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15 pages, 8790 KiB  
Article
A Graphene/MXene-Modified Flexible Fabric for Infrared Camouflage, Electrothermal, and Electromagnetic Interference Shielding
by Xianguang Hou, Ziyi Zang, Yaxin Meng, Tian Wang, Shuai Gao, Qingman Liu, Lijun Qu and Xiansheng Zhang
Nanomaterials 2025, 15(2), 98; https://doi.org/10.3390/nano15020098 - 9 Jan 2025
Cited by 2 | Viewed by 2092
Abstract
Although materials with infrared camouflage capabilities are increasingly being produced, few applications exist in clothing fabrics. Here, graphene/MXene-modified fabric with superior infrared camouflage, Joule heating, and electromagnetic shielding capabilities all in one was prepared by simply scraping a graphene slurry onto alkali-treated cotton [...] Read more.
Although materials with infrared camouflage capabilities are increasingly being produced, few applications exist in clothing fabrics. Here, graphene/MXene-modified fabric with superior infrared camouflage, Joule heating, and electromagnetic shielding capabilities all in one was prepared by simply scraping a graphene slurry onto alkali-treated cotton fabrics, followed by spraying MXene. The functionality of the modified fabrics after different treatment times was then tested and analyzed. The results indicate that the mid-infrared emissivity of the modified fabric decreases with an increase in the coating times of graphene and MXene. When the graphene/MXene-modified fabrics are prepared at loads of 5 and 1.2 mg/cm2, respectively, the modified fabrics have very low infrared emissivity in the 3–5 and 8–14 μm bands, and the surface temperature can be reduced by 53.1 °C when placed on a heater with a temperature of 100 °C (surface radiation temperature of 95 °C). The modified fabric also demonstrates excellent Joule heating capabilities; at 4 V of power, a temperature of 91.7 °C may be reached in 30 s. In addition, customized materials exhibit strong electromagnetic shielding performance. By simply folding the cloth, the electromagnetic interference shield effect can be increased to 64.3 dB. With their superior infrared camouflage, thermal management, and electromagnetic shielding performance, graphene/MXene-modified fabrics have found extensive use in intelligent wearables and military applications. Full article
(This article belongs to the Section 2D and Carbon Nanomaterials)
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13 pages, 4387 KiB  
Article
Electromagnetic Interference Shielding Effectiveness of Pure SiC–Ti3SiC2 Composites Fabricated by Reactive Melt Infiltration
by Mingjun Zhang, Zhijun Ma, Xueqin Pan, Yun Li, Nanlong Zhang, Jiaxiang Xue, Jianfeng Yang and Bo Wang
Materials 2025, 18(1), 157; https://doi.org/10.3390/ma18010157 - 2 Jan 2025
Cited by 2 | Viewed by 928
Abstract
Silicon carbide-based titanium silicon carbide (SiC–Ti3SiC2) composites with low free alloy content and varying Ti3SiC2 contents are fabricated by two-step reactive melt infiltration (RMI) thorough complete reactions between carbon and TiSi2 alloy in SiC-C preforms [...] Read more.
Silicon carbide-based titanium silicon carbide (SiC–Ti3SiC2) composites with low free alloy content and varying Ti3SiC2 contents are fabricated by two-step reactive melt infiltration (RMI) thorough complete reactions between carbon and TiSi2 alloy in SiC-C preforms obtained. The densities of SiC-C preform are tailored by the carbon morphology and volumetric shrinkage of slurry during the gel-casting process, and pure composites with variable Ti3SiC2 volume contents are successfully fabricated with different carbon contents of the preforms. Due to the increased Ti3SiC2 content in the obtained composites, both electrical conductivity and electromagnetic interference (EMI) shielding effectiveness improved progressively, while skin depth exhibited decreased consistently. The improvement in the EMI shielding effectiveness of the composite is due to the free electrons being bound to move in the conductive network formed by the Ti3SiC2 phase, converting electrical energy into thermal energy and reducing the energy of electromagnetic waves. Notably, at a Ti3SiC2 content of 31 vol.%, the EMI shielding effectiveness of the SiC–Ti3SiC2 composites in the X-band reached an impressive 62.1 dB, confirming that SiC–Ti3SiC2 composites can be treated as high-performance EMI shielding materials with extensive application prospects. Full article
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10 pages, 3210 KiB  
Article
Preparation of Reduced Graphene Oxide Films with High and Uniform Thickness for Electromagnetic Interference Shielding
by Meng Li, Li-Jing Xie, Zong-Lin Yi, Dong Liu, Zheng Wang, Ruo-Han Niu, Hui Jia and Qing-Qiang Kong
Crystals 2024, 14(4), 322; https://doi.org/10.3390/cryst14040322 - 29 Mar 2024
Viewed by 1541
Abstract
Reduced graphene films have attracted widespread commercial interest due to high electrical conductivity toward (EMI) shielding. At present, the preparation path of reduced graphene film is to use graphene oxide (GO) as the raw material through self-assembly and high-temperature heat treatment. However, the [...] Read more.
Reduced graphene films have attracted widespread commercial interest due to high electrical conductivity toward (EMI) shielding. At present, the preparation path of reduced graphene film is to use graphene oxide (GO) as the raw material through self-assembly and high-temperature heat treatment. However, the thickness of reduced graphene films is not high and uniform because of the higher mobility of the graphene oxide slurry, which destroys the reliability of the membrane in the field of electromagnetic interference shielding. Here, we propose the use of sodium carboxymethyl cellulose (CMC) to increase the viscosity of graphene oxide to prepare reduced graphene films with high and uniform thickness. After modification with sodium carboxymethyl cellulose, the EMI shielding effectiveness (EMI SE) of reduced graphene oxide films stabilized at 91–96 dB at 8–12 GHz, which is higher than pure graphene films. Meanwhile, the addition of CMC does not affect the structure of reduced graphene films. This work broadens the application of reduced graphene films in electromagnetic shielding. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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19 pages, 10297 KiB  
Article
Mechanism of and Prevention Technology for Water Inrush from Coal Seam Floor under Complex Structural Conditions—A Case Study of the Chensilou Mine
by Qi Wang, Shitian Zheng, Zhiyuan Shi, Pei Wu, Huayong Lv and Gang Wang
Processes 2023, 11(12), 3319; https://doi.org/10.3390/pr11123319 - 29 Nov 2023
Cited by 2 | Viewed by 1411
Abstract
Based on the complex hydrogeological conditions of the Chensilou mine, numerical simulations and field validation methods were used to study the mechanism of water inrush from the floor of the coal seam, which has faults and cracks, as well as the regional advanced [...] Read more.
Based on the complex hydrogeological conditions of the Chensilou mine, numerical simulations and field validation methods were used to study the mechanism of water inrush from the floor of the coal seam, which has faults and cracks, as well as the regional advanced grouting reinforcement technology during the coal mining process. The evolution laws of the roof stress field, displacement field, crack field, and plastic area are revealed at different mining distances. The coupling mechanism of floor water inrush channel formation under complex conditions is analyzed. Advanced grout filling reinforcement technology in the ground area is proposed, the slurry diffusion law of different grouting layers under different grouting pressures is revealed, and the grouting effect is evaluated, which provides a research basis for selecting a reasonable grouting pressure. Finally, the application of regional advanced grouting reinforcement technology was carried out at the site, and the grouting reconstruction effect was verified by the transient electromagnetic and three-dimensional DC resistivity method. The results show that the apparent resistivity of the floor after the grouting reinforcement is high, and the water yield of the verification borehole is less than 10 m3/h. The area where the three-dimensional direct current resistivity is less than 12 Ω·m only appears in the lower part of the middle of the working face, and there is no water in the verification borehole. Through our underground supplementary treatment and verification process, the initial water inflow meets the requirements of being less than 10 m3/h. It indicates that the ground regional advanced treatment project achieved significant results. The results of our research can also provide references for water hazard control in similar mines. Full article
(This article belongs to the Special Issue Advanced Technologies of Deep Mining)
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13 pages, 11068 KiB  
Article
Study on the Application of Elastic Wave CT Technique to Detect the Effect of Post-Grouting of Pile Foundation
by Shenggen Huang, Hui Cao, Jiawang Liu, Ruoyu Yan and Han Zhang
Appl. Sci. 2023, 13(1), 456; https://doi.org/10.3390/app13010456 - 29 Dec 2022
Cited by 2 | Viewed by 1508
Abstract
The post-grouting technology can effectively improve the bearing capacity and reliability of foundation piles, and it is of great academic and economic significance to evaluate the effect of post-grouting. However, in general, the evaluation of the effect of post-grouting slurry on foundation piles [...] Read more.
The post-grouting technology can effectively improve the bearing capacity and reliability of foundation piles, and it is of great academic and economic significance to evaluate the effect of post-grouting. However, in general, the evaluation of the effect of post-grouting slurry on foundation piles is still relatively single, and most researchers only test the improvement of the bearing characteristics of post-grouting piles, but there are few research results on the distribution state of slurry consolidation and the range of the reinforced soil. In this paper, elastic wave CT was used to detect the bridge piles of Taizhou Bay Du Xiaipu Bridge, and elastic wave CT technology was applied to the detection of the post-grouting effect of foundation piles experimentally. The spatial distribution characteristics of the underground grouting reinforcement area were revealed from the perspective of visualization, and the influencing factors of the elastic wave inversion results were analyzed. The conclusions obtained from elastic wave CT detection were similar to those of electromagnetic wave CT, and the laws are basically consistent with the current engineering experience, reflecting the applicability of using elastic wave CT to detect the effect of post-grouting of pile foundation. Full article
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13 pages, 23756 KiB  
Article
Microstructures and Mechanical Properties of A356 Alloy and A6061 Alloy through Rheo, Upsetting, Thixo, Forming Process, and T6 Heat Treatment
by Chul Kyu Jin
Metals 2022, 12(12), 2051; https://doi.org/10.3390/met12122051 - 29 Nov 2022
Cited by 4 | Viewed by 2828
Abstract
The thixo process has the benefit of producing a semi-solid material in which fine primary α-Al grains are uniformly distributed. However, it also has the disadvantage of a costly raw material billet. In this study, a semi-solid slurry was prepared from the rheo [...] Read more.
The thixo process has the benefit of producing a semi-solid material in which fine primary α-Al grains are uniformly distributed. However, it also has the disadvantage of a costly raw material billet. In this study, a semi-solid slurry was prepared from the rheo process by cooling and electromagnetic stirring, and then a billet for the thixo process was manufactured through an upsetting process with semi-solid slurry. Then, the billet was reheated (thixo process) to make a semi-solid state, and then a final sample was manufactured through a forming process. In both A356 and A6061 materials, the equivalent diameter of the primary α-Al grains became smaller and the roundness became close to one throughout rheo, upsetting, thixo, and forming processes. Due to the refinement and spheroidizing effect of the primary α-Al grains, the tensile strength was improved by each process, and the elongation was slightly decreased. However, after T6 heat treatment, the tensile strength of A356 was decreased, but the elongation was greatly improved. In the case of A6061, on the other hand, the tensile strength was significantly improved, and its elongation decreased after T6 heat treatment. Full article
(This article belongs to the Special Issue Advances in Semi-solid Forming)
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18 pages, 6083 KiB  
Article
Study on the Slurry Diffusion Law of Fluidized Filling Gangue in the Caving Goaf of Thick Coal Seam Fully Mechanized Caving Mining
by Liang Li, Qingxiang Huang, Xiao Zuo, Jie Wu, Baoning Wei, Yanpeng He, Weilong Zhang and Jie Zhang
Energies 2022, 15(21), 8164; https://doi.org/10.3390/en15218164 - 1 Nov 2022
Cited by 12 | Viewed by 2115
Abstract
Because of the problem of gangue discharge and surface subsidence during coal mining, the current research on underground filling mainly focuses on the paste filling, solid filling, and grouting filling of the overburden separation layer after scaffolding. We proposed the technology of fluidization [...] Read more.
Because of the problem of gangue discharge and surface subsidence during coal mining, the current research on underground filling mainly focuses on the paste filling, solid filling, and grouting filling of the overburden separation layer after scaffolding. We proposed the technology of fluidization gangue grouting for filling the collapse area based on our previous research. The prediction method of residual space in the collapse area and the diffusion law of gangue fluidization filling slurry are two essential points for successfully implementing the technology and maximizing the use of goaf for gangue backfilling and reducing overburden settlement. To further explore the remaining space distribution law of the collapsed goaf in thick seam fully mechanized top coal caving mining and the effect of coal gangue fluidization filling, the caving goaf of the 3307 fully mechanized top coal caving face in Sangshuping No. 2 coal mine in the Weibei mining area was detected by the transient electromagnetic method. We studied the distribution law of the measured abnormal area in the caving goaf, which reflects the distribution law of the remaining space from one aspect. The coefficient of the remaining space was calculated to be 19.5%. Then, we applied COMSOL simulation software. The diffusion law of coal gangue fluidized slurry in the caving goaf was simulated and analyzed. It shows that the most obvious diffusion direction of the coal gangue slurry is the trend of the gradual expansion of the “cavity pore” multi-type residual space, indicating that with the increase in the diffusion distance, the diffusion resistance gradually increases, and the slurry morphology gradually presents the “claw” form. According to the space theory and fractal dimension theory, the prediction method of the remaining space in the caving goaf is given, and the design basis of the filling drilling parameters is determined. Finally, the field-filling test was carried out. The results show that the high- and low-level fluidized filling in the caving goaf can safely and efficiently handle the gangue in the mine, and the residual space characteristics and slurry diffusion law in the caving goaf are consistent with the above. The research results provide theoretical support for the fluidization filling technology of coal gangue in thick seam fully mechanized top coal caving areas. Full article
(This article belongs to the Special Issue Advances in Coal and Water Co-mining)
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12 pages, 8370 KiB  
Article
Preparation of a Flexible X-Band Radar-Wave-Absorbing Composite Material by Using Beta-Silicon Carbide and Polyurethane as Substrates and Multiwalled Carbon Nanotubes as Additives
by Shao-Hwa Hu, Jiao-Jiao Yuan, Hang Dai, Yang-Yang Liu, Jing He and Jun-Ling Tu
Symmetry 2022, 14(10), 2144; https://doi.org/10.3390/sym14102144 - 14 Oct 2022
Cited by 10 | Viewed by 2583
Abstract
Silicon carbide (SiC) has good chemical resistance, excellent mechanical properties, thermal conductivity, especially in extreme conditions of application, and has proved to be a very promising electromagnetic absorption material. However, single silicon carbide cannot meet the increasing demand for high performance of absorbing [...] Read more.
Silicon carbide (SiC) has good chemical resistance, excellent mechanical properties, thermal conductivity, especially in extreme conditions of application, and has proved to be a very promising electromagnetic absorption material. However, single silicon carbide cannot meet the increasing demand for high performance of absorbing materials. It has become an important research direction to combine it with other absorbing materials to improve its absorbing performance. In this study, a composite absorber material was prepared by 50 wt.% micron-sized beta-silicon carbide (β-sic) powder, mixed with a 0.2 wt.% multiwalled carbon nanotubes (MWCNTs) and 50 wt.% polyurethane (PU) substrate. The mixture was stirred and deaerated to form a slurry, and sprayed onto synthetic fabric. The results showed that the composite material was flexible, with a thickness of less than 2 mm and favorable adhesion. The results obtained by reflection graph of the radar waves, indicated that the return loss within the X-band range (8–12 GHz) was less than −40 dB, indicating favorable radar wave absorption. Therefore, composite materials could thus be used successfully as radar wave absorbers, and was suitable for stealth materials in “asymmetric warfare”. Full article
(This article belongs to the Section Chemistry: Symmetry/Asymmetry)
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13 pages, 2545 KiB  
Article
Diffusion Mechanism of Slurry during Grouting in a Fractured Aquifer: A Case Study in Chensilou Coal Mine, China
by Minglei Zhai, Dan Ma and Haibo Bai
Mathematics 2022, 10(8), 1345; https://doi.org/10.3390/math10081345 - 18 Apr 2022
Cited by 14 | Viewed by 2584
Abstract
Grouting is one of the main technical means to prevent water inrush hazards in coal seam floor aquifers. It is of great significance to elucidate the diffusion law of slurry in the process of grouting in fractured aquifers for safe mining in coal [...] Read more.
Grouting is one of the main technical means to prevent water inrush hazards in coal seam floor aquifers. It is of great significance to elucidate the diffusion law of slurry in the process of grouting in fractured aquifers for safe mining in coal mines. In this paper, the mechanism of slurry diffusion in horizontal fractures of fractured aquifers was studied based on the Bingham slurry with time-varying characteristics; additionally, a one-dimensional seepage grouting theoretical model considering the temporal and spatial variation of slurry viscosity under constant grouting rate was established. In this model, the grouting pressure required by the predetermined slurry diffusion radius can be obtained by knowing the grouting hole pressure and injection flow. Slurry properties, fracture parameters, grouting parameters, and water pressure were the parameters affecting the slurry diffusion process. Looking at the problem of water disaster prevention of coal seam floor in the Working Face 2509 of the Chensilou Coal Mine, according to the aquifer parameters and model calculation results, a grouting scheme with a slurry diffusion radius of 20 m and grouting pressure of 12 MPa was proposed. Finally, with the comparative analysis of the transient electromagnetic method (TEM) and water inflow before and after grouting, it was verified that the design grouting pressure and the spacing of grouting holes were reasonable and the grouting effect was good. Full article
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44 pages, 7089 KiB  
Review
Experimental Characterization Techniques for Solid-Liquid Slurry Flows in Pipelines: A Review
by Rui C. Silva
Processes 2022, 10(3), 597; https://doi.org/10.3390/pr10030597 - 18 Mar 2022
Cited by 22 | Viewed by 9196
Abstract
In industrial environments, having instrumentation able to attain fast, accurate, and autonomous measurements is pivotal to understanding the dynamics of liquid and particles during transport. Ideally, these instruments, consisting of either probes or sensors, should be robust, fast, and unintrusive, i.e., not cause [...] Read more.
In industrial environments, having instrumentation able to attain fast, accurate, and autonomous measurements is pivotal to understanding the dynamics of liquid and particles during transport. Ideally, these instruments, consisting of either probes or sensors, should be robust, fast, and unintrusive, i.e., not cause interference on the very flows being monitored, and require minimal maintenance. Beyond monitoring, the process knowledge gained through real time inspection allows teams to make informed technical decisions based on particle behavior, i.e., settling of particles causing pipe wear and clustering or blockages that can damage the unit or cause shutdowns, both of which with economical drawbacks. The purpose of this review is to examine experimental measurement techniques used to characterize physical properties and operational parameters of solid-liquid slurry flows, focusing on non-ionizing radiation methods. With this text the intent is not to provide an exhaustive examination of each individual technique but rather an overview on the most pertinent types of instrumentation, which will be presented, in addition to application examples from the literature, while directing the reader for pertinent seminal and review papers for a more in-depth analysis. Full article
(This article belongs to the Section Process Control and Monitoring)
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18 pages, 3949 KiB  
Article
Study on a New Electromagnetic Flow Measurement Technology Based on Differential Correlation Detection
by Liang Ge, Junxian Chen, Guiyun Tian, Wen Zeng, Qi Huang and Ze Hu
Sensors 2020, 20(9), 2489; https://doi.org/10.3390/s20092489 - 28 Apr 2020
Cited by 24 | Viewed by 6127
Abstract
Under the conditions of low flow rate and strong noise, the current electromagnetic flowmeter (EMF) cannot satisfy the requirement for measurement or separate the actual flow signal and interference signal accurately. Correlation detection technology can reduce the bandwidth and suppress noise effectively using [...] Read more.
Under the conditions of low flow rate and strong noise, the current electromagnetic flowmeter (EMF) cannot satisfy the requirement for measurement or separate the actual flow signal and interference signal accurately. Correlation detection technology can reduce the bandwidth and suppress noise effectively using the periodic transmission of signal and noise randomness. As for the problem that the current anti-interference technology cannot suppress noise effectively, the noise and interference of the electromagnetic flowmeter were analyzed in this paper, and a design of the electromagnetic flowmeter based on differential correlation detection was proposed. Then, in order to verify the feasibility of the electromagnetic flow measurement system based on differential correlation, an experimental platform for the comparison between standard flow and measured flow was established and a verification experiment was carried out under special conditions and with flow calibration measurements. Finally, the data obtained in the experiment were analyzed. The research result showed that an electromagnetic flowmeter based on differential correlation detection satisfies the need for measurement completely. The lower limit of the flow rate of the electromagnetic flowmeter based on the differential correlation principle could reach 0.084 m/s. Under strong external interferences, the electromagnetic flowmeter based on differential correlation had a fluctuation range in output value of only 10 mV. This shows that the electromagnetic flowmeter based on the differential correlation principle has unique advantages in measurements taken under the conditions of strong noise, slurry flow, and low flow rate. Full article
(This article belongs to the Section Physical Sensors)
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14 pages, 4304 KiB  
Article
Numerical Simulation of Solidification Behavior and Solute Transport in Slab Continuous Casting with S-EMS
by Dongbin Jiang, Miaoyong Zhu and Lifeng Zhang
Metals 2019, 9(4), 452; https://doi.org/10.3390/met9040452 - 17 Apr 2019
Cited by 25 | Viewed by 4839
Abstract
A 3D numerical model was built to investigate the transport phenomena in slab continuous casting process with secondary electromagnetic stirring (S-EMS). In the model, the columnar grain grew from strand surface and it should be treated as a porous media. While for the [...] Read more.
A 3D numerical model was built to investigate the transport phenomena in slab continuous casting process with secondary electromagnetic stirring (S-EMS). In the model, the columnar grain grew from strand surface and it should be treated as a porous media. While for the equiaxed zone, the nucleated grain moves with fluid flow in the earlier stage and it was regarded as a slurry. The model was validated by measured strand surface temperature and magnetic induction intensity. The results show that the solidification end near the 1/4 width of slab was postponed, due to the liquid flow from a submerged entry nozzle injected to the strand’s narrow face. As the linear stirring in the same direction is applied, liquid moves from side B to side A and then penetrates deep downward with higher temperature. In the later stage, the solidification end near the side A is postponed and the solute element is concentrated. When linear stirring in the opposite direction is used, the solidification end near the side A moves backward, while that near the side B moves forward. Moreover, it is found that the solute segregation in the side B is deteriorated, but that in the side A is reduced. As rotational stirring mode is applied, the evenness of solidification end profile is improved and the centerline segregation is reduced, especially with higher current intensity. Therefore, it is concluded that the linear stirring mode is not appropriated for slab casting, while the rotational stirring mode is more suitable. Full article
(This article belongs to the Special Issue Advanced Simulation Technologies of Metallurgical Processing)
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11 pages, 2863 KiB  
Article
Study on the Preparation Technology of a Ceramic Panel with a Magnetic Interlayer for an Induction Cooker
by Aijin Pan, Haifeng Lan, Yongjun Huang, Peng Chen and Shuangxi Wang
Appl. Sci. 2019, 9(5), 970; https://doi.org/10.3390/app9050970 - 7 Mar 2019
Cited by 2 | Viewed by 2780
Abstract
In order to expand the range of pot materials for induction cookers, a kind of sandwich structural composite ceramic panel that consists of an Al2O3 ceramic substrate, magnetic heating interlayer, and ZrO2 ceramic substrate was developed by combining the [...] Read more.
In order to expand the range of pot materials for induction cookers, a kind of sandwich structural composite ceramic panel that consists of an Al2O3 ceramic substrate, magnetic heating interlayer, and ZrO2 ceramic substrate was developed by combining the tape casting process and the screen printing process. In this research, the slurry composition of the functional phase, glass powder, and organic carrier was optimized for preparing the heating interlayer with excellent electromagnetic properties. The influences of the glass powder content and the magnetic layer structure on the thermal shock resistance of the composite ceramic panel were studied. The finite element model of the composite ceramic panel under thermal load was established through ANSYS software. In the range of 0.1–0.3 mm thickness of a magnetic heating interlayer, the temperature field and the macroscopic stress field of the composite ceramic panel were simulated, and the influence of the magnetic layer structure on the thermal stress distribution of the composite ceramic panel was analyzed. The experimental results showed that the magnetic layer had the best quality when the amount of glass powder added was 9 wt%. The ANSYS simulation revealed that the gradient structure of the magnetic layer could reduce the stress between the alumina layer and the magnetic layer from 308 to 192 MPa, which significantly improved the thermal shock resistance of the composite ceramic panel. Therefore, the gradient structure of the magnetic layer could ensure the stability of the composite ceramic panel after five cycles of electromagnetic heating. Full article
(This article belongs to the Special Issue Ceramic Composites and Films)
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7 pages, 2828 KiB  
Communication
Synthesis of α-Fe2O3 and Fe-Mn Oxide Foams with Highly Tunable Magnetic Properties by the Replication Method from Polyurethane Templates
by Yuping Feng, Jordina Fornell, Huiyan Zhang, Pau Solsona, Maria Dolors Barό, Santiago Suriñach, Eva Pellicer and Jordi Sort
Materials 2018, 11(2), 280; https://doi.org/10.3390/ma11020280 - 11 Feb 2018
Cited by 12 | Viewed by 4431
Abstract
Open cell foams consisting of Fe and Fe-Mn oxides are prepared from metallic Fe and Mn powder precursors by the replication method using porous polyurethane (PU) templates. First, reticulated PU templates are coated by slurry impregnation. The templates are then thermally removed at [...] Read more.
Open cell foams consisting of Fe and Fe-Mn oxides are prepared from metallic Fe and Mn powder precursors by the replication method using porous polyurethane (PU) templates. First, reticulated PU templates are coated by slurry impregnation. The templates are then thermally removed at 260 °C and the debinded powders are sintered at 1000 °C under N2 atmosphere. The morphology, structure, and magnetic properties are studied by scanning electron microscopy, X-ray diffraction and vibrating sample magnetometry, respectively. The obtained Fe and Fe-Mn oxide foams possess both high surface area and homogeneous open-cell structure. Hematite (α-Fe2O3) foams are obtained from the metallic iron slurry independently of the N2 flow. In contrast, the microstructure of the FeMn-based oxide foams can be tailored by adjusting the N2 flow. While the main phases for a N2 flow rate of 180 L/h are α-Fe2O3 and FeMnO3, the predominant phase for high N2 flow rates (e.g., 650 L/h) is Fe2MnO4. Accordingly, a linear magnetization versus field behavior is observed for the hematite foams, while clear hysteresis loops are obtained for the Fe2MnO4 foams. Actually, the saturation magnetization of the foams containing Mn increases from 5 emu/g to 52 emu/g when the N2 flow rate (i.e., the amount of Fe2MnO4) is increased. The obtained foams are appealing for a wide range of applications, such as electromagnetic absorbers, catalysts supports, thermal and acoustic insulation systems or wirelessly magnetically-guided porous objects in fluids. Full article
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11 pages, 3604 KiB  
Article
Melt Processing and Characterization of Al-SiC Nanocomposite, Al, and Mg Foam Materials
by Ahmed M. Nabawy, Khalil Abdelrazek Khalil, Abdulrahman M. Al-Ahmari and El-Sayed M. Sherif
Metals 2016, 6(5), 110; https://doi.org/10.3390/met6050110 - 12 May 2016
Cited by 5 | Viewed by 5243
Abstract
In the present work, metallic foams of Al, Mg and an Al-SiC nanocomposite (MMNC) have been fabricated using a new manufacturing technique by employing melt infiltration assisted with an electromagnetic force. The aim of this investigation was to study and to develop a [...] Read more.
In the present work, metallic foams of Al, Mg and an Al-SiC nanocomposite (MMNC) have been fabricated using a new manufacturing technique by employing melt infiltration assisted with an electromagnetic force. The aim of this investigation was to study and to develop a reliable manufacturing technique consisting of different types of metallic foams. In this technique, an electromagnetic force was used to assist the infiltration of Al-SiC slurry and of pure liquid metal into a leachable pattern of NaCl, thus providing perfect cellular structures with micro-sized porosities. A high frequency induction coil unit equipped with a vacuum chamber and a hydraulic press was used to manufacture the foam materials. Microstructures of the produced foam materials were explored by using Field Emission Scanning Electron Microscopy (FESEM). The mechanical behavior of the manufactured foams was investigated by applying compression testing. The results indicate a high applicability of the new technique in producing metallic foams of pure metals and of a metal matrix nanocomposite . The produced foam materials displayed isotropic cellular structures with excellent compressive behaviors. Microstructure measurements indicate that the average pore size and strut thickness that can be achieved are in the ranges of 100–500 μm and 50–100 μm, respectively. The produced foam of the Al-SiC nanocomposite material provided the highest strength of 50 MPa prior to the densification stage, which equates to 25 times, and 10 times higher than the strength levels that were obtained by Al, and Mg foams, respectively. Full article
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