Search Results (256)

In this work, bio-based thermoelectric composites were developed using acrylated epoxidized soybean oil (AESO) as the polymer matrix and bismuth telluride (Bi₂Te₃) as the thermoelectric filler. The materials were formulated for both UV-curing and thermal-curing processes, with a focus on Digital Light Processing (DLP) 3D printing. Although UV curing proved ineffective at high filler concentrations due to the light opacity of Bi₂Te₃, thermal curing enabled the fabrication of stable, homogeneously dispersed composites. The samples were thoroughly characterized through rheology, FTIR, TGA, XRD, SEM, and density measurements. Thermoelectric performance was assessed under a 70 °C temperature gradient, with Seebeck coefficients reaching up to 51 µV/K. Accelerated chemical degradation studies in basic media confirmed the degradability of the matrix. The results demonstrate the feasibility of combining additive manufacturing with sustainable materials for low-power thermoelectric energy harvesting applications. Full article

Background/Objectives: The introduction of composite attachments has greatly improved orthodontic aligner therapy, through better force delivery, more predictable movements, and enhanced retention. This in vitro study aims to present and investigate an innovative digital protocol for aligner attachment fabrication incorporating the latest 3D technology used in dentistry. Methods: A virtual attachment measuring 2.5 × 2 × 2 mm was designed using computer-aided design (CAD) software (Meshmixer, Autodesk Inc., San Francisco, CA, USA) and exported as an individual STL file. The attachments were fabricated using a digital light processing (DLP) 3D printer (model: Elegoo 4 DLP, Shenzhen, China) and a dental-grade biocompatible resin. A custom 3D-printed placement guide was used to ensure precise positioning of the attachments on the printed maxillary dental models. A flowable resin was applied to secure the attachments in place. Following attachment placement, the models were scanned using a laboratory desktop scanner (Optical 3D Smart Big, Open Technologies, Milano, Italy) and three intraoral scanners: iTero Element (Align Technology, Tempe, AZ, USA), Aoral 2, and Aoral 3 (Shining 3D, Hangzhou, China). Results: Upon comparison, the scans revealed that the iTero Element exhibited the highest precision, particularly in the attachment, with an RMSE of 0.022 mm and 95.04% of measurements falling within a ±100 µm tolerance. The Aoral 2 scanner showed greater variability, with the highest RMSE (0.041 mm) in the incisor area and wider deviation margins. Despite this, all scanners produced results within clinically acceptable limits. Conclusions: In the future, custom attachments made by 3D printing could be a valid alternative to the traditional composite attachments when it comes to improving aligner attachment production. While these preliminary findings support the potential applicability of such workflows, further in vivo research is necessary to confirm clinical usability. Full article

The dimensional accuracy of 3D-printed edentulous jaw models is critical for successful prosthetic treatment outcomes. This study investigated the accuracy of 3D-printed working models of a completely edentulous jaw through comparative analysis of digital images generated by three laboratory scanners. A reference plaster model of a mandibular edentulous arch was digitized and used to produce ten resin models via digital light processing (DLP) technology. Each model was scanned using three different laboratory scanners: AutoScan-DS-EX, AutoScan-DS-EX Pro(H), and Optical 3D Scanner Vinyl. Digital comparison was performed using specialized software, evaluating the root mean square (RMS) deviation and percentage of values within an acceptable deviation range ±0.05 mm. All printed models showed significant deviations from the reference model (p < 0.05), with RMS values ranging from 109.2–139.7 µm and acceptable deviation percentages ranging from 29.34 to 32.31%. The mean precision RMS value was 66.37 µm. The mean intraclass correlation coefficient of 0.544 indicated moderate precision. Optical 3D Scanner Vinyl demonstrated the highest consistency, while AutoScan-DS-EX Pro(H) showed maximum variability. No statistically significant differences were found between scanners (p = 0.075). While the investigated scanners demonstrated reliable performance and sufficient accuracy, the additive manufacturing process introduced clinically significant deviations, highlighting the importance of verification between printed models and their digital originals before proceeding with clinical stages. Clinical practice should prioritize scanning systems with advanced software algorithms over those with superior hardware specifications alone. Full article

Three-dimensional (3D) printing has emerged as a transformative technology in dental splint fabrication, offering significant advancements in customization, production speed, material efficiency, and patient comfort. This comprehensive review synthesizes the current literature on the clinical use, benefits, limitations, and future directions of 3D-printed dental splints across various disciplines, including prosthodontics, orthodontics, oral surgery, and restorative dentistry. Key 3D printing technologies such as stereolithography (SLA), digital light processing (DLP), and material jetting are discussed, along with the properties of contemporary photopolymer resins used in splint fabrication. Evidence indicates that while 3D-printed splints generally meet ISO standards for flexural strength and wear resistance, their mechanical properties are often 15–30% lower than those of heat-cured PMMA in head-to-head tests (flexural strength range 50–100 MPa vs. PMMA 100–130 MPa), and study-to-study variability is high. Some reports even show significantly reduced hardness and fatigue resistance in certain resins, underscoring material-specific heterogeneity. Clinical applications reviewed include occlusal stabilization for bruxism and temporomandibular disorders, surgical wafers for orthognathic procedures, orthodontic retainers, and endodontic guides. While current limitations include material aging, post-processing complexity, and variability in long-term outcomes, ongoing innovations—such as flexible resins, multi-material printing, and AI-driven design—hold promise for broader adoption. The review concludes with evidence-based clinical recommendations and identifies critical research gaps, particularly regarding long-term durability, pediatric applications, and quality control standards. This review supports the growing role of 3D printing as an efficient and versatile tool for delivering high-quality splint therapy in modern dental practice. Full article

The output energy of Laser Active Optical Systems (LAOSs), in which image brightness is amplified within the laser-active medium, is always higher than the input energy. This contrasts with conventional optical systems (OSs). As a result, a LAOS enables the creation of laser beams with tailored energy distribution across the aperture, making them ideal for material processing applications. This concept was first successfully implemented using metal vapor lasers as the gain medium. In these systems, material processing was achieved by using a laser beam that either carried the required energy profile or the image of the object itself. Later, other laser media were utilized for LAOSs, including barium vapor, strontium vapor, excimer XeCl lasers, and solid-state media. Additionally, during the development of these systems, several modifications were introduced. For example, Space-Time Light Modulators (STLMs) and CCD cameras were incorporated, along with the use of multipass amplifiers, disk-shaped or thin-disk (TD) solid-state laser amplifiers, and other advancements. These techniques have significantly expanded the range of power, energy, pulse durations, and operating wavelengths. Currently, TD laser amplifiers and STLMs based on Digital Light Processor (DLP) technology or Digital Micromirror Devices (DMDs) enhance the potential to develop LAOS devices for Subtractive and Additive Technologies (ST, AT), applicable in both macromachining (cutting, welding, drilling) and micro-nano processing. This review presents comparable characteristics and requirements for these various LAOS applications. Full article

As three-dimensional (3D) printing becomes increasingly prevalent in microfluidic system fabrication, the demand for high precision has become critical. Among various 3D printing technologies, light-curing-based methods offer superior resolution and are particularly well suited for fabricating microfluidic channels and associated micron-scale components. Two-photon polymerization (TPP), one such method, can achieve ultra-high resolution at the submicron level. However, its severely limited printable volume and high operational costs significantly constrain its practicality for real-world applications. In contrast, digital light processing (DLP) 3D printing provides a more balanced alternative, offering operational convenience, lower cost, and print dimensions that are more compatible with practical microfluidic needs. Despite these advantages, most commercial DLP systems still struggle to fabricate intricate, high-resolution structures—particularly curve, thin-walled, or hollow ones—due to over-curing and interlayer adhesion issues. In this study, we developed a DLP-based projection micro-stereolithography (PμSL) system with a simple optical reconfiguration and fine-tuned its parameters to overcome limitations in printing precise and intricate structures. For demonstration, we selected an Archimedes microscrew as the target structure, as it serves as a key component in microfluidic micromixers. Based on our previous study, the most effective design was selected and fabricated in accordance with practical microfluidic dimensions. The PμSL system developed in this study, along with optimized parameters, provides a reference for applying DLP 3D printing in high-precision microfabrication and advancing microfluidic component development. Full article

Three-dimensional printing is rapidly growing in applied dentistry. In order to print faster, increase workflow, and minimize the consumption of resin material, it is important to use the right printer and the correct printing orientation. The objective of the present report is to analyze the flexural strength of specimens realized with two different dental light-curing resins (Keyguide and C&B) obtained from two different Digital Light Processing (DLP) 3D printers. Different printing orientations (0°, 45°, and 90°) were evaluated. 3D Builder, MeshMixer, RayWare, and Chitubox software were used to design the resin specimens. A total of 15 Keyguide and 15 C&B specimens in the shape of a rectangular parallelepiped, with dimensions of 2 mm × 2 mm × 25 mm, were obtained with the Sprintray Moonray S 3D printer, and the 15 Keyguide and 15 C&B specimens presented the same characteristics as those printed using the Moon Night printer. Prior to sample printing, a calibration protocol (tolerance test and dimensional accuracy test) was performed using RayWare software. This procedure allowed compensation for resin shrinkage or expansion, thus ensuring dimensional consistency in all printed samples. Each resin specimen, after printing and post-processing (MoonWash 2 and MoonLight 2), was subjected to a mechanical test with a universal testing machine. After breaking the specimen, the flexural strength values were recorded with computer software (Bluehill, Instron Corporation, Canton, MA, USA). According to the results obtained, the printing orientation of the specimens does not affect the flexural strength of the two materials examined. However, at the maximum load, some differences emerged for both materials printed with the Moon Night printer, depending on their build angle. Both light-cured resins tested had a higher maximum load resistance when printed with the newer Moon Night printer. This result could be due to the Moon Night printer’s better construction characteristics compared to those of the Sprintray or to issues related to the dimensional calibration of the specimens. Full article

The development of high-impact denture base formulations that are suitable for digital light processing (DLP) 3D printing is demanding. Indeed, a combination of high flexural strength/modulus and high fracture toughness is required. In this contribution, eight urethane macromonomers (UMs1-8) were synthesized in a one-pot, two-step procedure. Several rigid diols were first reacted with two equivalents of trimethylhexamethylene diisocyanate. The resulting diisocyanates were subsequently end-capped with a free-radically polymerizable monomer bearing a hydroxy group. UMs1-8 were combined with the monofunctional monomer (octahydro-4,7-methano-1H-indenyl)methyl acrylate and a poly(ε-caprolactone)-polydimethylsiloxane-poly(ε-caprolactone) (PCL-PDMS-PCL) triblock copolymer (BCP1) as a toughening agent. The double-bond conversion, glass transition temperature (T_g), and mechanical properties (flexural strength/modulus, fracture toughness) of corresponding light-cured materials were measured (cured in a mold using a light-curing unit). The results showed that the incorporation of BCP1 was highly efficient at significantly increasing the fracture toughness, as long as the obtained networks exhibited a low crosslink density. The structure of the urethane macromonomer (nature of the rigid group in the spacer; nature and number of polymerizable groups) was demonstrated to be crucial to reach the desired properties (balance between flexural strength/modulus and fracture toughness). Amongst the evaluated macromonomers, UM1 and UM2 were particularly promising. By correctly adjusting the BCP1 content, light-cured formulations based on those two urethane dimethacrylates were able to fulfill ISO20795-1:2013 standard requirements regarding high-impact materials. These formulations are therefore suitable for the development of 3D printable high-impact denture bases. Full article

Background/Objectives: This study investigates the chemical structure and molecular interactions in 3D-printed dental resins reinforced with varying concentrations of Yttria-Stabilized Zirconia (YSZ) nanoparticles, using Fourier-Transform Infrared Spectroscopy (FTIR) to assess the compatibility and bonding behavior at the molecular level. Methods: Three groups of 3D-printed methacrylate-based resin discs were fabricated: a control (0% YSZ), and experimental groups reinforced with 1% and 3% YSZ nanoparticles. Samples were produced using Digital Light Processing (DLP) technology and post-processed under standardized conditions. FTIR spectra were collected via ATR mode over a wavenumber range of 4000–600 cm⁻¹. Spectral differences at key wavenumbers (1721.16, 1237.11, and 929.62 cm⁻¹) were statistically analyzed using one-way ANOVA and Tukey’s post hoc test. Results: FTIR spectra showed no significant shifts in the ester carbonyl band at 1721.16 cm⁻¹, suggesting the preservation of the core resin matrix. However, a statistically significant increase in absorbance at 1237.11 cm⁻¹ was observed in the 1% YSZ group (p = 0.034), indicating dipolar interaction. A distinct new peak at 929.62 cm⁻¹, corresponding to Zr–O vibrations, emerged in the 3% YSZ group (p = 0.002), confirming successful nanoparticle integration. Conclusions: YSZ nanoparticles enhance specific molecular interactions within methacrylate-based dental resins without compromising structural integrity. These findings support the potential application of YSZ-reinforced 3D-printed resins in durable, biocompatible permanent dental restorations. Full article

The present study reports on the manufacturing of biphasic calcium phosphate (BCP) honeycomb scaffolds with tailored microporous walls using phase separation-assisted digital light processing (PS-DLP). To create micropores in BCP walls, camphene was used as the pore-forming agent for preparing BCP suspensions, since it could be completely dissolved in photopolymerizable monomers composed of triethylene glycol dimethacrylate (TEGDMA) and polyethylene glycol diacrylate (PEGDA) and then undergo phase separation when placed at 5 °C. Therefore, solid camphene crystals could be formed in phase-separated BCP layers and then readily removed via sublimation after the photopolymerization of monomer networks embedding BCP particles by DLP. This approach allowed for tight control over the microporosity of BCP walls by adjusting the camphene content. As the camphene content increased from 40 to 60 vol%, the microporosity increased from ~38 to ~59 vol%. Consequently, the overall porosity of dual-scale porosity scaffolds increased from ~51 to ~67 vol%, while their compressive strength decreased from ~70.4 to ~13.7 MPa. The mass transport ability increased remarkably with an increase in microporosity. Full article

The growing demand for sustainable materials with tunable thermal and structural properties has driven the development of composites reinforced with natural fibers in additive manufacturing (AM) technologies. This study investigates the thermal and chemical behavior of polymer composites produced via Digital Light Processing (DLP), an AM technique based on vat photopolymerization that stands out for its high resolution, dimensional control, and superior speed compared to methods such as FDM and SLA. Samples were manufactured with a UV-curable acrylate resin reinforced with jute fibers (Corchorus capsularis) in mass fractions of 0%, 2%, 2.5%, and 3% in solid geometries (CS-). TGA indicated a 4% reduction in the initial degradation temperature with increasing fiber content, from 326.3 °C (CS-0) to 313.2 °C (CS-3.0). TMA revealed a reduction of up to 19% in the coefficients of thermal expansion, indicating greater dimensional stability. The DMA indicated a 16.9% decrease in the storage modulus with 3% fibers, evidencing changes in the viscoelastic response. FTIR detected additional bands at 3340 cm⁻¹ and 1030 cm⁻¹, related to O–H and polysaccharides, confirming a fiber–matrix chemical interaction. These results demonstrate the potential of jute as a sustainable reinforcement in photopolymerizable resins, paving the way for ecological and functional applications in 3D-printed composites. Full article

This study evaluated the effects of print orientation and thermal aging on the flexural strength (FS) and flexural modulus (FM) of novel permanent three-dimensional (3D)-printed polymethyl methacrylate (PMMA) resins reinforced with nano-zirconia and nano-silica. Bar-shaped specimens (25 × 2 × 2 mm) were fabricated using a digital light processing (DLP) 3D printer (Asiga Max UV, Asiga Inc., Australia) in two orientations (0° and 90°). Specimens underwent three-point bending tests at 24 h and after artificial thermal aging (10,000 and 30,000 cycles) to simulate one and three years of intraoral conditions. Scanning electron microscopy (SEM) was used to analyze fracture patterns. Print orientation did not significantly affect FS or FM (p > 0.05). However, artificial aging significantly reduced FS and FM after 10,000 cycles (p < 0.001), with further deterioration after 30,000 cycles. The micro hybrid resin composite exhibited higher FS than the 3D-printed materials throughout aging. SEM analysis revealed distinct fracture patterns, with 3D-printed resins displaying radial fractures and the micro hybrid composite exhibiting horizontal fractures. These findings indicate that aging plays a more critical role in the long-term mechanical performance of 3D-printed restorative resins than print orientation. This study provides original data on the effects of print orientation and prolonged thermal aging on the mechanical behavior of permanent three-dimensional (3D)-printed dental resins. Furthermore, the comparative evaluation of aging protocols simulating one and three years of intraoral service represents a novel contribution to the existing literature. Further studies are required to optimize the mechanical durability of 3D-printed dental restorations. Full article

The present study evaluates the viability of fabricating unmanned aerial vehicle (UAV) propellers using fused filament fabrication (FFF), with an emphasis on low-cost, desktop-scale production. The study’s backdrop is the recent adoption of UAVs and advancements in additive manufacturing. While the scope targets accessibility for individual and small-scale users, the results have broader implications for scalable UAV propulsion systems. The research was conducted within an experimental UAV development framework aimed at optimizing propeller performance through strategic material selection, geometrical design optimization, and additive manufacturing processes. Six propeller variants were manufactured using widely available thermoplastic polymers, including polyethylene terephthalate glycol-modified (PETG) and thermoplastic polyurethane (TPU), as well as photopolymer-based propellers fabricated using vat photopolymerization, also known as digital light processing (DLP). Mechanical and aerodynamic characterizations were performed to assess the structural integrity, flexibility, and performance of each material under dynamic conditions. Two blade configurations, a toroidal propeller with anticipated aerodynamic advantages and a conventional tri-blade propeller (Gemfan 51466-3)—were comparatively analyzed. The primary contribution of this work is the systematic evaluation of performance metrics such as thrust generation, acoustic signature, mechanical strength, and thermal stress imposed on the electrical motor, thereby establishing a benchmark for polymer-based propeller fabrication via additive manufacturing. The findings underscore the potential of polymeric materials and layer-based manufacturing techniques in advancing the design and production of UAV propulsion components. Full article

This study evaluates the manufacturing accuracy of Merlon fracture models produced using two vat-photopolymerization-based three-dimensional (3D) printers: digital light processing (DLP) and liquid-crystal display (LCD). The Merlon fracture model is used to assess dimensional precision and machining accuracy. The root mean square (RMS) values, wall and bottom thicknesses, and field-emission scanning electron microscopy images are analyzed. The DLP-based printers exhibit lower RMS values and superior accuracy compared with LCD-based printing and subtractive milling. Polymer-based slurries for permanent dental applications exhibit better dimensional stability than those for temporary restorations. This study also highlights the significant impact of postprocessing and cleaning procedures on the final model accuracy. These findings suggest that optimizing the postprocessing parameters is crucial for enhancing the precision of 3D-printed dental restorations. The Merlon fracture model is a viable method for evaluating additive manufacturing accuracy, contributing to the improved clinical application of vat photopolymerization in dental prosthetics. Full article

Digital light processing (DLP) is widely recognized as one of the most promising additive manufacturing technologies for ceramic fabrication. Nevertheless, during the additive manufacturing of zirconia ceramics, debinding and sintering often lead to structural defects, which severely deteriorate the material properties and hinder their broader application. In this study, we added an oligomer into the photosensitive resin and systematically investigated the effects of oligomer content on the viscosity and curing properties of ceramic suspensions. The results demonstrated that the introduction of oligomers is conducive to enhancing the crosslinking density and reducing defects. Finally, a 45 vol% solid content zirconia ceramic slurry was prepared by adding 20 wt% oligomers to the resin system. After printing, debinding, and sintering, the final zirconia ceramics exhibited a uniform microstructure without delamination or cracks, its bending strength reached 682.4 MPa. This study demonstrates that zirconia ceramics fabricated by photopolymerization with oligomer photosensitive resin exhibit excellent mechanical properties, significantly expanding the potential applications for high-performance zirconia ceramic components with additive manufacturing. Full article