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  • Article
  • Open Access
1 Citations
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16 Pages
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Photoreactions of Sc3N@C80 with Disilirane, Silirane, and Digermirane: A Photochemical Method to Separate Ih and D5h Isomers

  • Masahiro Kako,
  • Kyosuke Miyabe,
  • Shinpei Fukazawa,
  • Shinji Kanzawa,
  • Masanori Yasui,
  • Michio Yamada,
  • Yutaka Maeda,
  • Zdeněk Slanina,
  • Filip Uhlík and
  • Takeshi Akasaka
  • + 5 authors
Photochem2022, 2(1), 122-137;https://doi.org/10.3390/photochem2010010

7 February 2022

Under photoirradiation, Sc3N@Ih-C80 reacted readily with disilirane 1, silirane 4, and digermirane 7 to afford the corresponding 1:1 adducts, whereas Sc3N@D5h-C80 was recovered without producing those adducts. Based on these results, we described a n...

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  • Feature Paper
  • Review
  • Open Access
13 Citations
6,967 Views
17 Pages
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Functionalization of Endohedral Metallofullerenes with Reactive Silicon and Germanium Compounds

  • Masahiro Kako,
  • Shigeru Nagase and
  • Takeshi Akasaka
Molecules2017, 22(7), 1179;https://doi.org/10.3390/molecules22071179

14 July 2017

Exohedral derivatization of endohedral metallofullerenes (EMFs) has been exploited as a useful method for characterizing the structural and chemical properties of EMFs, and for functionalizing them for potential applications. The introduction of hete...

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