Search Results (5,852)

This study aims to develop CoCrMo/xCu composites through liquid phase sintering. The primary focus is on investigating how the addition of copper influences sintering kinetics, microstructure, and mechanical properties. The copper volume fraction ranged from 10 to 25 wt.% relative to CoCrMo. Sintering was conducted at 1150 °C under an argon atmosphere. Characterization methods included scanning electron microscopy, computed microtomography, and X-ray diffraction analysis. It was observed that molten copper, which forms upon reaching its melting temperature, can fill the interparticle spaces left by CoCrMo particles in the green compacts. During sintering, densification is further enhanced by the dissolution of CoCrMo, resulting in the formation of intermetallic phases enriched in Cr and Mo, as well as a ternary Co-Cr-Cu compound. Both densification and intermetallic formation contribute to increased microhardness as Cu content rises. It is concluded that the CoCrMo/25Cu composite exhibits the best mechanical and corrosion properties because its densification was improved by the Cu liquid. Full article

TiN coatings have been widely employed in cutting tools due to their high hardness and excellent wear resistance. While most research on nitride coatings has focused on binary (e.g., TiN) and ternary (e.g., TiAlN, TiSiN) systems, the quaternary TiMoSiN system remains comparatively underexplored. In response to the growing demand for comprehensive coating performance under increasingly complex working conditions, this work incorporates Mo and Si into the TiN system to synergistically enhance mechanical, tribological, and corrosion-resistant properties. TiMoSiN coatings were deposited onto cemented carbide substrates by arc ion plating using a Ti_0.8Mo_0.1Si_0.1 alloy target. The influence of nitrogen partial pressure (0.2–1.7 Pa) on the microstructure, mechanical properties, tribological behavior, and electrochemical corrosion performance was investigated. The results show that nitrogen partial pressure plays a critical role in regulating the chemical composition, phase structure, and preferred orientation of the coatings. As the nitrogen partial pressure increases, surface macroparticles are reduced, while the Ti and Mo contents decrease and the Si and N contents increase. The phase structure evolves from a dual-phase mixture of TiN and Ti₂N to a single TiN phase, accompanied by a shift in preferred orientation from (111) to (200). The hardness of the coatings ranges from 36.2 to 43.1 GPa, reaching a maximum of 43.1 GPa at 1.0 Pa. The coating deposited at 0.6 Pa exhibits the best overall performance: it achieves the lowest friction coefficient (0.349) and wear rate (1.08 × 10⁻⁷ mm³/(N·m)), together with the highest corrosion resistance, as reflected by the most noble corrosion potential (−152 mV) and the lowest corrosion current density (8.99 × 10⁻⁸ A·cm⁻²). This study demonstrates that nitrogen partial pressure effectively controls the microstructure and multifunctional properties of TiMoSiN coatings, providing practical process guidelines for their application in demanding cutting environments. Full article

Carbon fiber-reinforced polymer (CFRP) composites are widely used in engineering applications due to their high strength-to-weight ratio and corrosion resistance. However, their mechanical performance depends strongly on laminate architecture, processing conditions, and environmental exposure. This study investigates the effects of fiber orientation, thermal post-curing, and corrosive SO₂ atmosphere on the mechanical properties of CFRP laminates. Three-layer carbon/epoxy laminates with 90°, 45°, and [90°/45°/90°] fiber orientations were manufactured by vacuum-assisted lamination. Selected specimens were post-cured at 80 °C for 10 h and exposed to sulfur dioxide according to ISO 3231. Tensile and Charpy impact tests showed that the 90° laminate exhibited the highest tensile strength (484 MPa), whereas the 45° laminate showed the lowest value due to shear-dominated load transfer. Post-curing increased tensile strength by approximately 10–30%, while exposure to the corrosive environment reduced both tensile strength and impact toughness. The observed behavior was associated with differences in load-transfer mechanism, possible increased degree of cure and/or residual stress relaxation after post-curing, and degradation of the epoxy–matrix and fiber–matrix interface after SO₂ exposure. The results demonstrate that suitable selection of laminate architecture and thermal treatment can significantly improve the durability of CFRP structures intended for aggressive environments. Full article

Radio frequency identification (RFID) technology has been widely adopted in a variety of practical applications. Usually, the size of a passive tag antenna largely determines the read performance of tag. However, excessively large tag antennas can hinder their practical application and a tag that is too small has poor performance. In this paper, a compact, flexible and corrosion-resistant folding dipole tag antenna is proposed, which has a geometrical dimension of 24 mm × 13 mm (0.074${\mathsf{\lambda }}_0\times 0.040{\mathsf{\lambda }}_0$). It is designed on only one surface of a flexible polyethylene terephthalate (PET) substrate, which can be folded. The paper proposes a single-sided laser-patterned GAF/PET flexible RFID tag that is mechanically folded to form a backside dipole arm without vias, targeting compact and corrosion-resistant UHF RFID operation. Changing the size of the folding arm can effectively adjust the resonant frequency and impedance of the tag antenna. A stepped radiation arm is used to extend the current path and lower the resonance frequency. The capacitance and inductance effects introduced by loading a T match for reducing the resonant frequency of the tag to the useful UHF RFID band. Finally, it can achieve a power transfer coefficient of 99.9% and exhibit high impedance matching between the tag antenna and the chip. The proposed tag antenna uses graphene-assembled film (GAF) as its conductor material. Thanks to the physicochemical properties of GAF, the proposed tag antenna maintains stable radiation performance even after prolonged exposure to acidic (5 wt%), alkaline (5 wt%), and salt (5 wt%) corrosion, as well as more than 1000 mechanical bending cycles. When the EIRP of the reader is 2.2 W, the maximum read range of the tag in the 800–1000 MHz is 1.38 m. Full article

Dual beam laser welding of UNS S32750 superduplex stainless steel was performed to investigate the effect of beam-power distribution on microstructure and mechanical properties. Plates with a thickness of 3 mm were welded at a constant total power and travel speed using leading and lagging power splits of 50:50, 80:20, and 65:35. The heat affected zone width was metallographically estimated at approximately 100 µm for all conditions, consistent with comparable gross thermal exposure under constant nominal linear energy input (P_total/v). A slight modification to the power distribution altered the solidification texture and austenite morphology. The 50:50 configuration produced a refined ferritic matrix with a continuous network of grain boundaries, Widmanstätten, and intragranular acicular austenite. The 80:20 condition increased ferrite path continuity, while the 65:35 split produced an intermediate morphology. Vickers hardness reached a maximum for the 80:20 split (HAZ: 345 HV; weld metal: 349 HV). Ultimate tensile strength remained statistically constant between 908 MPa and 914 MPa, whereas elongation decreased from 28% at 50:50 to 24% at 80:20 and 23% at 65:35. All welds exhibited ductile fracture with microvoid coalescence, and electrochemical performance was comparable, with critical pitting temperature values between 78 °C and 91 °C. Beam power distribution primarily affects solidification morphology and enables control of the hardness-to-ductility balance, with a 50:50 split providing the most favorable combination of properties. Full article

Carbon fiber-reinforced polymer (CFRP) composites are widely employed in the aerospace industry due to their excellent properties such as high specific strength and corrosion resistance. However, the delamination and tearing of composites are prone to occur in the machining of CFRP, which significantly affect its performance. The existing laser-assisted cutting model generally simplifies the machining process into high-temperature conventional cutting, and only reflects the thermal effect by modifying the material parameters. The core selective ablation characteristics of laser–CFRP interaction are completely ignored, and the unique mechanical behavior of bare fiber under a large cutting angle is not modeled, and the quantitative correlation between cutting force evolution and machining damage is lacking. In this study, an innovative method of partially exposing fibers is proposed to simulate laser-assisted machining. A micromechanical model is developed to analyze the removal mechanisms of different phases during CFRP processing, and a cutting force prediction model from the micro to macro scale is also established. At the micro-scale, a micromechanical model for fiber cutting in orthogonal machining of CFRP is constructed based on the elastic foundation beam theory. The results show that the proposed cutting force prediction model has high reliability, and the relative error between the predicted value and the experimental measured value is only 7.81%~8.99%. All experiments were repeated three times. Statistical analysis showed that the repeatability of the results was excellent. Compared with conventional cutting, laser-assisted cutting fundamentally changed the failure mode of the fiber from matrix-constrained crushing fracture to controllable free-end large-deflection bending fracture. This transformation leads to a smoother and more regular fiber fracture surface, which effectively inhibits fiber breakage, matrix tearing, and fiber–matrix interface debonding. Quantitative analysis confirms that under laser-assisted processing conditions, the matrix tearing length is positively linearly correlated with the cutting depth, cutting speed, and bare fiber length. Full article

The deterioration of steel reinforcement through corrosion triggers cracking and loss of concrete cover, ultimately weakening the structure’s strength and ductility. In practical design and assessment, it is vital to precisely quantify the shear capacity of corroded reinforced concrete beams (CRCBs). In this paper, machine learning (ML) models are developed to predict the shear capacity of CRCBs, including kernel ridge regression (KRR), K-nearest neighbors (KNN), decision trees (DT), random forest (RF), gradient-boosted regression trees (GBRT), and extreme gradient boosting (XGBoost). A total of 408 data entries on the shear strength of CRCBs under different corrosion conditions were collected to establish an extensive database. The reliability of the proposed ML models is examined by contrasting their outputs with the experimental data. The XGBoost model demonstrated superior predictive capability, achieving an R² value of 0.994 and outperforming all other tested models, including RF, GBRT, and DT. The Shapley Additive Explanations (SHAP) algorithm is adopted to reveal the contribution of each input feature to the predicted shear capacity of CRCBs. The interpretive SHAP results show that the ultimate shear capacity of CRCBs is most influenced by beam depth (h), with the shear span-to-depth ratio (λ) and concrete compressive strength ($f_{cl,150}$) being the subsequent key contributors. A comparative assessment between the XGBoost model and traditional analytical models was carried out to estimate the shear strength of CRCBs. Results demonstrate that the XGBoost model delivers enhanced predictive accuracy and improved performance. A parametric investigation examined its robustness under variations in geometry and material properties, while a user-friendly interface was created to support its practical use. Full article

Yttrium doping has been reported to be an effective approach to enhance the mechanical and protective properties of ZrN coatings by magnetron sputtering. Nitrogen (N₂) flow ratio during reactive magnetron sputtering is known to critically influence the stoichiometry, defect structure, and microstructure of nitride coatings. However, its systematic effect on Y-doped ZrN (ZrYN) coatings has remained unexplored. In this work, ZrYN coatings with a fixed Y content were deposited by reactive magnetron sputtering under varying N₂ flow ratios (0–10%). Their microstructure, mechanical properties, corrosion resistance in 3.5 wt% NaCl solution, and oxidation behavior at 650 °C were systematically investigated. Below 5% N₂ flow ratio, the coatings are metallic ZrY, showing very low hardness, poor corrosion resistance, and catastrophic oxidation failure. At N₂ flow ratio ≥ 5%, cubic ZrYN forms, with stoichiometry varying from sub-stoichiometric (5%) to near-stoichiometric (7.5%) to over-stoichiometric (10%). The near-stoichiometric coating at 7.5% exhibits the finest columnar grains and densest microstructure, leading to the highest hardness (32.2 ± 1.4 GPa) and an elastic modulus of (469.6 ± 24.5 GPa), as well as the best corrosion resistance (two orders of magnitude lower than bare 316 stainless steel). Upon oxidation, it forms a thin and dense epitaxial t-ZrO₂ scale stabilized by Y₂O₃, suppressing the destructive tetragonal to monoclinic transformation. Off-stoichiometric coatings at 5% and 10% develop thicker, cracked oxide scales and show inferior properties. Precise control of N₂ flow ratio is therefore essential to achieve a near-stoichiometric ZrYN coating with superior mechanical, anti-corrosion, and anti-oxidation performance. Full article

Optical fiber sensors deployed in harsh industrial fields, e.g., high-temperature wet-oxygen, face severe challenges in signal attenuation and mechanical degradation. While amorphous silicon oxycarbide (a-SiOC) coatings offer a promising solution due to their adjustable thermo-mechanical properties, balancing their structural density with environmental stability remains a critical technical bottleneck. In this study, a-SiOC coatings were deposited on optical fibers using hexamethyldisilane (HMDS) and trace oxygen via radio-frequency capacitively coupled plasma-enhanced chemical vapor deposition (PECVD). A systematic investigation was conducted to determine the impact of deposition temperature (70–420 °C) on the precursor dissociation kinetics, microstructural evolution, and corrosion resistance of the coatings. An elevation in temperature promotes the elimination of organic terminal groups (–CH₃, –H) and enhances surface diffusion, driving the coating from a loose, carbon-rich “polymer-like” structure (dominated by Si–C bonds) to a dense, inorganic “silica-like” skeleton (dominated by Si–O–Si bonds). High-temperature corrosion tests in a wet-oxygen environment (500–900 °C) demonstrate that the failure mechanism is highly dependent on deposition temperature. Coatings deposited at low temperatures suffer catastrophic cracking due to pronounced oxidative shrinkage and the release of volatile species, whereas coatings deposited at 420 °C exhibit microcracking caused by severe carbon phase separation and stress concentration within the rigid inorganic network. In the present system, 350 °C is identified as the optimal deposition temperature, as it achieves the best balance of network densification and structural flexibility, while exhibiting the best mechanical performance. Full article

The objective of this study was to further improve the wear and corrosion resistance of biomedical Ti6Al4V alloy micro-arc oxidation coating, so as to improve its comprehensive service performance. In this study, the effects of pulsed laser power (20–100 W) on the structure, composition, tribological properties and corrosion resistance of the composite coating were systematically studied by using pulsed laser remelting pretreatment technology. The results show that when the power is 100 W, the microwave stripe and fine grain structure formed by pulsed laser remelting can improve the discharge uniformity during the micro-arc oxidation process. The porosity of the composite coating decreases from 21.32% to 10.94%, and the thickness increases from 8.14 μm to 19.49 μm, which is beneficial to improve the compactness and uniformity of the micro-arc oxidation coating. In addition, the pulse laser remelting pretreatment increased the surface hardness of the composite coating to 745.5 HV, and the friction coefficient decreased from 0.76 to 0.51, thereby improving the wear resistance of the composite coating. The electrochemical test results show that the corrosion current density of the composite coating is reduced from 7.28 × 10⁻⁸ A·cm⁻² to 1.91 × 10⁻⁸ A·cm⁻² due to the optimization of the composite coating structure, and the corrosion resistance is significantly enhanced. This study provides an effective pretreatment strategy for the construction of high-performance MAO composite coatings. Full article

The corrosion of carbon steel in marine–industrial atmospheric environments remains a significant challenge due to the combined effect of aggressive ions such as chlorides and sulfates. In this context, this study aims to explore the inhibitory action of expired omeprazole applied to mild steel AISI 1018 evaluated on a solution simulating atmospheric corrosion (0.1 M Na₂SO₄ + 3% wt NaCl) over 72 h. The material was characterized using EDS to determine its composition of AISI 1018 steel, while Raman spectroscopy was employed to identify the functional groups and heteroatoms present on the molecular structure of omeprazole. Electrochemical noise (EN) measurements were used to evaluate the corrosion rate, type of corrosion and mechanism. Also, quantum chemical calculations of density function theory (DFT) were performed to predict the relationship between molecular structure and inhibition efficiency. The results indicate that 50 ppm provides the most stable and effective corrosion inhibition over time, as evidenced by increases in noise resistance and inhibition efficiency. In contrast, 75 ppm exhibits improved surface morphology at the end of the exposure period, which indicates enhanced surface coverage. The DFT results reveal that omeprazole possesses suitable electronic properties for corrosion inhibition, including moderate reactivity, electron-donating ability, and favorable charge distribution that promotes adsorption onto the metal surface. SEM analysis corroborates that surface damage is significantly reduced in the presence of the inhibitor, particularly at 75 ppm. This study provides new insights into the use of expired pharmaceutical compounds as corrosion inhibitors and demonstrates the capability of combining electrochemical noise analysis with DFT to evaluate both inhibition efficiency and film stability. Full article

In this study, 310S austenitic stainless-steel was welded using a laser with varying amounts of Nb to systematically investigate the effect of Nb on solidification cracking susceptibility, mechanical properties, and corrosion resistance of the weld. Under the present experimental conditions, the critical restraint width was higher for the 0.58 wt.% Nb and 1.45 wt.% Nb welds than for the Nb-free and 2.3 wt.% Nb welds, indicating that Nb addition affected the solidification cracking response of the weld. At low-to-moderate Nb contents, Nb can aggravate compositional segregation and increase the presence of low-melting-point liquid films, thereby increasing cracking susceptibility. At higher Nb contents, the reduced cracking susceptibility was accompanied by microstructural refinement and changes in the distribution of Nb-rich constituents during solidification. With increasing Nb content, the number of precipitated phases in the weld increases, mainly distributed at the austenite grain boundaries in granular, elongated, and chain-like forms. The introduction of Nb generally increases the microhardness and tensile strength of the welded joint, attributed to grain refinement strengthening and solid-solution strengthening. The reduction in area first increased and then decreased, suggesting that excessive Nb addition may reduce ductility because of the increased amount of grain-boundary precipitates and local strengthening heterogeneity. With increasing Nb content, the Ir/Ia ratio decreased from 67.6% to 52.2%, suggesting improved intergranular corrosion resistance. This improvement is likely related to the preferential reaction of Nb with carbon, which may suppress the formation of Cr-depleted zones at grain boundaries. Overall, Nb addition improved the corrosion resistance and increased the hardness and tensile strength of the weld; however, its effect on solidification cracking susceptibility was non-monotonic, indicating that careful control of Nb content is required to balance cracking susceptibility, mechanical properties, and corrosion resistance. Full article

The article is devoted to the study of the properties of the obtained heat-insulating refractory materials, based on fireclay scrap of various fractions (2.5 mm, 1.0 mm, 0.5 mm, and 0.1 mm) using a complex of mineral and oxide additives. The fillers used were titanium dioxide powder and silicon production wastes, which included microsilica powder, aluminum oxide, zinc oxide, zirconium oxide, chromium oxide, iron oxide, cement, lime, and baking soda. The choice of these fillers was due to the fact that they initially have corrosion resistance. Liquid glass acted as a binder. The resulting thermal barrier material was tested to determine its physical and mechanical properties, namely, thermal conductivity, porosity, compressive strength, and microstructure. According to the obtained results for the physical and mechanical properties, the secondary refractory material had properties close to GOST. So, according to GOST 12170-2021, the thermal conductivity values of the obtained materials were included in the 0.03–15.0 W/(m·K) range. The porosity values of the obtained samples complied with GOST 2409-2014 and were not more than 30%. The maximum compressive strength was 171.31 kgf/mm². The microstructure of the material of the obtained samples was very porous, and the pores were evenly distributed throughout the volume, which is extremely important for heat-insulating materials. A distinctive feature of the technology was the absence of a high-temperature firing stage: the required physical and mechanical properties of the material were achieved when heated to 180–300 °C with subsequent slow cooling in the furnace, which significantly reduces energy consumption compared to traditional refractory technologies. The use of waste from the production of chamotte scrap and microsilica will help to reduce negative impacts on the environment, save natural resources, and expand the raw material base. Full article

This study utilized a twisted wire rotating arc cladding method to in situ fabricate a Fe-containing multi-principal element alloy (HPEA) coating derived from NiCrCoTiMo stranded wire on 45 steel (equivalent to AISI 1045 steel). The macroscopic morphology, microstructure, mechanical properties, and electrochemical corrosion behavior of the prepared coatings were examined. The coating exhibited no visible cracks or pores and displayed a dual-phase face-centered cubic (FCC) + body-centered cubic (BCC) structure, with an average grain size of 78 μm for the FCC phase and 1 μm for the BCC phase. The microhardness of the coating is approximately 381.3 HV_0.1. Compared to 45 steel, the coating’s coefficient of friction (COF) decreased from 0.6265 to 0.5125, representing an 18.2% reduction. The calculated wear rate of the coating was 1.47 × 10⁻⁵ mm³/N·m, approximately six times lower than that of 45 steel (8.93 × 10⁻⁵ mm³/N·m). Electrochemical testing revealed that the coating’s open-circuit potential (OCP) was −0.405 V vs. the saturated calomel electrode (SCE), with a corrosion potential (E_corr) of −0.556 V vs. SCE and a corrosion current density (I_corr) of 4.458 × 10⁻⁶ A/cm². In comparison, 45 steel exhibited an OCP of −0.582 V vs. SCE, with corrosion parameters of E_corr = −0.840 V vs. SCE and I_corr = 1.302 × 10⁻⁵ A/cm². These results demonstrate the superior corrosion resistance and wear performance of the coating, underscoring its potential for applications in challenging environments that demand enhanced material durability. Full article

Dissimilar 7075-T6 and 6061-T6 aluminum alloy joints were fabricated using pulsed metal inert gas (P-MIG) welding with ER5356 filler wire. The effects of welding current (224 A, 234 A, and 244 A) on macro-morphology, microstructure, mechanical properties, and corrosion behavior were systematically investigated. As welding current increased, the top and bottom reinforcements first increased and then decreased, reaching maximum values at 234 A, while the front weld width exhibited the opposite trend. The weld zone consisted of equiaxed and dendritic grains, with partial remelting of AlFeMnSi intermetallic compounds observed in the heat-affected zones. The microhardness and tensile strength of the joints followed a similar trend of first decreasing and then increasing with welding current, achieving a maximum tensile strength of 203.9 MPa at 244 A, corresponding to 89.5% of the 6061-T6 base metal strength. Corrosion resistance varied across regions depending on the evaluation method. In intergranular corrosion tests, the 7075-HAZ showed the highest susceptibility due to grain boundary segregation of Mg and Zn. In electrochemical tests, the WZ exhibited the poorest corrosion resistance. For the 7075-HAZ, optimal corrosion resistance was achieved at 234 A, attributed to a stable passive film and uniform precipitate distribution. These findings provide valuable guidance for optimizing P-MIG welding parameters for dissimilar 7075/6061 aluminum alloy joints. Full article