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35 pages, 8287 KB  
Review
Leakage Mechanisms and Airtightness Challenges in FFF-Printed Soft Pneumatic Actuators: A Scoping Review
by Getachew Ambaye and Krishna Krishnan
Electronics 2026, 15(14), 3227; https://doi.org/10.3390/electronics15143227 - 22 Jul 2026
Viewed by 219
Abstract
Fused filament fabrication (FFF) is one of the most widely adopted additive manufacturing methods for thermoplastic polyurethane (TPU)-based soft pneumatic actuators, enabling low-cost fabrication, geometric customization, embedded pneumatic architectures, and rapid prototyping for soft robotic systems. However, despite these advantages, achieving reliable airtightness [...] Read more.
Fused filament fabrication (FFF) is one of the most widely adopted additive manufacturing methods for thermoplastic polyurethane (TPU)-based soft pneumatic actuators, enabling low-cost fabrication, geometric customization, embedded pneumatic architectures, and rapid prototyping for soft robotic systems. However, despite these advantages, achieving reliable airtightness remains a major challenge due to process-induced anisotropy, interlayer voids, incomplete filament fusion, residual porosity, seam discontinuities, material permeability, and interface-related leakage. These defects can significantly reduce pressure retention, actuation efficiency, deformation repeatability, and long-term pneumatic reliability. This review systematically examines the dominant leakage mechanisms affecting FFF-printed soft pneumatic actuators and comparatively analyzes fabrication approaches, TPU material systems, geometric design factors, post-processing methods, sealing strategies, and leakage characterization techniques. Representative experimental observations, including pressure-decay testing, submerged-bubble visualization, microscopy, and localized thermal surface treatment, are also discussed to connect the findings reported in the literature with experimentally observed leakage behavior. Emerging analytical leakage models, sensing technologies, AI-assisted predictive monitoring, and digital-twin-enabled manufacturing frameworks are reviewed as promising approaches for developing leakage-aware soft robotic systems. The review highlights current limitations related to standardized leakage testing, cyclic durability evaluation, scalable sealing strategies, and intelligent manufacturing integration. Overall, airtightness is identified as a coupled material-process-geometry challenge that must be systematically addressed to improve the reliability, scalability, and long-term operational stability of next-generation TPU-based soft pneumatic actuators. The review was conducted following the PRISMA-ScR framework and includes 248 studies published between 2017 and 2026. Full article
(This article belongs to the Special Issue New Trends in Soft Robotics and Mechatronics)
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18 pages, 4022 KB  
Article
Enhancing PLA Strength and Layer Adhesion: Physical and Microstructural Insights from Vibration-Assisted FFF/FDM
by Lotfi Ben Said, Fouzi Alhadar, Hamdi Hentati, Mondher Wali, Badreddine Ayadi, Sattam Alharbi and Muapper Alhadri
Polymers 2026, 18(14), 1767; https://doi.org/10.3390/polym18141767 - 20 Jul 2026
Viewed by 300
Abstract
Material Extrusion (MEX), particularly Fused Filament Fabrication (FFF), commercially known as Fused Deposition Modeling (FDM), has become one of the most widely used additive manufacturing technologies for producing polymer components. However, the mechanical performance of printed parts remains limited by weak interlayer bonding [...] Read more.
Material Extrusion (MEX), particularly Fused Filament Fabrication (FFF), commercially known as Fused Deposition Modeling (FDM), has become one of the most widely used additive manufacturing technologies for producing polymer components. However, the mechanical performance of printed parts remains limited by weak interlayer bonding and internal porosity. This study investigates the effectiveness of controlled low-frequency bed vibration in improving the physical and mechanical properties of PLA components manufactured by vibration-assisted FFF/FDM. The influence of printing speed, raster angle, and vibration level was experimentally evaluated through tensile, flexural, surface roughness, Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscopy (SEM) analyses. Response Surface Methodology (RSM) was employed to optimize the process parameters with respect to tensile strength, yield strength, flexural strength, and surface quality. The results demonstrate that moderate bed vibration (Level 2) provides the best overall performance, improving the mechanical properties by approximately 8–15% compared with conventional printing. SEM observations revealed an approximately 60% reduction in average pore size, together with enhanced filament fusion and interlayer adhesion, while FTIR analysis confirmed that the chemical structure of PLA remained unchanged. These findings demonstrate that controlled mechanical bed vibration is a simple and effective strategy for enhancing the quality, reliability, and structural performance of FFF/FDM-printed PLA components. The proposed approach also provides practical guidelines for optimizing additive manufacturing processes and supports the development of advanced polymer manufacturing capabilities in Hail’s growing industrial sector. Full article
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12 pages, 1177 KB  
Perspective
Current Developments in the Use of FDM 3D-Printed Materials for Efficient Heat Transfer Applications
by Paweł Madejski and Ali Raza
Materials 2026, 19(13), 2836; https://doi.org/10.3390/ma19132836 - 3 Jul 2026
Viewed by 382
Abstract
This work investigates the potential of additive manufacturing (AM) technologies for prototyping and developing functional components in thermal systems, with particular emphasis on thermal and mechanical performance. The study focuses on two complementary prototyping strategies: (i) the use of metal-filled polymer filaments in [...] Read more.
This work investigates the potential of additive manufacturing (AM) technologies for prototyping and developing functional components in thermal systems, with particular emphasis on thermal and mechanical performance. The study focuses on two complementary prototyping strategies: (i) the use of metal-filled polymer filaments in Fused Deposition Modeling (FDM), also known as Material Extrusion (MEX) according to ISO/ASTM 52900:2022, and (ii) a hybrid approach combining polymer 3D printing with conductive coating and electrochemical copper deposition. While metal-filled filaments provide a rapid and low-cost solution for early-stage prototyping, their mechanical properties remain similar to those of the polymer matrix, limiting their applicability in load-bearing structures. In contrast, the hybrid method enables the fabrication of hollow metallic geometries with improved thermal and electrical conductivity. This approach is more time-consuming and process-intensive and is therefore considered a subsequent stage in the prototyping workflow following initial MEX-based design iterations. Compared with conventional polymer-based MEX, several AM approaches enable the development and fabrication of fully metallic or metal-functional structures, including Powder Bed Fusion (PBF), Directed Energy Deposition (DED), and hybrid polymer–metal methods based on electroplating. Furthermore, understanding mechanical properties such as tensile strength is essential for assessing the applicability of AM materials in energy system components. The results contribute to bridging the gap between rapid prototyping and the implementation of advanced AM technologies in thermal-related applications. Full article
(This article belongs to the Special Issue Design and Application of Additive Manufacturing: 4th Edition)
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16 pages, 2236 KB  
Article
Development of Low-Resistance Conductive Threads from E-Waste for Smart Textiles
by Aman Ul Azam Khan, Nazmunnahar Nazmunnahar, Mehedi Hasan Roni, Aurghya Kumar Saha, Zarin Tasnim Bristy, Abdul Baqui and Abdul Md Mazid
Fibers 2026, 14(3), 36; https://doi.org/10.3390/fib14030036 - 12 Mar 2026
Cited by 1 | Viewed by 1746
Abstract
Conductive thread is an integral aspect of smart textiles in the domain of electronic textiles (e-textiles). This study unveils the development of twelve distinct variants of conductive threads using the twisting method: the fusion of copper filament with cotton and polyester threads. The [...] Read more.
Conductive thread is an integral aspect of smart textiles in the domain of electronic textiles (e-textiles). This study unveils the development of twelve distinct variants of conductive threads using the twisting method: the fusion of copper filament with cotton and polyester threads. The threads are coated with a carbon paste solution enriched with dissolved sea salt. The carbon paste is obtained from non-functional dry cell batteries, conventionally categorized as hazardous electronic waste (e-waste), which underscores an economically viable and environmentally sustainable approach. Experiments proved that each variant demonstrates minimal electrical resistance. The lowest resistance, 0.0164 ± 0.0001 Ω/cm, was achieved by Carbon-Coated Cotton Twisted Copper Thread-II. Comparative evaluation with commercially available conductive threads, including Bekaert Bekinox® VN type (12/1x275/100z), indicated comparable or moderately lower resistance values for the developed copper-based threads. Mechanical–electrical stability under bending, twisting, and wash–dry cycles confirmed consistent conductive performance with minimal resistance variation. Practical demonstrations further validated the integration of the threads into fabric-based flexible circuits and wearable electronic systems. These findings demonstrate that twisted copper-based conductive threads derived from sustainable coating materials provide a promising alternative for smart textile and wearable electronic applications. Future research should focus on scalable fabrication, enhanced coating fixation, and long-term durability assessment. Full article
(This article belongs to the Special Issue Smart Textiles—2nd Edition)
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24 pages, 3211 KB  
Article
Reinforcement of Novel PLA/17-4 PH Stainless Steel Hybrid Structures Fabricated by FDM: The Effects of Layer Configuration, Infill Density and Pattern
by Ramazan Ötüken, Cem Alparslan, Muhammed Furkan Erhan and Şenol Bayraktar
Polymers 2026, 18(6), 672; https://doi.org/10.3390/polym18060672 - 10 Mar 2026
Cited by 2 | Viewed by 1233
Abstract
Fused deposition modeling/fused filament fabrication (FDM/FFF) enables architectural tailoring of mechanical response through layer configuration and multi-material manufacturing strategies. However, the combined effects of layer arrangement, infill ratio, and packing geometry in polymer–metal hybrid structures and interfacial load transfer mechanisms are still not [...] Read more.
Fused deposition modeling/fused filament fabrication (FDM/FFF) enables architectural tailoring of mechanical response through layer configuration and multi-material manufacturing strategies. However, the combined effects of layer arrangement, infill ratio, and packing geometry in polymer–metal hybrid structures and interfacial load transfer mechanisms are still not sufficiently elucidated. In this study, the tensile behavior of single- and multi-material structures produced using PLA and 17-4 PH stainless steel filaments was systematically investigated. A total of 24 experimental parameter sets were created with four-layer configurations (PLA, 17-4 PH, PLA/17-4 PH/PLA, and 17-4 PH/PLA/17-4 PH), three infill ratios (20%, 60%, and 100%), and two packing patterns (linear and hexagonal); the samples were tested according to the ASTM D638 standard. Mechanical data were modeled using Response Surface Methodology (RSM) and ANOVA, and the developed regression models showed high accuracy (R2 > 0.95). The findings showed that tensile and yield strength are primarily controlled by the layer arrangement, while infill ratio and infill pattern have a secondary effect. The highest strength was measured in 100% infill linear PLA samples (≈10.35 MPa), and the lowest value was measured in 17-4 PH “green part” samples without sintering (≈0.92 MPa). Hybrid structures exhibited intermediate performance in the range of 2.9–4.9 MPa. ANOVA results showed that the majority of the mechanical variance was explained by the layer arrangement (70–85% contribution), while infill ratio and infill pattern had a secondary effect. Fracture surface analyses showed that high performance was associated with homogeneous filament fusion and low porosity; Studies have confirmed that poor performance is associated with delamination and interfacial separation. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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15 pages, 2119 KB  
Article
Effects of In Situ Preheating Technology on Mechanical Properties and Microstructure of FFF-Printed PEEK
by Junhua Wang, Yuanming Mao, Jianan Shen, Yan Lu, Kun Li, Junfei Xu, Zhuangya Zhang, Ruijie Gu and Tancheng Xie
Micromachines 2026, 17(3), 303; https://doi.org/10.3390/mi17030303 - 28 Feb 2026
Viewed by 712
Abstract
The Polyether ether ketone (PEEK) suffers from insufficient interlayer molecular chain diffusion and weak interfacial fusion during Fused Filament Fabrication (FFF) due to its high melt viscosity and rapid cooling characteristics, restricting the mechanical properties and engineering applications of printed parts. To improve [...] Read more.
The Polyether ether ketone (PEEK) suffers from insufficient interlayer molecular chain diffusion and weak interfacial fusion during Fused Filament Fabrication (FFF) due to its high melt viscosity and rapid cooling characteristics, restricting the mechanical properties and engineering applications of printed parts. To improve the interlayer bonding quality of FFF-printed PEEK, an in situ preheating technology integrated into the print nozzle was proposed and implemented. Through a high-temperature controllable preheating system that moves synchronously with the nozzle, local precise heating is performed on the surface of the deposited layer to actively regulate the thermal history of the interlayer interface. Systematic studies on the effect of preheating temperature were conducted. The results show that the influence of preheating temperature on part performance follows a trend of first increasing and then decreasing. When the preheating temperature is 280 °C, the comprehensive performance of the specimens is optimal: the tensile strength reaches 69.47 MPa, which is 21.3% higher than that of the non-preheated reference group; the elongation at break is 71.07%; and the porosity decreases to 8.36%. Microstructural analysis reveals that moderate preheating facilitates molecular chain diffusion and interfacial fusion, whereas excessive heating induces thermal oxidative degradation of PEEK, resulting in deteriorated mechanical performance. These findings confirm that in situ preheating represents an effective approach for enhancing interlayer bonding, thereby offering a practical solution for the additive manufacturing of high-performance PEEK components. Full article
(This article belongs to the Special Issue Advanced Micro- and Nano-Manufacturing Technologies, 3rd Edition)
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13 pages, 18580 KB  
Article
Optimization of Gamma Image Quality Through Experimental Evaluation Using 3D-Printed Phantoms Across Energy Window Levels
by Chanrok Park, Joowan Hong and Min-Gwan Lee
Bioengineering 2025, 12(11), 1211; https://doi.org/10.3390/bioengineering12111211 - 6 Nov 2025
Viewed by 1055
Abstract
Energy window selection is a critical parameter for optimizing planar gamma image quality in nuclear medicine. In this study, we developed dedicated nuclear medicine phantoms using 3D printing technology to evaluate the impact of varying energy window levels on image quality. Three types [...] Read more.
Energy window selection is a critical parameter for optimizing planar gamma image quality in nuclear medicine. In this study, we developed dedicated nuclear medicine phantoms using 3D printing technology to evaluate the impact of varying energy window levels on image quality. Three types of phantoms—a Derenzo phantom with six different sphere diameters, a modified Hoffman phantom incorporating lead for attenuation, and a quadrant bar phantom with four bar thicknesses constructed from bronze filament—were fabricated using Fusion 360 and an Ultimaker S5 3D printer with PLA and bronze-based materials. Planar images were acquired using 37 MBq of Tc-99m for 60 s at energy windows centered at 122, 140, and 159 keV. Quantitative assessments included contrast-to-noise ratio (CNR), coefficient of variation (COV), peak signal-to-noise ratio (PSNR), and structural similarity index measure (SSIM), comparing all images with the 140 keV image as the reference. The results showed a consistent decline in image quality at 122 keV and 159 keV, with the highest CNR, lowest COV, and optimal PSNR/SSIM values obtained at 140 keV. In visual analysis using the quadrant bar phantom, thinner bars were more clearly discernible at 140 keV than at other energy levels. These findings demonstrate that the application of an appropriate energy window—particularly 140 keV for Tc-99m—substantially improves image quality in planar gamma imaging. The use of customized, material-specific 3D-printed phantoms also enables flexible, reproducible evaluation protocols for energy-dependent imaging optimization and quality assurance in clinical nuclear medicine. Full article
(This article belongs to the Section Biomedical Engineering and Biomaterials)
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13 pages, 1994 KB  
Communication
Injection Mold for Plastics Manufactured by Metal-FFF with Conformal Cooling Channels: A Proof-of-Concept Case
by José Enrique Solís, Juan Claver, Marta María Marín, Eva María Rubio and Amabel García-Domínguez
Machines 2025, 13(9), 784; https://doi.org/10.3390/machines13090784 - 1 Sep 2025
Viewed by 1606
Abstract
Injection molding is widely used for mass-producing plastic components, demanding precise thermal control to optimize cycle times and part quality. Traditional CNC-machined molds limit design flexibility and restrict advanced cooling features like conformal cooling channels (CCCs). Integrating CCCs improves cooling performance, reduces cycle [...] Read more.
Injection molding is widely used for mass-producing plastic components, demanding precise thermal control to optimize cycle times and part quality. Traditional CNC-machined molds limit design flexibility and restrict advanced cooling features like conformal cooling channels (CCCs). Integrating CCCs improves cooling performance, reduces cycle times, and offers more efficient, cost-effective designs. Additive manufacturing (AM), especially Metal-Fused Filament Fabrication (Metal-FFF), offers geometries unattainable by machining. While most mold research focuses on Laser Powder Bed Fusion (LPBF), the feasibility of Metal-FFF molds remains underexplored. This study presents the design, fabrication, and experimental evaluation of an injection mold produced via Metal-FFF with integrated CCCs. The process included computational design, resistance simulations, fabrication, debinding, sintering, and post-processing, followed by testing under injection molding conditions. Results show that Metal-FFF molds with CCCs boost cooling efficiency, cutting cycle times by about 30% compared to conventional molds, while offering greater design freedom and economic benefits. Nonetheless, issues such as porosity and shrinkage need further refinement to fully leverage this technology for industrial use. Full article
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24 pages, 4087 KB  
Article
Optimization of Nozzle Diameter and Printing Speed for Enhanced Tensile Performance of FFF 3D-Printed ABS and PLA
by I. S. ELDeeb, Ehssan Esmael, Saad Ebied, Mohamed Ragab Diab, Mohammed Dekis, Mikhail A. Petrov, Abdelhameed A. Zayed and Mohamed Egiza
J. Manuf. Mater. Process. 2025, 9(7), 221; https://doi.org/10.3390/jmmp9070221 - 1 Jul 2025
Cited by 16 | Viewed by 5738
Abstract
Fused Filament Fabrication (FFF) is a widely adopted additive manufacturing technique, yet its mechanical performance is highly dependent on process parameters, particularly nozzle diameter and printing speed. This study evaluates the influence of these parameters on the tensile behavior of Acrylonitrile Butadiene Styrene [...] Read more.
Fused Filament Fabrication (FFF) is a widely adopted additive manufacturing technique, yet its mechanical performance is highly dependent on process parameters, particularly nozzle diameter and printing speed. This study evaluates the influence of these parameters on the tensile behavior of Acrylonitrile Butadiene Styrene (ABS) and Polylactic Acid (PLA), aiming to determine optimal conditions for enhanced strength. ASTM D638-Type IV specimens were printed using nozzle diameters ranging from 0.05 to 0.25 mm and speeds from 15 to 80 mm/s. For ABS, tensile strength increased from 56.46 MPa to 60.74 MPa, representing a 7.6% enhancement, as nozzle diameter increased, with the best performance observed at 0.25 mm and 45 mm/s, attributed to improved melt flow and interlayer fusion. PLA exhibited a non-linear response, reaching a maximum strength of 89.59 MPa under the same conditions, marking a 22.3% enhancement over the minimum value. The superior performance of PLA was linked to optimal thermal management that enhanced crystallinity and interlayer bonding. Fractographic analysis revealed reduced porosity and smoother fracture surfaces under optimized conditions. Overall, PLA consistently outperformed ABS across all settings, with an average tensile strength advantage of 47.5%. The results underscore the need for material-specific parameter tuning in FFF and offer practical insights for optimizing mechanical performance in applications demanding high structural integrity, including biomedical, aerospace, and functional prototyping. Full article
(This article belongs to the Special Issue Recent Advances in Optimization of Additive Manufacturing Processes)
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17 pages, 3640 KB  
Article
Sustainable Development of PLA-Based Biocomposites Reinforced with Pineapple Core Powder: Extrusion and 3D Printing for Thermal and Mechanical Performance
by Kawita Chattrakul, Anothai Pholsuwan, Athapon Simpraditpan, Ekkachai Martwong and Wichain Chailad
Polymers 2025, 17(13), 1792; https://doi.org/10.3390/polym17131792 - 27 Jun 2025
Cited by 9 | Viewed by 1905
Abstract
This study developed sustainable biocomposites composed of polylactic acid (PLA) and surface-treated pineapple core powder (PACP), fabricated via extrusion and fused deposition modelling (FDM). PACP loadings of 1–3 vol% were combined after chemical modification with NaOH and silane to improve interfacial bonding. Particle [...] Read more.
This study developed sustainable biocomposites composed of polylactic acid (PLA) and surface-treated pineapple core powder (PACP), fabricated via extrusion and fused deposition modelling (FDM). PACP loadings of 1–3 vol% were combined after chemical modification with NaOH and silane to improve interfacial bonding. Particle morphology showed increased porosity and surface roughness following treatment. The melt flow index (MFI) increased from 31.56 to 35.59 g/10 min at 2 vol% PACP, showing improved flowability. Differential scanning calorimetry (DSC) showed the emergence of cold crystallization (Tcc ~121 °C) and an increase in crystallinity from 35.7% (neat PLA) to 47.3% (2 vol% PACP). Thermogravimetric analysis showed only slight decreases in T5 and Tmax, showing the thermal stability. The mechanical testing of extruded filaments showed increased modulus (1463 to 1518 MPa) but a decrease in tensile strength and elongation. For the 3D-printed samples, elongation at break increased slightly at 1–2 vol% PACP, likely because of the improvement in interlayer fusion. Though, at 3 vol% PACP, the mechanical properties declined, consistent with filler agglomeration observed in SEM. Overall, 2 vol% PACP offered the optimal balance between printability, crystallinity, and mechanical performance. These results reveal the possibility of PACP as a value-added biowaste filler for eco-friendly PLA composites suitable for extrusion and 3D printing applications. Full article
(This article belongs to the Special Issue Sustainable Biopolymers and Bioproducts from Bioresources)
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15 pages, 2767 KB  
Article
Solid-to-Solid Manufacturing Processes for High-Performance Li-Ion Solid-State Batteries
by David Orisekeh, Byeong-Min Roh and Xinyi Xiao
Polymers 2025, 17(13), 1788; https://doi.org/10.3390/polym17131788 - 27 Jun 2025
Cited by 7 | Viewed by 2303
Abstract
Batteries are used as energy storage devices in various equipment. Today, research is focused on solid-state batteries (SSBs), replacing the liquid electrolyte with a solid separator. The solid separators provide electrolyte stability, no leakage, and provide mechanical strength to the battery. Separators are [...] Read more.
Batteries are used as energy storage devices in various equipment. Today, research is focused on solid-state batteries (SSBs), replacing the liquid electrolyte with a solid separator. The solid separators provide electrolyte stability, no leakage, and provide mechanical strength to the battery. Separators are mostly manufactured by either traditional processes or 3D printing technologies. These processes involve making a slurry of plastic, active and conductive material and usually adding a plasticizer when making thin films or filaments for 3D printing. This study investigates the additive manufacturing of solid-state electrolytes (SSEs) by employing fused deposition modeling (FDM) with recyclable, bio-derived polylactic acid (PLA) filaments. Precise control of macro-porosity is achieved by systematically varying key process parameters, including raster orientation, infill percentage, and interlayer adhesion conditions, thereby enabling the formation of tunable, interconnected pore networks within the polymer matrix. Following 3D printing, these engineered porous frameworks are infiltrated with lithium hexafluorophosphate (LiPF6), which functions as the active ionic conductor. A tailored thermal sintering protocol is then applied to promote solid-phase fusion of the embedded salt throughout the macro-porous PLA scaffold, resulting in a mechanically robust and ionically conductive composite separator. The electrochemical ionic conductivity and structural integrity of the sintered SSEs are characterized through electrochemical impedance spectroscopy (EIS) and standardized mechanical testing to assess their suitability for integration into advanced solid-state battery architectures. The solid-state separator achieved an average ionic conductivity of 2.529 × 10−5 S·cm−1. The integrated FDM-sintering process enhances ion exchange at the electrode–electrolyte interface, minimizes material waste, and supports cost-efficient, fully recyclable component fabrication. Full article
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24 pages, 9732 KB  
Article
Development and Validation of a Desktop 3D Printing System with Thermo-Mechanical In Situ Consolidation for Continuous Fiber-Reinforced Polymer Composites
by Hannes Oberlercher, Marius Laux, Gean Henrique Marcatto de Oliveira and Sergio T. Amancio-Filho
J. Compos. Sci. 2025, 9(3), 128; https://doi.org/10.3390/jcs9030128 - 10 Mar 2025
Cited by 2 | Viewed by 3431
Abstract
A controlled laminate consolidation is one of the most essential approaches in the production of fiber-reinforced thermoplastics components. With the use of specific consolidation models, almost the entire strength potential of the material can be exploited. However, a controlled thermo-mechanical in situ consolidation [...] Read more.
A controlled laminate consolidation is one of the most essential approaches in the production of fiber-reinforced thermoplastics components. With the use of specific consolidation models, almost the entire strength potential of the material can be exploited. However, a controlled thermo-mechanical in situ consolidation (TMIC) strategy in the fused filament fabricated (FFF) process of continuous fiber-reinforced polymer composites (CFRPC) has not been considered so far and leads to deconsolidation defects in the 3D-printed material. These defects in terms of micro and macro volumetric flaws in the joining zone indicate a poor process parameter selection and inadequate thermo-mechanical consolidation. These imperfections lead to a reduction in the fiber volume content and a significant deterioration in the mechanical properties. In this work, a self-developed test rig is presented, which is able to influence and monitor the consolidation during the additive manufacturing (AM) process with a TMIC unit in a controlled manner. To evaluate the test rig, the mechanical construction and the implemented sensors were tested for full functionality. Subsequently, test specimens were fabricated for mechanical characterization using three-point bending (3PB) tests and microstructural analysis. Based on these results, the influence of TMIC, with its dependent process parameters (consolidation force, temperature, printing speed), is presented. A perspective on the future development of controlled consolidation in AM of CFRPC is shown. Full article
(This article belongs to the Special Issue Polymer Composites and Fibers, 3rd Edition)
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28 pages, 8366 KB  
Article
Artificial Neural Network Modeling of Mechanical Properties of 3D-Printed Polyamide 12 and Its Fiber-Reinforced Composites
by Catalin Fetecau, Felicia Stan and Doina Boazu
Polymers 2025, 17(5), 677; https://doi.org/10.3390/polym17050677 - 3 Mar 2025
Cited by 25 | Viewed by 3283
Abstract
Fused filament fabrication (FFF) has recently emerged as a sustainable digital manufacturing technology to fabricate polymer composite parts with complex structures and minimal waste. However, FFF-printed composite parts frequently exhibit heterogeneous structures with low mechanical properties. To manufacture high-end parts with good mechanical [...] Read more.
Fused filament fabrication (FFF) has recently emerged as a sustainable digital manufacturing technology to fabricate polymer composite parts with complex structures and minimal waste. However, FFF-printed composite parts frequently exhibit heterogeneous structures with low mechanical properties. To manufacture high-end parts with good mechanical properties, advanced predictive tools are required. In this paper, Artificial Neural Network (ANN) models were developed to evaluate the mechanical properties of 3D-printed polyamide 12 (PA) and carbon fiber (CF) and glass fiber (GF) reinforced PA composites. Tensile samples were fabricated by FFF, considering two input parameters, such as printing orientation and infill density, and tested to determine the mechanical properties. Then, single- and multi-target ANN models were trained using the forward propagation Levenberg–Marquardt algorithm. Post-training performance analysis indicated that the ANN models work efficiently and accurately in predicting Young’s modulus and tensile strength of the 3D-printed PA and fiber-reinforced PA composites, with most relative errors being far less than 5%. In terms of mechanical properties, such as Young’s modulus and tensile strength, the 3D-printed composites outperform the unreinforced PA. Printing PA composites with 0° orientation and 100% infill density results in a maximum increase in Young’s modulus (up to 98% for CF/PA and 32% for GF/PA) and tensile strength (up to 36% for CF/PA and 18% for GF/PA) compared to the unreinforced PA. This study underscores the potential of the ANN models to predict the mechanical properties of 3D-printed parts, enhancing the use of 3D-printed PA composite components in structural applications. Full article
(This article belongs to the Special Issue 3D Printing of Polymer Composite Materials)
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63 pages, 15790 KB  
Review
Detecting Multi-Scale Defects in Material Extrusion Additive Manufacturing of Fiber-Reinforced Thermoplastic Composites: A Review of Challenges and Advanced Non-Destructive Testing Techniques
by Demeke Abay Ashebir, Andreas Hendlmeier, Michelle Dunn, Reza Arablouei, Stepan V. Lomov, Adriano Di Pietro and Mostafa Nikzad
Polymers 2024, 16(21), 2986; https://doi.org/10.3390/polym16212986 - 24 Oct 2024
Cited by 75 | Viewed by 12349
Abstract
Additive manufacturing (AM) defects present significant challenges in fiber-reinforced thermoplastic composites (FRTPCs), directly impacting both their structural and non-structural performance. In structures produced through material extrusion-based AM, specifically fused filament fabrication (FFF), the layer-by-layer deposition can introduce defects such as porosity (up to [...] Read more.
Additive manufacturing (AM) defects present significant challenges in fiber-reinforced thermoplastic composites (FRTPCs), directly impacting both their structural and non-structural performance. In structures produced through material extrusion-based AM, specifically fused filament fabrication (FFF), the layer-by-layer deposition can introduce defects such as porosity (up to 10–15% in some cases), delamination, voids, fiber misalignment, and incomplete fusion between layers. These defects compromise mechanical properties, leading to reduction of up to 30% in tensile strength and, in some cases, up to 20% in fatigue life, severely diminishing the composite’s overall performance and structural integrity. Conventional non-destructive testing (NDT) techniques often struggle to detect such multi-scale defects efficiently, especially when resolution, penetration depth, or material heterogeneity pose challenges. This review critically examines manufacturing defects in FRTPCs, classifying FFF-induced defects based on morphology, location, and size. Advanced NDT techniques, such as micro-computed tomography (micro-CT), which is capable of detecting voids smaller than 10 µm, and structural health monitoring (SHM) systems integrated with self-sensing fibers, are discussed. The role of machine-learning (ML) algorithms in enhancing the sensitivity and reliability of NDT methods is also highlighted, showing that ML integration can improve defect detection by up to 25–30% compared to traditional NDT techniques. Finally, the potential of self-reporting FRTPCs, equipped with continuous fibers for real-time defect detection and in situ SHM, is investigated. By integrating ML-enhanced NDT with self-reporting FRTPCs, the accuracy and efficiency of defect detection can be significantly improved, fostering broader adoption of AM in aerospace applications by enabling the production of more reliable, defect-minimized FRTPC components. Full article
(This article belongs to the Special Issue Fibre-Reinforced Polymer Laminates: Structure and Properties)
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42 pages, 8616 KB  
Review
Cancellous Skeleton, Microskeleton, Ultramicroskeleton: A Geo/Biomorphological Bone Mineral Microbiome of Hierarchical Force Translation and Ancient Golgi-Directed Lineage
by Jean E. Aaron
Biophysica 2024, 4(3), 369-410; https://doi.org/10.3390/biophysica4030026 - 22 Aug 2024
Viewed by 3715
Abstract
Bone minerals may be more complex than the prevailing opinion suggests. Understanding its biomaterial properties in health and disease may address fundamental geo/biomorphological ambiguities recurrent within its calcified cancellous hierarchy of macro-, micro-, and nano-skeletal networks. (i) There is evidence that the outer [...] Read more.
Bone minerals may be more complex than the prevailing opinion suggests. Understanding its biomaterial properties in health and disease may address fundamental geo/biomorphological ambiguities recurrent within its calcified cancellous hierarchy of macro-, micro-, and nano-skeletal networks. (i) There is evidence that the outer mineral macroskeleton of interconnected trabeculae (150 µm diameter) is modulated according to axes of tensile stress by permeating arrays of periosteal Sharpey’s fibres (collagen type III/VI, 5–25 µm thick) studded with tenascin organiser protein. (ii) Its substructural mineral microskeleton is a reticulation of bridged and deformable calcium phosphate/carbonate microspheres (about 1 µm diameter). These organically enshrouded (e.g., bone sialoprotein, osteocalcin, osteopontin) objects, configured by the adhesive organiser protein fibronectin and tempered by trace elements (e.g., Si, Mg, Fe, Al), display differential histochemistry (e.g., acid phosphatase, carbonic anhydrase) and anomalous traits (tetracycline binding, gram-positive microbial staining and nucleic acid staining affinity). The calcified microspheres are intracellular fabrications of osteocyte cohorts developed within “switched on” Golgi cisternae prior to aggregation at the extracellular calcification front in chains and looped assemblies. (iii) Within each microsphere, a less dense centre is encircled by a mineral nanoskeleton of beaded filaments (5 nm in diameter) transmutable in electron density, with a trait for lateral fusion into ladder-like struts, stays and senescent fenestrated plates, constituting domains of microparticle slip and crystal fracture. The evidence suggests a bone mineral biosystem of integrated complexity within which a particulate assemblage at the animate: inanimate calcification front resembles a colonial construct of prokaryote-like, Golgi-fabricated objects calcified with phosphate and harbouring a resident biochemistry. A self-contained “Petrified Microbiome” is proposed to be orchestrated according to a biodynamic primordial paradigm. Full article
(This article belongs to the Special Issue Biomaterials and Bone)
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