Search Results (1,284)

The environmentally sustainable decontamination of chemical warfare agents (CWAs) remains a critical challenge. This study reports the solar-driven photocatalytic degradation of live CWAs—GD, HD, HN1, and HN2—using titanium dioxide (TiO₂) under natural sunlight. Experiments were conducted in an OPCW-designated laboratory to ensure authenticity and practical relevance. TiO₂ exhibited substantial photocatalytic activity, achieving 60% degradation of GD, 63% of HD, 76% of HN1, and 93% of HN2 after 6 h. High-resolution mass spectrometry (HR-MS) analysis suggested plausible degradation pathways for nitrogen mustards consistent with the higher apparent reactivity of HN2; detailed identification of intermediates and reactive oxygen species remains a subject for future investigation. These findings provide mechanistic insights into the photocatalytic behavior of nitrogen-based agents and address a notable gap in studies that have largely focused on sulfur mustards and nerve agents. Beyond military applications, this solar-assisted photocatalytic approach provides mechanistic information relevant to the green remediation of highly toxic organic contaminants and broader chemical hazard mitigation. This work contributes foundational knowledge toward eco-friendly decontamination technologies capable of mitigating diverse CWA threats. Full article

The problem of chromium contamination, especially Cr(VI), in acidic wastewater has drawn significant attention, requiring effective and sustainable remediation measures. In this study, tannic-acid/Fe₃O₄-modified corn straw biochar (Fe-TA-CSB) is prepared by a grinding-calcination method to remove Cr(VI). The factors influencing the removal effect of Fe-TA-CSB are investigated through static adsorption experiments. The removal mechanism is explored by combining adsorption kinetics, isothermal adsorption, and thermodynamics, as well as characterization methods. The results show that the removal efficiency of Cr(VI) increases with the increase in pH, contact time (t), and solid–liquid ratio (m/v), but decreases with the increase in initial concentration (C₀). Under optimal conditions of TA/Fe₃O₄ mass ratio = 12.5%, pH = 3.0, m/v = 1.0 g/L, and C₀ = 10 mg/L, the removal efficiency value is 94.02%, which is approximately 81.44% after four adsorption–desorption cycles. The adsorption behavior is fitted well by the Sips isotherm model and Elovich kinetics model, suggesting the adsorption process of heterogeneous monolayer chemisorption. The removal mechanism of Cr(VI) by Fe-TA-CSB involves electrostatic interaction with Cr(VI), reduction in Cr(VI) to Cr(III) through C–O and Fe(II), and complexation of reduced Cr(III) with the introduced Fe–O and phenolic hydroxyl groups. Fe-TA-CSB is an environmentally friendly and renewable adsorbent with good potential for the treatment of acidic wastewater. Full article

Population aging has increased the need for public open spaces that older adults can use safely, comfortably, and confidently. In many urban parks and community squares, however, resting facilities are still designed as standardized street furniture, with cold materials, insufficient hand support, limited wheelchair-inclusive space, and weak support for everyday social interaction. This study examines age-friendly public facilities as micro-scale spatial elements that shape sitting, standing, staying, communication, and willingness to remain in small urban open spaces. Drawing on field observation, behavioral analysis, semi-structured interviews, and a multi-criteria design-evaluation process, the study identifies older adults’ key facility-use needs and translates them into design indicators and alternative facility schemes. The results show that physical support and inclusive spatial use are the most important design priorities. Standing-up assistance, sitting-posture support, perceived structural stability, and age-appropriate dimensional adaptation were more influential than purely decorative or auxiliary functions. Among the three alternative schemes, the modular pergola system performed best because it combined stable hand support, independent seating, an age-friendly interactive table, shaded resting space, wheelchair-inclusive layout, and wood-based sensory comfort. The sensitivity analysis further confirmed that this scheme maintained a stable advantage under most weight-adjustment conditions. The findings suggest that age-friendly public facility design should move beyond the improvement of individual furniture products and instead integrate bodily support, spatial accessibility, social interaction, material comfort, and environmental pattern quality. This study provides a design-decision framework for improving the inclusiveness, accessibility, and health-supportive capacity of urban public open spaces for older adults. Full article

The sustainable development of forest ecotourism relies on the effective stimulation of tourists’ environmentally responsible behavior, and the intervention of participatory art and aesthetics provides a new driving force for this process. Taking Xiqiaoshan National Forest Park (Nanhai Land Art Festival) as a case study, we propose an extended stimulus–organism–response (S-O-R) theoretical framework to reveal the psychological perception and transmission mechanism of participatory art and aesthetic experience in empowering the sustainable development of ecotourism. We used a hybrid approach combining PLS-SEM and artificial neural networks (ANNs) to analyze survey data from 596 Chinese tourists. The study found that sensory impressions driven by art and aesthetics significantly and positively influence tourists’ natural connections, perceived value, and ecotourism attitudes. These three constructs function as significant parallel mediators between sensory impressions and environmentally responsible behavior, while chain mediation effects are statistically significant but of small magnitude. The new environmental paradigm (NEP), conceptualized as an individual trait boundary condition, exhibits a significant negative moderating effect on the relationship between sensory impressions and connectedness to nature. ANN sensitivity analysis further complements the findings by demonstrating the prominent nonlinear predictive role of ecotourism attitudes in behavioral transformation. This study extends the application boundaries of the S-O-R theory to art-integrated ecotourism research, clarifies the internalization process of tourist experiences from sensory perception to behavioral enactment, and provides empirical evidence for forest tourism managers to optimize experience design and implement differentiated guidance strategies. Full article

This study aims to investigate the effect of organizational identification (OI) on green organizational behavior (GOB) and the mediating role of psychological well-being (PWB) in this relationship. To achieve this research goal, a quantitative study was conducted using a structured questionnaire designed to assess the relevant variables. Data was collected from 264 white-collar employees in the service sector in Istanbul. Surveys were collected from participants face-to-face, using a judgmental sampling method. Hypotheses were tested using AMOS22, SPSS 24 and PROCESS Macro. The significance of indirect effects was analyzed by employing the bootstrapping technique. The results indicate that OI has positive and significant direct effects on GOB and PWB. Furthermore, PWB was found to significantly predict GOB. The bootstrapping analysis revealed that the indirect effect was significant, supporting a partial mediation model. This research illustrates that OI increases GOB both directly and indirectly through PWB. The findings are considered to be of relevance to the literature because this is one of the few studies that addresses the concept of green organizational behavior, which is a focal point in the organizational behavior literature, and it emphasizes the importance of psychological resources in promoting environmentally friendly behaviors within organizations. Full article

Two bio-based insulating oils (BHOs) with average carbon chain lengths of approximately 18 and 22 were investigated as short- and long-chain BHOs. By constructing an oil-paper composite insulation system, the generation law of characteristic gases in the two systems was studied by partial discharge experiments. Based on the ReaxFF reaction molecular dynamics simulation under electrothermal coupling stress, the cracking path, cracking rate, evolution of oxygen-containing small molecules, and generation path of characteristic gases of cellulose polymer were revealed. Both systems produced H₂, CH₄, C₂H₂, C₂H₄, C₂H₆, CO, and CO₂, with CO₂ dominant and C₂H₆ least abundant. The short-chain BHO generated markedly higher amounts of H₂, CO, C₂H₂, and C₂H₄ than the long-chain BHO; after 15 min, its H₂ and CO concentrations were about 3.4- and 2.1-times those in the long-chain system, respectively. ReaxFF simulations showed that cellulose degradation in the short-chain BHO followed stepwise chain scission and continuous decarbonylation, favoring CO and unsaturated gas precursors. In contrast, cellulose chains disappeared faster in the long-chain BHO, producing more oxygen-containing organic fragments and C₁-C₅ oxygenated molecules and a higher small-molecule conversion ratio. Characteristic gas pathway analysis revealed that all seven gases could be generated from cellulose pyrolysis intermediates, and different oil environments primarily influenced gas generation behavior by altering the evolution pathways of these intermediates. These findings, at the molecular scale, elucidate the impact of BHO environments on the degradation mechanism of cellulose polymers, providing a theoretical basis for the condition assessment and design of environmentally friendly oil-paper insulation systems. Full article

This study evaluates the characteristics and environmental behavior of river sediments impacted by coal mining in the southern coal region of Santa Catarina, Brazil. Sediments accumulated in mining-affected rivers represent an environmental liability due to the presence of potentially toxic elements and their limited management options. In this context, ceramization is investigated as an alternative strategy for reducing contaminant mobility through thermal treatment of sediments collected at four sampling points (PU1–PU4) along the Urussanga River. Initially, leaching and solubilization tests were performed to assess the mobility of chemical elements, and the raw sediments were further characterized by chemical, mineralogical, and thermal analyses. Subsequently, ceramic specimens were produced from the sediments and subjected to thermal treatment at 1100 °C. After firing, the specimens were re-evaluated through leaching and solubilization assays to verify changes in contaminant mobility after the ceramization process. The results showed that raw sediments exhibited aluminum, iron, and manganese concentrations in the solubilized extract that exceeded regulatory thresholds, particularly for iron, which reached up to 21.91 mg/L. After thermal treatment, a substantial reduction in the solubility of these elements was observed, with concentrations falling below the established limits at all sampling points. This reduction in mobility is likely associated with physicochemical transformations occurring during firing, including matrix densification and the incorporation of elements into less soluble phases, as reported in previous ceramic processing studies. Overall, the findings demonstrate that ceramization represents a promising strategy for reducing contaminant mobility in coal mining-impacted river sediments, offering a viable and environmentally friendly alternative for sediment management and valorization. Full article

This article proposes a sustainable approach to producing eco-friendly paper from fibers derived from water hyacinth (Eichhornia crassipes), an invasive aquatic species with potential high lignocellulose content. The research evaluated the possibility of using its biomass as a non-wood raw material for papermaking through an industrial-oriented processing framework. About 10 groups of water hyacinth samples were analyzed by separating their components (roots, leaves, and stems) to determine moisture content, dry biomass yield, fiber distribution, and performance in papermaking. Mechanical pulping and mild alkaline treatment with sodium hydroxide were compared to evaluate their effects on fiber behavior and paper quality. The results showed a high moisture content in the biomass, averaging approximately 88%, while the remaining dry matter represented the usable fibrous material fraction. After fiber classification, it was revealed that the long fibers predominated over the short fibers and the fine fibers (waste), favoring the hydrogen bonding and structural anchoring during sheet formation. Mechanical quality analyses were conducted using the Corrugating Medium Test (CMT), Concora Crush Test (CCT), Ring Crush Test (RCT), and Short Compression Test (SCT). Untreated water hyacinth paper demonstrated mechanical properties comparable to those of an industrial reference paper, including consistent compression resistance and corrugating performance. In contrast, the alkaline-treated sample showed greater structural uniformity but lower mechanical strength due to fiber fragmentation and increased fine production. Overall, the findings showed that Eichhornia crassipes represents a viable and sustainable alternative to non-wood fibers for paper production, offering potential environmental benefits by serving as an invasive species and reducing dependence on wood-based raw materials. Full article

The self-formed rust layer is significant for weathering steels because their corrosion resistance in a marine atmospheric environment mainly relies on the stability, uniformity and compactness of the rust layer. However, the initial stage of rust formation is vulnerable and prone to being disturbed by the external environment, compromising the protectiveness of the rust layer at a later stage. Therefore, weathering steel often requires the application of rust stabilization techniques. This study has developed a waterborne polyurethane (WPU)-based coating incorporated with mesoporous/hollow SiO₂ nanoparticles, acting as the primary components for the construction of pathways for gaseous H₂O and O₂, as well as for Cl⁻ dissolved in moisture, while blocking liquid water. Salt spray was applied to accelerate the rust formation process, and rust can form beneath the coating, which provides shelter for rust formation against the external environment. Hexamethyldisilazane (HMDS) was applied to further hydrophobize the nanoparticles, and a hydrophobic surface with self-cleaning properties was achieved. The hydrophobized and non-hydrophobized coatings with different thicknesses (10–80 µm) were systematically compared: the morphology of the rust layer and coating surface after salt spray was investigated, the ability of the rust layer to inhibit chloride ingress was compared, and the electrochemical behaviors were analyzed. This study presents a new strategy for weathering steel rust stabilization that features maneuverability, environmental friendliness and low cost. Full article

Protected cultivation, as a core model of modern agriculture, holds a crucial strategic position in alleviating the shortage of arable land resources and increasing farmers’ income. However, due to the closed environment of protected cultivation, suitable temperature and humidity conditions for pathogen reproduction, serious continuous cropping obstacles, disease transmission easily caused by irrigation, and the lack of natural ultraviolet inhibition and crop rotation conditions, soil-borne pathogens accumulate year by year, resulting in early onset, rapid spread, and great difficulty in control. Traditional pesticide formulations often have limitations such as environmental hazards, low utilization rate, unstable active ingredients, excessive use, and short persistence in the control process. In recent years, pesticide slow-release carriers developed based on nanotechnology to regulate the slow-release behavior of pesticide active ingredients have shown great potential in improving pesticide efficacy and safety. This article reviews several commonly used materials for mineral carriers, metal oxide carriers, organic polymer carriers, and organic–inorganic hybrid carriers. With their high specific surface area, high drug loading rate, environmental friendliness, and stimulus-responsive properties, these materials can significantly improve the effective utilization rate of pesticides, extend the persistence period, and enhance targeting, thus providing strong technical support for solving the problem of soil-borne disease control in protected cultivation and promoting the green and sustainable development of protected cultivation. Full article

Lipopeptide biosurfactants and petroleum sulphonates (PSs) have complementary molecular structures that can achieve ultralow interfacial tension (IFT), which is considered the primary mechanism for enhanced oil recovery (EOR). In this study, the phase behavior of lipopeptide compounded with PS/crude oil/water was investigated, which revealed that lipopeptide addition led to the formation of Winsor III middle-phase microemulsion. The synergistic mechanism of ultralow IFT and microemulsion formation enables the lipopeptide-compounded system (LASP) to achieve superior oil displacement efficiency compared with the regular alkaline/surfactant/polymer (ASP) flooding system. Core flooding results proved that under the same conditions, the LASP system increased oil recovery by 10.58% relative to the ASP system. Furthermore, when the ASP system could no longer improve recovery, switching to the LASP system provided an additional 9.55% oil recovery rate. Moreover, the LASP system exhibited superior wettability, interfacial activity, and anti-adsorption properties. These findings highlight the potential of lipopeptide biosurfactants as high-performance, environmentally friendly alternatives to synthetic surfactants in EOR processes. Full article

This study aims to develop a sustainable, low-cost, and high-performance supercapacitor electrode by valorizing waste date seeds (Phoenix dactylifera) into activated carbon and integrating it with a polymer-based hydrogel electrolyte. Waste date seeds were successfully converted into high-performance activated carbon through hydrothermal carbonization followed by sulfuric acid (H₂SO₄) chemical activation. The obtained date seed activated carbon (DSAC) was applied as an electrode material and incorporated into a hydrogel electrolyte for supercapacitor applications. Structural, thermal, and morphological analyses using SEM, FTIR, XRD, and TGA confirmed the formation of a predominantly microporous carbon framework enriched with oxygen-containing functional groups, indicating effective carbonization and activation. The porous structure and surface chemistry contributed to enhanced electrochemical behavior. The electrochemical behavior of the prepared DSAC electrode was investigated through cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) analyses. The material exhibited a highest specific capacitance of 179 F g⁻¹ at a scan rate of 5 mV s⁻¹ and 159 F g⁻¹ at a current density of 0.2 A g⁻¹, demonstrating reliable and stable capacitive characteristics suitable for biomass-derived carbon-based supercapacitor applications. The device also exhibited excellent cycling stability over 5500 cycles, confirming long-term durability. The results demonstrate a promising and environmentally friendly strategy for advanced energy storage systems. Furthermore, the sustainability and cost-effectiveness of the proposed approach are attributed to the utilization of abundant date seed biomass and the simplicity of the hydrothermal–chemical activation process. The enhanced electrochemical performance is primarily associated with the hierarchical porous structure of the activated carbon and the improved ion transport facilitated by the hydrogel electrolyte, which collectively contribute to stable capacitive behavior and long-term cycling durability. Full article

Bamboo, as a rapidly renewable and sustainable material, has gained increasing attention in the construction, furniture, automotive interiors, and packaging industries due to its excellent mechanical properties, light weight, and environmental friendliness. However, the inherent flammability of bamboo, characterized by its porous structure and high hemicellulose content, poses a significant fire hazard that severely limits its wide application. This review systematically synthesizes recent advances in the fire performance and flame-retardant modification of bamboo-based materials. First, the thermal degradation behavior and combustion mechanisms of bamboo are discussed in relation to its primary chemical constituents, including cellulose, hemicellulose, and lignin. Subsequently, various flame-retardant strategies are reviewed, including inorganic flame retardants, phosphorus–nitrogen systems, nanomaterial-based additives, and bio-based flame-retardant approaches. The effectiveness of different modification techniques, such as impregnation treatment, adhesive modification, and surface coating, is also analyzed. Future research directions are proposed, emphasizing the development of environmentally friendly flame-retardant systems, multifunctional modification strategies, and the design of high-performance flame-retardant bamboo-based materials. This review aims to provide a comprehensive framework for advancing the fire safety design and sustainable application of bamboo-based materials. Full article

Tetracycline (TC) contamination in reservoirs poses environmental and human health risks, particularly antibiotic resistance in ecosystems. Bagasse fly ash (BFA), a by-product from the sugarcane processing industry, has gained attention as an environmentally friendly adsorbent. In this study, we aimed to investigate the mechanism of TC adsorption using batch experiments to evaluate the effects of various factors. For example, pH value ranged from 4 to 10, contact time varied between 0 and 90 min, adsorbent doses were noted as 0.5–2.5 g per 50 mL, the initial concentrations of TC were 10–40 mg/L, and the temperature ranged from 293.15 to 318.15 K. To perform surface characterization of BFA, we employed the scanning electron microscopy (SEM) technique. Based on the results of Fourier transform infrared spectroscopy (FTIR) and surface area analysis (Brunauer–Emmett–Teller; BET), its structure and chemical properties are favorable for TC adsorption. Our results demonstrate that the optimal conditions for adsorption were at pH 7.0 and 60 min contact time. The adsorption capacity tended to increase with the initial concentrations of TC and reached a maximum of 0.58 mg/g when the initial concentration was 40 mg/L. Our kinetic analysis results demonstrate that the pseudo-second-order model exhibited the best fit with the experimental data (R² = 0.95638); in comparison, the results of the isotherm behavior study using the Temkin model (R² = 0.97338) indicated the complex adsorption pathway on the BFA surface. Full article

Rural public spaces are crucial to the daily activities of older adults; however, limited research has examined the effects of their environmental characteristics on older adults’ spatiotemporal behavior and perception from a multisensory perspective. This study hypothesizes that composite sensory environments have significant nonlinear predictive effects on older adults’ behavior types and satisfaction. In this study, 10 sample spaces were selected in Qingdao, China. Multi-source data were collected through a two-week period of unobtrusive observation and subjective questionnaire surveys (N = 241). Multiple logistic regression was used to analyze the main effects of environmental characteristics, and an MLP model with a single hidden layer of 100 units was constructed to predict dwell time and satisfaction. The results show that, in the investigated rural context, older adults’ dominant behavior was social activity (81.12%), which mainly occurred in built spaces such as squares. Multiple logistic regression indicated that, among the various environmental factors, visual aesthetics had a statistically significant effect on behavior types (p = 0.013). The MLP model achieved prediction accuracies of 85.3% for dwell time and 93.1% for satisfaction. The key predictive variables were volume perception (100% importance), the Natural Sound Index (NSI) (92.1%), and visual aesthetics (89.3%). Subgroup heterogeneity analysis further showed that older-old adults and those with poorer health conditions were more sensitive to pavement quality and physical comfort, whereas older adults living alone or with limited household companionship were more strongly influenced by visual aesthetics and natural soundscape quality. The theoretical significance of this study lies in proposing quantitative measures of natural sound and odor indices and revealing that, in the specific northern rural built environment, the coordinated design of visual and auditory environments plays an important role in improving spatial quality. The findings provide empirical support for the age-friendly micro-renewal of rural public spaces in specific regions. However, due to the limitations of single-season data and a relatively small sample size, their generalizability needs to be further verified across regions. Full article