Energy Applications)
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51 pages, 5106 KiB  
Article
Evaluating Solar Energy Potential Through Clear Sky Index Characterization Across Elevation Profiles in Mozambique
by Fernando Venâncio Mucomole, Carlos Augusto Santos Silva and Lourenço Lázaro Magaia
Solar 2025, 5(3), 30; https://doi.org/10.3390/solar5030030 - 1 Jul 2025
Viewed by 394
Abstract
The characteristics and types of the sky can greatly influence photovoltaic (PV) power generation, potentially leading to a reduction in both the lifespan and efficiency of the entire system. Driven by the challenge of addressing fluctuations in solar PV energy utilization, the aim [...] Read more.
The characteristics and types of the sky can greatly influence photovoltaic (PV) power generation, potentially leading to a reduction in both the lifespan and efficiency of the entire system. Driven by the challenge of addressing fluctuations in solar PV energy utilization, the aim was to assess the solar energy potential by analyzing the clear sky index Kt* across elevation profiles. To achieve this, a theoretical model for determining Kt* was employed, which encapsulated the solar energy analysis. Initially, solar energy data collected from approximately 16 stations in various provinces of Mozambique, as part of the solar energy measurement initiatives by INAM, FUNAE, AERONET, and Meteonorm, was processed. Subsequently, the clear sky radiation was calculated, and Kt* was established. The statistical findings indicate a reduction in energy contribution from the predictors, accounting for 28% of the total incident energy; however, there are progressive increases averaging around ~0.02, with Kt* values ranging from 0.4 to 0.9, demonstrating a strong correlation between 0.7 and 0.9 across several stations and predictor parameters. No significant climate change effects were noted. The radiation flux is directed from areas with higher Kt* to those with lower values, as illustrated in the heat map. The region experiences an increase in atmospheric parameter deposition, with concentrations around ~0.20, yet there remains a substantial energy flow potential of 92% for PV applications. This interaction can also be applied in other locations to assess the potential for available solar energy, as the analyzed solar energy spectrum aligns closely with the theoretical statistical calibration of energy distribution relevant to the global solar energy population process. Full article
(This article belongs to the Topic Solar Forecasting and Smart Photovoltaic Systems)
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34 pages, 3719 KiB  
Article
Experimental and Numerical Study of Film Boiling Around a Small Nickel Sphere
by Charles Brissot, Léa Cailly-Brandstäter, Romain Castellani, Elie Hachem and Rudy Valette
Fluids 2025, 10(7), 162; https://doi.org/10.3390/fluids10070162 - 24 Jun 2025
Viewed by 246
Abstract
This work—mixing an original experimental approach, as well as numerical simulations—proposes to study film boiling modes around a small nickel sphere. While dealing with a simple looking phenomenon that is found in many industrial processes and has been solved for basic quenching regimes, [...] Read more.
This work—mixing an original experimental approach, as well as numerical simulations—proposes to study film boiling modes around a small nickel sphere. While dealing with a simple looking phenomenon that is found in many industrial processes and has been solved for basic quenching regimes, we focus on describing precisely how vapor formation and film thicknesses, as well as vapor bubble evacuation, affect cooling kinetics. As instrumenting small spheres may lead to experimental inaccuracies, we optically captured, using a high-speed camera, the vapor film thickness at mid height, the vapor bubble volume, and the bubble detachment frequency, along with the heat flux. More precisely, an estimation of the instant sphere temperature, in different conditions, was obtained through cooling time measurement before the end of the film boiling mode, subsequently facilitating heat flux evaluation. We encountered a nearly linear decrease in both the vapor film thickness and vapor bubble volume as the sphere temperature decreased. Notably, the detachment frequency remained constant across the whole temperature range. The estimation of the heat fluxes confirmed the prevalence of conduction as the primary heat transfer mode; a major portion of the energy was spent increasing the liquid temperature. The results were then compared to finite element simulations using an in-house multiphysics solver, including thermic phase changes (liquid to vapor) and their hydrodynamics, and we also captured the interfaces. While presenting a challenge due to the contrast in densities and viscosities between phases, the importance of the small circulations along them, which improve the heat removal in the liquid phase, was highlighted; we also assessed the suitability of the model and the numerical code for the simulation of such quenching cases when subcooling in the vicinity of a saturation temperature. Full article
(This article belongs to the Section Heat and Mass Transfer)
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16 pages, 3301 KiB  
Article
Crystal Chemistry and Thermodynamic Properties of Mineralogically Probable Phosphate Ca2.62Cu1.94Co1.44(PO4)4—Structurally Related to Natural Arsenate Zubkovaite
by Olga Yakubovich, Galina Kiriukhina, Larisa Shvanskaya and Alexander Vasiliev
Minerals 2025, 15(6), 645; https://doi.org/10.3390/min15060645 - 13 Jun 2025
Viewed by 339
Abstract
In this paper, we report the details of the synthesis, single crystal X-ray diffraction study, comparative crystal chemical analysis, and magnetic behavior of a new phosphate variation of the arsenate mineral zubkovaite. The title compound was obtained as a high-temperature flux product in [...] Read more.
In this paper, we report the details of the synthesis, single crystal X-ray diffraction study, comparative crystal chemical analysis, and magnetic behavior of a new phosphate variation of the arsenate mineral zubkovaite. The title compound was obtained as a high-temperature flux product in the form of a partly ordered solid solution and was studied using scanning electron microscopy and microprobe analysis. It possesses a monoclinic symmetry with a P21/n space group; the unit cell parameters are a = 8.8040 (2), b = 4.8970 (1), c = 14.5772 (3), and β = 93.993(2)°. The Ca2.62Cu1.94Co1.44(PO4)4 crystal structure exhibits some statistical disorder. Our refinement showed that two positions are mixed, being occupied by Cu/Co (M1) and Ca/Co (M2) atoms. Two types of layers that are nearly parallel to the (101) plane can be distinguished in the structure. One of them is built by sharing corners of CuO4 squares, M1O5 square pyramids, and PO4 tetrahedra. The second type of layer formed from Ca2+- and M2+-centered polyhedra alternates in the [1¯01] direction to construct a tri-periodic framework. Ca2.62Cu1.94Co1.44(PO4)4 experiences long-range antiferromagnetic ordering at low temperatures, as evidenced by both dc— and ac—magnetic susceptibilities, as well as by the specific heat measurements. Full article
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19 pages, 4283 KiB  
Article
Simulating Energy Balance Dynamics to Support Sustainability in a Seasonally Dry Tropical Forest in Semi-Arid Northeast Brazil
by Rosaria R. Ferreira, Keila R. Mendes, Pablo E. S. Oliveira, Pedro R. Mutti, Demerval S. Moreira, Antonio C. D. Antonino, Rômulo S. C. Menezes, José Romualdo S. Lima, João M. Araújo, Valéria L. Amorim, Nikolai S. Espinoza, Bergson G. Bezerra, Cláudio M. Santos e Silva and Gabriel B. Costa
Sustainability 2025, 17(12), 5350; https://doi.org/10.3390/su17125350 - 10 Jun 2025
Cited by 1 | Viewed by 543
Abstract
In semi-arid regions, seasonally dry tropical forests are essential for regulating the surface energy balance, which can be analyzed by examining air heating processes and water availability control. The objective of this study was to evaluate the ability of the Brazilian Developments on [...] Read more.
In semi-arid regions, seasonally dry tropical forests are essential for regulating the surface energy balance, which can be analyzed by examining air heating processes and water availability control. The objective of this study was to evaluate the ability of the Brazilian Developments on the Regional Atmospheric Modelling System (BRAMS) model in simulating the seasonal variations of the energy balance components of the Caatinga biome. The surface measurements of meteorological variables, including air temperature and relative humidity, were also examined. To validate the model, we used data collected in situ using an eddy covariance system. In this work, we used the BRAMS model version 5.3 associated with the Joint UK Land Environment Simulator (JULES) version 3.0. The model satisfactorily represented the rainfall regime over the northeast region of Brazil (NEB) during the wet period. In the dry period, however, the coastal rainfall pattern over the NEB region was underestimated. In addition, the results showed that the surface fluxes linked to the energy balance in the Caatinga were impacted by the effects of rainfall seasonality in the region. The assessment of the BRAMS model’s performance demonstrated that it is a reliable tool for studying the dynamics of the dry forest in the region, providing valuable support for sustainable management and conservation efforts. Full article
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23 pages, 5923 KiB  
Article
Sustainable Increase in Thermal Resistance of Window Construction: Experimental Verification and CFD Modelling of the Air Cavity Created by a Shutter
by Borys Basok, Volodymyr Novikov, Anatoliy Pavlenko, Hanna Koshlak, Svitlana Goncharuk, Oleksii Shmatok and Dmytro Davydenko
Materials 2025, 18(12), 2702; https://doi.org/10.3390/ma18122702 - 9 Jun 2025
Viewed by 644
Abstract
This study investigates, both experimentally and theoretically, the impact of incorporating window shutters on the thermal resistance of double-glazed window units, employing computational fluid dynamics (CFD) modelling. The integration of shutters, whether installed internally or externally, introduces an additional air layer that significantly [...] Read more.
This study investigates, both experimentally and theoretically, the impact of incorporating window shutters on the thermal resistance of double-glazed window units, employing computational fluid dynamics (CFD) modelling. The integration of shutters, whether installed internally or externally, introduces an additional air layer that significantly influences heat transfer between indoor and outdoor environments. This effect on the thermal performance of the transparent structure was analysed through experimental measurements under real operating conditions and numerical simulations involving fluid dynamics and energy equations for the air gaps, alongside heat conduction equations for the solid components. Fourth-kind boundary conditions, considering both radiative and conductive components of the total heat flux emanating from the building’s interior, were applied at the solid–gas interfaces. The simulation results, comparing heat transfer through double-glazed windows with and without shutters, demonstrate a substantial increase in thermal resistance, ranging from 2 to 2.5 times, upon shutter implementation. These findings underscore the effectiveness of employing shutters as a strategy to enhance the energy efficiency of windows and, consequently, the overall energy performance of buildings. This research contributes to the advancement of sustainable materials for engineering applications by providing insights into the optimisation of thermal performance in building envelopes. Full article
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