Search Results (31)

Small decentralized water supply systems are often sensitive to local pollution and require a clear understanding of recharge conditions and the hydrodynamics within the water resource catchment. This study develops a conceptual hydrogeological model for the Šmarna Gora area based on geological mapping, long-term monitoring of chemical parameters, and stable isotope analyses (δ¹⁸O, δ²H) of precipitation and groundwater. The study was initiated in response to rising pollutant concentrations in the drinking water. Estimates of transit time (TT) and mean residence time (MRT) were used to characterize recharge, mixing processes, and differences between the SG and ZAVRH wells, the existing and alternative water supply wells. Isotope data show that the aquifer is predominantly recharged during colder periods and that Mediterranean air masses have become an increasingly important source of precipitation, suggesting a shift in precipitation patterns. The results indicate that SG has longer TT (6–8 months) and MRT (up to 1–2 years). In contrast, ZAVRH shows shorter TT and MRT (4–6 months), and lower pollutant concentrations. The hydrogeological regime in the catchment of the ZAVRH well is characterized by a dynamic, fast-flowing system with limited storage and more intensive dilution of contaminants by infiltrating water, whereas the catchment of the SG well functions as a deeper and more buffered aquifer with prolonged groundwater residence and a more direct hydraulic linkage to the contaminant source. The findings distinguish two hydrogeological regimes and provide a basis for planning water supply solutions and protection measures. Full article

Land degradation and declining groundwater availability threaten the sustainability of rural livelihoods across semi-arid regions. This study evaluates the hydrological performance of contour-based trenches as a low-cost and replicable nature-based solution (Nbs) for soil restoration, runoff regulation, and potential distributed managed aquifer recharge (MAR) in Guerrero, Mexico. The structures were installed on 12% slopes and designed using a simplified water balance criterion based on trench storage capacity, runoff coefficient, and representative rainfall events. Each trench was constructed along contour lines with overflow notches and connecting micro-trenches to improve hydraulic continuity, reduce erosion, and enhance infiltration opportunities under degraded field conditions. After one year of field monitoring, the trenches reached an average filling efficiency of approximately 90% per effective rainfall event, with estimated infiltration rates ranging from 0.0069 to 0.011 L·s⁻¹. Soil moisture in the upper soil layer showed a relative increase of approximately 10–18% compared to adjacent untreated areas, while visible reductions in runoff velocity, sediment transport, and surface erosion were observed across the treated plot. Based on trench storage capacity, observed infiltration behavior, and assumed deep percolation fractions, the potential induced recharge was estimated between 216 and 360 m³·yr⁻¹ (43–72 mm·yr⁻¹). These values represent indicative plot-scale estimates rather than direct measurements of aquifer recharge, since no tracer studies or piezometric validation were performed. The results demonstrate that contour-based trenches contribute not only to infiltration enhancement and runoff control, but also to short-term soil restoration and improved water availability in rainfed agricultural systems. Their low-cost implementation, combined with community-based maintenance and adaptation to local environmental conditions, makes them a viable complementary strategy for strengthening decentralized water management, soil resilience, and climate adaptation in semi-arid rural landscapes. However, long-term effectiveness remains dependent on maintenance continuity, institutional support, and local governance conditions. Further multi-year monitoring and direct hydrogeological validation are recommended to improve the design and replicability of decentralized MAR systems. Full article

This study reports the development of a hierarchically porous material based on natural diatomite, thermally treated diatomite (450 °C), and an activated carbon-modified diatomite composite for saline groundwater treatment in West Kazakhstan, addressing the need for efficient desalination solutions under real environmental conditions. The material was synthesized via sequential thermal activation at 450 °C followed by incorporation of activated carbon, with bentonite used as a binder to improve mechanical stability. Comprehensive physicochemical characterization (SEM, XRD, XRF, BET, DTA, and FTIR) confirmed significant structural and compositional transformations, including silica enrichment, removal of impurities, and the development of a well-defined hierarchical porous network. The specific surface area increased from 8 to 10 m²/g for natural diatomite to 35–40 m²/g for thermally treated diatomite and further to 55–60 m²/g for the activated carbon-modified diatomite composite, accompanied by enhanced pore volume and mesoporosity. Performance evaluation using real groundwater samples demonstrated that thermally treated diatomite (450 °C) improved removal efficiency by approximately 19%, while the activated carbon-modified diatomite composite achieved 35–37% removal of chloride, sulfate, and total dissolved solids under multi-ion competitive conditions. The enhanced adsorption performance is attributed to the synergistic effect of increased surface area, improved pore accessibility, and additional active sites introduced by activated carbon. The adsorption process is governed by ion bridging mediated by multivalent cations, pore filling within the hierarchical pore structure, and surface complexation on silanol and metal–hydroxyl functional groups. Leaching tests confirmed the structural stability of the composite and indicated no significant release of environmentally relevant elements under aqueous conditions. Compared with natural diatomite, the thermally treated and activated carbon-modified materials demonstrate improved adsorption efficiency and stable performance under realistic groundwater conditions. These results highlight their applicability for decentralized water treatment systems in regions affected by saline groundwater contamination. Full article

This study presents a short-term, IoT-enabled sensor-based assessment of treated municipal water and decentralized groundwater in Bragança, northeastern Portugal. Two drinking-water supply contexts were compared: treated surface-water-derived municipal water from the public supply system and groundwater from a decentralized supply system serving part of a higher education campus. Five sampling points were monitored during three campaigns between January and March 2026. At each point, pH, electrical conductivity, temperature, oxidation–reduction potential, and total dissolved solids were recorded at 10 s intervals over approximately 10 min monitoring windows using a multiparameter probe integrated into an IoT-enabled data acquisition workflow. Microbiological analyses were performed on groundwater samples as complementary information. Treated municipal water showed lower mineralization, narrower parameter ranges, and higher oxidation–reduction potential, reflecting source-water characteristics, treatment, and operational control. Groundwater showed higher mineralization, lower oxidation–reduction potential, and greater variability among sampling points and campaigns, consistent with stronger local hydrogeochemical and operational influences. The repeated short-interval readings provided more detailed physicochemical profiles than isolated spot measurements, although the short monitoring windows do not represent continuous long-term high-frequency monitoring. Overall, the results support standardized IoT-enabled sensor-based monitoring as a complementary tool for short-term water-quality assessment and indicate the need for longer seasonal datasets and laboratory confirmation. Full article

Damage to urban water supply infrastructure can rapidly compromise access to safe water and force households to rely on alternative sources of uncertain quality. This study presents a case-based assessment of water quality and emergency household-level treatment options in Mykolaiv, Ukraine, following conflict-induced disruption of the centralized water supply system. Water samples collected from selected groundwater and distribution-network points were analyzed for physicochemical, organoleptic, and microbiological indicators, including total dissolved solids, hardness, sulfates, chlorides, iron, permanganate oxidizability, total microbial count, and E. coli. The results showed elevated mineralization, increased sulfate and chloride concentrations, high hardness, organic load indicators, and episodic microbiological contamination in several samples. A low-cost four-stage household treatment procedure combining chemical oxidation, thermal treatment, sorption, and short-term preservation was evaluated as a preliminary emergency approach. The procedure improved odor, taste, hardness, iron content, permanganate oxidizability, and microbiological safety; however, it did not fully reduce total dissolved solids, sulfates, or chlorides to drinking-water standards. Therefore, the treated water should be considered non-potable and suitable mainly for limited domestic and hygienic uses unless additional desalination or blending is applied. The study highlights both the potential and the limitations of simple household-level interventions under emergency water supply disruption and emphasizes the need for decentralized treatment support, monitoring, and long-term infrastructure recovery. Full article

This study evaluated the occurrence, spatial distribution, and associated human health risks of trace metals in water intended for human consumption from urban and rural areas of Satu Mare County (northwestern Romania) based on monitoring data collected between 2022 and 2024. A total of 271 samples from 122 localities were analyzed for As, Cd, Cr, Mn, Ni, Pb, and Se using high-resolution continuum source graphite furnace atomic absorption spectrometry (HR-CS GFAAS). Spatial analysis, non-parametric statistics, Spearman correlation, and principal component analysis (PCA) were applied to identify distribution patterns and differences between supply systems. Arsenic was identified as the main contaminant of concern, with concentrations reaching 320.5 µg/L, primarily in rural groundwater sources. Most other metals remained below regulatory limits, and elevated concentrations were spatially localized rather than widespread. Non-carcinogenic risk (HRI > 1) was observed in 5.74% of samples, while arsenic-related carcinogenic risk (ILCR > 10⁻⁶) occurred in a limited number of locations in 2024, with no values exceeding 10⁻⁴. Risk estimates were based on total arsenic concentrations and should be interpreted conservatively due to the lack of speciation. No statistically significant differences between urban and rural areas were observed for most metals, except for manganese. Multivariate analysis revealed distinct geochemical behaviors, with a Pb–Ni–Se–Cd cluster in rural samples, while arsenic and manganese showed more independent patterns consistent with redox-controlled processes. Urban samples showed more coherent patterns and higher variance explained by PCA (78.9%) compared to rural datasets (60.1%). Risk estimates were based on total arsenic concentrations and should be interpreted conservatively. The findings highlight the vulnerability of decentralized groundwater systems and support targeted monitoring strategies in line with Directive (EU) 2020/2184. Full article

Millions of people across rural and peri-urban regions worldwide remain exposed to unsafe concentrations of naturally occurring fluoride in groundwater. In West Bengal, India, community-level water purification plants (CWPPs) have been widely installed to remove excess fluoride, yet their long-term operational performance remains minimally documented. This study assessed the pre-filter and post-filter water quality of 58 such groundwater-based CWPPs across the fluoride-affected districts of Bankura and Purulia in West Bengal, to evaluate in-field fluoride removal performance and potential hydrogeochemical, operational, and management drivers. Evaluation included fluoride concentration and key physicochemical parameters such as pH, temperature, electrical conductivity (EC), oxidation-reduction potential (ORP), total dissolved solids (TDS), and other anions including bromide, chloride, bicarbonate, nitrite, nitrate, phosphate, and sulphate. Fluoride concentration ranged from 1.7 mg/L to 8.2 mg/L and 1.6 mg/L to 3.9 mg/L in the sampled source water of Bankura and Purulia respectively, with both pre- and post-filter water of all the observed treatment units exceeding the WHO guideline of 1.5 mg/L. Potential contributors to underperformance may include inappropriate filter media selection, insufficient backwashing and regeneration, limited operational oversight and/or non-tailored treatment approaches. However, details on the adsorbent media and operational details were not available, and thus findings reflect observed field performance rather than necessarily causal relationships. These operational insights will contribute to the global discussion on improving decentralized groundwater treatment systems in resource-constrained settings. Full article

In Mediterranean climate regions, water scarcity, seasonal droughts and hydrological extremes are exacerbated by climate change. In these areas, small dams are increasingly used as decentralized water infrastructure for water supply, especially in agricultural areas. However, several challenges must overcome when planning and managing small reservoirs. This review combines evidence from case studies to analyze the benefits and challenges of small dams. The findings show that small reservoirs may offer a wide array of ecological, agricultural, hydrological, and socio-economic benefits when strategically planned and properly maintained, providing water and contributing to groundwater recharge, vegetative restoration, and biodiversity conservation, while simultaneously controlling flash floods in a cost-effective and participatory manner. On the other hand, evaporation losses and sedimentation may affect water quality and reduce storage capacity. In addition, small dams may negatively affect river ecosystems. Persistent disturbance of downstream flow and sediment regime contributes to altered river morphology and habitat, with effects on biota, and may reduce river system resilience. These impacts are context-dependent, influenced by dam density, geomorphic setting, and climate. Finally, this study highlighted the importance of governance and maintenance practices. Polycentric and participative systems may promote more adaptable responses to water stress, whereas fragmented institutions exacerbate trade-offs between water supply and ecological integrity. Full article

Algeria’s transition toward sustainable energy requires the exploitation of its abundant solar and wind resources for green hydrogen production. This study assesses the techno-economic feasibility of an off-grid PV/wind hybrid system integrated with a hydrogen subsystem (electrolyzer, fuel cell, and hydrogen storage) to supply both electricity and hydrogen to decentralized sites in Algeria. Using HOMER Pro, five representative Algerian regions were analyzed, accounting for variations in solar irradiation, wind speed, and groundwater availability. A deferrable water-extraction and treatment load was incorporated to model the water requirements of the electrolyzer. In addition, a comprehensive sensitivity analysis was conducted on solar irradiation, wind speed, and the capital costs of PV panels and wind turbines to capture the effects of renewable resource and investment cost fluctuations. The results indicate significant regional variation, with the levelized cost of energy (LCOE) ranging from 0.514 to 0.868 $/kWh, the levelized cost of hydrogen (LCOH) between 8.31 and 12.4 $/kg, and the net present cost (NPC) between 10.28 M$ and 17.7 M$, demonstrating that all cost metrics are highly sensitive to these variations. Full article

Warsaw’s Oligocene Groundwater Intakes (OGIs) represent a unique but overlooked component of the city’s Urban Water System (UWS), originally developed to supplement municipal supply. This study investigates whether the existing OGI network can still contribute to Urban Water Resilience (UWR) under contemporary conditions. A mixed-methods approach was applied, combining archival research, geospatial analysis of 89 public intakes, and on-site assessments of selected facilities in the Praga Północ and Praga Południe districts. The results show that while OGIs form a decentralized and technically functional system with high resilience potential, their spatial coverage is uneven, their public use has sharply declined, and management is fragmented across multiple entities. Despite this marginalization, OGIs retain strategic value as an emergency safeguard and could be revitalized as part of Warsaw’s resilience strategy. Full article

For the first time, the AGRUM model consortium—consisting of the agro-economic model RAUMIS, the water balance model mGROWA, the hydrological nutrient transport models DENUZ, WeKu and MEPhos, and the urban emission model MONERIS—was jointly set up throughout Germany (357,000 km²). This provided a nationwide consistent nutrient model to capture the current status of N and P inputs to surface waters from diffuse sources and urban areas. Diffuse nutrient emissions were quantified in high spatial resolution for the input pathways’ groundwater, drainage runoff, and natural interflow (100 m × 100 m), as well as for water erosion and wash-off (25 m × 25 m). The sum of diffuse nutrient inputs to surface waters is about 385,000 metric tons N/yr and ca. 11,530 metric tons P/yr. Urban emissions were quantified either as point source inputs (wastewater treatment plants, industrial direct dischargers) or at municipality scale for different collection and treatment systems, e.g., rainwater sewers or decentralized treatment plants, and sum up to ca. 95,000 t N/yr and 7500 t P/yr. As modelled, total N and P inputs into surface waters correspond well with observed N and P loads in rivers. The model results represent valuable information for water managers, being responsible for the preparation of management plans for the third management cycle of the EC Water Framework Directive spanning from 2021 to 2027. Full article

Low-volume meat processing facilities often rely on decentralized wastewater treatment due to cost constraints and the lack of access to centralized treatment. Improved characterization of these facilities’ wastewater is crucial for meeting local groundwater discharge permits. This study also directly correlates treatment systems and facility characteristics to the results of the characterization. The total nitrogen (TN), biochemical oxygen demand (BOD), and phosphorus (P) reductions ranged from −15% to 83%, 43% to 95%, and −75% to 62%, respectively. Slaughtering and smoking were found to significantly increase nutrient concentrations. The average TN leaving the slaughterhouses and processing-only facilities was 519 mg/L-N and 154 mg/L-N, respectively. The average BOD produced by the slaughterhouses and processors was 3002 mg/L and 1660 mg/L, respectively. Filtration was found to reduce BOD, chemical oxygen demand (COD), and trace metals. Aeration in a treatment lagoon was found to significantly reduce BOD, COD, and N compounds. The results indicate that even simple decentralized wastewater treatment systems, combined with facility management practices, can substantially reduce permitted wastewater characteristics. The facility with the best BOD removal had an effluent value of 71.3 mg/L, representing a 96% reduction. The facility with the best TN removal had an effluent value of 20 mg/L, representing a 92% reduction prior to discharge. Full article

The conventional point-estimate human health risk assessment (HHRA) primarily uses average concentrations of a limited number of samples due to the high monitoring costs of heavy metals in groundwater. The results can be erroneous when concentrations significantly deviate from the average across the collected samples in an investigation region. The present research developed a hierarchical fuzzy-based HHRA (F-HHRA) framework to handle variations in limited data sets and subjectively established a broader range of risks for various exposure groups. Groundwater samples from 80 to 120 m deep in shallow wells were collected from agricultural farms along Wadi Rumah in the Qassim Region of Saudi Arabia. Laboratory testing found total dissolved solids much higher than the promulgated drinking water quality standards. As the aftertaste issue eliminated the raw water potability, the study considered dermal exposure for HHRA. The collected samples were tested for thirteen potential heavy metals (HMs), including barium (Ba), boron (B), cadmium (Cd), chromium (Cr), copper (Cu), iron (Fe), lead (Pb), lithium (Li), manganese (Mn), silver (Ag), strontium (Sr), thallium (TI), and zinc (Zn). Cu, Fe, Pb, Ag, and TI were lower than the detectable limit of the inductively coupled plasma mass spectrometry device. Concentrations of the remaining HMs in wastewater outfalls that were much less than the groundwater eradicated the impact of anthropogenic activities and affirmed natural contamination. Apart from 10% of the samples for Mn and 90% of the samples for Sr, all the other HMs remained within the desired maximum allowable concentrations. Point-estimate and fuzzy-based approaches yielded ‘low’ dermal non-cancer risk and cancer risk for all groups other than adults, where dermal cancer risk of Cr remained in the ‘acceptable’ (1 × 10⁻⁶ and 1 × 10⁻⁵) risk zone. Although dermal risk does not require controls, scenario analysis established the rationality of F-HHRA for more contaminated samples. The proposed hierarchical F-HHRA framework will facilitate the decision-makers in concerned agencies to plan risk mitigation strategies (household level and decentralized systems) for shallow well consumers in Saudi Arabia and other arid regions. Full article

The sustainable development and utilization of groundwater resources are of paramount importance for the progress of society, the economy, and the environment. This study focuses on the planning area of Jining City and establishes an evaluation index system for groundwater functional zoning by analyzing key factors such as resource supply function, geo-environmental stability function, and ecological environmental protection function. To evaluate the groundwater functions, this study employs the barrel effect AHP. Through the overlay analysis of different groundwater functions, the planning area of Jining City is categorized into distinct zones based on their groundwater functions. These zones include centralized development and utilization areas (5.69%), decentralized development and utilization areas (65.67%), fragile geo-environmental areas (10.44%), ecological protection areas (8.38%), and unsuitable development and utilization areas (9.82%). The comprehensive zoning map of groundwater functions in the planning area of Jining City is generated. Taking into account the challenges posed by human activities, such as groundwater pollution, this study proposes recommendations for the sustainable development of groundwater in the planning area of Jining City. By systematically examining the functional zoning and sustainable management of groundwater, this study provides a scientific foundation for the responsible development and protection of groundwater resources. Full article

The maintenance of people’s lifestyle against global climate change, exhaustion of groundwater, depletion of minerals, and water scarcity has instigated the recycling and reuse of water from unlikely sources. This situation has motivated researchers to develop effective technologies for treating wastewater, enabling its reuse. Water security has been ensured in myriad, highly populated regions through large-scale centralized treatment facilities. The development and implementation of small-scale, renewable-energy-based, decentralized, on-site treatment methodologies ensure water sustainability in rural areas, where centralized treatment facilities are impractical for application. This review article focuses on the recently reported low-cost purification techniques for recycling wastewater generated by single and community-based households in sparsely populated areas. Here we propose treatment technologies for efficient waste management that can be easily integrated in the upcoming years to the lavatories built under the Swachh Bharat Mission (SBM), a momentous cleanliness campaign that has been successfully implemented by the Government of India (GOI). Specifically, we suggest an electrochemical (EC) method to treat the supernatant of the Blackwater (BW) to produce purified non-potable water for reuse in diverse purposes. The EC technique does not require external chemicals for treatment and can be powered by sustainable technologies (like solar panels), thus reducing the treatment cost. Subsequently, vermicomposting, microwave, biogas, and phycoremediation methods are considered to treat the solid sludge to produce value-added products such as enriched organic fertilizer for agriculture and biofuel. The above methods also ensure the satisfactory reduction in Biochemical Oxygen Demand (BOD) (>85%) and Chemical Oxygen Demand (COD) (81–91%) and the complete removal of pathogens and other harmful pollutants. Finally, the novel treatment techniques discussed here are not only limited to rural areas of India but can be implemented in any rural area of the world. Full article