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20 pages, 3840 KB  
Article
Metallogenesis of Hydrothermal-Filling-Type Tremolite Jade in Sanchakou, Qinghai Province: Constraints from Elemental Geochemistry and Sr Isotopes
by Yuye Zhang, Haiyan Yu, Zizhou Dai, Hongyin Chen and Ling Liu
Minerals 2026, 16(4), 373; https://doi.org/10.3390/min16040373 - 31 Mar 2026
Viewed by 283
Abstract
The hydrothermal-filling-type tremolite jade (nephrite) deposit in sanchakou, Qinghai Province is hosted in marine dolomite, and its ore-forming fluid sources and metallogenic mechanisms remain poorly constrained. Here, we conducted an integrated study involving field geological mapping, petrographic observations, and geochemical analyses (major and [...] Read more.
The hydrothermal-filling-type tremolite jade (nephrite) deposit in sanchakou, Qinghai Province is hosted in marine dolomite, and its ore-forming fluid sources and metallogenic mechanisms remain poorly constrained. Here, we conducted an integrated study involving field geological mapping, petrographic observations, and geochemical analyses (major and trace elements, REEs, Sr isotopes) to constrain material sources, fluid physicochemical features and mineralization processes of the deposit. Results show that the ore-forming fluids were derived from deep crust, with homogeneous initial 87Sr/86Sr ratios ranging from 0.70949 to 0.70959, distinctly higher than the host dolomite (~0.707683), indicating intensive water–rock interaction with Sr-radiogenic lithologies during fluid upwelling. The host dolomite provided the main Ca and Mg, while Si and partial Mg were sourced from deep Si-Mg rich hydrothermal fluids, with negligible contribution from coeval gabbro. The ore-forming fluids were rich in Si, Mg, large-ion lithophile elements and volatiles (e.g., F), characterized by medium-high to medium-low temperature evolution and fluctuating oxidation states. Mineralization can be divided into four stages: deep fluid generation and migration, infiltration metasomatism and silicification, tremolite crystallization at peak oxidation, and open-space filling and jade precipitation. High-quality tremolite jade mainly formed via pulsed hydrothermal injection and direct crystallization in tectonic fractures. This study establishes a genetic model for hydrothermal-filling-type nephrite, enriching relevant metallogenic theories and supporting subsequent exploration. Full article
(This article belongs to the Section Mineral Deposits)
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27 pages, 25673 KB  
Article
Effect of Asphalt Mixture Surface Preparation Methodology on Determining Luminance Level in Laboratory Conditions: Case Study in Poland
by Dominik Grzyb, Marta Wasilewska and Władysław Gardziejczyk
Materials 2026, 19(7), 1277; https://doi.org/10.3390/ma19071277 - 24 Mar 2026
Viewed by 246
Abstract
This paper verifies a method for determining the luminance of a pavement surface made of SMA mixtures at the design stage under laboratory conditions. Tests were conducted on surfaces made of six types of SMA mixtures with varying grain sizes (between 8 and [...] Read more.
This paper verifies a method for determining the luminance of a pavement surface made of SMA mixtures at the design stage under laboratory conditions. Tests were conducted on surfaces made of six types of SMA mixtures with varying grain sizes (between 8 and 11 mm) and coarse aggregate types like trachybasalt with a luminance coefficient in diffused light of Qd—53 mcd/m2/lx, gabbro with Qd—83 mcd/m2/lx, and granite with Qd—115 mcd/m2/lx. The effect of the glassblasting process on the changes in the luminance coefficient in diffused light (Qd) was analyzed while simultaneously monitoring parameters describing skid resistance and macrotexture. Additionally, it was decided that tests would be performed on two sets of specimens differing in their conditioning temperatures. It was found that conditioning at −15 °C significantly improved the binder film removal process from asphalt mixture surfaces compared to those conditioned at 22 °C. Differences were recorded between individual specimens conditioned at −15 °C at the end of the glassblasting. The lowest Qd values were found for specimens with the darkest trachybasalt aggregate (SMA 8—53.0; SMA 11—51.7 mcd/m2/lx) and the highest for specimens with the lightest granite aggregate (SMA 8—63.9; SMA 11—59.8 mcd/m2/lx). However, considering the differences in Qd between individual coarse aggregates, the differences between specimens with these aggregates are insignificant. Glassblasting is a cheap and quick procedure for removing a binder from the surface of specimens, preparing them for luminance determination in the laboratory. It should be noted that glassblasted surfaces should not be used to determine the skid resistance and macrotexture changes at the design stage of an asphalt mixture. Full article
(This article belongs to the Special Issue Advances in Asphalt Materials (3rd Edition))
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28 pages, 11195 KB  
Article
Late Early Jurassic Continental Arc Magmatism in the Northern Erguna Block: Implications for the Southward Subduction of the Mongol–Okhotsk Ocean
by Wenlong Li, Zhanlong Li, Chenglu Li, Masroor Alam and Zhaoxun Cheng
Minerals 2026, 16(3), 305; https://doi.org/10.3390/min16030305 - 13 Mar 2026
Viewed by 329
Abstract
Late Early Jurassic continental arc magmatism in the northern Greater Khingan Range enables the investigation of complicated tectonic processes associated with the subduction and closure of the Mongol–Okhotsk Ocean. To further clarify the timing, genesis, and geodynamic mechanisms driving the magmatic activity during [...] Read more.
Late Early Jurassic continental arc magmatism in the northern Greater Khingan Range enables the investigation of complicated tectonic processes associated with the subduction and closure of the Mongol–Okhotsk Ocean. To further clarify the timing, genesis, and geodynamic mechanisms driving the magmatic activity during this period, the present study addresses these critical questions by integrating zircon U–Pb geochronological, geochemical, and isotopic analyses of a wide variety of igneous rocks, including gabbro, gabbro-diorite, granodiorite, porphyritic monzogranite, and biotite-bearing monzogranite from the Fushan region. Zircon U–Pb geochronology constrains the timing of magmatic activity to 184–179 Ma, coinciding with active subduction phases. Geochemical data reveal arc-like signatures characterized by enrichment in light rare-earth elements (LREEs) and large-ion lithophile elements (LILEs), together with pronounced depletion in high field strength elements (HFSEs). A comprehensive analysis of geochemical and Sr–Nd–Hf isotopic signatures suggests that the mafic rocks originated from an enriched lithospheric mantle modified by subduction-related fluids and sediment-derived melts. By contrast, the granodiorite and porphyritic monzonite exhibit adakitic characteristics, indicating partial melting of the thickened Mesoproterozoic lower crust with contributions from mantle-derived or newly formed crustal material. The biotite-bearing monzogranite, with its pronounced Eu anomaly and lower zircon saturation temperatures, reflects advanced magmatic differentiation from a shallower source. These findings indicate extensive crust–mantle interactions during the southward subduction of the Mongol–Okhotsk Ocean, driven by high-angle subduction and slab rollback. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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18 pages, 13192 KB  
Article
Interstitial Microstructures in the Baima Gabbro Pegmatite, SW China: Constraints on the Late-Stage Evolution Processes in Mafic Pegmatites
by Xinyu Wei, Huan Dong, Kun Wang and Siyu Yu
Minerals 2026, 16(3), 245; https://doi.org/10.3390/min16030245 - 27 Feb 2026
Viewed by 319
Abstract
Interstitial microstructures in igneous rocks record key evidence of late-stage evolution processes. In order to constrain the late-stage evolution of a Baima gabbro pegmatite (Panxi region, SW (Southwestern Sichuan Province), China), we investigated its mineral compositions and late-stage microstructures. These microstructures include replacive [...] Read more.
Interstitial microstructures in igneous rocks record key evidence of late-stage evolution processes. In order to constrain the late-stage evolution of a Baima gabbro pegmatite (Panxi region, SW (Southwestern Sichuan Province), China), we investigated its mineral compositions and late-stage microstructures. These microstructures include replacive symplectites and fish-hook clinopyroxene. Replacive symplectites include fine-grained lamellar intergrowths of anorthite (An)-rich plagioclase + clinopyroxene/amphibole/biotite that are rooted to Fe-Ti oxides and replacing nearby plagioclase primocrysts (Type I) and intergrowths of An-rich plagioclase + clinopyroxene/amphibole that are rooted to olivine and replacing nearby plagioclase primocrysts (Type II). Rare replacive symplectites composed of biotite + plagioclase are also present. Those replacive symplectites and fish-hook clinopyroxene grew at a late magmatic stage with temperatures of 867–1023 °C. An-rich plagioclase in the replacive symplectites and fish-hook textures have An contents up to 94 mol.%, much higher than those of plagioclase primocrysts. Interstitial microstructures are interpreted to reflect interaction between primocrysts and an Fe-rich residual interstitial liquid, consistent with separation and migration of conjugate immiscible melts in a crystal mush. We propose that the hydrous interstitial melt in the Baima gabbro pegmatite may have undergone silicate immiscibility during late-stage magma crystallization. As the crystal fraction increased, crystal-mush compaction and porous melt migration likely became the primary controls on the evolution of the late-stage interstitial melt, rather than convection or diffusion. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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18 pages, 7123 KB  
Article
Plagioclase Zoning and Sr Isotopes Constrain Mush–Magma Mixing in the Late Triassic Xiuyan Granitic Pluton, East China
by Zisong Zhao, Shengwei Wu, Fucheng Yu, Shanping Li and Zhiyi Zhao
Geosciences 2026, 16(3), 91; https://doi.org/10.3390/geosciences16030091 - 24 Feb 2026
Viewed by 499
Abstract
Mafic microgranular enclaves (MMEs) are widespread in granitic plutons and provide valuable insights into mush–magma mixing processes in crustal magma reservoirs. In this study, we characterize chemical zoning and Sr isotopic compositions of plagioclase in the MMEs, gabbro and host monzogranite from the [...] Read more.
Mafic microgranular enclaves (MMEs) are widespread in granitic plutons and provide valuable insights into mush–magma mixing processes in crustal magma reservoirs. In this study, we characterize chemical zoning and Sr isotopic compositions of plagioclase in the MMEs, gabbro and host monzogranite from the Late Triassic Xiuyan pluton in East China, to constrain the origin of MMEs and the role of crystal mushes in magma mixing. The MMEs in the Xiuyan pluton are angular and range from centimeters to several meters in size. They exhibit sharp contacts with the host monzogranite and show diverse disequilibrium textures. Plagioclase in MMEs occurs as fine-grained antecryst with normal zoning (An46–66 in the core and An17–29 in the rim). The cores are commonly characterized by coarse sieve textures, patchy zoning, and resorption surfaces at core–rim boundaries. In situ Sr isotopic compositions show subtle but systematic core–rim variations, with (87Sr/86Sr)i increasing slightly from cores (~0.70639) to rims (~0.70664), and rim values overlapping the whole-rock (87Sr/86Sr)i of MMEs. These features suggest that the rim was crystallized from locally hybridized melts produced by interaction between interstitial melts in a basaltic mush and granitic magma. Plagioclase in the gabbro occurs as medium-grained phenocryst with normal zoning (An46–65 in the core and An18–27 in the rim) but shows nearly homogeneous (87Sr/86Sr)i across individual grains (0.70612–0.70637), comparable to whole-rock gabbro values of 0.70623. The plagioclase cores in gabbro also show coarse sieve texture and patchy zoning with the resorption surface in the margin of the core and rim. We interpret the sieve textures in plagioclase cores from both MMEs and gabbro to record partial dissolution during rapid ascent and decompression of an initially H2O-undersaturated, crystal-bearing basaltic magma, during which increased effective water activity reduced plagioclase stability prior to the growth of the rim. Plagioclase in the host monzogranite is medium- to coarse-grained, compositionally homogeneous, and characterized by low An contents (An12–24) and elevated (87Sr/86Sr)i of ~0.70828. We propose that MMEs in the Xiuyan pluton formed when semi-consolidated mafic mush was mechanically disaggregated into angular fragments and subsequently entrained into coexisting granitic melt. This study reveals that MMEs formed by mechanical disaggregation of a semi-consolidated mafic mush into angular fragments, followed by their entrainment into the granitic melts. Full article
(This article belongs to the Section Geochemistry)
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19 pages, 15723 KB  
Article
Petrology and Geochemistry of Scandium in Wailukum Ni Laterites, East Halmahera, Indonesia
by Abdul Bari, Mega Fatimah Rosana, Euis Tintin Yuningsih, Ade Kadarusman, Rubima Aisha Yulman, Muhammad Chandra R. M. and Thaha Rizal Ulhaque
Minerals 2026, 16(2), 222; https://doi.org/10.3390/min16020222 - 22 Feb 2026
Viewed by 379
Abstract
The Wailukum area in North Maluku Province, Indonesia, is an ultramafic rock complex with a high degree of serpentinization. The mineral composition of ultramafic and mafic rocks strongly influences the distribution and enrichment of scandium (Sc) during lateritization. In this study, we aim [...] Read more.
The Wailukum area in North Maluku Province, Indonesia, is an ultramafic rock complex with a high degree of serpentinization. The mineral composition of ultramafic and mafic rocks strongly influences the distribution and enrichment of scandium (Sc) during lateritization. In this study, we aim to analyze three types of geological materials in a lateritic profile that contains Sc, specifically bedrock, saprolite, and limonite, in terms of element distribution, mineral composition, and rock identification. We used the analytical methods of petrography, X-ray diffraction (XRD), X-Ray Fluorescence (XRF), and Inductively Coupled Plasma–Optical Emission Spectroscopy (ICP-OES). The results show that Sc in bedrock is mainly associated with clinopyroxene minerals such as augite and diopside. In saprolite, Sc content decreases due to higher mobility but remains partly associated with clinopyroxene, and in limonite zone, Sc reaches maximum enrichment. Among rock types, gabbro contains the highest absolute Sc concentration (23.25 ppm in bedrock and up to 58.5 ppm in limonite), while wehrlite records the greatest enrichment ratio, with a 9.18-fold increase from bedrock to limonite. By contrast, gabbro shows the lowest enrichment ratio (2.52-fold) despite its high initial Sc content. These patterns indicate that Sc enrichment is controlled by clinopyroxene as the primary host in bedrock, affecting its relative stability during weathering. Full article
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17 pages, 2104 KB  
Article
Preliminary Evaluation of Gabbro Rock for Its Application in Agriculture as a Soil Remineralizer
by Karen Muñoz-Salas, María Guzmán-Florez, Xilena Galezo-Diaz, Claudete Gindri Ramos, Fausto A. Canales, Ruben Cantero-Rodelo and Edson Campanhola Bortoluzzi
Agriculture 2026, 16(4), 398; https://doi.org/10.3390/agriculture16040398 - 9 Feb 2026
Viewed by 520
Abstract
Dependence on fertilizers limits the sustainability of tropical agriculture. Remineralization using rock byproducts offers a solution that is conditioned by the mineralogical–soil interaction. This study evaluated the agronomic and geochemical potential of a gabbro rock byproduct (GRB) as a bulk amendment in yellow [...] Read more.
Dependence on fertilizers limits the sustainability of tropical agriculture. Remineralization using rock byproducts offers a solution that is conditioned by the mineralogical–soil interaction. This study evaluated the agronomic and geochemical potential of a gabbro rock byproduct (GRB) as a bulk amendment in yellow maize (Zea mays L.) cultivation in Atlántico, Colombia. The specific objectives were (1) to characterize the mineralogy and geochemistry of the local GRB; (2) to quantify its neutralizing and fertilizing effect in an acidic Arenosol soil; and (3) to evaluate the biometric response of yellow maize (Zea mays L.) in a field trial. The trial was conducted in an acidic haplic Arenosol (pH 5.4) in 2023, with a 70-day cycle, comparing three management systems: M1 (control), M2 (47 Mg·ha−1 GRB, seed type: ICA-109), and M3 (47 Mg·ha−1 GRB, seed type: V-114). The assessed GRB, with 52.75% SiO2 and 5.46% CaO, is rich in calcic plagioclase, clinopyroxenes, and zeolites. Application of GRB at 47 Mg·ha−1 in treatment M3 coincided with marked changes in soil properties over the course of the trial, with pH rising from 5.4 to 6.4, cation exchange capacity from 5.0 to 12.1 cmol_c·kg−1, and available phosphorus from 9.8 to 35.0 mg·kg−1. Plants in M3 showed statistically significant increases (p < 0.001) in ear weight (median: 150 g vs. 60.5 g in M1) and in vegetative development. Because the trial was pseudo-replicated, used a high single-dose “shock-loading” rate, involved different maize genotypes across treatments, and covered only one 70-day cycle, these results should be interpreted as exploratory and site-specific. Even so, they indicate that GRB can act as an effective acidity corrector and slow-release multinutrient source under Arenosol conditions, with relevance for circular-economy strategies. Future work should evaluate agronomically doses, include replicated multi-cycle trials, and incorporate comparative and risk-assessment analyses. Full article
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22 pages, 11470 KB  
Article
Geochronology and Geochemistry of Late Cretaceous Plutonic Rocks in Southeastern Anatolian Orogenic Belt, Eastern Türkiye: Implications for Petrogenesis and Tectonic Evolution
by Abdullah Sar and Mustafa Eren Rizeli
Minerals 2026, 16(2), 173; https://doi.org/10.3390/min16020173 - 5 Feb 2026
Viewed by 630
Abstract
Late Cretaceous plutonic rocks are commonly observed along the Southeastern Anatolian Orogenic Belt (SAOB), which constitutes a significant part of the Alpine–Himalayan Orogenic Belt. Here, we present new whole-rock geochemical analyses, zircon U–Pb ages, and zircon trace element data of plutonic rocks located [...] Read more.
Late Cretaceous plutonic rocks are commonly observed along the Southeastern Anatolian Orogenic Belt (SAOB), which constitutes a significant part of the Alpine–Himalayan Orogenic Belt. Here, we present new whole-rock geochemical analyses, zircon U–Pb ages, and zircon trace element data of plutonic rocks located in the SAOB (eastern Türkiye). This study aims to determine the petrogenesis of the studied plutonic rocks in light of new data and to contribute to the tectonic evolution of the SAOB. Geochemical data demonstrate that the studied granodiorites, diorites, and gabbros are tholeiitic–calc–alkaline in composition, metaluminous, and I-type granite. Zircon U-Pb ages yielded crystallisation ages of 73.52 ± 0.24 Ma for the studied granodiorites and 78.86 ± 0.39 Ma for the diorites. These age data indicate that the studied plutonic rocks represent the youngest granodiorite and diorite formations observed around the study area. High Th/U ratios (granodiorite: 0.15–0.29; diorite: 0.31–0.96) and positive Ce/Ce* (granodiorite: 8.11 to 609.86; diorite: 58.07 to 564.31) and negative Eu/Eu* (granodiorite: 0.49 to 0.62; diorite: 0.59–0.97) values obtained in zircon grains suggest that they are of magmatic origin. Geochemical data indicate that the studied diorites and gabbros originate from a spinel-bearing source representing shallow depths. In light of all the data, the studied plutonic rocks are products of arc magmatism resulting from the subduction of the NeoTethys Oceanic lithosphere along the SAOB. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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20 pages, 6564 KB  
Article
The Kovdozero and Pados-Tundra Complexes, Kola Peninsula, Russia: Comparable Geochemistry and Age
by Andrei Y. Barkov, Pavel A. Serov, Robert F. Martin, Tamara B. Bayanova and Tatyana V. Kaulina
Minerals 2026, 16(1), 8; https://doi.org/10.3390/min16010008 - 21 Dec 2025
Viewed by 583
Abstract
Geochemical whole-rock variations in the Kovdozero complex in the Lapland–Belomorian Belt (LBB) are compared with those observed in the Pados-Tundra layered complex in the Serpentinite Belt (SB) in the complementary structure in the Fennoscandian Shield. A great variety of coronitic associations exists in [...] Read more.
Geochemical whole-rock variations in the Kovdozero complex in the Lapland–Belomorian Belt (LBB) are compared with those observed in the Pados-Tundra layered complex in the Serpentinite Belt (SB) in the complementary structure in the Fennoscandian Shield. A great variety of coronitic associations exists in the entire LBB–SB system. The Kovdozero complex largely consists of more evolved products of crystallization. Our results of U–Pb dating (zircon and baddeleyite) give the dates of 2514 ± 5 and 2478 ± 6 Ma, leading to the revised age ~2.5 Ga for the Kovdozero complex. It is thus considered to be coeval with Pados-Tundra, Perchatka, and gabbro–anorthosite associations of the Belomorian province in the White Sea region. The variation trends are generally extensive, continuous and close to linear at Kovdozero, which point to crystallization of chonolithic bodies of the complex from a single portion of melt, in separate reservoirs that likely communicated to develop as a whole in the connected system. The extreme degree of differentiation of derivatives of the initial komatiitic magma occurred in the large-scale plume. It led to the development of shallowly emplaced complexes grading from dunitic rocks and associated chromitites with Ru–Os–Ir mineralization at Pados-Tundra (the center) to leucocratic gabbroic rocks at Kovdozero, and likely to gabbro–anorthosite rocks of the Belomorian province (the periphery); these are considered the final products in the megastructure. The εNd(T) values are slightly negative at Kovdozero: −0.43 and −0.60. They imply some degree of crustal contamination of the initial magma. The generalized date of 2.5 Ga likely represents the age of the coronitic complexes of ultrabasic–basic rocks that crystallized from portions of komatiite-derived melts in hypabyssal settings of the LBB–SB megastructure in the eastern Fennoscandian Shield. Full article
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30 pages, 6600 KB  
Article
Mineralogical and Geochemical Characteristics of the Fe-Ti Mineralized Mafic-Ultramafic Intrusions at Wajilitag, Tarim Basin, China: With Special Emphasis on the Role of Apatite
by Weicheng Wang, Zhigang Kong, Maohong Chen, Jinmao Yin, Maihemuti Maimaiti and Donghui Liu
Minerals 2025, 15(11), 1208; https://doi.org/10.3390/min15111208 - 16 Nov 2025
Viewed by 1156
Abstract
The Early Permian Tarim Large Igneous Province is a prominent magmatic-metallogenic province in China, hosting significant Fe-Ti mineralized mafic-ultramafic intrusions. Among them, the Wajilitag Fe-Ti oxide deposit stands out, which is hosted by olivine pyroxenite, clinopyroxenite, and gabbro. In the present study, we [...] Read more.
The Early Permian Tarim Large Igneous Province is a prominent magmatic-metallogenic province in China, hosting significant Fe-Ti mineralized mafic-ultramafic intrusions. Among them, the Wajilitag Fe-Ti oxide deposit stands out, which is hosted by olivine pyroxenite, clinopyroxenite, and gabbro. In the present study, we have examined the mineralogical and geochemical characteristics of apatite to elucidate a deeper understanding of the magmatic evolutionary processes and source characteristics of the mafic-ultramafic intrusions in the Wajilitag area. Petrographic analysis revealed three distinct types of apatite: (1) an inclusion phase within pyroxene and plagioclase, (2) an intergranular phase associated with Fe-Ti oxides, and (3) a late-stage phase found in association with biotite and/or amphibole. Geochemical analysis showed that the inclusion and intergranular apatites exhibited high fluoride (F) and low chlorine (Cl) concentrations, while the late-stage apatite displayed the reverse. A negative correlation between F and Cl was observed, suggesting different formation conditions for each apatite type. The high F/Cl ratios (>3) and enrichment of light rare earth elements (LREEs/HREEs = 12.8–29.5) in the apatite, in conjunction with Sr/Th-La/Sm diagrams, indicated that the parent magma originated from an enriched mantle source, influenced by ancient subduction-related fluids. Furthermore, low sulfur content (0.01%–0.16%) in apatite, along with estimated melt sulfur concentrations (19–54 ppm), points to a low sulfur fugacity environment. These findings collectively suggest that the Wajilitag deposit formed from magma derived from partial melting of an enriched mantle, followed by extensive magmatic differentiation, crystallization of Fe-Ti oxides, and low sulfur fugacity conditions. Full article
(This article belongs to the Special Issue Mineralization and Metallogeny of Iron Deposits)
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11 pages, 2514 KB  
Article
Influence of Western Keivy Massif Rocks on the Chemical Composition of Natural Waters (Kola Peninsula, Russia)
by Svetlana Mazukhina, Vladimir Masloboev, Sergey Mudruk and Svetlana Drogobuzhskaya
Minerals 2025, 15(11), 1197; https://doi.org/10.3390/min15111197 - 14 Nov 2025
Viewed by 442
Abstract
The presented work is a logical continuation of the study of the chemical composition of the Lovozero district waters (the Kola Peninsula, Russia), an area inhabited by indigenous populations. The problem was posed due to the discovery of rare earth elements in drinking [...] Read more.
The presented work is a logical continuation of the study of the chemical composition of the Lovozero district waters (the Kola Peninsula, Russia), an area inhabited by indigenous populations. The problem was posed due to the discovery of rare earth elements in drinking water in the Lovozero district (the Krasnoshchelye village). For monitoring, inductively coupled plasma was used, and the “water–rock” interaction was studied using “Selector” software. The results showed the Western Keivy Massif influence on the chemical composition of natural waters, which are used for drinking purposes for humans and animals. The interaction of water with magmatic rocks such as gabbro and subalkaline granites also leads to the formation of some major cations, anions, and heavy metals. Li, Sr, Y, La, and Ce concentrations are higher than in the Central’niy water intake located within the Khibiny Massif. The results of the modeling demonstrate the high migration capabilities of rare earth elements. The presence of rare elements and REEs in drinking surface and groundwaters, if consumed on a regular basis, can cause diseases of the nervous system and other organs. Full article
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39 pages, 23544 KB  
Article
Zircon Isotopic Constraints on Age, Magma Genesis, and Evolution of the Betic Ophiolites, Nevado-Filábride Complex, Spain
by Encarnación Puga, Antonio Díaz de Federico, Miguel A. Díaz Puga and José Miguel Nieto
Geosciences 2025, 15(10), 406; https://doi.org/10.3390/geosciences15100406 - 20 Oct 2025
Viewed by 867
Abstract
Metabasic rocks (eclogites and amphibolites) from four Betic ophiolite outcrops (Lugros, Almirez, Cóbdar, and Algarrobo), comprising Ol-Px gabbros, dolerites, and MORB-affinity basalts, were studied. U-Pb SHRIMP zircon dating yielded Early to Middle Jurassic ages (187–174 Ma). At Cóbdar and Algarrobo, several magmatic levels [...] Read more.
Metabasic rocks (eclogites and amphibolites) from four Betic ophiolite outcrops (Lugros, Almirez, Cóbdar, and Algarrobo), comprising Ol-Px gabbros, dolerites, and MORB-affinity basalts, were studied. U-Pb SHRIMP zircon dating yielded Early to Middle Jurassic ages (187–174 Ma). At Cóbdar and Algarrobo, several magmatic levels were identified (187 ± 1.7 to 174 ± 1.8 Ma, and 184 ± 1.8 to 180 ± 1.6 Ma, respectively). In Lugros, two gabbros were dated to 187 ± 2.5 and 184 ± 1.4 Ma, while a dolerite dyke intruding serpentinites in Almirez gave 184 ± 1.6 Ma. Algarrobo xenocrystic zircons, predominantly Precambrian, resemble those from the MAR (13° N–15° N) in age and chemistry, suggesting a similar tectonic setting. δ18O values (4.2–6.2‰) of Betic ophiolite zircons (gabbros, basalts, dolerites) match those of MAR and SWIR samples, reflecting also oceanic alteration. Some zircons preserve δ18O variations linked to Jurassic (~150 Ma) oceanic metamorphism and later orogenic overprints. REE patterns show depletions in HREE and Y, with localized enrichments in LREE and Hf, which are more marked in metamorphically recrystallized zones. Xenocrystic zircons may derive from Precambrian protoliths assimilated during Jurassic magma ascent near transform faults. This integrated geochronological and geochemical evidence provides the key constraints for a revised geodynamic framework, confirming the existence of a Betic Jurassic ocean basin, which is a crucial precursor to the Alpine orogenic events that shaped the region. Full article
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30 pages, 8388 KB  
Article
ASTER and Hyperion Satellite Remote Sensing Data for Lithological Mapping and Mineral Exploration in Ophiolitic Zones: A Case Study from Lasbela, Baluchistan, Pakistan
by Saima Khurram, Zahid Khalil Rao, Amin Beiranvand Pour, Khurram Riaz, Arshia Fatima and Amna Ahmed
Mining 2025, 5(3), 53; https://doi.org/10.3390/mining5030053 - 2 Sep 2025
Cited by 3 | Viewed by 2652
Abstract
This study evaluates the capabilities of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Hyperion remote sensing sensors for mapping ophiolitic sequences and identifying manganese mineralization in the Bela Ophiolite region, located along the axial fold–thrust belt northwest of Karachi, Pakistan. [...] Read more.
This study evaluates the capabilities of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Hyperion remote sensing sensors for mapping ophiolitic sequences and identifying manganese mineralization in the Bela Ophiolite region, located along the axial fold–thrust belt northwest of Karachi, Pakistan. The study area comprises tholeiitic basalts, gabbros, mafic and ultramafic rocks, and sedimentary formations where manganese occurrences are associated with jasperitic chert and shale. To delineate lithological units and Mn mineralization, advanced image processing techniques were applied, including band ratio (BR), Principal Component Analysis (PCA), and Spectral Angle Mapper (SAM) on visible and near-infrared (VNIR) and shortwave infrared (SWIR) bands of ASTER. Using these methods, gabbros, basalts, and mafic-ultramafic rocks were effectively mapped, and previously unrecognized basaltic outcrops and gabbroic outcrops were also discovered. The ENVI Spectral Hourglass Wizard was used to analyze the hyperspectral data, integrating the Minimum Noise Fraction (MNF), Pixel Purity Index (PPI), and N-Dimensional Visualizer to extract the spectra of end-members associated with Mn-bearing host rocks. In addition, the Hyperspectral Material Identification (HMI) tool was tested to recognize Mn minerals. The remote sensing results were validated by petrographic analysis and ground-truth data, confirming the effectiveness of these techniques in ophiolite mapping and mineral exploration. This study shows that ASTER band combinations (3-6-7, 3-7-9) and band ratios (1/4, 4/9, 9/1 and 3/4, 4/9, 9/1) provide optimal results for lithological discrimination. The results show that remote sensing-based image processing is a powerful tool for mapping ophiolites on a regional scale and can help geologists identify potential mineralization zones in ophiolitic sequences. Full article
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23 pages, 12646 KB  
Article
Titanite Textures, U-Pb Dating, Chemistry, and In Situ Nd Isotopes of the Lalingzaohuo Mafic Magmatic Enclaves and Host Granodiorites in the East Kunlun Orogen Belt: Insights into Magma Mixing Processes
by Zisong Zhao, Bingzhang Wang, Shengwei Wu and Jiqing Li
Minerals 2025, 15(9), 886; https://doi.org/10.3390/min15090886 - 22 Aug 2025
Cited by 2 | Viewed by 1240
Abstract
Widespread Triassic granitic magmatism is archived in the East Kunlun Orogen Belt (EKOB) of Northern Qinghai–Tibet Plateau. Mafic magmatic enclaves (MMEs), commonly hosted in these plutons, are generally interpreted as products of magma mixing; however, the specific magmatic processes remain poorly understood. In [...] Read more.
Widespread Triassic granitic magmatism is archived in the East Kunlun Orogen Belt (EKOB) of Northern Qinghai–Tibet Plateau. Mafic magmatic enclaves (MMEs), commonly hosted in these plutons, are generally interpreted as products of magma mixing; however, the specific magmatic processes remain poorly understood. In this study, we present new data on the complex zoning patterns, in situ U–Pb ages, trace element compositions, and Nd isotopic characteristics of titanite grains from the MMEs and host granodiorite of Laningzaohuo Zhongyou pluton. Whole-rock geochemical data indicate that the pluton is composed of volcanic arc-related, calc-alkaline, metaluminous I-type granodiorite. Titanite in the MMEs and the granodiorite yield similar U–Pb ages of ~244 Ma but display distinct textural and compositional features. Titanite from the granodiorite is typically euhedral, characterized by magmatic core and mantle with deuteric rim, and exhibits sector and fir-tree zoning in the core. In contrast, titanite from the MMEs is generally anhedral, also showing magmatic core and mantle as well as deuteric rims, but exhibits oscillatory zoning and incomplete sector and fir-tree zoning in the core. Titanite cores in the MMEs have εNd(t) ranging from −2.5 to −3.4, comparable to those of the coeval gabbro and MMEs elsewhere in the EKOB. These cores also show higher LREE/HREE ratios compared to titanite cores in the granodiorite, suggesting crystallization from mixed magmas with greater contributions from enriched lithospheric mantle sources. Titanite mantles in the MMEs yield εNd(t) of −4.0 to −4.8, slightly lower than the cores in the MMEs but higher than those of titanite cores and mantles in the granodiorite (−4.6 to −5.5). The mantle can be interpreted as crystallized from mixed magmas with less mafic components. Titanite rims in the MMEs have εNd(t) of −5.0 to −5.7, identical to those in the granodiorite, and have REE concentrations and Th/U and Nb/Ta ratios consistent with the titanite rims in the granodiorite, clearly indicative of crystallization from evolved, hydrated, granodioritic magmas. Plagioclase in the MMEs exhibits disequilibrium textures such as sieve texture and reverse zoning, with An36–66, contrasting with the more uniform An contents (An35–37) in the granodiorite. This suggests that plagioclase in the MMEs crystallized in an environment influenced by both mafic and felsic magmas. Amphibole thermobarometry indicates that amphibole in the MMEs crystallized at ~788 °C and ~295 MPa, slightly higher than the crystallization conditions in the granodiorite (~778 °C and ~259 MPa). We thus propose that the chemical and textural differences between titanite in the MMEs and granodiorite suggest that the MMEs formed within a mushy hybrid layer generated by injection of upwelling basaltic magma into a pre-existing granitic magma chamber. Titanite cores and mantles in the MMEs likely crystallized from variably mixed magmas. They subsequently underwent resorption and disequilibrium growth within the hybrid layer, and were eventually overgrown by rims formed from evolved interstitial granitic melts within the mushy enclaves. These findings demonstrate that the complex zoning and geochemical titanite in the MMEs provide valuable insights into magma mixing processes. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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20 pages, 10834 KB  
Article
Genesis of Basalts of the Raohe Subduction–Accretion Complex in the Wandashan Block, NE China, and Its Inspirations for Evolution of the Paleo-Pacific Ocean
by Qing Liu, Cui Liu, Jixu Liu, Jinfu Deng and Shipan Tian
Appl. Sci. 2025, 15(15), 8139; https://doi.org/10.3390/app15158139 - 22 Jul 2025
Viewed by 882
Abstract
The Raohe subduction–accretion complex (RSAC) in the Wandashan Block, NE China, comprises ultramafic rocks, gabbro, mafic volcanic rocks, deep-sea and hemipelagic sediments, and trench–slope turbidites. We investigate the basalts within the RSAC to resolve debates on its origin. Zircon U-Pb dating of pillow [...] Read more.
The Raohe subduction–accretion complex (RSAC) in the Wandashan Block, NE China, comprises ultramafic rocks, gabbro, mafic volcanic rocks, deep-sea and hemipelagic sediments, and trench–slope turbidites. We investigate the basalts within the RSAC to resolve debates on its origin. Zircon U-Pb dating of pillow basalt from Dadingzi Mountain yields a concordant age of 117.5 ± 2.1 Ma (MSWD = 3.6). Integrating previous studies, we identify three distinct basalt phases. The Late Triassic basalt (210 Ma–230 Ma) is characterized as komatites–melilitite, exhibiting features of island arc basalt, as well as some characteristics of E-MORB. It also contains high-magnesium lava, suggesting that it may be a product of a juvenile arc. The Middle Jurassic basalt (around 159 Ma–172 Ma) consists of a combination of basalt and magnesium andesite, displaying features of oceanic island basalt and mid-ocean ridge basalt. Considering the contemporaneous sedimentary rocks as hemipelagic continental slope deposits, it is inferred that these basalts were formed in an arc environment associated with oceanic subduction, likely as a result of subduction of the young oceanic crust. The Early Cretaceous basalt (around 117 Ma) occurs in pillow structures, exhibiting some characteristics of oceanic island basalt but also showing transitional features towards a continental arc. Considering the regional distribution of the rocks, it is inferred that this basalt likely formed in a back-arc basin. Integrating the formation ages, nature, and tectonic attributes of the various structural units within the RSAC, as well as previous research, it is inferred that subduction of the Paleo-Pacific Ocean had already begun during the Late Triassic and continued into the Early Cretaceous without cessation. Full article
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