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Search Results (919)

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Keywords = equivalent impedance

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18 pages, 5378 KB  
Article
Enhancing Common-Mode Loop Stability of Three-Phase Four-Bridge Grid-Connected Inverters via Control Delay
by Qiyu Zhong, Hao Bai, Guangming Chen, Yingjie Tan, Jieyu Lin and Yipeng Liu
Energies 2026, 19(3), 646; https://doi.org/10.3390/en19030646 - 27 Jan 2026
Abstract
As the three-phase four-bridge inverter (3P4B) can effectively compensate for the unbalanced three-phase loads in the grid, it is an important converter option for distributed generation grid connection. As in a three-phase three-bridge inverter (3P3B), the wide variation in grid impedance also poses [...] Read more.
As the three-phase four-bridge inverter (3P4B) can effectively compensate for the unbalanced three-phase loads in the grid, it is an important converter option for distributed generation grid connection. As in a three-phase three-bridge inverter (3P3B), the wide variation in grid impedance also poses instability issues for 3P4B. This issue has been well-addressed for 3P3B, which can be seen as a differential-mode circuit. However, 3P4B has an extra common-mode circuit, and the solution to the instability problem has not been investigated so far. To address this issue, this paper first analyzes the mechanism of 3P4B common-mode circuit instability and discovers its stability range difference from its differential-mode circuit. Then, an equivalent control delay compensator is independently introduced into the common-mode loop, which extends its stable range. This paper also conducts a detailed analysis of the control delay compensator’s impacts on the common-mode control loop and proposes a quantitative design method for the compensator accordingly. Experimental results validate that the proposed method effectively mitigates common-mode loop instability even under a wide range of grid impedance variations. Full article
(This article belongs to the Special Issue Energy, Electrical and Power Engineering: 5th Edition)
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14 pages, 3060 KB  
Article
Bias-Induced Modulation of Charge Transport and Relaxation Dynamics in Perovskite Solar Cells: An Impedance Spectroscopy Approach
by Yassine Tabbai, Abdelhadi Mortadi, Houda Lifi and Hamid Nasrellah
Eng 2026, 7(2), 55; https://doi.org/10.3390/eng7020055 - 23 Jan 2026
Viewed by 131
Abstract
In this study, we employ impedance spectroscopy to investigate the internal mechanisms influencing the efficiency and performance of perovskite solar cells (PSCs). Using SCAPS-1D software (version 3.3.10), we simulate the FTO/ZnO/MASnI3/NiOx/Au heterostructure to analyze the complex impedance (Z*) and electric modulus [...] Read more.
In this study, we employ impedance spectroscopy to investigate the internal mechanisms influencing the efficiency and performance of perovskite solar cells (PSCs). Using SCAPS-1D software (version 3.3.10), we simulate the FTO/ZnO/MASnI3/NiOx/Au heterostructure to analyze the complex impedance (Z*) and electric modulus (M*). This approach allows us to differentiate between bulk material properties and interface phenomena, such as ion migration, charge transport, and recombination dynamics. Through Nyquist and Bode plots, we identify three distinct relaxation processes associated with charge migration, interface polarization, and charge injection/extraction at the electrodes. To achieve a more comprehensive understanding, we model the impedance and modulus spectra using an equivalent electrical circuit, which accurately reproduces the experimental data. Our analysis reveals that increasing the bias voltage extends the relaxation times for charge transport and interface polarization, highlighting a decline in performance under higher operational voltages. This performance drop is attributed to elevated resistive losses and enhanced recombination processes, which become more pronounced at higher fields. These findings emphasize the importance of optimizing both bulk material properties and interface engineering to mitigate losses and improve the overall performance and stability of PSCs. Full article
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18 pages, 5390 KB  
Article
Multilevel Modeling and Validation of Thermo-Mechanical Nonlinear Dynamics in Flexible Supports
by Xiangyu Meng, Qingyu Zhu, Qingkai Han and Junzhe Lin
Machines 2026, 14(1), 131; https://doi.org/10.3390/machines14010131 - 22 Jan 2026
Viewed by 73
Abstract
Prediction accuracy for complex flexible support systems is often limited by insufficiently characterized thermo-mechanical couplings and nonlinearities. To address this, we propose a multilevel hybrid parallel–serial model that integrates the thermo-viscous effects of a Squeeze Film Damper (SFD) via a coupled Reynolds–Walther equation, [...] Read more.
Prediction accuracy for complex flexible support systems is often limited by insufficiently characterized thermo-mechanical couplings and nonlinearities. To address this, we propose a multilevel hybrid parallel–serial model that integrates the thermo-viscous effects of a Squeeze Film Damper (SFD) via a coupled Reynolds–Walther equation, the structural flexibility of a squirrel-cage support using Finite Element analysis, and the load-dependent stiffness of a four-point contact ball bearing based on Hertzian theory. The resulting state-dependent system is solved using a force-controlled iterative numerical algorithm. For validation, a dedicated bidirectional excitation test rig was constructed to decouple and characterize the support’s dynamics via frequency-domain impedance identification. Experimental results indicate that equivalent damping is temperature-sensitive, decreasing by approximately 50% as the lubricant temperature rises from 30 °C to 100 °C. In contrast, the system exhibits pronounced stiffness hardening under increasing loads. Theoretical analysis attributes this nonlinearity primarily to the bearing’s Hertzian contact mechanics, which accounts for a stiffness increase of nearly 240%. This coupled model offers a distinct advancement over traditional linear approaches, providing a validated framework for the design and vibration control of aero-engine flexible supports. Full article
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28 pages, 978 KB  
Article
Computable Reformulation of Data-Driven Distributionally Robust Chance Constraints: Validated by Solution of Capacitated Lot-Sizing Problems
by Hua Deng and Zhong Wan
Mathematics 2026, 14(2), 331; https://doi.org/10.3390/math14020331 - 19 Jan 2026
Viewed by 83
Abstract
Uncertainty in optimization models often causes awkward properties in their deterministic equivalent formulations (DEFs), even for simple linear models. Chance-constrained programming is a reasonable tool for handling optimization problems with random parameters in objective functions and constraints, but it assumes that the distribution [...] Read more.
Uncertainty in optimization models often causes awkward properties in their deterministic equivalent formulations (DEFs), even for simple linear models. Chance-constrained programming is a reasonable tool for handling optimization problems with random parameters in objective functions and constraints, but it assumes that the distribution of these random parameters is known, and its DEF is often associated with the complicated computation of multiple integrals, hence impeding its extensive applications. In this paper, for optimization models with chance constraints, the historical data of random model parameters are first exploited to construct an adaptive approximate density function by incorporating piecewise linear interpolation into the well-known histogram method, so as to remove the assumption of a known distribution. Then, in view of this estimation, a novel confidence set only involving finitely many variables is constructed to depict all the potential distributions for the random parameters, and a computable reformulation of data-driven distributionally robust chance constraints is proposed. By virtue of such a confidence set, it is proven that the deterministic equivalent constraints are reformulated as several ordinary constraints in line with the principles of the distributionally robust optimization approach, without the need to solve complicated semi-definite programming problems, compute multiple integrals, or solve additional auxiliary optimization problems, as done in existing works. The proposed method is further validated by the solution of the stochastic multiperiod capacitated lot-sizing problem, and the numerical results demonstrate that: (1) The proposed method can significantly reduce the computational time needed to find a robust optimal production strategy compared with similar ones in the literature; (2) The optimal production strategy provided by our method can maintain moderate conservatism, i.e., it has the ability to achieve a better trade-off between cost-effectiveness and robustness than existing methods. Full article
(This article belongs to the Section D: Statistics and Operational Research)
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21 pages, 8455 KB  
Article
Comparative Experimental Performance Assessment of Tilted and Vertical Bifacial Photovoltaic Configurations for Agrivoltaic Applications
by Osama Ayadi, Reem Shadid, Mohammad A. Hamdan, Qasim Aburumman, Abdullah Bani Abdullah, Mohammed E. B. Abdalla, Haneen Sa’deh and Ahmad Sakhrieh
Sustainability 2026, 18(2), 931; https://doi.org/10.3390/su18020931 - 16 Jan 2026
Viewed by 182
Abstract
Agrivoltaics—the co-location of photovoltaic energy production with agriculture—offers a promising pathway to address growing pressures on land, food, and clean energy resources. This study evaluates the first agrivoltaic pilot installation in Jordan, located in Amman (935 m above sea level; hot-summer Mediterranean climate), [...] Read more.
Agrivoltaics—the co-location of photovoltaic energy production with agriculture—offers a promising pathway to address growing pressures on land, food, and clean energy resources. This study evaluates the first agrivoltaic pilot installation in Jordan, located in Amman (935 m above sea level; hot-summer Mediterranean climate), during its first operational year. Two 11.1 kWp bifacial photovoltaic (PV) systems were compared: (i) a south-facing array tilted at 10°, and (ii) a vertical east–west “fence” configuration. The tilted system achieved an annual specific yield of 1962 kWh/kWp, approximately 35% higher than the 1288 kWh/kWp obtained from the vertical array. Seasonal variation was observed, with the performance gap widening to ~45% during winter and narrowing to ~22% in June. As expected, the vertical system exhibited more uniform diurnal output, enhanced early-morning and late-afternoon generation, and lower soiling losses. The light profiles measured for the year indicate that vertical systems barely impede the light requirements of crops, while the tilted system splits into distinct profiles for the intra-row area (akin to the vertical system) and sub-panel area, which is likely to support only low-light requirement crops. This configuration increases the levelized cost of electricity (LCOE) by roughly 88% compared to a conventional ground-mounted system due to elevated structural costs. In contrast, the vertical east–west system provides an energy yield equivalent to about 33% of the land area at the tested configuration but achieves this without increasing the LCOE. These results highlight a fundamental trade-off: elevated tilted systems offer greater land-use efficiency but at higher cost, whereas vertical systems preserve cost parity at the expense of lower energy density. Full article
(This article belongs to the Special Issue Energy Economics and Sustainable Environment)
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14 pages, 1687 KB  
Article
Analysis on the Transient Synchronization Stability of a Wind Farm with Multiple PLL-Based PMSGs
by Bixing Ren, Dajiang Wang, Xinyao Zhu, Ningyu Zhang, Chunyu Chen and Qiang Li
Processes 2026, 14(2), 321; https://doi.org/10.3390/pr14020321 - 16 Jan 2026
Viewed by 143
Abstract
The presence of multiple permanent magnet synchronous generators (PMSGs) results in a highly complex and high-dimensional wind-farm model, making its transient synchronizing stability characteristics insufficiently understood and difficult to analyze. This paper investigates the mechanism by which interactions among multiple wind generators trigger [...] Read more.
The presence of multiple permanent magnet synchronous generators (PMSGs) results in a highly complex and high-dimensional wind-farm model, making its transient synchronizing stability characteristics insufficiently understood and difficult to analyze. This paper investigates the mechanism by which interactions among multiple wind generators trigger transient synchronizing instability in wind farms. First, considering the influence of line impedance ratios, a reduced single-machine aggregated model suitable for transient synchronizing stability analysis of a wind farm with multiple PMSGs was derived from the similarity normalization transformation of the state-space matrices. Based on the aggregated model, the concepts of equivalent accelerating area and equivalent decelerating area were introduced to evaluate transient synchronizing stability of the wind farm. Through a comprehensive analysis of the effects of the generator dynamics, number of generators, network topology, and system parameters on these indices, the mechanism by which multi-PMSG interactions induce transient synchronization instability in PMSG wind farms is revealed. Finally, case studies were conducted to validate the accuracy and applicability of the analysis. Full article
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15 pages, 4871 KB  
Article
Numerical Simulation and Experimental Investigation of Conductive Carbon Fiber-Reinforced Asphalt Concrete
by Yusong Yan, Lingjuan Huang, Pengzhe Xie, Bin Lei and Hanbing Zhao
Buildings 2026, 16(2), 369; https://doi.org/10.3390/buildings16020369 - 15 Jan 2026
Viewed by 114
Abstract
Numerical simulation of the electrical conductivity of carbon fiber-reinforced asphalt concrete is essential for understanding its electrical behavior, yet research in this area remains limited. This study prepared six groups of Marshall specimens with carbon fiber (CF) contents of 0.1 wt%, 0.2 wt%, [...] Read more.
Numerical simulation of the electrical conductivity of carbon fiber-reinforced asphalt concrete is essential for understanding its electrical behavior, yet research in this area remains limited. This study prepared six groups of Marshall specimens with carbon fiber (CF) contents of 0.1 wt%, 0.2 wt%, 0.3 wt%, 0.4 wt%, 0.5 wt%, and 0.6 wt%. The resistivity and asphalt concrete (AC) impedance spectra were measured to analyze the effect of fiber content on electrical performance. Nyquist diagrams were fitted to establish an equivalent circuit model, and a representative volume element (RVE) finite element model was developed. The Generalized Effective Medium (GEM) equation was employed to fit the resistivity data. The results show that the resistivity exhibits a two-stage characteristic—an abrupt decrease followed by stabilization, with an optimal CF content range of 0.2–0.4 wt%. Among the equivalent circuit parameters, the contact resistance (R1) and tunneling resistance (R2) significantly decreased, the growth of interface capacitance (C1) slowed, the constant phase element ZQ increased, and the non-monotonic change of volume resistance (R3) reflected the heterogeneity of the internal void distribution of the material. The finite element numerical solution for resistivity, derived from the GEM equation, aligns well with experimental values, validating the proposed simulation approach. Full article
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15 pages, 1201 KB  
Article
Optimal Operation of Distribution Networks Considering an Improved Voltage Stability Margin
by Chen Dai, Sitong Yan, Chuang Yu, Xiufeng Wang, Qianran Zhang, Lichao Zhou, Zifa Liu and Ming Gong
Energies 2026, 19(2), 426; https://doi.org/10.3390/en19020426 - 15 Jan 2026
Viewed by 113
Abstract
To address the voltage instability in distribution networks with a high penetration of renewable energy, a multi-objective optimal scheduling method is proposed based on an enhanced static voltage stability margin ratio (SVSMR). The SVSMRd index suitable for complex distribution networks is constructed [...] Read more.
To address the voltage instability in distribution networks with a high penetration of renewable energy, a multi-objective optimal scheduling method is proposed based on an enhanced static voltage stability margin ratio (SVSMR). The SVSMRd index suitable for complex distribution networks is constructed by analytical derivation and equivalent impedance correction, and the distributed access characteristics of distributed power generation are considered. Based on the simulation analysis of the PS_CAD simulation platform, the effectiveness and engineering applicability of the SVSMRd index are compared in the multi-energy station distribution network scenario, and the calculation results of SVSMRF and SDSCR are used to verify it. A multi-objective mixed-integer optimisation model is constructed, with the objective function encompassing electricity purchase cost, network loss cost, and energy storage revenue, and the lowest value of the SVSMRd index of various new energy nodes is used as the optimisation object to carry out stability targets. Based on the epsilon constraint method, a Pareto frontier solution set is generated through example analysis, which has non-dominant characteristics. The results of the example analysis show that the proposed method can effectively reduce the operating cost, ensure the voltage stability margin of the system, and realise the collaborative optimisation of source–network–load–storage resources. This paper provides a new idea and method for the optimal operation of the distribution network, and optimises the distribution network under a high proportion of new energy access in the distribution network. Full article
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19 pages, 6578 KB  
Article
High-Resolution Spatiotemporal-Coded Differential Eddy-Current Array Probe for Defect Detection in Metal Substrates
by Qi Ouyang, Yuke Meng, Lun Huang and Yun Li
Sensors 2026, 26(2), 537; https://doi.org/10.3390/s26020537 - 13 Jan 2026
Viewed by 144
Abstract
To address the problems of weak geometric features, low signal response amplitude, and insufficient spatial resolvability of near-surface defects in metal substrates, a high-resolution spatiotemporal-coded eddy-current array probe is proposed. The probe adopts an array topology with time-multiplexed excitation and adjacent differential reception, [...] Read more.
To address the problems of weak geometric features, low signal response amplitude, and insufficient spatial resolvability of near-surface defects in metal substrates, a high-resolution spatiotemporal-coded eddy-current array probe is proposed. The probe adopts an array topology with time-multiplexed excitation and adjacent differential reception, achieving a balance between high common-mode rejection ratio and high-density spatial sampling. First, a theoretical electromagnetic coupling model between the probe and the metal substrate is established, and finite-element simulations are conducted to investigate the evolution of the skin effect, eddy-current density distribution, and differential impedance response over an excitation frequency range of 1–10 MHz. Subsequently, a 64-channel M-DECA probe and an experimental testing platform are developed, and frequency-sweeping experiments are carried out under different excitation conditions. Experimental results indicate that, under a 50 kHz excitation frequency, the array eddy-current response achieves an optimal trade-off between signal amplitude and spatial geometric consistency. Furthermore, based on the pixel-to-physical coordinate mapping relationship, the lateral equivalent diameters of near-surface defects with different characteristic scales are quantitatively characterized, with relative errors of 6.35%, 4.29%, 3.98%, 3.50%, and 5.80%, respectively. Regression-based quantitative analysis reveals a power-law relationship between defect area and the amplitude of the differential eddy-current array response, with a coefficient of determination R2=0.9034 for the bipolar peak-to-peak feature. The proposed M-DECA probe enables high-resolution imaging and quantitative characterization of near-surface defects in metal substrates, providing an effective solution for electromagnetic detection of near-surface, low-contrast defects. Full article
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13 pages, 5213 KB  
Article
Active Damping Control for the Modular Multi-Active-Bridge Converter
by Wusong Wen, Yingchao Zhang, Tianwen Zhan, Sheng Long and Hao Deng
Energies 2026, 19(2), 369; https://doi.org/10.3390/en19020369 - 12 Jan 2026
Viewed by 108
Abstract
The modular multi-active bridge (MMAB) converter—characterized by electrical isolation, modular design, high power density, and high efficiency—can be readily scaled to multiple DC ports through an internal shared high-frequency bus (HFB), establishing it as a viable topology for DC transformer (DCT) applications. However, [...] Read more.
The modular multi-active bridge (MMAB) converter—characterized by electrical isolation, modular design, high power density, and high efficiency—can be readily scaled to multiple DC ports through an internal shared high-frequency bus (HFB), establishing it as a viable topology for DC transformer (DCT) applications. However, its interconnection to a DC grid via low-damping inductors may provoke low-frequency oscillations and instability. To mitigate this issue, this paper employs a pole-zero cancellation approach to model the conventional constant-power control (CPC) loop as a second-order system, thereby elucidating the relationship between equivalent line impedance and stability. An active damping control strategy based on virtual impedance is then introduced, supported by systematic design guidelines for the damping compensation stage. Simulation and experimental results confirm that under weak damping conditions, the proposed method raises the damping coefficient to 0.707 and effectively suppresses low-frequency oscillations—all without altering physical line impedance, introducing additional power losses or requiring extra sensing devices—thereby markedly improving grid-connected stability. Full article
(This article belongs to the Section F3: Power Electronics)
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22 pages, 6056 KB  
Article
Interface-Engineered Copper–Barium Strontium Titanate Composites with Tunable Optical and Dielectric Properties
by Mohammed Tihtih, M. A. Basyooni-M. Kabatas, Redouane En-nadir and István Kocserha
Nanomaterials 2026, 16(2), 96; https://doi.org/10.3390/nano16020096 - 12 Jan 2026
Viewed by 245
Abstract
We report the synthesis and multifunctional characterization of copper-reinforced Ba0.85Sr0.15TiO3 (BST) ceramic composites with Cu contents ranging from 0 to 40 wt%, prepared by a sol–gel route and densified using spark plasma sintering (SPS). X-ray diffraction and FT-IR [...] Read more.
We report the synthesis and multifunctional characterization of copper-reinforced Ba0.85Sr0.15TiO3 (BST) ceramic composites with Cu contents ranging from 0 to 40 wt%, prepared by a sol–gel route and densified using spark plasma sintering (SPS). X-ray diffraction and FT-IR analyses confirm the coexistence of cubic and tetragonal BST phases, while Cu remains as a chemically separate metallic phase without detectable interfacial reaction products. Microstructural observations reveal abnormal grain growth induced by localized liquid-phase-assisted sintering and progressive Cu agglomeration at higher loadings. Scanning electron microscopy reveals abnormal grain growth, with the average BST grain size increasing from approximately 3.1 µm in pure BST to about 5.2 µm in BST–Cu40% composites. Optical measurements show a continuous reduction in the effective optical bandgap (apparent absorption edge) from 3.10 eV for pure BST to 2.01 eV for BST–Cu40%, attributed to interfacial electronic states, defect-related absorption, and enhanced scattering rather than Cu lattice substitution. Electrical characterization reveals a percolation threshold at approximately 30 wt% Cu, where AC conductivity and dielectric permittivity reach their maximum values. Impedance spectroscopy and equivalent-circuit analysis demonstrate strong Maxwell–Wagner interfacial polarization, yielding a maximum permittivity of ~1.2 × 105 at 1 kHz for BST–Cu30%. At higher Cu contents, conductivity and permittivity decrease due to disrupted Cu connectivity and increased porosity. These findings establish BST–Cu composites as tunable ceramic–metal systems with enhanced dielectric and optical responses, demonstrating potential for specialized high-capacitance decoupling applications where giant permittivity is prioritized over low dielectric loss. Full article
(This article belongs to the Section Nanophotonics Materials and Devices)
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27 pages, 1690 KB  
Article
Optimal Reduced Network Based on PSO-OPF-Kron Algorithm for Load Rejection Electromagnetic Transient Studies
by Kamile Fuchs, Roman Kuiava, Thelma Solange Piazza Fernandes, Wagner Felipe Santana Souza, Mateus Duarte Teixeira, Alexandre Rasi Aoki, Miguel Armindo Saldanha Mikilita and Rafael Martins
Energies 2026, 19(2), 321; https://doi.org/10.3390/en19020321 - 8 Jan 2026
Viewed by 191
Abstract
Modern power systems have become increasingly complex, making the detailed modeling and analysis of large-scale networks computationally demanding and often impractical. Therefore, network reduction techniques are essential for representing a smaller area of interest while preserving the electrical behavior of the complete system. [...] Read more.
Modern power systems have become increasingly complex, making the detailed modeling and analysis of large-scale networks computationally demanding and often impractical. Therefore, network reduction techniques are essential for representing a smaller area of interest while preserving the electrical behavior of the complete system. For electromagnetic transient (EMT) studies, such as load rejection analysis, reduced networks are commonly derived using classical methods like Kron reduction under maximum power transfer conditions. However, this approach can lead to discrepancies in load flow and short-circuit levels between the reduced and complete systems. In addition, Kron reduction may introduce negative resistances in the reduced-order model, compromising system stability by producing non-passive equivalents and potentially causing unrealistic or numerically unstable EMT simulations. To address these limitations, this paper proposes an optimization-based approach, termed PSO-OPF-Kron, which integrates Optimal Power Flow (OPF) with the Particle Swarm Optimization (PSO) algorithm to refine the equivalent network parameters. The method optimally determines power injections, bus voltages, transformer tap settings, and impedances to align the reduced model with the full system’s operating point and short-circuit levels. Validation on the IEEE 39-bus system demonstrates that the proposed method significantly improves accuracy and numerical stability, ensuring reliable EMT simulations for load rejection studies. Full article
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23 pages, 8503 KB  
Article
A Novel Mixed Stimulation Pattern for Balanced Pulmonary EIT Imaging Performance
by Zhibo Zhao, Zhijun Gao, Heyao Zhu, Zhanqi Zhao, Meng Dai, Zilong Liu, Feng Fu and Lin Yang
Bioengineering 2026, 13(1), 72; https://doi.org/10.3390/bioengineering13010072 - 8 Jan 2026
Viewed by 354
Abstract
Pulmonary electrical impedance tomography (EIT) offers non-invasive and real-time imaging in a compact device size, making it valuable for pulmonary ventilation monitoring. However, conventional EIT stimulation patterns face a trade-off dilemma between anti-noise performance and image interpretability. To address this challenge, we propose [...] Read more.
Pulmonary electrical impedance tomography (EIT) offers non-invasive and real-time imaging in a compact device size, making it valuable for pulmonary ventilation monitoring. However, conventional EIT stimulation patterns face a trade-off dilemma between anti-noise performance and image interpretability. To address this challenge, we propose a novel mixed stimulation pattern that integrates opposite and adjacent stimulation patterns with a tunable weight ratio. The results of simulations and human experiments (involving 30 subjects) demonstrated that the mixed stimulation pattern uses 200 stimulation–measurement channels, preserves a high signal-to-noise ratio, improves lung separation, and reduces artifacts compared with the opposite and adjacent stimulation patterns. It maintained stable imaging at 600 μA of stimulation current amplitude (equivalent to 1 mA) and preserved most imaging and clinical indicators’ stability at 200 μA (except GI/RVDSD). The adjustable weight ratio enables imaging performance to be flexibly adjusted according to different noise levels in acquisition environments. In conclusion, the pattern we proposed offers a superior alternative to traditional patterns, achieving a favorable balance of real-time capability, anti-noise performance, and image interpretability for pulmonary EIT imaging. Full article
(This article belongs to the Section Biosignal Processing)
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16 pages, 3832 KB  
Article
High-Capacitance Gold Nanoparticles from Rhus coriaria: Green Synthesis, Characterization and Electrochemical Evaluation for Supercapacitor Technologies
by Mehmet Firat Baran, Elchin Huseynov, Aziz Eftekhari, Abdulkadir Levent, Erdal Ertaş, Taras Kavetskyy, Ondrej Šauša, Evgeny Katz and Oleh Smutok
Micromachines 2026, 17(1), 82; https://doi.org/10.3390/mi17010082 - 8 Jan 2026
Viewed by 260
Abstract
The structural and electrochemical properties of gold nanoparticles biosynthesized from Rhus coriaria L. (Rc@AuNPs) were comprehensively investigated and characterized. R. coriaria (sumac) served as a natural gold reducing and capping agent due to its rich polyphenolic and phytochemical composition, enabling the sustainable, low-cost, [...] Read more.
The structural and electrochemical properties of gold nanoparticles biosynthesized from Rhus coriaria L. (Rc@AuNPs) were comprehensively investigated and characterized. R. coriaria (sumac) served as a natural gold reducing and capping agent due to its rich polyphenolic and phytochemical composition, enabling the sustainable, low-cost, and environmentally friendly synthesis of Rc@AuNPs. The electrochemical behavior of the hybrid material was evaluated using cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS). Rc@AuNPs exhibited specific capacitances of 129.48 F/g, 156.32 F/g, and 280.37 F/g in H2SO4, Na2SO4, and KOH electrolytes, respectively, indicating strong potential for supercapacitor and energy-storage applications. GCD analysis further showed Csp values of 107.69 F/g (H2SO4), 133.23 F/g (Na2SO4), and 348.34 F/g (KOH), confirming the highest charge-storage performance in basic media. EIS measurements supported these results, yielding equivalent series resistance (ESR) values of 67.96 Ω in H2SO4, 64.42 Ω in Na2SO4, and a notably lower 24.43 Ω in KOH, consistent with its higher ionic conductivity and more efficient charge transfer. Overall, the superior Csp and low ESR observed in KOH demonstrate the excellent capacitive behavior of Rc@AuNPs. These biosynthesized gold nanoparticles represent a promising and sustainable electrode material for high-performance energy-storage technologies. Full article
(This article belongs to the Section D:Materials and Processing)
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15 pages, 6356 KB  
Article
Hexagonal Microsphere/Cubic Particle ZnIn2S4 Heterojunctions: A Robust Photocatalyst for Visible-Light-Driven Conversion of 5-Hydroxymethylfurfural to 2,5-Diformylfuran Under Ambient Air Conditions
by Lin-Yu Jiao, Ze-Long Sun, Wen-Yu Luo, Fei Wen, Jun-Bo Ye, Kang-Lai Chen, Long Xu, Bin Tian and Shan-Shan Liu
Catalysts 2026, 16(1), 69; https://doi.org/10.3390/catal16010069 - 7 Jan 2026
Viewed by 361
Abstract
In recent years, biomass utilization has attracted extensive attention. Herein, hexagonal/cubic ZnIn2S4 (ZIS) heterojunction catalysts were synthesized via a solvothermal method for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF). The results demonstrated that the constructed heterojunctions effectively promoted [...] Read more.
In recent years, biomass utilization has attracted extensive attention. Herein, hexagonal/cubic ZnIn2S4 (ZIS) heterojunction catalysts were synthesized via a solvothermal method for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF). The results demonstrated that the constructed heterojunctions effectively promoted carrier separation. The optimal catalyst achieved an HMF conversion rate of 88.8% and a DFF yield of 86.6% within 1 h in the open air. X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) characterizations confirmed the successful fabrication of the composite phase structure and revealed a porous spherical morphology. Equivalent circuit fitting of electrochemical impedance spectroscopy (EIS) data indicated that the hexagonal/cubic heterojunctions possessed the lowest charge transfer resistance (Rct = 5825 Ω), which effectively reduced interfacial charge transfer resistance and accelerated the transport of photoinduced carriers. Radical quenching experiments and electron paramagnetic resonance (EPR) spectroscopy identified superoxide radicals (·O2) as the primary reactive species. Meanwhile, density functional theory (DFT) calculations elucidated the formation of the built-in electric field and the charge transfer mechanism. This work’s construction of Type-II ZIS heterojunctions effectively addressed the issue of rapid carrier recombination in pristine ZIS materials, providing a feasible strategy for biomass valorization. Full article
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