Search Results (52)

Punch velocity is a key performance indicator in boxing and reflects effective coordination along the kinetic chain. This study aimed to investigate the relationship between punch acceleration and plantar pressure distribution using wearable sensing technologies. Twenty-four collegiate boxers (12 professional-level and 12 amateur-level athletes) performed jab and cross punches under controlled conditions. Punch acceleration was measured using a glove-mounted inertial measurement unit (IMU), while plantar pressure distribution was recorded using pressure-sensing insoles. Professional boxers demonstrated significantly higher punch acceleration (22–31%, p < 0.05) and greater forefoot plantar pressure (18–27%, p < 0.05) compared to amateur athletes. Correlation analysis revealed significant positive associations between forefoot pressure and punch acceleration (r = 0.62–0.71, p < 0.01), indicating that increased lower-limb force contributes to higher upper-limb striking performance. These findings demonstrate that combined wearable sensing provides a practical approach for quantifying punching biomechanics and identifying level-dependent kinetic-chain characteristics in boxing. Full article

Head injuries remain one of the major health concerns in contact sports such as boxing. Despite the widespread use of protective gloves and helmets, their biomechanical effectiveness in mitigating head acceleration and reducing brain injury risk remains uncertain. This study aims to biomechanically assess available boxing equipment solutions and identify the brain–skull system’s response to physical forces from a boxing punch. A dedicated experimental setup was developed using mini triaxial accelerometers and a high-speed camera to measure head accelerations in a Primus unbreakable dummy. Tests were performed using gloves of different masses (0 oz, 10 oz, and 16 oz) and three head protection configurations: no helmet, rugby helmet, and boxing helmet. The resultant accelerations were analyzed and compared across test conditions. Peak wrist accelerations ranged from 195.00 to 271.77 m/s², while head accelerations did not exceed biomechanical injury thresholds. The boxing helmet, composed of multilayer polyurethane foam, did not consistently decrease acceleration; in some cases, it produced higher overloads due to increased head mass and moment of inertia. A rugby helmet made of open-cell EVA (ethylene vinyl acetate) foam with lower density exhibited more favorable energy-dissipation characteristics under low-impact conditions. Glove mass also influenced acceleration differently between male and female participants, likely due to variations in punch velocity and force generation. This work is a pilot study using two trained adult volunteers to validate the combined IMU–video measurement framework. The results serve as hypothesis-generating mechanistic observations rather than population-level effect estimates. Protective effectiveness in boxing depends on a complex interaction between material properties, geometry, and user biomechanics. Optimal equipment design should balance energy absorption and mass to minimize both linear and rotational accelerations. Future studies should integrate advanced material modeling and finite element simulations to support the development of adaptive, lightweight protective systems. Full article

A fiber-optic visible–near-infrared absorption spectroscopy system in a glove box was demonstrated for remote quantification of Am(III) (0–500 µM) and HNO₃ (0.1–9 M) using partial least squares regression (PLSR) models. The sensor platform, featuring a simple plug-and-play spectrophotometer, can enable noninvasive, real-time monitoring of actinide process solutions. To establish a flexible PLSR model calibration strategy, a D-optimal design developed using Nd(III) in previous studies was successfully extended to an actinide system with Am(III) to effectively minimize sample set size while maintaining robust prediction performance. The results suggest strong spectral similarities between Nd(III) and Am(III) and validate Nd(III) as an effective optical surrogate for trivalent actinide species. This work also supports the generalizability of a D-optimal training set selection approach for two-factor systems. The PLS1 models for Am(III) and HNO₃ outperformed a PLS2 model and maintained reasonable performance in the presence of interfering U(VI). The resulting sensor system and multivariate approach provides a flexible and scalable solution for process monitoring, control, and safety in diverse nuclear applications. Full article

The Signal Amplification By Reversible Exchange (SABRE) technique provides enhancement of Nuclear Magnetic Resonance (NMR) signals up to several orders of magnitude using chemical exchange of a substrate and parahydrogen on an iridium complex. Therefore, the availability of such a catalytic complex to a broader community is an absolutely vital step for dissemination of the groundbreaking SABRE methodology. The most common SABRE catalyst, which is activated in situ, is based on Ir-IMes system (IMes = 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene). Earlier approaches for the synthesis of this catalyst often relied on specialized equipment and were limited to a comparatively small scale. This, in turn, increased the barrier of entry for new scientists to the area of SABRE hyperpolarization. Here, we present a robust, inexpensive, and easy to reproduce synthetic procedure for the preparation of this SABRE catalyst, which does not require specialized inert atmosphere equipment like a glove box or Schlenk line. The synthesis was validated on the scale of several grams vs. tens of milligrams scale in the reported approaches. The resulting SABRE catalyst, [Ir(IMes)(COD)Cl], was activated in situ and further evaluated in hyperpolarization experiments resulting in signal enhancements comparable to (or higher than) those for the catalyst prepared using Schlenk line equipment. Full article

This study examines the effects of two plyometric training interventions over an eight-week preparatory period on straight punch impact force, cardiovascular fitness, and muscle strength in national-level boxers. Twenty male professional boxers participated voluntarily, with an average age of 22.64 ± 3.12 years and an average training experience of 5.11 ± 0.88 years. Their mean body weight and height were 70.20 ± 10.13 kg and 184.28 ± 5.38 cm, respectively. The participants were randomly assigned to two groups. Group 1, the Plyometric Stair Jump group, consisted of ten male boxers, while Group 2, the Plyometric Reaction Box Jump group, also included ten male boxers. To assess maximum punching velocity (PVmax), an accelerometer was embedded within the boxing glove, capturing data during three maximal-speed jabs with each arm to evaluate both rear-arm (RA) and lead-arm (LA) punches. Upper-body strength was assessed using a one-repetition maximum (1RM) bench press (BP) test, while maximum velocity at various percentages of 1RM was recorded via a linear encoder. Significant correlations were observed between the right arm punch velocity maximum (RA PVmax) and the bench press velocity at all submaximal intensities in both intervention groups (p < 0.05). However, no correlation was found between left arm punch velocity maximum (LA PVmax) and bench press velocity at any intensity within the Plyometric Reaction Jump (PRJ) group. Conversely, in the Plyometric Stair Jump (PSJ) group, a velocity at 80% of 1RM was the sole significant predictor of RA PVmax at submaximal bench press intensities. Adjusting for the strength-to-weight ratio significantly influenced the predictive values in intergroup comparisons (p < 0.005). These findings suggest that high-load bench press exercises (e.g., at 80% 1RM) may serve as reliable predictors of performance in specific boxing movements. However, since no significant relationship was observed with LA PVmax in this study, further research is warranted to identify exercises and intensities that may explain left arm punch velocity. Full article

Virtual reality (VR) is a promising tool in spinal cord injury (SCI) rehabilitation, particularly through virtual adaptations of functional tests like the Box and Block test (BBT). However, a comprehensive dynamic comparison between real and virtual BBT is lacking. This study investigates the kinematic and electromyographic (EMG) differences between healthy individuals and SCI patients performing both real (RBBT) and virtual (VBBT) versions of the BBT. An electromagnetic motion-tracking system, an instrumented glove, and surface EMG electrodes were used to capture hand trajectories, joint angles, and forearm muscle activation. The analysis included cycle-averaged and temporal kinematic and EMG parameters. Our findings reveal that both groups showed increased trajectory length and velocity peaks during the VBBT, with more pronounced increases in SCI patients. Unlike healthy individuals, SCI patients also showed increased finger and thumb flexion during VBBT. Cycle-averaged EMG values were lower in healthy participants during VBBT, likely due to reduced motor demands and lack of real grasping. Conversely, SCI patients exhibited higher muscle activity, suggesting impaired coordination and compensatory overactivation. Healthy individuals showed consistent temporal kinematic synergies and muscle activation, whereas they were altered in SCI patients, especially during reaching. These findings highlight the need for rehabilitation strategies to improve motor control and feedback integration. Full article

Solution processing represents a widely adopted methodology for perovskite solar cell (PSC) fabrication. Nevertheless, the prevalent use of toxic solvents and anti-solvents in conventional approaches presents significant challenges for PSC commercialization. Water, as an environmentally benign solvent with exceptional Pb(NO₃)₂ solubility, offers a promising alternative for perovskite film preparation. However, the sluggish conversion kinetics of Pb(NO₃)₂ to perovskite often results in morphological imperfections and incomplete conversion, particularly detrimental to planar inverted PSCs derived from aqueous solutions, which currently exhibit limited power conversion efficiencies (PCE) of approximately 6%. To mitigate the Ostwald ripening effect induced by slow reaction kinetics and enhance the conversion efficiency of deep-layer Pb(NO₃)₂ and PbI₂, this study proposes a strategy of increasing the pore size in porous Pb(NO₃)₂ structures. Through the incorporation of sodium dodecyl sulfonate (SDS) surfactant into the Pb(NO₃)₂ precursor solution, we successfully fabricated high-quality perovskite films. Comprehensive characterization revealed that SDS doping effectively modified the surface properties of Pb(NO₃)₂ films, accelerating their conversion to perovskite. The optimized PSCs based on SDS-modified perovskite films demonstrated improved energy level alignment, enhanced charge carrier extraction, and suppressed non-radiative recombination. Consequently, the PCE of planar inverted aqueous PSCs increased significantly from 12.27% (control devices) to 14.82% following surfactant modification. After being stored in a nitrogen glove box for 800 h, the performance of the device still remained above 90% of its original level. It can still maintain 60% of its original performance after a 100 h heating aging test at 80 degrees. Full article

Ensuring comfort in light mobility is a crucial aspect for supporting individuals’ well-being and safety while driving scooters, riding bicycles, etc. In fact, factors such as the hand grip on the handlebar, positions of the wrist and arm, overall body posture, and affecting vibrations play key roles. Wearable systems offer the ability to noninvasively monitor physiological parameters, such as body temperature and heart rate, aiding in personalized comfort assessment. In this context, user positions while driving or riding are, on the other hand, more challenging to monitor ecologically. Developing effective smart gloves as a support for comfort and movement monitoring introduces technical complexities, particularly in sensor selection and integration. Light and flexible sensors can help in this regard by ensuring reliable sensing and thus addressing the optimization of the comfort for the driver. In this work, a novel wireless smart glove is proposed, integrating four bend sensors, four force-sensitive sensors, and one inertial measurement unit for measuring the finger movements, hand orientation, and the contact force exerted by the hand while grasping the handlebar during driving or riding. The smart glove has been proven to be repeatable (1.7%) and effective, distinguishing between different grasped objects, such as a flask, a handlebar, a tennis ball, and a small box. Additionally, it proved to be a valuable tool for monitoring specific actions while riding bicycles, such as braking, and for optimizing the posture during the ride. Full article

Bismuth-based perovskite derivatives, (CH₃NH₃)₃Bi₂I₉ (MBI), are promising non-toxic light-absorbing materials widely used in various photoelectric devices because of their excellent stability. However, MBI-based perovskite solar cells (PSCs) are limited by poor film quality, and the performance of such a device is far behind that of lead-based PSCs. In this work, the crystal structure and morphological properties of MBI films were compared across different preparation methods. The two-step vapor-assisted method can prepare continuous dense MBI films because MBI crystal nucleation is induced by the BiI₃ seed layer. The MBI film grown by this method is better for the production of excellent PSCs compared to the film prepared by the solution method. The best photovoltaic device based on the MBI film could obtain a power conversion efficiency of 1.13%. An MBI device is stored in the glove box for 60 days, and the device’s performance is maintained at 99%. These results indicate that the vapor-assisted deposition of MBI films can be an effective method to improve the performance of bismuth-based planar PSCs. Full article

Material characterization and investigation are the basis for improving the performance of electrochemical devices. However, many compounds with electrochemical applications are sensitive to atmospheric gases and moisture; therefore, even their characterization should be performed in a controlled atmosphere. In some cases, it is impossible to execute such investigations in a glove box, and, therefore, in the present work, an air-tight 3D printed cell was developed that preserves samples in a controlled atmosphere while allowing spectroscopic measurements in reflectance geometry. Equipped with a cheap 1 mm thick CaF₂ optical window or a more expensive 0.5 mm thick ZnS window, the cell was used for both optical photothermal infrared and Raman spectroscopy measures; imaging of the samples was also possible. The far-infrared range reflectance measurements were performed with a cell equipped with a diamond window. Full article

As we move towards the commercialization and upscaling of perovskite solar cells, it is essential to fabricate them in ambient environment rather than in the conventional glove box environment. The efficiency of ambient-processed perovskite solar cells lags behind those fabricated in controlled environments, primarily owing to external environmental factors such as humidity and temperature. In the case of device fabrication in ambient environments, relying solely on a single parameter, such as temperature or humidity, is insufficient for accurately characterizing environmental conditions. Therefore, the dew point is introduced as a parameter which accounts for both temperature and humidity. In this study, a machine learning model was developed to predict the efficiency of ambient-processed perovskite solar cells based on meteorological data, particularly the dew point. A total of 238 perovskite solar cells were fabricated, and their photovoltaic parameters and dew points were collected from March to December 2023. The collected data were used to train various tree-based machine learning models, with the random forest model achieving the highest accuracy. The efficiencies of the perovskite solar cells fabricated in January and February 2024 were predicted with a MAPE of 4.44%. An additional Shapley Additive exPlanations analysis confirmed the significance of the dew point in the performance of perovskite solar cells. Full article

The control of the performance of single-walled carbon nanotube (SWCNT) random network-based transistors is of critical importance for their applications in electronic devices, such as complementary metal oxide semiconducting (CMOS)-based logics. In ambient conditions, SWCNTs are heavily p-doped by the H₂O/O₂ redox couple, and most doping processes have to counteract this effect, which usually leads to broadened hysteresis and poor stability. In this work, we coated an SWCNT network with various common polymers and compared their thin-film transistors’ (TFTs’) performance in a nitrogen-filled glove box. It was found that all polymer coatings will decrease the hysteresis of these transistors due to the partial removal of charge trapping sites and also provide the stable control of the doping level of the SWCNT network. Counter-intuitively, polymers with electron-withdrawing functional groups lead to a dramatically enhanced n-branch in their transfer curve. Specifically, SWCNT TFTs with poly (vinylidene fluoride) coating show an n-type mobility up to 61 cm²/Vs, with a decent on/off ratio and small hysteresis. The inverters constructed by connecting two ambipolar TFTs demonstrate high gain but with certain voltage loss. P-type or n-type doping from polymer coating layers could suppress unnecessary n- or p-branches, shift the threshold voltage and optimize the performance of these inverters to realize rail-to-rail switching. Similar devices also demonstrate interesting antiambipolar performance with tunable on and off voltage when tested in a different configuration. Full article

This study focuses on the hole transport layer of molybdenum trioxide (MoO₃) for inverted bulk heterojunction (BHJ) organic photovoltaics (OPVs), which were fabricated using a combination of a spray coating and low-temperature annealing process as an alternative to the thermal evaporation process. To achieve a good coating quality of the sprayed film, the solvent used for solution-processed MoO₃ (S-MoO₃) should be well prepared. Isopropanol (IPA) is added to the as-prepared S-MoO₃ solution to control its concentration. MoO₃ solutions at concentrations of 5 mg/mL and 1 mg/mL were used for the spray coating process. The power conversion efficiency (PCE) depends on the concentration of the MoO₃ solution and the spray coating process parameters of the MoO₃ film, such as flow flux, spray cycles, and film thickness. The results of devices fabricated from solution-processed MoO₃ with various spray fluxes show a lower PCE than that based on thermally evaporated MoO₃ (T-MoO₃) due to a limiting FF, which gradually increases with decreasing spray cycles. The highest PCE of 2.8% can be achieved with a 1 mg/mL concentration of MoO₃ solution at the sprayed flux of 0.2 mL/min sprayed for one cycle. Additionally, S-MoO₃ demonstrates excellent stability. Even without any encapsulation, OPVs can retain 90% of their initial PCE after 1300 h in a nitrogen-filled glove box and under ambient air conditions. The stability of OPVs without any encapsulation still has 90% of its initial PCE after 1300 h in a nitrogen-filled glove box and under air conditions. The results represent an evaluation of the feasibility of solution-processed HTL, which could be employed for a large-area mass production method. Full article

Study Design: Face and content validation of a surgical simulation model. Objective: Accidental transection of the inferior alveolar nerve (IAN) during bilateral sagittal split osteotomies (BSSO) has a reported incidence of up to 7%, determining important sensory disturbances in patients. Proper repair demands the need of microsurgical anastomosis skills. No previous training models have been described to simulate this. Therefore, we present a validated simulation model for intraoral repair of transected IAN. Methods: A CT scan of an orthognathic surgery patient was modified and a 3D model of a mandible with BSSO was printed. Chicken thigh anatomy was reviewed, and 2.5 mm sciatic nerves were dissected and mounted in the model. In order to simulate intraoral work depth, it was put inside a dental phantom or medical glove box. The model was tested by a group of experts (n = 12), simulating a transected IAN repair inside the mouth with both loupes and a double visor surgical training microscope. A survey was conducted to assess Face and Content validity. Results: The model was named RIANOS after Repair of Inferior Alveolar Nerve in Orthognathic Surgery Simulator. The printing cost of each model was approximately US$3 and the design file is open-source and available for download. All experts “Strongly Agreed” that the model was useful for training inferior alveolar nerve microsurgical repair and would consider implementing it with their residents. Conclusions: We developed a low cost, reproducible, open-source simulator for IAN injury repair training during BSSO. Face and Content validity was achieved through evaluation by a group of experts. Full article

Most 2D materials are unstable under ambient conditions. Assembly of van der Waals heterostructures in the inert atmosphere of the glove box with ex situ lithography partially solves the problem of device fabrication out of unstable materials. In our paper, we demonstrate an approach to the next-generation inert-atmosphere (nitrogen, <20 ppm oxygen content) fabrication setup, including optical contact mask lithography with a 2 $\mathsf{\mu }$m resolution, metal evaporation, lift-off and placement of the sample to the cryostat for electric measurements in the same inert atmosphere environment. We consider basic construction principles, budget considerations, and showcase the fabrication and subsequent degradation of black-phosphorous-based structures within weeks. The proposed solutions are surprisingly compact and inexpensive, making them feasible for implementation in numerous 2D materials laboratories. Full article