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Keywords = harmonic measurements

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19 pages, 1107 KiB  
Article
A Novel Harmonic Clocking Scheme for Concurrent N-Path Reception in Wireless and GNSS Applications
by Dina Ibrahim, Mohamed Helaoui, Naser El-Sheimy and Fadhel Ghannouchi
Electronics 2025, 14(15), 3091; https://doi.org/10.3390/electronics14153091 (registering DOI) - 1 Aug 2025
Abstract
This paper presents a novel harmonic-selective clocking scheme that facilitates concurrent downconversion of spectrally distant radio frequency (RF) signals using a single low-frequency local oscillator (LO) in an N-path receiver architecture. The proposed scheme selectively generates LO harmonics aligned with multiple RF bands, [...] Read more.
This paper presents a novel harmonic-selective clocking scheme that facilitates concurrent downconversion of spectrally distant radio frequency (RF) signals using a single low-frequency local oscillator (LO) in an N-path receiver architecture. The proposed scheme selectively generates LO harmonics aligned with multiple RF bands, enabling simultaneous downconversion without modification of the passive mixer topology. The receiver employs a 4-path passive mixer configuration to enhance harmonic selectivity and provide flexible frequency planning.The architecture is implemented on a printed circuit board (PCB) and validated through comprehensive simulation and experimental measurements under continuous wave and modulated signal conditions. Measured results demonstrate a sensitivity of 55dBm and a conversion gain varying from 2.5dB to 9dB depending on the selected harmonic pair. The receiver’s performance is further corroborated by concurrent (dual band) reception of real-world signals, including a GPS signal centered at 1575 MHz and an LTE signal at 1179 MHz, both downconverted using a single 393 MHz LO. Signal fidelity is assessed via Normalized Mean Square Error (NMSE) and Error Vector Magnitude (EVM), confirming the proposed architecture’s effectiveness in maintaining high-quality signal reception under concurrent multiband operation. The results highlight the potential of harmonic-selective clocking to simplify multiband receiver design for wireless communication and global navigation satellite system (GNSS) applications. Full article
(This article belongs to the Section Microwave and Wireless Communications)
23 pages, 3453 KiB  
Article
Robust Peak Detection Techniques for Harmonic FMCW Radar Systems: Algorithmic Comparison and FPGA Feasibility Under Phase Noise
by Ahmed El-Awamry, Feng Zheng, Thomas Kaiser and Maher Khaliel
Signals 2025, 6(3), 36; https://doi.org/10.3390/signals6030036 - 30 Jul 2025
Viewed by 199
Abstract
Accurate peak detection in the frequency domain is fundamental to reliable range estimation in Frequency-Modulated Continuous-Wave (FMCW) radar systems, particularly in challenging conditions characterized by a low signal-to-noise ratio (SNR) and phase noise impairments. This paper presents a comprehensive comparative analysis of five [...] Read more.
Accurate peak detection in the frequency domain is fundamental to reliable range estimation in Frequency-Modulated Continuous-Wave (FMCW) radar systems, particularly in challenging conditions characterized by a low signal-to-noise ratio (SNR) and phase noise impairments. This paper presents a comprehensive comparative analysis of five peak detection algorithms: FFT thresholding, Cell-Averaging Constant False Alarm Rate (CA-CFAR), a simplified Matrix Pencil Method (MPM), SVD-based detection, and a novel Learned Thresholded Subspace Projection (LTSP) approach. The proposed LTSP method leverages singular value decomposition (SVD) to extract the dominant signal subspace, followed by signal reconstruction and spectral peak analysis, enabling robust detection in noisy and spectrally distorted environments. Each technique was analytically modeled and extensively evaluated through Monte Carlo simulations across a wide range of SNRs and oscillator phase noise levels, from 100 dBc/Hz to 70 dBc/Hz. Additionally, real-world validation was performed using a custom-built harmonic FMCW radar prototype operating in the 2.4–2.5 GHz transmission band and 4.8–5.0 GHz harmonic reception band. Results show that CA-CFAR offers the highest resilience to phase noise, while the proposed LTSP method delivers competitive detection performance with improved robustness over conventional FFT and MPM techniques. Furthermore, the hardware feasibility of each algorithm is assessed for implementation on a Xilinx FPGA platform, highlighting practical trade-offs between detection performance, computational complexity, and resource utilization. These findings provide valuable guidance for the design of real-time, embedded FMCW radar systems operating under adverse conditions. Full article
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13 pages, 1132 KiB  
Review
M-Edge Spectroscopy of Transition Metals: Principles, Advances, and Applications
by Rishu Khurana and Cong Liu
Catalysts 2025, 15(8), 722; https://doi.org/10.3390/catal15080722 - 30 Jul 2025
Viewed by 277
Abstract
M-edge X-ray absorption spectroscopy (XAS), which probes 3p→3d transitions in first-row transition metals, provides detailed insights into oxidation states, spin-states, and local electronic structure with high element and orbital specificity. Operating in the extreme ultraviolet (XUV) region, this technique provides [...] Read more.
M-edge X-ray absorption spectroscopy (XAS), which probes 3p→3d transitions in first-row transition metals, provides detailed insights into oxidation states, spin-states, and local electronic structure with high element and orbital specificity. Operating in the extreme ultraviolet (XUV) region, this technique provides sharp multiplet-resolved features with high sensitivity to ligand field and covalency effects. Compared to K- and L-edge XAS, M-edge spectra exhibit significantly narrower full widths at half maximum (typically 0.3–0.5 eV versus >1 eV at the L-edge and >1.5–2 eV at the K-edge), owing to longer 3p core-hole lifetimes. M-edge measurements are also more surface-sensitive due to the lower photon energy range, making them particularly well-suited for probing thin films, interfaces, and surface-bound species. The advent of tabletop high-harmonic generation (HHG) sources has enabled femtosecond time-resolved M-edge measurements, allowing direct observation of ultrafast photoinduced processes such as charge transfer and spin crossover dynamics. This review presents an overview of the fundamental principles, experimental advances, and current theoretical approaches for interpreting M-edge spectra. We further discuss a range of applications in catalysis, materials science, and coordination chemistry, highlighting the technique’s growing impact and potential for future studies. Full article
(This article belongs to the Special Issue Spectroscopy in Modern Materials Science and Catalysis)
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16 pages, 2562 KiB  
Article
Harmonic and Interharmonic Measurement Method Using Two-Fold Compound Convolution Windows and Zoom Fast Fourier Transform
by Xiangui Xiao, Lei Zhao, Shengjun Zhou, Haijun Liu, Zhong Fu and Dan Hu
Energies 2025, 18(15), 4047; https://doi.org/10.3390/en18154047 - 30 Jul 2025
Viewed by 162
Abstract
With the rapidly increasing penetration of new energy resources, the power grid faces significant threats from harmonics. To measure and suppress these harmonics, numerous harmonic measurement methods have been proposed. However, accurately identifying the parameters of harmonics and interharmonics remains challenging. To address [...] Read more.
With the rapidly increasing penetration of new energy resources, the power grid faces significant threats from harmonics. To measure and suppress these harmonics, numerous harmonic measurement methods have been proposed. However, accurately identifying the parameters of harmonics and interharmonics remains challenging. To address this issue, we propose a new method that combines two-fold convolution windows and ZoomFFT. This method leverages the advantages of low side lobe peaks and high side lobe attenuation rates of compound convolution windows to suppress spectral leakage. Additionally, a six-spectral-line interpolation method is employed to correct the calculation results. Furthermore, ZoomFFT is utilized to locally amplify the spectrum, enabling the distinction between interharmonics and harmonics with closely spaced frequencies. The simulation results demonstrate that the proposed algorithm effectively identifies interharmonics with similar frequencies, outperforming single-window functions and ZoomFFT in terms of accuracy. Full article
(This article belongs to the Section F: Electrical Engineering)
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23 pages, 11587 KiB  
Article
Robust Sensorless Active Damping of LCL Resonance in EV Battery Grid-Tied Converters Using μ-Synthesis Control
by Nabeel Khan, Wang Cheng, Muhammad Yasir Ali Khan and Danish Khan
World Electr. Veh. J. 2025, 16(8), 422; https://doi.org/10.3390/wevj16080422 - 27 Jul 2025
Viewed by 220
Abstract
LCL (inductor–capacitor–inductor) filters are widely used in grid-connected inverters, particularly in electric vehicle (EV) battery-to-grid systems, for harmonic suppression but introduce resonance issues that compromise stability. This study presents a novel sensorless active damping strategy based on μ-synthesis control for EV batteries connected [...] Read more.
LCL (inductor–capacitor–inductor) filters are widely used in grid-connected inverters, particularly in electric vehicle (EV) battery-to-grid systems, for harmonic suppression but introduce resonance issues that compromise stability. This study presents a novel sensorless active damping strategy based on μ-synthesis control for EV batteries connected to the grid via LCL filters, eliminating the need for additional current sensors while preserving harmonic attenuation. A comprehensive state–space and process noise model enables accurate capacitor current estimation using only grid current and point-of-common-coupling (PCC) voltage measurements. The proposed method maintains robust performance under ±60% LCL parameter variations and integrates a proportional-resonant (PR) current controller for resonance suppression. Hardware-in-the-loop (HIL) validation demonstrates enhanced stability in dynamic grid conditions, with total harmonic distortion (THD) below 5% (IEEE 1547-compliant) and current tracking error < 0.06 A. Full article
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20 pages, 7725 KiB  
Article
Harmonic Distortion Peculiarities of High-Frequency SiGe HBT Power Cells for Radar Front End and Wireless Communication
by Paulius Sakalas and Anindya Mukherjee
Electronics 2025, 14(15), 2984; https://doi.org/10.3390/electronics14152984 - 26 Jul 2025
Viewed by 236
Abstract
High-frequency (h. f.) harmonic distortion (HD) of advanced SiGe heterojunction bipolar transistor (HBT)-based power cells (PwCs), featuring optimized metallization interconnections between individual HBTs, was investigated. Single tone input power (Pin) excitations at 1, 2, 5, and 10 GHz frequencies were [...] Read more.
High-frequency (h. f.) harmonic distortion (HD) of advanced SiGe heterojunction bipolar transistor (HBT)-based power cells (PwCs), featuring optimized metallization interconnections between individual HBTs, was investigated. Single tone input power (Pin) excitations at 1, 2, 5, and 10 GHz frequencies were employed. The output power (Pout) of the fundamental tone and its harmonics were analyzed in both the frequency and time domains. A rapid increase in the third harmonic of Pout was observed at input powers exceeding −8 dBm for a fundamental frequency of 10 GHz in two different PwC technologies. This increase in the third harmonic was analyzed in terms of nonlinear current waveforms, the nonlinearity of the HBT p-n junction diffusion capacitances, substrate current behavior versus Pin, and avalanche multiplication current. To assess the RF power performance of the PwCs, scalar and vectorial load-pull (LP) measurements were conducted and analyzed. Under matched conditions, the SiGe PwCs demonstrated good linearity, particularly at high frequencies. The key power performance of the PwCs was measured and simulated as follows: input power 1 dB compression point (Pin_1dB) of −3 dBm, transducer power gain (GT) of 15 dB, and power added efficiency (PAE) of 50% at 30 GHz. All measured data were corroborated with simulations using the compact model HiCuM L2. Full article
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20 pages, 2792 KiB  
Article
Capturing High-Frequency Harmonic Signatures for NILM: Building a Dataset for Load Disaggregation
by Farid Dinar, Sébastien Paris and Éric Busvelle
Sensors 2025, 25(15), 4601; https://doi.org/10.3390/s25154601 - 25 Jul 2025
Viewed by 245
Abstract
Advanced Non-Intrusive Load Monitoring (NILM) research is important to help reduce energy consumption. Very-low-frequency approaches have traditionally faced challenges in separating appliance uses due to low discriminative information. The richer signatures available in high-frequency electrical data include many harmonic orders that have the [...] Read more.
Advanced Non-Intrusive Load Monitoring (NILM) research is important to help reduce energy consumption. Very-low-frequency approaches have traditionally faced challenges in separating appliance uses due to low discriminative information. The richer signatures available in high-frequency electrical data include many harmonic orders that have the potential to advance disaggregation. This has been explored to some extent, but not comprehensively due to a lack of an appropriate public dataset. This paper presents the development of a cost-effective energy monitoring system scalable for multiple entries while producing detailed measurements. We will detail our approach to creating a NILM dataset comprising both aggregate loads and individual appliance measurements, all while ensuring that the dataset is reproducible and accessible. Ultimately, the dataset can be used to validate NILM, and we show through the use of machine learning techniques that high-frequency features improve disaggregation accuracy when compared with traditional methods. This work addresses a critical gap in NILM research by detailing the design and implementation of a data acquisition system capable of generating rich and structured datasets that support precise energy consumption analysis and prepare the essential materials for advanced, real-time energy disaggregation and smart energy management applications. Full article
(This article belongs to the Section Intelligent Sensors)
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39 pages, 13464 KiB  
Article
Micro-Doppler Signal Features of Idling Vehicle Vibrations: Dependence on Gear Engagements and Occupancy
by Ram M. Narayanan, Benjamin D. Simone, Daniel K. Watson, Karl M. Reichard and Kyle A. Gallagher
Signals 2025, 6(3), 35; https://doi.org/10.3390/signals6030035 - 24 Jul 2025
Viewed by 338
Abstract
This study investigates the use of a custom-built 10 GHz continuous wave micro-Doppler radar system to analyze external vibrations of idling vehicles under various conditions. Scenarios included different gear engagements with one occupant and parked gear with up to four occupants. Motivated by [...] Read more.
This study investigates the use of a custom-built 10 GHz continuous wave micro-Doppler radar system to analyze external vibrations of idling vehicles under various conditions. Scenarios included different gear engagements with one occupant and parked gear with up to four occupants. Motivated by security concerns, such as the threat posed by idling vehicles with multiple occupants, the research explores how micro-Doppler signatures can indicate vehicle readiness to move. Experiments focused on a mid-size SUV, with similar trends seen in other vehicles. Radar data were compared to in situ accelerometer measurements, confirming that the radar system can detect subtle frequency changes, especially during gear shifts. The system’s sensitivity enables it to distinguish variations tied to gear state and passenger load. Extracted features like frequency and magnitude show strong potential for use in machine learning models, offering a non-invasive, remote sensing method for reliably identifying vehicle operational states and occupancy levels in security or monitoring contexts. Spectrogram and PSD analyses reveal consistent tonal vibrations around 30 Hz, tied to engine activity, with harmonics at 60 Hz and 90 Hz. Gear shifts produce impulse signatures primarily below 20 Hz, and transient data show distinct peaks at 50, 80, and 100 Hz. Key features at 23 Hz and 45 Hz effectively indicate engine and gear states. Radar and accelerometer data align well, supporting the potential for remote sensing and machine learning-based classification. Full article
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25 pages, 2495 KiB  
Article
Integration Strategies for Large-Scale Renewable Interconnections with Grid Forming and Grid Following Inverters, Capacitor Banks, and Harmonic Filters
by Soham Ghosh, Arpit Bohra, Sreejata Dutta and Saurav Verma
Energies 2025, 18(15), 3934; https://doi.org/10.3390/en18153934 - 23 Jul 2025
Viewed by 218
Abstract
The transition towards a power system characterized by a reduced presence of synchronous generators (SGs) and an increased reliance on inverter-based resources (IBRs), including wind, solar photovoltaics (PV), and battery storage, presents new operational challenges, particularly when these sources exceed 50–60% of the [...] Read more.
The transition towards a power system characterized by a reduced presence of synchronous generators (SGs) and an increased reliance on inverter-based resources (IBRs), including wind, solar photovoltaics (PV), and battery storage, presents new operational challenges, particularly when these sources exceed 50–60% of the system’s demand. While current grid-following (GFL) IBRs, which are equipped with fast and rigid control systems, continue to dominate the inverter landscape, there has been a notable surge in research focused on grid-forming (GFM) inverters in recent years. This study conducts a comparative analysis of the practicality and control methodologies of GFM inverters relative to traditional GFL inverters from a system planning perspective. A comprehensive framework aimed at assisting system developers and consulting engineers in the grid-integration of wide-scale renewable energy sources (RESs), incorporating strategies for the deployment of inverters, capacitor banks, and harmonic filters, is proposed in this paper. The discussion includes an examination of the reactive power capabilities of the plant’s inverters and the provision of additional reactive power to ensure compliance with grid interconnection standards. Furthermore, the paper outlines a practical approach to assess the necessity for enhanced filtering measures to mitigate potential resonant conditions and achieve harmonic compliance at the installation site. The objective of this work is to offer useful guidelines and insights for the effective addition of RES into contemporary power systems. Full article
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24 pages, 9734 KiB  
Article
Investigating the Influence of PWM-Driven Cascaded H-Bridges Multilevel Inverter on Interior Permanent Magnet Synchronous Motor Power Losses
by Claudio Nevoloso, Gioacchino Scaglione, Giuseppe Schettino, Antonino Oscar Di Tommaso, Fabio Viola, Ciro Spataro and Rosario Miceli
Energies 2025, 18(15), 3911; https://doi.org/10.3390/en18153911 - 22 Jul 2025
Viewed by 240
Abstract
This paper presents an accurate analysis of the power losses of an interior permanent magnet synchronous motor fed by a cascaded H-bridge multilevel inverter. The main goal of this study is to investigate the impact of the cascaded h-bridge inverter, multicarrier PWM strategies, [...] Read more.
This paper presents an accurate analysis of the power losses of an interior permanent magnet synchronous motor fed by a cascaded H-bridge multilevel inverter. The main goal of this study is to investigate the impact of the cascaded h-bridge inverter, multicarrier PWM strategies, and inverter switching frequency on the synchronous motor power losses. With this aim in mind, a detailed frequency domain power analysis was carried out on motor power losses at different operating points in the frequency–torque plane. Motor power losses were further categorized into fundamental and harmonic power losses. This evaluation involved driving the power converter using six distinct multicarrier PWM strategies at four different switching frequencies. Additionally, a comparison was conducted with a conventional two-level PWM inverter to quantify the reduction in motor power losses. The experimental results show that the cascaded h-bridge inverter guarantees a notable increase in the motor efficiency, up to 7%, and losses in segregation at the fundamental frequency, if compared to the standard two-level PWM inverter, especially at low speed and with partial-load conditions. Such results mark out the cascaded H-bridge inverter as a valuable choice, also with regard to low-voltage drive applications. Full article
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26 pages, 55836 KiB  
Article
Experimental Acoustic Investigation of Rotor Noise Directivity and Decay in Multiple Configurations
by Giovanni Fasulo, Giosuè Longobardo, Fabrizio De Gregorio and Mattia Barbarino
Aerospace 2025, 12(7), 647; https://doi.org/10.3390/aerospace12070647 - 21 Jul 2025
Viewed by 235
Abstract
In the framework of the MATIM project, an acoustic test campaign was conducted on a platform derived from a commercial-class quadcopter within the CIRA semi-anechoic chamber. A dedicated rotor rig allowed systematic measurements of thrust, torque, and shaft speed together with near- and [...] Read more.
In the framework of the MATIM project, an acoustic test campaign was conducted on a platform derived from a commercial-class quadcopter within the CIRA semi-anechoic chamber. A dedicated rotor rig allowed systematic measurements of thrust, torque, and shaft speed together with near- and far-field noise using ten calibrated 1/2-inch precision microphones. Three configurations were examined: an isolated rotor, the same rotor mounted on an aluminium quadcopter plate, and the full four-rotor assembly. The resulting data set, acquired over 3000–8000 rpm, documents the azimuthal directivity and radial decay of tonal and broadband noise while separating motor, propeller, and installation contributions. Analysis shows that a nearby rigid plate scatters part of the sound field towards frontal and oblique observers and produces a shielding effect in the rotor plane. The combined operation of four rotors further redistributes energy and broadens blade-passing frequency harmonics. The database is intended as a benchmark for aeroacoustics codes and for the development of reduced-order models. Full article
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22 pages, 10293 KiB  
Article
Inter-Turn Short Circuits in Stator Winding of Permanent Magnet Synchronous Generator Dedicated for Small Hydroelectric Power Plants
by Adam Gozdowiak and Maciej Antal
Energies 2025, 18(14), 3799; https://doi.org/10.3390/en18143799 - 17 Jul 2025
Viewed by 176
Abstract
This article presents the simulation results of inter-turn short circuits in the stator winding of a permanent magnet synchronous generator (PMSG) dedicated for small hydroelectric power plants. During the calculations, a field–circuit model is used via ANSYS software. The simulations were performed for [...] Read more.
This article presents the simulation results of inter-turn short circuits in the stator winding of a permanent magnet synchronous generator (PMSG) dedicated for small hydroelectric power plants. During the calculations, a field–circuit model is used via ANSYS software. The simulations were performed for both a fault-free generator and faulty generator with various degrees of short-circuited turns under various operating conditions. The degree of stator winding damage is modeled by changing the number of shorted turns in one phase. The studied generator has a two-layer stator winding made of winding wire. In addition, it is made of three parallel branches. In this way, a more difficult-to-detect condition is simulated. We analyzed the influences of short-circuit fault on the magnetic field and their impact on generator behavior. The analysis of the obtained results indicates the possibility of using the measurement of the stator current histogram, higher-order harmonics of the stator current, back electromotive force (back EMF), phase current growth, and power factor fluctuations for early detection of an inter-turn short circuit. Full article
(This article belongs to the Section F: Electrical Engineering)
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37 pages, 397 KiB  
Article
Food Safety in the European Union: A Comparative Assessment Based on RASFF Notifications, Pesticide Residues, and Food Waste Indicators
by Radosław Wolniak and Wiesław Wes Grebski
Foods 2025, 14(14), 2501; https://doi.org/10.3390/foods14142501 - 17 Jul 2025
Viewed by 537
Abstract
Guaranteeing food safety in the European Union (EU) is a continuing issue affected by diverse national traditions, regulatory power, and consumer culture. Despite the presence of a harmonized regulatory context, there continues to be variability in performance among the 27 member states. This [...] Read more.
Guaranteeing food safety in the European Union (EU) is a continuing issue affected by diverse national traditions, regulatory power, and consumer culture. Despite the presence of a harmonized regulatory context, there continues to be variability in performance among the 27 member states. This study gives an extensive comparative evaluation of EU food safety based on three indicators: Rapid Alert System for Food and Feed (RASFF) alerts, pesticide maximum-residue-limit (MRL) violation, and per capita food loss. Fuzzy TOPSIS, K-means clustering, and scenario-based sensitivity tests are used to give an extensive appraisal of the performance of member states. Alarming differences are quoted as findings of significance. The highest number of RASFF notifications (212) and percentage of pesticide MRL non-compliance (1.5%) were reported in 2022 by Bulgaria, whereas the lowest values were reported by Estonia and Lithuania—15–20 RASFF notifications and less than 0.6% MRL violation rates. A statistically significant correlation (r = 0.72, p < 0.001) between pesticide MRL violation and food safety warnings was confirmed in favor of pesticide regulation as the optimal predictor of food safety warnings. On the other hand, food loss did not significantly affect safety measures but indicated very high variation (from 76 kg/capita per year in Croatia to 142 kg/capita per year in Greece). These findings suggest that while food loss remains an environmental problem, pesticide control is more central to the protection of food safety. Targeted policy is what the research necessitates: intervention and stricter enforcement in low-income countries, and diffusion of best practice from successful states. The composite approach adds to EU food safety policy discourse through the combination of performance indicators and targeted regulatory emphasis. Full article
(This article belongs to the Section Food Quality and Safety)
32 pages, 2160 KiB  
Article
Green Finance for Green Land: Coupling Economic and Ecological Systems Through Financial Innovation
by Fengchen Wang, Huijia Chen and Chengming Li
Systems 2025, 13(7), 582; https://doi.org/10.3390/systems13070582 - 15 Jul 2025
Viewed by 364
Abstract
The coupled development of economic and ecological systems is crucial for achieving sustainable growth, with the financial system playing a pivotal adaptive role. Green financial innovation (GFI) is central to enhancing this adaptation. Urban land use eco-efficiency (ULUEE) serves as an effective measure [...] Read more.
The coupled development of economic and ecological systems is crucial for achieving sustainable growth, with the financial system playing a pivotal adaptive role. Green financial innovation (GFI) is central to enhancing this adaptation. Urban land use eco-efficiency (ULUEE) serves as an effective measure of economic–ecological coupling. Using China’s Green Finance Reform and Innovation Pilot Zones (GFRPZs) as a quasi-natural experiment, this study assesses the impact of GFI on ULUEE, employing panel data from 283 prefecture-level cities (2013–2021). The results show that GFI significantly enhances ULUEE through technological spillovers, strengthened environmental regulation, industrial upgrading, and resource agglomeration. Heterogeneity analyses further reveal that GFI’s positive effects are more pronounced in economically developed regions, cities without legacy heavy-industry reliance, and those with deeper financial development. Additionally, GFI demonstrates cross-regional spillover effects, effectively interacting with other environmental policies. While GFI’s impact is more pronounced in economic growth, its ecological governance improvements are modest. This study provides critical insights for tailored green financial policies aimed at harmonizing economic and ecological objectives. Full article
(This article belongs to the Section Systems Practice in Social Science)
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18 pages, 12019 KiB  
Article
Influence of Temperature on the Optical Properties of Ternary Organic Thin Films for Photovoltaics
by Gabriela Lewinska, Jerzy Sanetra, Konstanty W. Marszalek, Alexander Quandt and Bouchta Sahraoui
Materials 2025, 18(14), 3319; https://doi.org/10.3390/ma18143319 - 15 Jul 2025
Viewed by 306
Abstract
This study investigates the influence of temperature on the linear and nonlinear optical properties of ternary organic thin films for solar cell applications. Three-component organic thin films (poly({4,8-bis[(2-ethylhexyl)oxy]benzo [1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl] thieno[3,4-b]thiophenediyl}) and (poly([2,6′-4,8-di(5-ethylhexylthienyl)benzo[1,2-b;3,3-b]dithiophene]{3-fluoro-2[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl}), marked PTB7 and PTB7th- donors, PCBM, phenyl-C61-butyric acid methyl ester acceptor, [...] Read more.
This study investigates the influence of temperature on the linear and nonlinear optical properties of ternary organic thin films for solar cell applications. Three-component organic thin films (poly({4,8-bis[(2-ethylhexyl)oxy]benzo [1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl] thieno[3,4-b]thiophenediyl}) and (poly([2,6′-4,8-di(5-ethylhexylthienyl)benzo[1,2-b;3,3-b]dithiophene]{3-fluoro-2[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl}), marked PTB7 and PTB7th- donors, PCBM, phenyl-C61-butyric acid methyl ester acceptor, and Y5: 2,2′-((2Z,2′Z)-((12,13-bis(2-ethylhexyl)-3,9-diundecyl-12,13-dihydro[1,2,5]thiadiazolo[3,4e]thieno[2′,3′:4′,5′] thieno[2′,3′:4,5]pyrrolo[3,2-g] thieno[2′,3′:4,5]thieno[3,2-b]indole-2,10-diyl)bis(methanylylidene))bis(3-oxo-2,3-dihydro1H-indene-2,1-diylidene))dimalononitrile) and Y6 non-fullerene acceptors: (2,2′-((2Z,2′Z)-((12,13-bis(2-ethylhexyl)-3,9-diundecyl-12,13- dihydro-[1,2,5]thiadiazolo[3,4- e] thieno [2,″3″:4′,5′]thieno [2′,3′:4,5]), non-fullerene acceptors, were analyzed using spectroscopic ellipsometry and third-harmonic generation techniques across a temperature range of 30 °C to 120 °C. The absorption spectra of the ternary layers remained largely stable with temperature, but ellipsometry revealed temperature-dependent changes in layer thickness (a few percent increase during heating) and variations in refractive index and extinction coefficients, suggesting modest structural alterations. Analysis using a gradient model indicated that film composition varies with thickness. Third-harmonic generation measurements showed a decrease in χ(3) after annealing, with the most significant change observed in the PTB7th:Y5:PCBM layer. Full article
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