Search Results (392)

The homogeneity of methane hydrates in marine sediments plays a significant role in determining the efficiency of gas production during exploitation processes. Revealing their distribution mechanisms is crucial for optimizing the development of gas hydrates. This work systematically investigates the evolution patterns of effective thermal conductivity (ETC) during the formation and dissociation of methane hydrate in marine sediments, focusing on their major mineral components, such as quartz sand, illite, and montmorillonite. The results reveal the influence of thermal conductivity (TC) characteristics in porous media on hydrate phase transition behavior and spatial distribution. Key findings demonstrate that the TC characteristics of porous media are one of the dominant factors controlling hydrate formation rates. High-conductivity porous media significantly accelerate hydrate formation through efficient heat transfer. The swelling characteristics of montmorillonite and its coupling effects with salt ions impair heat transfer pathways, thereby inhibiting hydrate formation. Further analysis reveals that the spatial heterogeneity in reservoir TC is the primary intrinsic mechanism responsible for the macroscopic heterogeneous distribution of hydrates. Additionally, the hydrate dissociation process disrupts solid-state thermal bridging and generates gaseous thermal barriers, causing irreversible attenuation of reservoir TC. This phenomenon exacerbates the non-uniformity of the front during dissociation and increases the risk of secondary formation during exploitation. From a novel perspective of reservoir TC heterogeneity, this study establishes mechanistic links between the thermophysical properties of porous media and the spatial distribution patterns of hydrates. This provides significant theoretical guidance for resource exploration and the safe, efficient exploitation of marine gas hydrate reservoirs. Full article

As a future abundant and environmentally friendly clean energy source, the decomposition process of natural gas hydrates is significantly regulated by reservoir structural characteristics. Improper extraction can easily trigger geological hazards, yet current research on the coupling mechanism between wellbore microstructure and decomposition remains incomplete. To elucidate the regulatory role of reservoir structural characteristics, this study employed a self-developed physical simulation system to conduct triaxial creep experiments. It compared the mechanical response and decomposition dynamics of sediments under layered and homogeneous hydrate distribution patterns, while simultaneously monitoring gas production and formation displacement parameters. Results indicate that layered distribution significantly influences overall sediment creep behavior and failure patterns: low-saturation sublayers dominate the creep softening–hardening mechanism, while strain evolution at different timescales and long-term bearing capacity are controlled by low- and high-saturation sublayers, respectively. Creep cohesion and internal friction angle exhibit distinct differences between the two distribution patterns, with the influence mechanisms of relevant mechanical indicators closely related to the roles of sublayers with varying saturations. The study also uncovers the intrinsic link between gas production and stratigraphic subsidence during hydrate decomposition, clarifying the core mechanism by which reservoir structures influence decomposition stability through regulating mechanical responses. The methodologies and conclusions of this research provide scientific support for predicting the long-term stability of natural gas hydrate reservoirs and enabling safe, efficient extraction, while laying the groundwork for the systematic development of comprehensive hydrate technologies. Full article

Natural gas hydrates (NGHs) are a promising alternative energy source with huge global reserves, but they face significant challenges in commercial production and require more efficient exploitation methods. Based on field data from China’s first offshore NGH pilot production, this study systematically investigates the enhancement effect of boundary sealing and wellbore heating on the development of Class 1 hydrate reservoirs with five-spot wells. Numerical simulation findings illustrate that when the sealing layer thickness is 1 m and the permeability is 0.001 mD, it can effectively expand the radial propagation of pressure, promote the gas output, and significantly reduce water production. When the heating power is 100 W/m, the highest energy efficiency ratio can be achieved, which can promote dissociation and inhibit the secondary hydrate generation. The combination of two technologies shows a synergistic effect, which increases the cumulative gas production and gas-to-water ratio to 197.4% and 224.3% of the base case, respectively, achieving the optimal balance between high recovery rate and economic efficiency, which provides key insights for the effective development of Class 1 hydrate reservoirs. Full article

Commercialization of natural gas hydrates still faces challenges. Before large-scale production becomes feasible, efficient exploitation methods must be continuously explored. Based on field data from China’s first trial production, a novel five-spot radial wells system design, combined with boundary sealing and wellbore heating, is proposed to improve production capacity. Simulation results indicate that boundary sealing can inhibit water invasion and concentrate energy, thereby promoting hydrate dissociation. The radial laterals significantly expand the drainage area and increase pressure propagation. Wellbore heating can accelerate the dissociation of hydrates while inhibiting secondary hydrate generation. The combined application of these technologies has significantly increased the cumulative gas production and gas-to-water ratio to 244.9% and 134.6% of the base case, respectively, providing theoretical references for the effective exploitation of Class 1 hydrate reservoirs. Full article

This study employed machine learning to investigate the mechanical behavior of one-part geopolymer (OPG)-stabilized soil subjected to acid erosion. Based on the unconfined compressive strength (UCS) data of acid-eroded OPG-stabilized soil, eight machine learning models, namely, Adaptive Boosting (AdaBoost), Decision Tree (DT), Extra Trees (ET), Gradient Boosting (GB), Light Gradient Boosting Machine (LightGBM), Random Forest (RF), Support Vector Machine (SVM), and eXtreme Gradient Boosting (XGBoost), along with hyper-parameter optimization by Genetic Algorithm (GA), were used to predict the degradation of the UCS of OPG-stabilized soils under different durations of acid erosion. The results showed that GA-SVM (R² = 0.9960, MAE = 0.0289) and GA-XGBoost (R² = 0.9961, MAE = 0.0282) achieved the highest prediction accuracy. SHAP analysis further revealed that solution pH was the dominant factor influencing UCS, followed by the FA/GGBFS ratio, acid-erosion duration, and finally, acid type. The 2D PDP combined with SEM images showed that the microstructure of samples eroded by HNO₃ was marginally denser than that of samples eroded by H₂SO₄, yielding a slightly higher UCS. At an FA/GGBFS ratio of 0.25, abundant silica and hydration products formed a dense matrix and markedly improved acid resistance. Further increases in FA content reduced hydration products and caused a sharp drop in UCS. Extending the erosion period from 0 to 120 days and decreasing the pH from 4 to 2 enlarged the pore network and diminished hydration products, resulting in the greatest UCS reduction. The results of the study provide a new idea for applying the ML model in geoengineering to predict the UCS performance of geopolymer-stabilized soils under acidic erosion. Full article

Depressurization combined with thermal stimulation based on injection-production well patterns is considered promising for gas hydrate development. Nevertheless, its direct application to Shenhu challenging hydrates may be problematic due to the presence of low reservoir permeability and permeable boundaries. The present study proposes to improve the development potential of Shenhu hydrate by reservoir reconstruction, including boundary sealing and reservoir fracturing, and numerically investigates the production performance. The results showed that water intrusion, hot loss, and gas leakage can be effectively addressed by boundary sealing. Nevertheless, it cannot enhance productivity as thermal decomposition gas accumulated around the injection well. Conversely, reservoir fracturing can significantly improve extraction efficiency as substantial amounts of hydrates dissociate along the fractures, and the gas can be well recovered through the fractures. However, reservoir fracturing was not conducive to water control and energy utilization as it induced more severe water flooding and gas leakage. Under the synergistic effect of the two, there was no methane leakage, and the gas production rate increased with increasing fracture conductivity, while the gas-to-water ratio and energy ratio presented the opposite trend. To obtain a favorable production performance, a fracture with a conductivity of 1–10 D·cm was recommended. Therefore, the combination of boundary sealing and reservoir fracturing makes it feasible for safe and efficient extraction of offshore challenging hydrate under the injection-production mode. Full article

Drill pipe pullback gravel packing is a novel sand control method for marine natural gas hydrate reservoirs, enabling rapid and uniform filling by synchronizing fluid injection with pipe retraction. However, the complex liquid–solid two-phase flow mechanisms and parameter sensitivities in this dynamic process remain unclear. To address this gap, a coupled Computational Fluid Dynamics and Discrete Element Method (CFD-DEM) approach is adopted in accordance with the trial production requirements in the South China Sea. This investigation systematically analyzes the relative contributions of injection rate (0.8–2.2 m³/min) and sand-carrying ratio (30–60%) to the packing effectiveness. Additionally, the effects of carrier fluid viscosity and drill pipe pullback speed are explored. Results show that injection rate and sand-carrying ratio positively affect performance, with sand-carrying ratio as the decisive factor, exhibiting an impact approximately 73 times greater than that of the injection rate. Optimal parameters in this study are injection rate of 2.2 m³/min and sand-carrying ratio of 60%, which yield the highest gravel volume fraction and stable bed height. Furthermore, it is also found that while increasing carrier fluid viscosity improves bed height, excessive viscosity hinders particle settling and compaction. Similarly, a trade-off exists for the pullback speed to balance packing density and pipe burial risks. These findings provide a theoretical basis for optimizing sand control operations in hydrate trial productions. Full article

Under the dual challenges of energy supply demand imbalance and the efficient operation of underground gas storage (UGS) facilities, this study investigated the mechanical behavior of reservoir rocks and optimal production pressure differential in a depleted gas reservoir in China under multi-cycle injection-production. For the first time, we reveal the mechanical degradation mechanism of hydration and cyclic fatigue for three typical lithologies in depleted sandstone reservoirs. Rock mechanics tests were conducted to analyze the effects of lithology, water saturation, and cyclic loading on mechanical properties, and appropriate failure criteria were evaluated. The main findings are as follows: (1) Under a confining pressure of 45 MPa, the peak strength of fine sandstone was the highest at 160.13 MPa, and the peak strength of argillaceous sandstone was the lowest at 114.92 MPa. The strength increased approximately linearly with confining pressure. (2) Increasing water saturation significantly weakened rock strength, particularly in argillaceous sandstone due to hydration effects. At 45% water saturation, its strength decreased by 37.38%. while Young’s modulus and Poisson’s ratio remained relatively unaffected. (3) Rock strength progressively degraded with the number of loading cycles. Siltstone showed the most significant degradation, with a strength reduction of 28.50% after 200 cycles. The damage induced by cyclic loading was less severe than that caused by hydration. (4) Among five failure criteria evaluated, the Mogi–Coulomb criterion demonstrated superior predictive capability by incorporating three-dimensional principal stress effects, showing closest agreement with the experimental data. We further established a depth-dependent production pressure differential profile and proposed a lithology-specific injection-production strategy. These findings provide theoretical foundations for optimizing injection-production strategies and sand control measures in depleted reservoir UGS systems. Full article

This study explores the production of hydrates with binary (CH₄/C₂H₆) gaseous mixtures, varying the concentration of each species from 25 to 75 vol%. The thermodynamics of this process are explored in detail, and the achieved results are explained in terms of cage occupancy and compared with the phase boundary equilibrium conditions of pure methane and pure ethane hydrates. The addition of ethane is found to not contribute significantly to the quantity of gas captured in hydrates. Conversely, it delays the massive growth of hydrates, shifting the process towards conditions supporting the formation of pure methane hydrates. The presence of C₂H₆ molecules within the hydrate lattices improved their overall stability and avoided the dissociation of water cages even under temperature increases (from the conditions measured at the end of formation) up to 14.40 °C. This latter property makes ethane a viable support species for the solid storage of energy gases in the form of hydrates. Full article

Submarine methane-rich fluids migrating through geological conduits significantly influence gas hydrate production during depressurization. However, the coupled effects of methane, water, and heat delivered by these fluids on hydrate dissociation and methane recovery remain unclear. This study establishes a conceptual coupled numerical model of “pressure reduction–fluid response–reservoir evolution” based on reservoir parameters from Well W11 in the Shenhu area, South China Sea (SCS), and representative conduit characteristics. Hydrate dissociation and gas production are simulated under steady pressure reduction conditions with varying fluid invasion scenarios. Results show that the invasion of methane-rich fluid into gas hydrate systems exhibits a three-phase impact on gas production dynamics. Initially, the invasion has little effect on gas production; in the intermediate stage, it temporarily inhibits gas production; and under sustained invasion, it significantly enhances gas production. Limited water inflow with enhanced heat input promotes efficient hydrate-derived gas recovery. High methane flux enhances gas production while limiting hydrate dissociation. Excessive methane input may induce secondary hydrate formation, with the amount of newly formed hydrate exceeding that of the dissociated hydrate in the reservoir. A strong synergistic “1 + 1 > 2” effect occurs under low water or methane invasion, increasing gas output up to 4.3 times compared with a no-invasion case. These findings enhance understanding of dynamic hydrate exploitation systems and support the safe and efficient co-production of gas hydrates and associated deep gas. Full article

In recent years, a new type of natural gas hydrate reservoir (designated as Class 1S reservoir) has been discovered in the Qiongdongnan Basin. Within this hydrate reservoir, free gas and hydrate coexist within the same stratum. The Class 1S reservoir is comprised of three distinct zones: the gas accumulation zone, the three-phase zone, and the hydrate-bearing zone. It exhibits significant commercial development potential. This paper analyzes the formation mechanism and geological context of Class 1S hydrates. A geological model was established and numerical simulation methods were employed to evaluate its production capacity, elucidating the evolutionary patterns of hydrate saturation distribution at different well locations. The simulation results indicate that production wells should be prioritised in gas accumulation zones in order to achieve the highest cumulative gas production. Additional production wells may be considered in later stages to enhance recovery rates. Secondary hydrate formation significantly impacts production in Hydrate-bearing zone and three-phase zone. Measures such as wellbore heating can be employed to minimize secondary hydrate formation around the wellbore. Full article

With the rapid increase in municipal solid waste and the associated production of incineration fly ash (IFA) in Taiwan, sustainable utilization of industrial by-products has become a pressing concern. This study evaluates the mechanical, environmental, and structural performance of ultra-high-performance concrete (UHPC) incorporating water-quenched slag (WQS) and IFA as partial replacements for cement or quartz powder. Laboratory-scale specimens were tested for compressive and flexural strength, followed by full-scale load-bearing tests on trench covers (60 × 35 × 4 cm) and manhole covers (120 × 60 × 5 cm) with varying steel fiber contents and welded steel mesh reinforcement. Mechanical behavior, heavy-metal leaching (TCLP), carbon emissions, and life cycle impact assessment (LCIA) were examined. The results show that WQS maintained or enhanced strength, while IFA caused strength loss and surface corrosion due to gas release during hydration. Trench covers with 15% WQS achieved the highest peak load (14,733 kg), exceeding heavy-traffic requirements, whereas IFA-based covers met the 10-ton standard but showed corrosion. Manhole covers did not reach the 75-ton design load, indicating applicability only for light or non-traffic areas. All UHPC mixes immobilized heavy metals within regulatory limits, and partial cement replacement reduced the carbon footprint by 60–120 kg CO₂e/m³. LCIA further indicated that 20% IFA replacement provided the greatest overall environmental benefit. In conclusion, WQS-incorporated UHPC offers reliable structural and environmental performance, while IFA requires pretreatment or modification to ensure long-term durability. Full article

Natural gas hydrate (NGH) is a highly promising alternative energy source for the future, which is widely distributed in marine clayey-silty sediments. Permeability is the key factor determining the efficiency of NGH exploitation. However, clay particles can migrate and clog the pores, leading to a decrease in reservoir permeability during the development of NGH. This review summarizes the permeability damage law during the NGH production from clayey-silty sediments, with a focus on the influence of clay particle migration. For the scientific problem of clay particle migration, the governing equation of clay particle migration was first clarified through force balance analysis. Then, the influencing factors and laws of clay particle migration were systematically summarized from two aspects: internal factors such as clay type, content, particle size, reservoir heterogeneity, and external conditions such as salinity, flow rate, temperature, pH, and stress field. The detachment, migration, aggregation and clogging characteristics of clay particles in porous media were observed and outlined based on microscopic visualization technology. Thirdly, the numerical simulation methods of particle migration were summarized, and the permeability damage laws and its influence mechanism were analyzed. Finally, the limitations on clay particle migration and permeability damage in the current research were discussed, and corresponding suggestions were given to promote the efficient development of NGH. Full article

Fines migration and clogging in porous media have significant implications for engineering applications. For example, during the extraction of marine gas hydrates, fines migration can lead to pore clogging and reduced permeability. This study combines micromodel experiments with DEM-CFD simulations to investigate the effects of fine type (latex/mica), fine shape (spherical/flake), pore size (50 to 700 μm), and pore fluid composition (DW/brine) on fines migration, fine clogging behavior, and the evolution of host sediment porosity. Experiments demonstrate that clogging is geometrically influenced by the relationship between pore size and fines dimensions. Even when the size of fines (mica) is smaller than the pore throat size, their aggregates can still lead to clogging at very low concentrations (0.1–0.2%). The aggregate size of irregular mica is affected by changes in pore fluid properties, which may occur due to the freshening of pore water during hydrate dissociation. Furthermore, a moving gas/liquid interface concentrates fines, thereby increasing the risk of pore clogging. Simulations further reveal that fines migration causes dynamic changes in porosity, which requires a comprehensive consideration of the coupled effects of fine type, fluid velocity, pore size, and fluid chemistry. This study elucidates the microscopic mechanisms and quantifies the macroscopic effects of fines migration behavior in porous media, providing a theoretical foundation for further research. Full article