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15 pages, 2799 KB  
Article
An Experimental Study on the Effects of Pre-Chamber Geometry on the Combustion Characteristics of Ammonia/Air Mixtures Using Turbulent Jet-Post Spark Ignition Strategy
by Yichen Gao, Xipu Zhang, Yang Cao, Jiashen Zhang, Rongjie Li, Huimin Wu, Shijun Dong and Zhaowen Wang
Energies 2025, 18(21), 5659; https://doi.org/10.3390/en18215659 - 28 Oct 2025
Viewed by 191
Abstract
As a carbon-free fuel, ammonia faces challenges in engine applications due to its low flame propagation speed and high ignition energy. The pre-chamber turbulent jet-post spark ignition strategy (TJ-PSI) has been proven effective in accelerating the combustion of stoichiometric ammonia/air mixtures. This study [...] Read more.
As a carbon-free fuel, ammonia faces challenges in engine applications due to its low flame propagation speed and high ignition energy. The pre-chamber turbulent jet-post spark ignition strategy (TJ-PSI) has been proven effective in accelerating the combustion of stoichiometric ammonia/air mixtures. This study investigates the effects of orifice configuration on the combustion characteristics of stoichiometric ammonia/air premixed mixtures under TJ-PSI mode. Experiments are performed in a constant-volume combustion vessel filled with stoichiometric ammonia/air mixtures, and the spark plug used to trigger the ignition of the mixture in the main chamber is located downstream of the pre-chamber turbulent jet flow. With pre-chamber volume maintained constant, pre-chambers with different orifice numbers (Φ1.4 mm × 1, Φ1.4 mm × 4, Φ1.4 mm × 6) and orifice diameters (Φ4.0 mm × 1) are tested, along with varying time intervals (TI) between the main chamber and pre-chamber spark timings. Experimental results show that the pre-chamber with single large orifice (Φ4.0 mm × 1) produces jet flames but offers limited combustion enhancement. In contrast, a single small orifice (Φ1.4 mm) generates flameless turbulent jets, which reduce combustion duration by 53% compared to the large-orifice case. This improvement is attributed to the pre-chamber jet enhancing turbulence in the main chamber, whereas larger orifices yield lower turbulence intensity. Although multi-orifice configurations provide less pronounced enhancement compared to the single-orifice case, they effectively prevent flame kernel extinction at short TIs (e.g., 10 ms). Consequently, the total combustion duration from pre-chamber spark to the end of main chamber combustion can be significantly shortened. Full article
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23 pages, 4302 KB  
Article
Numerical Investigation on the Effect of the Ignition Changes on the Combustion Process of a Free Piston Engine Generator Through Computational Fluid Dynamics
by Xiaoxu Hu, Huihua Feng, Chang Liu, Boru Jia, Qiming Lei, Lei Xu and Yidi Wei
Appl. Sci. 2025, 15(20), 10907; https://doi.org/10.3390/app152010907 - 10 Oct 2025
Viewed by 337
Abstract
To address the challenges of short dwell time near top dead center (TDC) and uneven heat release, this paper presents a comprehensive analysis of the effects of different ignition schemes on combustion characteristics, flame formation and development, and emissions. A three-dimensional model of [...] Read more.
To address the challenges of short dwell time near top dead center (TDC) and uneven heat release, this paper presents a comprehensive analysis of the effects of different ignition schemes on combustion characteristics, flame formation and development, and emissions. A three-dimensional model of coupled reaction’s kinetic mechanism was established using Converge 3.0 and validated by experimental data. The results show that ignition position, whether synchronous or asynchronous changes, significantly influence pressure. The pressure in synchronous cases can reach up to 62.5 bar, representing a 10.8% increase, exhibiting a distinct upward trend with advanced ignition position. In asynchronous cases, the pressure variation shows a distinct nonlinear characteristic due to the negative effects of in-cylinder airflow and flame core collision. When the ignition position is advanced, the ignition delay increases for both synchronous and asynchronous strategies. However, for synchronous cases, the combustion duration is reduced by up to 1.5 ms, whereas for asynchronous cases, the reduction is only 0.135 ms. Regardless of the schemes, the layout and the strong counterclockwise swirl lead to the flame core gradually developing from right to left, ultimately engulfing the left-side flame core. Compared then to that case, the left and right flame kernels may collide prematurely, leading to incomplete local combustion and consequently reducing combustion efficiency. Compared to synchronous changes, the emission differences during asynchronous changes are smaller and maintained at a relatively low level. Full article
(This article belongs to the Section Applied Thermal Engineering)
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21 pages, 2989 KB  
Article
Numerical Investigation of Hydrogen Substitution Ratio Effects on Spray Characteristics, Combustion Behavior, and Emissions in a Dual-Fuel Compression Ignition Engine
by Takwa Hamdi, Fathi Hamdi, Samuel Molima, Victor M. Domínguez, José Rodríguez-Fernández, Juan José Hernández and Mouldi Chrigui
Machines 2025, 13(10), 880; https://doi.org/10.3390/machines13100880 - 23 Sep 2025
Viewed by 742
Abstract
Hydrogen is a promising alternative fuel for internal combustion engines due to its high specific energy, fast flame speed, and carbon-free combustion. In dual-fuel operation, it offers a practical route to reducing greenhouse gas emissions while remaining compatible with existing engine hardware. This [...] Read more.
Hydrogen is a promising alternative fuel for internal combustion engines due to its high specific energy, fast flame speed, and carbon-free combustion. In dual-fuel operation, it offers a practical route to reducing greenhouse gas emissions while remaining compatible with existing engine hardware. This work evaluates how the hydrogen energy substitution ratio (HSR = 50, 70, and 90%) influences spray dynamics, combustion characteristics, and emissions in a heavy-duty compression ignition engine. Simulations are validated against experiments and use a URANS RNG k–ε framework with a hybrid combustion model: the Eddy Dissipation Concept (EDC) coupled with detailed kinetics (111 species, 768 reactions) for auto-ignition and diffusion burning of diesel, and a G-equation for propagation of a hydrogen-rich premixed flame. The results reveal clear spray–combustion linkages. At HSR 50, the higher Weber number induces stronger breakup, yielding a smaller Sauter mean diameter and higher number-averaged droplet velocity; at HSR 90, the spray is more stable and less atomized, with larger droplets and a shorter vapor penetration length. Increasing the HSR reduces unburned hydrocarbons (UHCs) by more than 50% from HSR 50 to HSR 90 while modestly altering combustion phasing (a later CA50 and a shorter burn duration due to faster hydrogen flame propagation). The validated model provides a practical tool for optimizing dual-fuel settings and HSR–EGR–SOI trade-offs to balance efficiency and emissions. Full article
(This article belongs to the Section Electromechanical Energy Conversion Systems)
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25 pages, 29369 KB  
Article
Assessment of a Cost-Effective Multi-Fidelity Conjugate Heat Transfer Approach for Metal Temperature Prediction of DLN Gas Turbine Combustor Liners
by Gianmarco Lemmi, Stefano Gori, Giovanni Riccio and Antonio Andreini
Energies 2025, 18(18), 4877; https://doi.org/10.3390/en18184877 - 13 Sep 2025
Viewed by 464
Abstract
Over the last decades, Computational Fluid Dynamics (CFD) has become a fundamental tool for the design of gas turbine combustors, partly making up for the costs and duration issues related to the experimental tests involving high-pressure reactive processes. Nevertheless, high-fidelity simulations of reactive [...] Read more.
Over the last decades, Computational Fluid Dynamics (CFD) has become a fundamental tool for the design of gas turbine combustors, partly making up for the costs and duration issues related to the experimental tests involving high-pressure reactive processes. Nevertheless, high-fidelity simulations of reactive flows remain computationally expensive, particularly for conjugate heat transfer (CHT) analyses aimed at predicting liner metal temperatures and characterising wall heat losses. This work investigates the robustness of a cost-effective numerical setup for CHT simulations, focusing on the prediction of cold-side thermal loads in industrial combustor liners under realistic operating conditions. The proposed approach is tested using both Reynolds-Averaged Navier–Stokes (RANS) and unsteady Stress-Blended Eddy Simulation (SBES) turbulence models for the combustor flame tube, coupled via a time desynchronisation strategy with transient heat conduction in the solid domain. Cold-side heat transfer is modelled using a 1D correlation-based tool, runtime coupled with the CHT simulation to account for cooling-induced thermal loads without explicitly resolving complex cooling passages. The methodology is applied to a single periodic sector of the NovaLTTM16 annular combustor, developed by Baker Hughes and operating under high-pressure conditions with natural gas. Validation against experimental data demonstrates the methodology’s ability to predict liner metal temperatures accurately, account for modifications in cooling geometries, and support design-phase evaluations efficiently. Overall, the proposed approach offers a robust trade-off between computational cost and predictive accuracy, making it suitable for practical engineering applications. Full article
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17 pages, 11294 KB  
Article
Enhanced Ablative Performance of Additively Manufactured Thermoplastic Composites for Lightweight Thermal Protection Systems (TPS)
by Teodor Adrian Badea, Lucia Raluca Maier and Alexa-Andreea Crisan
Polymers 2025, 17(18), 2462; https://doi.org/10.3390/polym17182462 - 11 Sep 2025
Viewed by 721
Abstract
The research investigated the potential of five novel additively manufactured (AM) fiber-reinforced thermoplastic composite (FRTPC) configurations as alternatives for ablative thermal protection system (TPS) applications. The thermal stability and ablative behavior of ten samples developed via fused deposition modeling (FDM) three-dimensional (3D) printing [...] Read more.
The research investigated the potential of five novel additively manufactured (AM) fiber-reinforced thermoplastic composite (FRTPC) configurations as alternatives for ablative thermal protection system (TPS) applications. The thermal stability and ablative behavior of ten samples developed via fused deposition modeling (FDM) three-dimensional (3D) printing out of fire-retardant thermoplastics were investigated using an in-house oxyacetylene torch bench. All samples featured an innovative internal thermal management architecture with three air chambers. Furthermore, the enhancement of thermal benefits was achieved through several approaches: ceramic coating, mechanical hybridization, or continuous fiber reinforcement. For each configuration, two samples were exposed to flame at 1450 ± 50 °C for 30 s and 60 s, respectively, with the front surface subjected to direct exposure at a distance of 100 mm during the ablation tests. Internal temperatures recorded at two back-side contact points remained below 50 °C, well under the 180 °C maximum allowable back-face temperature for TPS during testing. Continuous reinforced configurations 4 and 5 displayed higher thermal stability the lowest values in terms of thickness, mass loss, and recession rates. Both configurations showed half of the weight losses measured for the other tested configurations, ranging from approximately 5% (30 s) to 10–12% (60 s), confirming the trend observed in the thickness loss measurements. However, continuous glass-reinforced configuration 5 exhibited the lowest weight loss values for both exposure durations, benefiting from its non-combustible nature, low thermal conductivity, and high abrasion resistance intrinsic characteristics. In particular, the Al2O3 surface coated configuration 1 showed a mass loss comparable to reinforced configurations, indicating that an enhanced surface coat adhesion could provide a potential benefit. A key outcome of the study was the synergistic effect of the novel air chamber architecture, which reduces thermal conductivity by forming small internal air pockets, combined with the continuous front-wall fiber reinforcement functioning as a thermal and abrasion barrier. This remains a central focus for future research and optimization. Full article
(This article belongs to the Section Polymer Applications)
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21 pages, 5487 KB  
Article
Numerical Simulation on the Influence of Oxygen Content and Coke Size on the Performance of Fuel Layered-Distribution Sintering Process
by Jin Xu, Xiaobo Yang, Ziyue Tian, Zongyan Zhou, Yuelei Wang and Qibin Zhang
Metals 2025, 15(9), 953; https://doi.org/10.3390/met15090953 - 27 Aug 2025
Viewed by 581
Abstract
Fuel layered-distribution sintering (FLDS) is a technology that can effectively reduce fuel consumption and achieve a more uniform temperature distribution within the sintering bed compared to traditional iron ore sintering. In this study, the melting quality index, combined with the maximum temperature and [...] Read more.
Fuel layered-distribution sintering (FLDS) is a technology that can effectively reduce fuel consumption and achieve a more uniform temperature distribution within the sintering bed compared to traditional iron ore sintering. In this study, the melting quality index, combined with the maximum temperature and the duration of melting temperature, are used as performance indicators to investigate the effects of coke size and oxygen content on sintering characteristics under layered fuel distribution conditions. The results indicate that increasing the oxygen content can enhance the velocity of the flame front in the sinter pot, thereby accelerating the sintering process. However, excessive oxygen content may lead to fluctuations in the quality of the sinter. Small coke sizes provide higher melting quality in the upper region of the sinter pot, while large coke sizes perform better in the lower region. For a 600 mm sintering bed layer, an oxygen enrichment time of 6 min with oxygen concentration of 27% and coke particle diameter of 2.0 mm can balance sintered ore quality, sintering time, and flame front speed, ensuring the yield of sintered ore. These findings provide an effective pathway for energy saving and emission reduction in iron ore sintering plants. Full article
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15 pages, 2038 KB  
Article
Experimental and Mechanistic Study of Geometric Asymmetry Effects on Gas–Coal Dust Coupling Explosions in Turning Pipelines
by Shaoshuai Guo, Yuansheng Wang, Guoxun Jing and Yue Sun
Symmetry 2025, 17(8), 1301; https://doi.org/10.3390/sym17081301 - 12 Aug 2025
Viewed by 349
Abstract
The geometric symmetry of the pipeline constitutes a critical determinant in regulating the energy propagation dynamics during the explosion process. In the present study, a transparent plexiglass pipe experimental system incorporating a range of angles (30° to 150°) was meticulously constructed. Leveraging high-frequency [...] Read more.
The geometric symmetry of the pipeline constitutes a critical determinant in regulating the energy propagation dynamics during the explosion process. In the present study, a transparent plexiglass pipe experimental system incorporating a range of angles (30° to 150°) was meticulously constructed. Leveraging high-frequency pressure sensors in conjunction with high-speed camera technology, this investigation examines the influence of the pipe angle, which disrupts geometric symmetry, on the coupling explosion of gas and coal dust. The experimental findings illustrate that an increase in the pipeline turning angle significantly enhances the velocity of the explosion flame front (with the maximum velocity escalating from 97.92 m/s to 361.28 m/s) and concurrently reduces the total propagation time (from 71 ms to 56.5 ms). Moreover, there is a notable reduction in the duration of the explosion flame, decreasing from 240.5 ms to 64.17 ms at the coal dust deposition point. The peak overpressure of the shock wave exhibits a significant increase with the augmentation of the turning angle (rising from 7.07 kPa at 30° to 88.40 kPa at 150°). Furthermore, the overpressure in the fore section of the turning is amplified, attributable to the superimposition of reflected waves and turbulent effects. This study elucidates critical mechanisms including turbulence-enhanced combustion, secondary dust generation from coal dust, and energy dissipation resulting from abrupt alterations in pipeline geometry, thereby offering a theoretical framework for the prevention and effective emergency management of coal mine explosion disasters. Full article
(This article belongs to the Section Engineering and Materials)
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21 pages, 4924 KB  
Article
Quantifying the Influence of Parameters on Heat Release Rate in Electrical Cabinet Fires
by Umang Selokar, Brian Y. Lattimer, Urvin Salvi, Elvan Sahin, Mohammad Amer Allaf and Juliana Pacheco Duarte
Fire 2025, 8(7), 256; https://doi.org/10.3390/fire8070256 - 30 Jun 2025
Viewed by 839
Abstract
Electrical cabinet fire scenarios constitute a significant risk within nuclear facilities, emphasizing the need to mitigate uncertainties in risk evaluations. Owing to the disparate nature of electrical cabinet parameters, only a few factors have been experimentally explored and statistically analyzed to assess their [...] Read more.
Electrical cabinet fire scenarios constitute a significant risk within nuclear facilities, emphasizing the need to mitigate uncertainties in risk evaluations. Owing to the disparate nature of electrical cabinet parameters, only a few factors have been experimentally explored and statistically analyzed to assess their impact on peak HRR. In this study, we conducted both a cabinet parameter study and a combustible configuration study to systematically evaluate their influence on peak HRR and time-to-peak HRR. A series of 51 simulation matrices were created using statistical experiment design (SED) and ANOVA to quantify the influence of cabinet volume, combustible surface area, vent area, ignition characteristics, and burning behavior (e.g., HRRPUA and duration). A computational fluid dynamics (CFD) model, specifically a Fire Dynamics Simulator (FDS), was used to model the ignition source and flame spread inside of the electrical cabinet that influence peak HRR. The most impactful parameters influencing peak HRR and time-to-peak HRR were identified. The findings revealed that the configuration of combustibles and the placement of the ignition source play a pivotal role in determining the peak HRR. A partition screening analysis was conducted to identify the conditions under which the ventilation area becomes a more significant parameter. Additionally, a comparison between experimental results and numerical simulations demonstrated good agreement, further validating the predictive capability of the model. Full article
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22 pages, 2619 KB  
Article
Influence of Fuel Types and Equivalence Ratios on NOx Emissions in Combustion: A Comparative Analysis of Methane, Methanol, Propane, and Hydrogen Blends
by Amr Abbass
Clean Technol. 2025, 7(2), 42; https://doi.org/10.3390/cleantechnol7020042 - 21 May 2025
Cited by 1 | Viewed by 2192
Abstract
This study utilizes a zero-dimensional, constant-pressure, perfectly stirred reactor (PSR) model within the Cantera framework to examine the combustion characteristics of hydrogen, methane, methanol, and propane, both singly and in hydrogen-enriched mixtures. The impact of the equivalence ratio (ϕ = 0.75, 1.0, 1.5), [...] Read more.
This study utilizes a zero-dimensional, constant-pressure, perfectly stirred reactor (PSR) model within the Cantera framework to examine the combustion characteristics of hydrogen, methane, methanol, and propane, both singly and in hydrogen-enriched mixtures. The impact of the equivalence ratio (ϕ = 0.75, 1.0, 1.5), fuel composition, and residence duration on temperature increase, heat release, ignition delay, and emissions (NOx and CO2) is methodically assessed. The simulations are performed under steady-state settings to emulate the ignition and flame propagation processes within pre-chambers and primary combustion zones of internal combustion engines. The results demonstrate that hydrogen significantly improves combustion reactivity, decreasing ignition delay and increasing peak flame temperature, especially at short residence times. The incorporation of hydrogen into hydrocarbon fuels, such as methane and methanol, enhances ignition speed, improves thermal efficiency, and stabilizes lean combustion. Nevertheless, elevated hydrogen concentrations result in increased NOx emissions, particularly at stoichiometric equivalence ratios, due to higher flame temperatures. The examination of fuel mixtures at varying hydrogen concentrations (10–50% by mole) indicates that thermal performance is optimal under stoichiometric settings and diminishes in both fuel-lean and fuel-rich environments. A thermodynamic model was created utilizing classical combustion theory to validate the heat release estimates based on Cantera. The model computes the heat release per unit volume (MJ/m3) by utilizing stoichiometric oxygen demand, nitrogen dilution, fuel mole fraction, and higher heating values (HHVs). The thermodynamic estimates—3.61 MJ/m3 for H2–CH3OH, 3.43 MJ/m3 for H2–CH4, and 3.35 MJ/m3 for H2–C3H8—exhibit strong concordance with the Cantera results (2.82–3.02 MJ), thereby validating the physical consistency of the numerical methodology. This comparison substantiates the Cantera model for the precise simulation of hydrogen-blended combustion, endorsing its use in the design and development of advanced low-emission engines. Full article
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17 pages, 2913 KB  
Article
On-Orbit Functional Verification of Combustion Science Experimental System in China Space Station
by Pingping Zhao, Xiaowu Zhang, Yu Fang, Hailong Wu, Xiaofang Yang and Huilong Zheng
Aerospace 2025, 12(5), 448; https://doi.org/10.3390/aerospace12050448 - 20 May 2025
Viewed by 613
Abstract
We demonstrated the development, implementation, and functional verification of the combustion science payload deployed on the China Space Station. The Combustion Science Experiment System (CSES) integrated seven subsystems and modular plugins to address the major challenges facing microgravity combustion research, including the lack [...] Read more.
We demonstrated the development, implementation, and functional verification of the combustion science payload deployed on the China Space Station. The Combustion Science Experiment System (CSES) integrated seven subsystems and modular plugins to address the major challenges facing microgravity combustion research, including the lack of long-duration experimental platforms, spatial constraints, and safety risks. Through on-orbit testing, the core functions of the CSES under microgravity conditions were validated, including gas supply, ignition, combustion diagnostic, exhaust purification, and emission. The system achieved autonomous experiment execution by ground-injected commands. Data from on-orbit methane combustion experiments demonstrated that the CSES was capable of stably supplying oxygen and fuel gas at a preset flow rate, real-time combustion diagnosis, and provided high-resolution flame image. Effectively exhaust gas purification and emission control of the CSES have also been tested and verified. It provides a safe, reliable, and stable microgravity environment of long-duration research for the combustion science and the development of spacecraft fire safety technology. Full article
(This article belongs to the Section Astronautics & Space Science)
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24 pages, 7039 KB  
Article
Performance Study of Spark-Ignited Methanol–Hydrogen Engine by Using a Fractal Turbulent Combustion Model Coupled with Chemical Reaction Kinetics
by Yingting Zhang, Yu Ding, Xiaohui Ren and La Xiang
J. Mar. Sci. Eng. 2025, 13(5), 959; https://doi.org/10.3390/jmse13050959 - 15 May 2025
Viewed by 895
Abstract
Methanol, a renewable and sustainable fuel, provides an effective strategy for reducing greenhouse gas emissions when synthesized through carbon dioxide hydrogenation integrated with carbon capture technology. The incorporation of hydrogen into methanol-fueled engines enhances combustion efficiency, mitigating challenges such as pronounced cycle-to-cycle variations [...] Read more.
Methanol, a renewable and sustainable fuel, provides an effective strategy for reducing greenhouse gas emissions when synthesized through carbon dioxide hydrogenation integrated with carbon capture technology. The incorporation of hydrogen into methanol-fueled engines enhances combustion efficiency, mitigating challenges such as pronounced cycle-to-cycle variations and cold-start difficulties. A simulation framework was developed using Python 3.13 and the Cantera 3.1.0 library to model the combustion system of a four-stroke spark-ignited (SI) methanol–hydrogen engine. This framework integrates a fractal turbulent combustion model with chemical reaction kinetics, complemented by early flame development and near-wall combustion models to address limitations during the initial and terminal combustion phases. The model was validated by using experimental data measured from a spark-ignited methanol engine. The effects of varying Hydrogen Energy Rates (HER) on engine power performance, combustion characteristics, and emissions (like formaldehyde and carbon monoxide) were subsequently analyzed under different operating loads, whilst the knock limit boundaries were established for different operational conditions. Findings demonstrate that increasing HER improves the engine power output and thermal efficiency, shortens the combustion duration, and reduces the formaldehyde and carbon monoxide emissions. Nevertheless, under high-load conditions, higher HER increases the knocking tendency, which constrains the maximum permissible HER decreasing from approximately 40% at 15% load to 20% at 100% load. The model has been developed into a Python library and will be open-sourced on Github. Full article
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15 pages, 3232 KB  
Article
Effect of Methanol Injection Timing on Performance of Marine Diesel Engines and Emission Reduction
by Hao Guo, Veysi Başhan, Cairui Yu, Firat Bolat, Hakan Demirel and Xin Tian
J. Mar. Sci. Eng. 2025, 13(5), 949; https://doi.org/10.3390/jmse13050949 - 13 May 2025
Viewed by 1438
Abstract
Methanol is a promising low-carbon fuel that can effectively reduce environmental pollution from ships compared to traditional fuels. The timing of methanol injection is a major factor affecting the performance of internal combustion engines, and either too late or too early injection can [...] Read more.
Methanol is a promising low-carbon fuel that can effectively reduce environmental pollution from ships compared to traditional fuels. The timing of methanol injection is a major factor affecting the performance of internal combustion engines, and either too late or too early injection can severely impact the combustion efficiency of an engine. This paper focused on a 4135Aca marine diesel engine produced by the Shanghai Diesel Engine Factory in China. Using CONVERGE/3.0 software for numerical simulation, the study analyzed the impact of methanol injection timing on the combustion and emission characteristics of marine diesel engines. It was found that the determination of methanol injection timing should comprehensively consider the effects of the combustion start point, mixture quality, flame front propagation speed, and evaporation heat absorption. Appropriate methanol injection timing can improve the combustion duration, cylinder pressure, and heat release rate, enhancing the power performance of marine diesel engines. This study shows that methanol injection at −30 °CA can effectively control the in-cylinder combustion process, improve combustion efficiency, and significantly reduce the emissions of pollutants such as soot (by 60.5%), HC (by 3.6%), CO (by 95.3%), etc. However, it can lead to an increase in NOx (by 3.7%) generation under high-temperature conditions. This research can provide a certain reference for the engineering application of methanol direct injection engines for ships. Full article
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21 pages, 8395 KB  
Article
Deep Artificial Neural Network Modeling of the Ablation Performance of Ceramic Matrix Composites in the Hydrogen Torch Test
by Jayanta Bhusan Deb, Christopher Varela, Fahim Faysal, Yiting Wang, Chiranjit Maiti and Jihua Gou
J. Compos. Sci. 2025, 9(5), 239; https://doi.org/10.3390/jcs9050239 - 13 May 2025
Cited by 1 | Viewed by 1479
Abstract
In recent years, there has been increasing interest in new materials such as ceramic matrix composites (CMCs) for power generation and aerospace propulsion applications through hydrogen combustion. This study employed a deep artificial neural network (DANN) model to predict the ablation performance of [...] Read more.
In recent years, there has been increasing interest in new materials such as ceramic matrix composites (CMCs) for power generation and aerospace propulsion applications through hydrogen combustion. This study employed a deep artificial neural network (DANN) model to predict the ablation performance of CMCs in the hydrogen torch test (HTT). The study was conducted in three phases to increase the accuracy of the model’s predictions. Initially, to predict the thermal behavior of ceramic composites, two linear machine learning models were used known as Lasso and Ridge regression. In the second step, four decision tree-based ensemble machine learning models, namely random forest, gradient boosting regression, extreme gradient boosting regression, and extra tree regression, were used to improve the prediction accuracy metrics, including root mean square error (RMSE), mean absolute error (MAE), correlation coefficient (R2 score), and mean absolute percentage error (MAPE), relative to the previously introduced linear models. Finally, to forecast the thermal stability of CMCs with time, an optimized DANN model with two hidden layers having rectified linear unit activation function was developed. The data collection procedure involved preparing CMCs with continuous Yttria-Stabilized Zirconia (YSZ) fibers and silicon carbide (SiC) matrix using a polymer infiltration and pyrolysis (PIP) technique. The samples were exposed to a hydrogen flame at a high heat flux of 183 W/cm2 for a duration of 10 min. A good agreement between the DANN model’s predictions and experimental data with an R2 score of 0.9671, RMSE of 16.45, an MAE of 14.07, and an MAPE of 3.92% confirmed the acceptability of the developed neural network model in this study. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2025)
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24 pages, 4582 KB  
Article
Multiple Hits on Cerebral Folate, Tetrahydrobiopterin and Dopamine Metabolism in the Pathophysiology of Parkinson’s Disorder: A Limited Study of Post-Mortem Human Brain Tissues
by Dhruti Balakrishna Doddaballapur, Derren J. Heyes and Jaleel A. Miyan
Metabolites 2025, 15(5), 307; https://doi.org/10.3390/metabo15050307 - 5 May 2025
Viewed by 1841
Abstract
Background: Parkinson’s disorder (PD) affects around 1:500 individuals and is associated with enlarged ventricles and symptoms of normal pressure hydrocephalus (NPH). These features suggest disrupted cerebrospinal fluid (CSF) dynamics and folate metabolism. With L-DOPA treatment showing diminishing benefits over time, there is [...] Read more.
Background: Parkinson’s disorder (PD) affects around 1:500 individuals and is associated with enlarged ventricles and symptoms of normal pressure hydrocephalus (NPH). These features suggest disrupted cerebrospinal fluid (CSF) dynamics and folate metabolism. With L-DOPA treatment showing diminishing benefits over time, there is an urgent need to investigate upstream metabolic disruptions, including folate and tetrahydrobiopterin (BH4) pathways, in post-mortem CSF and brain tissue to understand their roles in PD pathogenesis. Methods: CSF and brain tissue from 20 PD patients (mean age 84 years; 55% male; disease duration 10–30 years) and 20 controls (mean age 82 years; 50% male) were analysed. Western and Dot Blots measured proteins and metabolites, spectroscopic assays assessed enzyme activities, BH4 and Neopterin levels were measured using ELISA, and levels of hydrogen peroxide, used as a proxy for reactive oxygen species, and calcium were quantified using horseradish peroxidase and flame photometry assays, respectively. ClinVar genetic data were analysed for variants in genes encoding key enzymes. Statistical significance was assessed using unpaired t-tests (p < 0.05). Results: All enzymes were significantly reduced in PD compared to controls (p < 0.01) except for methyltetrahydrofolate reductase (MTHFR), which was elevated (p < 0.0001). Enzymes were functional in control but undetectable in PD CSF except tyrosine hydroxylase (TH). BH4 and Neopterin were elevated in PD CSF (p < 0.0001, p < 0.001) but significantly reduced (p < 0.001) or unchanged in tissue. Peroxide was increased in both PD CSF (p < 0.001) and tissue (p < 0.0001) selectively inhibiting TH. Calcium was 40% higher in PD than controls (p < 0.05). No pathogenic variants in enzyme genes were found in ClinVar data searches, suggesting the observed deficiencies are physiological. Conclusions: We identified significant disruptions in folate and BH4 pathways in PD, with enzyme deficiencies, oxidative stress and calcium dysregulation pointing to choroid plexus dysfunction. These findings highlight the choroid plexus and CSF as key players in cerebral metabolism and promote further exploration of these as therapeutic targets to address dopaminergic dysfunction and ventricular enlargement in PD. Full article
(This article belongs to the Special Issue Metabolomics in Neurodegenerative Diseases, 2nd Edition)
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26 pages, 17793 KB  
Article
Study on the Spatial and Temporal Evolution of Hydrogen-Blended Natural Gas Leakage and Flare-Up in the Typical Semi-Open Space
by Xu Wang, Saitao Hu, Shengzhu Zhang, Yingquan Duo, Jinhuai Xu and Tong Zhao
Fire 2025, 8(4), 146; https://doi.org/10.3390/fire8040146 - 4 Apr 2025
Cited by 1 | Viewed by 759
Abstract
Numerical simulations reveal the combustion dynamics of hydrogen-blended natural gas (H-BNG) in semi-open spaces. In the typical semi-open space scenario, increasing the hydrogen blending ratio from 0% to 60% elevates peak internal pressure by 107% (259.3 kPa → 526.0 kPa) while reducing pressure [...] Read more.
Numerical simulations reveal the combustion dynamics of hydrogen-blended natural gas (H-BNG) in semi-open spaces. In the typical semi-open space scenario, increasing the hydrogen blending ratio from 0% to 60% elevates peak internal pressure by 107% (259.3 kPa → 526.0 kPa) while reducing pressure rise time by 56.5% (95.8 ms → 41.7 ms). A vent size paradox emerges: 0.5 m openings generate 574.6 kPa internal overpressure, whereas 2 m openings produce 36.7 kPa external overpressure. Flame propagation exhibits stabilized velocity decay (836 m/s → 154 m/s, 81.6% reduction) at hydrogen concentrations ≥30% within 2–8 m distances. In street-front restaurant scenarios, 80% H-BNG leaks reach alarm concentration (0.8 m height) within 120 s, with sensor response times ranging from 21.6 s (proximal) to 40.2 s (distal). Forced ventilation reduces hazard duration by 8.6% (151 s → 138 s), while door status shows negligible impact on deflagration consequences (412 kPa closed vs. 409 kPa open), maintaining consistent 20.5 m hazard radius at 20 kPa overpressure threshold. These findings provide crucial theoretical insights and practical guidance for the prevention and management of H-BNG leakage and explosion incidents. Full article
(This article belongs to the Special Issue Hydrogen Safety: Challenges and Opportunities)
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