Skip to Content

4 Results Found

  • Article
  • Open Access
12 Citations
3,128 Views
16 Pages

Thermodynamics and Spectroscopy of Halogen- and Hydrogen-Bonded Complexes of Haloforms with Aromatic and Aliphatic Amines

  • Emmanuel Adeniyi,
  • Olivia Grounds,
  • Zachary Stephens,
  • Matthias Zeller and
  • Sergiy V. Rosokha

19 September 2022

Similarities and differences of halogen and hydrogen bonding were explored via UV–Vis and 1H NMR measurements, X-ray crystallography and computational analysis of the associations of CHX3 (X=I, Br, Cl) with aromatic (tetramethyl-p-phenylenediam...

  • Article
  • Open Access
8 Citations
7,512 Views
14 Pages

Aqueous Chlorination of D-Limonene

  • Albert T. Lebedev,
  • Elena A. Detenchuk,
  • Tomas B. Latkin,
  • Mojca Bavcon Kralj and
  • Polonca Trebše

Limonene (1-methyl-4-(1-methylethenyl)-cyclohexene) is one of the most widespread monocyclic terpenes, being both a natural and industrial compound. It is widely present in the environment, including in water supplies. Therefore, it may be subjected...

  • Article
  • Open Access
13 Citations
5,415 Views
12 Pages

18 March 2016

An electrochemical treatment (EC) was applied at different intensities to degrade the chromophoric groups of dyes C.I. Reactive Black 5 (RB5) and C.I. Reactive Blue 7 (Rb7) until uncolored species were obtained. Decolorization rate constants of the a...

  • Article
  • Open Access
5 Citations
7,134 Views
12 Pages

Correlation of the Rates of Solvolysis of i-Butyl Fluoroformate and a Consideration of Leaving-Group Effects

  • Yelin Lee,
  • Kyoung-Ho Park,
  • Mi Hye Seong,
  • Jin Burm Kyong and
  • Dennis N. Kevill

10 November 2011

The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 °C in 22 pure and binary solvents. These results correlated well with the extended Grunwald-Winstein (G-W) equation, which incorporated the NT solvent nucleophi...