Search Results (627)

Understanding the limitations of cold-formed aluminum alloys in practice applications is essential, particularly due to the risk of substructural changes and a reduction in strength when exposed to elevated temperatures. In this study, the thermal stability of the ultra-fine-grained (UFG) structure formed by equal channel angular pressing (ECAP) at room temperature and the mechanical properties of the AlSi7MgCu0.5 alloy were investigated. Prior to ECAP, the plasticity of the as-cast alloy was enhanced by a heat treatment consisting of solution annealing, quenching, and artificial aging to achieve an overaged state. Four repetitive passes via ECAP route A resulted in the homogenization of eutectic Si particles within the α-solid solution, the formation of ultra-fine grains and/or subgrains with high dislocation density, and a significant improvement in alloy strength due to strain hardening. The main objective of this work was to assess the microstructural and mechanical stability of the alloy after post-ECAP annealing in the temperature range of 373–573 K. The UFG microstructure was found to be thermally stable up to 523 K, above which notable grain and/or subgrain coarsening occurred as a result of discontinuous recrystallization of the solid solution. Mechanical properties remained stable up to 423 K; above this temperature, a considerable decrease in strength and a simultaneous increase in ductility were observed. Synchrotron radiation X-ray diffraction (XRD) was employed to analyze the phase composition and crystallographic characteristics, while transmission electron microscopy (TEM) was used to investigate substructural evolution. Mechanical properties were evaluated through tensile testing, impact toughness testing, and hardness measurements. Full article

The continuous deposition of coal fine in the well can lead to complex problems, such as pump blockage and reduced capacity. The traditional critical velocity model applicable to rigid spherical particles, such as sand grains and glass beads, finds it difficult to accurately predict the migration behavior of coal fine in the wellbore. Therefore, this study aims to reveal the sedimentation law of coal fine particles, establish a critical velocity prediction model applicable to pulverized coal, and provide a theoretical basis for effectively preventing pump blockage and capacity decline problems. This paper analyzes the particle characteristics of coal fine in different mining areas and conducts experiments on the static settling of coal fine particles and the critical transport velocity. The experimental results showed that the larger the mesh size of coal fine, the lower the static settling velocity of coal fine particles. The critical velocity of coal fine increased with the particle size and concentration of the coal fine particles, as well as with the increase of the pipe column inclination. A new empirical formula for calculating the critical velocity of coal fine particles was derived by considering the effects of the coal fine concentration and pipe inclination. Full article

Biopolymers, owing to their environmentally friendly and sustainable characteristics, have become a promising alternative for soil stabilization in geotechnical engineering. The application of protein-based biopolymers as binders for soil stabilization is less prevalent in geotechnical engineering compared to polysaccharide-based biopolymers. This study explores the potential of gelatin, a protein-based biopolymer derived from animal collagen, for stabilizing silty sand and improving its geotechnical properties. Gelatin was mixed into the soil at concentrations ranging from 0.25% to 2% of the dry weight of soil, and its effects on various soil characteristics were evaluated. The tests conducted include liquid limit, plastic limit, compaction behavior, and unconfined compressive strength (UCS); the addition of 1% gelatin led to an approximate 1.69 times increase in the strength of the unamended soil. After 28 days of curing, the UCS improved by approximately 5.03 times compared to the untreated soil, and the treated soil exhibited increased resistance to deformation under load. Microstructural analysis using scanning electron microscopy (SEM) revealed that gelatin facilitated the formation of a cohesive matrix, enhancing particle bonding and reducing void spaces within the soil. Carbon footprint analysis (CFA) conducted on an isolated footing stabilized with gelatin showed that the carbon emissions were reduced by 99.8% and 99% compared to traditional stabilizers such as lime and cement. Additionally, the interaction between the biopolymer and the fine-grained soil is distinctly evident in the FTIR and XRD analysis through hydrogen bonding and the formation of cementitious compounds. Full article

The overtopping-induced lateral erosion breaching of tailings dams represents a critical disaster mechanism threatening structural safety, particularly in reinforced fine-grained tailings dams where erosion behaviors demonstrate pronounced water–soil coupling characteristics and material anisotropy. Through physical model tests and numerical simulations, this study systematically investigates lateral erosion failure patterns of reinforced fine-grained tailings under overtopping flow conditions. Utilizing a self-developed hydraulic initiation test apparatus, with aperture sizes of reinforced geogrids (2–3 mm) and flow rates (4–16 cm/s) as key control variables, the research elucidates the interaction mechanisms of “hydraulic scouring-particle migration-geogrid anti-sliding” during lateral erosion processes. The study revealed that compared to unreinforced specimens, reinforced specimens with varying aperture sizes (2–3 mm) demonstrated systematic reductions in final lateral erosion depths across flow rates (4–16 cm/s): 3.3–5.8 mm (15.6−27.4% reduction), 3.1–7.2 mm (12.8–29.6% reduction), 2.3–11 mm (6.9–32.8% reduction), and 2.5–11.4 mm (6.2–28.2% reduction). Smaller-aperture geogrids (2 mm × 2 mm) significantly enhanced anti-erosion performance through superior particle migration inhibition. Concurrently, a pronounced positive correlation between flow rate and lateral erosion depth was confirmed, where increased flow rates weakened particle erosion resistance and exacerbated lateral erosion severity. The numerical simulation results are in basic agreement with the lateral erosion failure process observed in model tests, revealing the dynamic process of lateral erosion in the overtopping breach of a reinforced tailings dam. These findings provide critical theoretical foundations for optimizing reinforced tailings dam design, construction quality control, and operational maintenance, while offering substantial engineering applications for advancing green mine construction. Full article

During the construction of subgrade, the remolding water content w of lime–sand-stabilized clay usually varies in a wide range, leading to inconsistent effectiveness in strength enhancement. Until now, this aspect has not been investigated. In this study, an unconfined compression test and microscopic observation were carried out on clay and stabilized clay (adding 4% lime by mass and 50% sand by volume). The results show the following: (1) remolding water content w had a strong effect on the soil fabrics of pure clay and lime-stabilized clay. An increase in the w from the dry to wet side of optimum reduced matric suction, which diminished the aggregation effect among fine-grained particles in both clay and lime-stabilized clay. Correspondingly, fine-grained aggregate progressively disintegrated, and dispersed fine-grained particles increased. As a result, the w increment at w ≤ w_cha made the dispersed fine-grained particles successively fill the large pores between aggregates, densifying the soil fabric. In contrast, at w > w_cha, the ongoing disintegration of aggregate resulted in progressive structural weakening. Herein, w_cha was defined as the characteristic water content at which the soil fabric transitioned from structural densification to weakening. (2) The UCS of both pure clay and lime–sand-stabilized clay followed a bell-shaped pattern as the w increased, with w_cha acting as the turning point. For pure clay soils, the UCS increased with increasing w up to w_cha because of structural densification, but decreased beyond w_cha due to structural weakening. In lime–sand-stabilized clay, where a sand grain skeleton developed, the compression of lime-stabilized clay induced by the movement of sand grains during shearing activated its contribution to the overall strength. The compressive capacity of the lime-stabilized clay varied in a bell-shaped manner with w, and this trend was mirrored in the UCS of lime–sand-stabilized clay. (3) At a low w, the fact that the clay aggregate exhibited sand-like mechanical behavior reduced the effectiveness of incorporating sand and lime for enhancing the UCS. As the w increased at w ≤ w_cha, the breakdown of aggregates enlarged the distinction between pure clay and sand, resulting in a more pronounced improvement in the UCS with the addition of sand and lime. At w > w_cha, the lubrication effect occurring at the contact between sand grains diminished the interlocking between the sand grains. Consequently, the effectiveness of the UCS enhancement decreased. Full article

Recycled concrete fines (RCFs) have the potential to serve as a supplementary cementitious material (SCM) after carbonation. Traditionally, carbonation of RCFs results in calcium carbonate primarily in the form of calcite, which significantly limits the development of RCFs as an SCM. In this research, a wet grinding carbonation (WGC) technique was introduced to enhance the reactivity of RCFs. The research indicates that RCFs after WGC exhibit a finer particle size and a larger specific surface area. The carbonation products include calcite with smaller grains, metastable calcium carbonate, and nanoscale silica gel and Al-Si gel. When RCF-WGC is used as an SCM in ordinary Portland cement (OPC), it significantly promotes the hydration of the cement paste, as evidenced by the advancement and increased intensity of the exothermic peaks of aluminates and silicates. RCF-WGC can significantly enhance the compressive strength of hydrated samples, particularly at early ages. Specifically, at a curing age of 1 day, the compressive strength of WGC5, WGC10, and WGC20 samples increased by 9.9%, 22.5%, and 7.7%, respectively, compared to the Ref sample (0% RCF-WGC). At a curing age of 3 days, the compressive strength of the WGC5, WGC10, and WGC20 samples showed even more significant improvements, increasing by 20.8%, 21.9%, and 11.8%, respectively. The performance enhancement of the WGC samples is attributed to the chemical reactions involving nanoscale silica gel, Al-Si gel, and calcium carbonate in the RCFs. When RCF-WGC is used as an SCM to replace 5%, 10%, and 20% of cement, it can reduce carbon emissions by 27.5 kg/t, 55 kg/t, and 110 kg/t, respectively. Large-scale application of RCFs as a high-value SCM can significantly reduce the life-cycle carbon emissions of the cement industry, contributing to the achievement of carbon peaking in China’s cement sector. Full article

Poly(methyl methacrylate) (PMMA)-based bone cements are widely used in orthopaedic surgery, yet their inherent brittleness, lack of bioactivity, and exothermic polymerization remain critical limitations. Recent strategies have focused on modifying PMMA with functional additives to improve not only mechanical performance but also thermal behaviour and biological interactions. This study investigates the mechanical properties of two commercial PMMA cements—Palamed^® (antibiotic-free) and Refobacin Plus G (gentamicin-loaded)—reinforced with glassy carbon (GC) particles of two different grain sizes (0.4–1.2 µm and 20–50 µm) and various concentrations. The results demonstrate that coarse GC particles (20–50 µm) significantly reduced compressive strength, particularly in the antibiotic-loaded cement. In contrast, the incorporation of fine GC particles (0.4–1.2 µm) did not markedly impair mechanical performance in Palamed^®, suggesting better compatibility with the PMMA matrix. In addition to mechanical enhancement, the structural and chemical stability of glassy carbon may contribute to improved biological response and reduced polymerization heat. These findings highlight the potential of glassy carbon as a functional additive for designing PMMA-based biomaterials that combine improved mechanical properties with favourable characteristics for long-term implant integration. Full article

Based on laser cladding technology, six composite coatings with different amounts of Inconel 718 and 0~5% CeO₂ were successfully prepared on the 316L stainless steel substrate. The effect of different amounts of CeO₂ particles was investigated and discussed, such as microstructure, phases, elemental distribution, microhardness, wear resistance and corrosion resistance. The results show that the phases are composed of γ~(Fe, Ni), Ni₃Nb, (Nb_0.03Ti_0.97)Ni₃, and MC_X(M = Cr, Nb and Mo). When the amount of CeO₂ particles is higher than 1%, some Ce₂O₃ compounds can be detected in coatings. The average microhardness values of N0~N5 are 604.6, 754.5, 771.6, 741.4, 694.5 and 677.3 HV_0.2, respectively. There is a trend that the microhardness increases firstly and then decreases, because an appropriate amount of CeO₂ can improve the solid solution strength. The average wear rate values of N0~N5 are 2.97 × 10⁻⁵, 1.22 × 10⁻⁵, 0.94 × 10⁻⁵, 1.53 × 10⁻⁵, 1.81 × 10⁻⁵ and 2.26 × 10⁻⁵ mm³∙N⁻¹∙min⁻¹, respectively. The N2 coating has the smallest corrosion current density of 2.05 × 10⁻⁴ A·cm⁻², which is about 56% of the N0 coating. When the amount of CeO₂ particles is 2%, the coating has the best wear resistance and corrosion resistance due to fine grains and Cr, Nb and Mo compounds. Full article

Traditional coal quality assessment methods rely exclusively on the laboratory testing of physical samples, which impedes detailed stratigraphic evaluation and limits the integration of intelligent precision mining technologies. To resolve this challenge, this study investigates geophysical logging as an innovative method for coal quality prediction. By integrating scanning electron microscopy (SEM), X-ray analysis, and optical microscopy with interdisciplinary methodologies spanning mathematics, mineralogy, and applied geophysics, this research analyzes the coal quality and mineral composition of the Shanxi Formation coal seams in northern Jiangsu, China. A predictive model linking geophysical logging responses to coal quality parameters was established to delineate relationships between subsurface geophysical data and material properties. The results demonstrate that the Shanxi Formation coals are gas coal (a medium-metamorphic bituminous subclass) characterized by low sulfur content, low ash yield, low fixed carbon, high volatile matter, and high calorific value. Mineralogical analysis identifies calcite, pyrite, and clay minerals as the dominant constituents. Pyrite occurs in diverse microscopic forms, including euhedral and semi-euhedral fine grains, fissure-filling aggregates, irregular blocky structures, framboidal clusters, and disseminated particles. Systematic relationships were observed between logging parameters and coal quality: moisture, ash content, and volatile matter exhibit an initial decrease, followed by an increase with rising apparent resistivity (LLD) and bulk density (DEN). Conversely, fixed carbon and calorific value display an inverse trend, peaking at intermediate LLD/DEN values before declining. Total sulfur increases with density up to a threshold before decreasing, while showing a concave upward relationship with resistivity. Negative correlations exist between moisture, fixed carbon, calorific value lateral resistivity (LLS), natural gamma (GR), short-spaced gamma-gamma (SSGG), and acoustic transit time (AC). In contrast, ash yield, volatile matter, and total sulfur correlate positively with these logging parameters. These trends are governed by coalification processes, lithotype composition, reservoir physical properties, and the types and mass fractions of minerals. Validation through independent two-sample t-tests confirms the feasibility of the neural network model for predicting coal quality parameters from geophysical logging data. The predictive model provides technical and theoretical support for advancing intelligent coal mining practices and optimizing efficiency in coal chemical industries, enabling real-time subsurface characterization to facilitate precision resource extraction. Full article

Biochar has garnered considerable attention for its potential to improve soil properties due to its unique characteristics. However, the precise measurement of soil water content using electromagnetic sensors becomes challenging after biochar is incorporated. This study investigated the impact of biochar on soil water content measurement by adding biochar of varying dosages and particle sizes to a typical loess, under both room and subzero temperature conditions by using time domain reflectometry (TDR) and frequency domain reflectometry (FDR) techniques. The results demonstrate that biochar amendment significantly influenced the measurement accuracy of both TDR and FDR. A clear dosage-dependent relationship was observed, with measurement errors exhibiting progressive escalation as biochar addition rates increased. At room temperature, the root mean square error (RMSE) values for loess were remarkably low (TDR: 0.029; FDR: 0.093). In contrast, the 9% coarse-grained biochar-amended soil (BAS-9%C) showed substantially elevated RMSE values (TDR: 0.2006; FDR: 0.1468). Furthermore, comparative analysis revealed that particle size significantly affected measurement precision, with coarse-grained biochar demonstrating more pronounced interference effects than fine-grained biochar at equivalent application rates. At subzero temperatures, BAS-6%C exhibited significantly higher RMSE values (TDR: 0.1753; FDR: 0.2022) compared to BAS-6%F (TDR: 0.079; FDR: 0.1872). A dielectric mixing model was established for calculating the dielectric constant of BAS. In addition, calibration equations for accurately determining the water content of biochar-amended loess under both room and subzero temperature conditions were established. Furthermore, the mechanisms by which biochar influenced the performance of the TDR and FDR sensors are comprehensively discussed. These findings can provide valuable theoretical foundation and practical guidance for future soil improvement with biochar and accurate water content measurement in BAS. Full article

Electroless silver (Ag) plating has emerged as a simple yet effective surface modification technique, garnering significant attention in consumer electronics and composite materials. This study systematically investigates the influence of glucose dosage on the microstructural refinement of Ag coatings deposited from silver–ammonia solutions onto iron (Fe) particles while also evaluating the oxidation resistance of Ag-plated particles through thermogravimetric analysis. Optimal results were achieved at a silver nitrate concentration of 0.02 mol/L and a glucose concentration of 0.05 mol/L, producing Fe particles with a uniform and dense silver coating featuring an average Ag grain size of 76 nm. The moderate excess glucose played a dual role: facilitating Ag⁺ ion reduction while simultaneously inhibiting the growth of Ag atomic clusters, thereby ensuring microstructural refinement of the silver layer. Notably, the Ag-plated particles demonstrated superior oxidation resistance compared to their uncoated counterparts. These findings highlight the significance of fine-grained electroless Ag plating in developing high-temperature conductive metal particles and optimizing interfacial structures in composite materials. Full article

The present study focuses on the dynamics of trace metals (TM) in two European rivers, the Mosel and the Meuse. A deterministic description of hydro-sedimentary processes has been performed. The model used to describe pollutant transport and dilution at the watershed scale has been enhanced with the implementation of the MicMod sub-model. The objective of this study is to characterise the dynamics of TM in the water column and bed sediment. A multi-class grain size representation has been developed in MicMod. The dissolved and particulate TM phases have been calculated with specific partitioning coefficients associated with each suspended sediment (SS) class. The processes involved in TM fate have been calibrated in MicMod, including settling velocity, TM releases from the watershed (point and diffuse loads), etc. Following the calibration of the parameters involved in TM transport within the river ecosystem, the main goal is to describe TM dynamics using a pressure–impact relationship model. It was demonstrated that the description of at least one class of fine particles is necessary to obtain an adequate representation of TM concentrations. The focus of this study is low flow periods, which are characterised by the presence of fine particles. The objective is to gain a deeper understanding of the processes that control the transport of TM. This paper establishes consistent pressure–impact relationships between TM loads (urban, industrial, soils) from watersheds and concentrations in rivers. Full article

With the increasing penetration of renewable energy and the large-scale integration of electric vehicles (EVs), the economic optimization dispatch of EV-integrated virtual power plants (VPPs) faces multiple uncertainties and challenges. This paper first proposes an optimized dispatching model for EV clusters to form large-scale coordinated regulation capabilities. Subsequently, considering diversified resources such as energy storage systems and photovoltaic (PV) generation within VPPs, a low-carbon economic optimization dispatching model is established to minimize the total system operation costs and polluted gas emissions. To address the limitations of traditional algorithms in solving high-dimensional, nonlinear dispatching problems, this paper introduces a plant root-inspired growth optimization algorithm. By simulating the nutrient-adaptive uptake mechanism and branching expansion strategy of plant roots, the algorithm achieves a balance between global optimization and local fine-grained search. Compared with the genetic algorithm, particle swarm optimization algorithm and bat algorithm, simulation results demonstrate that the proposed method can effectively enhance the low-carbon operational economy of VPPs with high PV, ESS, and EV penetration. The research findings provide theoretical support and practical references for optimal dispatch of multi-stakeholder VPPs. Full article

In this study, copper–titanium (Cu-Ti) composite coatings with 6 wt.% titanium content were fabricated via cold spray additive manufacturing (CSAM) using nitrogen as the propellant gas. The synergistic effects of propellant gas temperatures (600 °C, 700 °C, 800 °C) and post-heat treatment temperatures (350 °C, 380 °C, 400 °C) on the microstructure and tensile properties were systematically investigated. Tensile testing, microhardness characterization, and fractography analysis revealed that increasing the propellant gas temperature significantly enhanced the plastic deformation of copper particles, leading to simultaneous improvements in deposit density and interfacial bonding strength. The as-sprayed specimen prepared at 800 °C propellant gas temperature exhibited a tensile strength of 338 MPa, representing a 69% increase over the 600 °C specimen. Post-heat treatment effectively eliminated the work-hardening effects induced by cold spraying, with the 400 °C treated material achieving an elongation of 15% while maintaining tensile strength above 270 MPa. Microstructural analysis demonstrated that high propellant gas temperatures (800 °C) promoted the formation of dense lamellar stacking structures in copper particles, which, combined with a recrystallized fine-grained microstructure induced by 400 °C heat treatment, enabled synergistic optimization of strength and ductility. This work provides critical experimental insights for process optimization in CSAM-fabricated Cu-Ti composites. Full article

This paper aims to explore the influences of the content and gradation of mineral powder on the rheological properties of styrene-butadiene-styrene (SBS) modified asphalt mastic at different aging stages and temperatures. In the experiment, SBS modified asphalt mastic samples with different powder-to-binder ratios (0.6, 0.8, and 1.0) and different mineral powder gradations (500 mesh passing rates of 76.89% and 100%) were prepared. Following aging periods of 5, 25, and 45 h in the pressure aging vessel (PAV), the asphalt underwent comprehensive rheological characterization using a dynamic shear rheometer (DSR). The research shows that mineral powder can boost mastic’s deformation resistance and elastic effect. When aged by PAV for 45 h, the powder-to-binder ratio increased from 0.6 to 1.0, and its complex modulus increased by nearly 2.5 times at 58 °C. For SBS modified asphalt mastic of PAV 0 h, the powder-to-binder ratio increased from 0.6 to 1.0 and its phase angle was reduced from 59.6 to 53.2, which indicated that the elasticity of mastic was improved. However, this accelerated the degradation rate of SBS, making the aging process more complex. Fine-grained mineral powder is more effective in enhancing mastic’s deformation resistance than coarse-grained mineral powder. The fine-graded mastic had better rutting resistance after 45 h of aging than after 25 h of aging because the mineral powder compensated for the SBS loss-induced elasticity reduction. Smaller mineral powder particles lead to better a mastic anti-aging effect. After 45 h of aging, fine-grained mineral powder offered a better elastic effect. But the ways in which mineral powder and SBS boost mastic elasticity differ greatly. The results of this study provide a reference for optimizing the design of asphalt mixtures. Full article