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24 pages, 2863 KiB  
Article
An Integrated Bond Graph Methodology for Building Performance Simulation
by Abdelatif Merabtine
Energies 2025, 18(15), 4168; https://doi.org/10.3390/en18154168 (registering DOI) - 6 Aug 2025
Abstract
Building performance simulation is crucial for the design and optimization of sustainable buildings. However, the increasing complexity of building systems necessitates advanced modeling techniques capable of handling multi-domain interactions. This paper presents a novel application of the bond graph (BG) methodology to simulate [...] Read more.
Building performance simulation is crucial for the design and optimization of sustainable buildings. However, the increasing complexity of building systems necessitates advanced modeling techniques capable of handling multi-domain interactions. This paper presents a novel application of the bond graph (BG) methodology to simulate and analyze the thermal behavior of an integrated trigeneration system within an experimental test cell. Unlike conventional simulation approaches, the BG framework enables unified modeling of thermal and hydraulic subsystems, offering a physically consistent and energy-based representation of system dynamics. The study investigates the system’s performance under both dynamic and steady-state conditions across two distinct climatic periods. Validation against experimental data reveals strong agreement between measured and simulated temperatures in heating and cooling scenarios, with minimal deviations. This confirms the method’s reliability and its capacity to capture transient thermal behaviors. The results also demonstrate the BG model’s effectiveness in supporting predictive control strategies, optimizing energy efficiency, and maintaining thermal comfort. By integrating hydraulic circuits and thermal exchange processes within a single modeling framework, this work highlights the potential of bond graphs as a robust and scalable tool for advanced building performance simulation. Full article
(This article belongs to the Section G: Energy and Buildings)
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19 pages, 15989 KiB  
Article
Influence of Radial Pressure Gradient on Secondary Flows: Numerical Study and Design Optimization for High-Speed Annular Sector Cascades
by Moritz Klappenberger, Christian Landfester, Robert Krewinkel and Martin Böhle
Int. J. Turbomach. Propuls. Power 2025, 10(3), 18; https://doi.org/10.3390/ijtpp10030018 - 5 Aug 2025
Abstract
Secondary flow phenomena have a significant influence on the generation of losses and the propagation of coolant on the turbine end walls. The majority of film cooling studies are carried out on linear rather than annular cascades due to the structural simplicity and [...] Read more.
Secondary flow phenomena have a significant influence on the generation of losses and the propagation of coolant on the turbine end walls. The majority of film cooling studies are carried out on linear rather than annular cascades due to the structural simplicity and ease of measurement integration of the former. This approach neglects the effects of the radial pressure gradient that is naturally imposed on the vortex flow in annular cascades. The first part of this paper numerically investigates the effect of the radial pressure gradient on the secondary flow under periodic flow conditions by comparing a linear and an annular case. It is shown that the radial pressure gradient has a significant influence on the propagation of the secondary flow induced vortices in the wake of the nozzle guide vanes (NGV). In the second part of the paper, a novel approach of a five-passage annular sector cascade is presented, which avoids the hub boundary layer separation, as is typical for this type of test rig. To increase the periodicity, a benchmark approach is introduced that includes multiple pointwise and integral flow quantities at different axial positions. Based on the optimized best-case design, general design guidelines are derived that allow a straightforward design process for annular sector cascades. Full article
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15 pages, 2970 KiB  
Article
A Study on the Heat Dissipation Effects During the Meshing Process of Involute Gears with Variable Tooth Thickness
by Huicheng Zhang, Yongping Liu and Junhai Guo
Machines 2025, 13(8), 686; https://doi.org/10.3390/machines13080686 - 5 Aug 2025
Abstract
The involute gear with variable tooth thickness lacks established methods for calculating meshing heat and studying oil-jet lubrication and cooling effects. This study aims to theoretically estimate the meshing heat generated during the engagement process of involute gears with variable tooth thickness. To [...] Read more.
The involute gear with variable tooth thickness lacks established methods for calculating meshing heat and studying oil-jet lubrication and cooling effects. This study aims to theoretically estimate the meshing heat generated during the engagement process of involute gears with variable tooth thickness. To achieve this, a heat calculation model is derived based on the corresponding tooth surface equations. The impact of oil-jet lubrication parameters—jet velocity, pitch cone angle, face width ratio, and axial displacement—on the gear surface temperature and internal gearbox environment is systematically studied. Numerical simulations of the temperature field are validated through experimental measurements. The results indicate that an oil-jet velocity of 15 m/s combined with a pitch cone angle of 4° significantly reduces both gear surface and internal flow field temperatures. Additionally, smaller face width ratios and axial displacements effectively lower the internal temperature of the gearbox. These findings offer a theoretical basis for calculating meshing heat and designing oil-jet lubrication systems for variable-tooth-thickness involute gears. Full article
(This article belongs to the Section Machine Design and Theory)
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20 pages, 3035 KiB  
Article
Study of Taconis-Based Cryogenic Thermoacoustic Engine with Hydrogen and Helium
by Matthew P. Shenton, Jacob W. Leachman and Konstantin I. Matveev
Energies 2025, 18(15), 4114; https://doi.org/10.3390/en18154114 - 2 Aug 2025
Viewed by 249
Abstract
Taconis oscillations represent spontaneous excitation of acoustic modes in tubes with large temperature gradients in cryogenic systems. In this study, Taconis oscillations in hydrogen and helium systems are enhanced with a porous material resulting in a standing-wave thermoacoustic engine. A theoretical model is [...] Read more.
Taconis oscillations represent spontaneous excitation of acoustic modes in tubes with large temperature gradients in cryogenic systems. In this study, Taconis oscillations in hydrogen and helium systems are enhanced with a porous material resulting in a standing-wave thermoacoustic engine. A theoretical model is developed using the thermoacoustic software DeltaEC, version v6.4b2.7, to predict system performance, and an experimental apparatus is constructed for engine characterization. The low-amplitude thermoacoustic model predicts the pressure amplitude, frequency, and temperature gradient required for excitation of the standing-wave system. Experimental measurements, including the onset temperature ratio, acoustic pressure amplitudes, and frequencies, are recorded for different stack materials and geometries. The findings indicate that, independent of stack, hydrogen systems excite at smaller temperature differentials than helium (because of different properties such as lower viscosity for hydrogen), and the stack geometry and material affect the onset temperature ratio. However, pressure amplitude in the excited states varies minimally. Initial measurements are also conducted in a cooling setup with an added regenerator. The configuration with stainless-steel mesh screens produces a small cryogenic refrigeration effect with a decrease in temperature of about 1 K. The reported characterization of a Taconis-based thermoacoustic engine can be useful for the development of novel thermal management systems for cryogenic storage vessels, including refrigeration and pressurization. Full article
(This article belongs to the Section A5: Hydrogen Energy)
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34 pages, 7297 KiB  
Article
Passive Design for Residential Buildings in Arid Desert Climates: Insights from the Solar Decathlon Middle East
by Esra Trepci and Edwin Rodriguez-Ubinas
Buildings 2025, 15(15), 2731; https://doi.org/10.3390/buildings15152731 - 2 Aug 2025
Viewed by 279
Abstract
This study investigates the effectiveness of passive design in low-rise residential buildings located in arid desert climates, using the Dubai Solar Decathlon Middle East (SDME) competition as a case study. This full-scale experiment offers a unique opportunity to evaluate design solutions under controlled, [...] Read more.
This study investigates the effectiveness of passive design in low-rise residential buildings located in arid desert climates, using the Dubai Solar Decathlon Middle East (SDME) competition as a case study. This full-scale experiment offers a unique opportunity to evaluate design solutions under controlled, realistic conditions; prescriptive, modeled performance; and monitored performance assessments. The prescriptive assessment reviews geometry, orientation, envelope thermal properties, and shading. Most houses adopt compact forms, with envelope-to-volume and envelope-to-floor area ratios averaging 1 and 3.7, respectively, and window-to-wall ratios of approximately 17%, favoring north-facing openings to optimize daylight while reducing heat gain. Shading is strategically applied, horizontal on south façades and vertical on east and west. The thermal properties significantly exceed the local code requirements, with wall performance up to 80% better than that mandated. The modeled assessment uses Building Energy Models (BEMs) to simulate the impact of prescriptive measures on energy performance. Three variations are applied: assigning minimum local code requirements to all the houses to isolate the geometry (baseline); removing shading; and applying actual envelope properties. Geometry alone accounts for up to 60% of the variation in cooling intensity; shading reduces loads by 6.5%, and enhanced envelopes lower demand by 14%. The monitored assessment uses contest-period data. Indoor temperatures remain stable (22–25 °C) despite outdoor fluctuations. Energy use confirms that houses with good designs and airtightness have lower cooling loads. Airtightness varies widely (avg. 14.5 m3/h/m2), with some well-designed houses underperforming due to construction flaws. These findings highlight the critical role of passive design as the first layer for improving the energy performance of the built environment and advancing toward net-zero targets, specifically in arid desert climates. Full article
(This article belongs to the Special Issue Climate-Responsive Architectural and Urban Design)
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25 pages, 3590 KiB  
Article
Effectiveness of Firefighter Training for Indoor Intervention: Analysis of Temperature Profiles and Extinguishing Effectiveness
by Jan Hora
Fire 2025, 8(8), 304; https://doi.org/10.3390/fire8080304 - 1 Aug 2025
Viewed by 194
Abstract
This study assessed the effectiveness of stress-based cognitive-behavioral training compared to standard training in firefighters, emphasizing their ability to distribute extinguishing water and cool environments evenly during enclosure fires. Experiments took place at the Zbiroh training facility with two firefighter teams (Team A [...] Read more.
This study assessed the effectiveness of stress-based cognitive-behavioral training compared to standard training in firefighters, emphasizing their ability to distribute extinguishing water and cool environments evenly during enclosure fires. Experiments took place at the Zbiroh training facility with two firefighter teams (Team A with stress-based training and Team B with standard training) under realistic conditions. Using 58 thermocouples and 4 radiometers, temperature distribution and radiant heat flux were measured to evaluate water distribution efficiency and cooling performance during interventions. Team A consistently achieved temperature reductions of approximately 320 °C in the upper layers and 250–400 °C in the middle layers, maintaining stable conditions, whereas Team B only achieved partial cooling, with upper-layer temperatures remaining at 750–800 °C. Additionally, Team A recorded lower radiant heat flux densities (e.g., 20.74 kW/m2 at 0°) compared to Team B (21.81 kW/m2), indicating more effective water application and adaptability. The findings confirm that stress-based training enhances firefighters’ operational readiness and their ability to distribute water effectively during interventions. This skill is essential for safer and effective management of indoor fires under extreme conditions. This study supports the inclusion of stress-based and scenario-based training in firefighter education to enhance safety and operational performance. Full article
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34 pages, 9378 KiB  
Article
Contribution of Glazed Additions as Passive Elements of the Reduction in Energy Consumption in Detached Houses
by Hristina Krstić, Dušan Ranđelović, Vladan Jovanović, Marko Mančić and Branislava Stoiljković
Buildings 2025, 15(15), 2715; https://doi.org/10.3390/buildings15152715 - 1 Aug 2025
Viewed by 125
Abstract
If implemented properly in architectural design, passive measures can contribute to achieving the desired comfort in a building while reducing its energy consumption. Glazed additions in the form of sunspaces or greenhouses can influence the improvement of building energy efficiency and, at the [...] Read more.
If implemented properly in architectural design, passive measures can contribute to achieving the desired comfort in a building while reducing its energy consumption. Glazed additions in the form of sunspaces or greenhouses can influence the improvement of building energy efficiency and, at the same time, create appealing and pleasant building extensions. Through energy simulations performed using EnergyPlus software, this study aims to analyze the potential contribution of glazed additions to a detached house to reducing energy consumption and creating additional space for living. Research was performed as a case study at the following locations: Niš (Serbia), Berlin (Germany), and Tromsø (Norway). For the purposes of this study, five models (M0–M4) were developed and subjected to analysis across two different scenarios. The results of the conducted research showed that the integration of glazed elements can significantly contribute to energy savings: maximum total annual savings regarding heating and cooling go from 21% for Tromsø, up to 32% for Berlin and 40% for Niš, depending on whether the building to which the glazed element(s) is/are attached is insulated or not and the number and the position of glazed elements. Although glazed additions can create a pleasant microclimate around the house, the overheating observed in the study indicates that proper ventilation and shading are mandatory, especially in more southern locations. Full article
(This article belongs to the Section Architectural Design, Urban Science, and Real Estate)
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27 pages, 10397 KiB  
Article
Methods for Measuring and Computing the Reference Temperature in Newton’s Law of Cooling for External Flows
by James Peck, Tom I-P. Shih, K. Mark Bryden and John M. Crane
Energies 2025, 18(15), 4074; https://doi.org/10.3390/en18154074 - 31 Jul 2025
Viewed by 244
Abstract
Newton’s law of cooling requires a reference temperature (Tref) to define the heat-transfer coefficient (h). For external flows with multiple temperatures in the freestream, obtaining Tref is a challenge. One widely used method, [...] Read more.
Newton’s law of cooling requires a reference temperature (Tref) to define the heat-transfer coefficient (h). For external flows with multiple temperatures in the freestream, obtaining Tref is a challenge. One widely used method, referred to as the adiabatic-wall (AW) method, obtains Tref by requiring the surface of the solid exposed to convective heat transfer to be adiabatic. Another widely used method, referred to as the linear-extrapolation (LE) method, obtains Tref by measuring/computing the heat flux (qs) on the solid surface at two different surface temperatures (Ts) and then linearly extrapolating to qs=0. A third recently developed method, referred to as the state-space (SS) method, obtains Tref by probing the temperature space between the highest and lowest in the flow to account for the effects of Ts or qs on Tref. This study examines the foundation and accuracy of these methods via a test problem involving film cooling of a flat plate where qs switches signs on the plate’s surface. Results obtained show that only the SS method could guarantee a unique and physically meaningful Tref where Ts=Tref on a nonadiabatic surface qs=0. The AW and LE methods both assume Tref to be independent of Ts, which the SS method shows to be incorrect. Though this study also showed the adiabatic-wall temperature, TAW, to be a good approximation of Tref (<10% relative error), huge errors can occur in h about the solid surface where |TsTAW| is near zero because where Ts=TAW, qs0. Full article
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21 pages, 5366 KiB  
Article
Multifaceted Analysis of Pr2Fe16.75Ni0.25 Intermetallic Compound: Crystallographic Insights, Critical Phenomena, and Thermomagnetic Behavior near Room Temperature
by Jihed Horcheni, Hamdi Jaballah, Sirine Gharbi, Essebti Dhahri and Lotfi Bessais
Magnetochemistry 2025, 11(8), 65; https://doi.org/10.3390/magnetochemistry11080065 - 31 Jul 2025
Viewed by 78
Abstract
The alloy Pr2Fe16.75Ni0.25 has been examined to investigate its structural properties, critical behavior, and magnetocaloric effects. Rietveld’s refinement of X-ray diffraction patterns has revealed a rhombohedral structure with an R3¯m space group. Pr2Fe [...] Read more.
The alloy Pr2Fe16.75Ni0.25 has been examined to investigate its structural properties, critical behavior, and magnetocaloric effects. Rietveld’s refinement of X-ray diffraction patterns has revealed a rhombohedral structure with an R3¯m space group. Pr2Fe16.9Ni0.25 also demonstrates a direct magnetocaloric effect near room temperature, accompanied by a moderate magnetic entropy change (ΔSMmax = 5.5 J kg−1 K−1 at μ0ΔH=5 T) and a broad working temperature range. Furthermore, the Relative Cooling Power (RCP) is approximately 89% of the widely recognized gadolinium (Gd) for μ0ΔH=2 T. This compound exhibits a commendable magnetocaloric response, on par with or even surpassing that of numerous other intermetallic alloys. Critical behavior was analyzed using thermo-magnetic measurements, employing methods such as the modified Arrott plot, critical isotherm analysis, and Kouvel-Fisher techniques. The obtained critical exponents (β, γ, and δ) exhibit similarities to those of the 3D-Ising model, characterized explicitly by intermediate range interactions. Full article
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18 pages, 7553 KiB  
Article
Investigating Experimental and Computational Fluid Dynamics of 3D-Printed TPMS and Lattice Porous Structures
by Guru Varun Penubarthi, Kishore Bhaskar Suresh Babu, Senthilkumar Sundararaj and Shung Wen Kang
Micromachines 2025, 16(8), 883; https://doi.org/10.3390/mi16080883 - 29 Jul 2025
Viewed by 207
Abstract
This study investigates the capillary performance and wetting behavior of SLA (Stereolithography) 3D-printed porous structures, focusing on TPMS (triply periodic minimal surfaces)-Gyroid, Octet, Diamond, and Isotruss lattice designs. High-speed imaging was used to analyze droplet interactions, including penetration, spreading, and contact angles, with [...] Read more.
This study investigates the capillary performance and wetting behavior of SLA (Stereolithography) 3D-printed porous structures, focusing on TPMS (triply periodic minimal surfaces)-Gyroid, Octet, Diamond, and Isotruss lattice designs. High-speed imaging was used to analyze droplet interactions, including penetration, spreading, and contact angles, with 16 μL water droplets dropping from 30 mm at 0.77 m/s. Results showed variable contact angles, with Isotruss and Octet having higher angles, while Diamond faced measurement challenges due to surface roughness. Numerical simulations of TPMS-Gyroid of 2 mm3 unit cells validated the experimental results, and Diamond, Octet, and Isotruss structures were simulated. Capillary performance was assessed through deionized (DI) water weight–time (w-t) measurements, identifying that the TPMS-Gyroid structure performed adequately. Structures with 4 mm3 unit cells had low capillary performance, excluding them from permeability testing, whereas smaller 2 mm3 structures demonstrated capillary effects but had printability and cleaning issues. Permeability results indicated that Octet performed best, followed by Isotruss, Diamond, and TPMS-Gyroid. Findings emphasize unit cell size, beam thickness, and droplet positioning as key factors in optimizing fluid dynamics for cooling, filtration, and fluid management. Full article
(This article belongs to the Special Issue Micro Thermal Devices and Their Applications, 2nd Edition)
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21 pages, 8624 KiB  
Article
Comparison of GOES16 Data with the TRACER-ESCAPE Field Campaign Dataset for Convection Characterization: A Selection of Case Studies and Lessons Learnt
by Aida Galfione, Alessandro Battaglia, Mariko Oue, Elsa Cattani and Pavlos Kollias
Remote Sens. 2025, 17(15), 2621; https://doi.org/10.3390/rs17152621 - 28 Jul 2025
Viewed by 256
Abstract
Convective updrafts are one of the main characteristics of convective clouds, responsible for the convective mass flux and the redistribution of energy and condensate in the atmosphere. During the early stages of their lifecycle, convective clouds experience rapid cloud-top ascent manifested by a [...] Read more.
Convective updrafts are one of the main characteristics of convective clouds, responsible for the convective mass flux and the redistribution of energy and condensate in the atmosphere. During the early stages of their lifecycle, convective clouds experience rapid cloud-top ascent manifested by a decrease in the geostationary IR brightness temperature (TBIR). Under the assumption that the convective cloud top behaves like a black body, the ascent rate of the convective cloud top can be estimated as (TBIRt), and it can be used to infer the near cloud-top convective updraft. The temporal resolution of the geostationary IR measurements and non-uniform beam-filling effects can influence the convective updraft estimation. However, the main shortcoming until today was the lack of independent verification of the strength of the convective updraft. Here, Doppler radar observations from the ESCAPE and TRACER field experiments provide independent estimates of the convective updraft velocity at higher spatiotemporal resolution throughout the convective core column and can be used to evaluate the updraft velocity estimates from the IR cooling rate for limited samples. Isolated convective cells were tracked with dedicated radar (RHIs and PPIs) scans throughout their lifecycle. Radial Doppler velocity measurements near the convective cloud top are used to provide estimates of convective updrafts. These data are compared with the geostationary IR and VIS channels (from the GOES satellite) to characterize the convection evolution and lifecycle based on cloud-top cooling rates. Full article
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22 pages, 7102 KiB  
Article
Electrolytic Plasma Hardening of 20GL Steel: Thermal Modeling and Experimental Characterization of Surface Modification
by Bauyrzhan Rakhadilov, Rinat Kurmangaliyev, Yerzhan Shayakhmetov, Rinat Kussainov, Almasbek Maulit and Nurlat Kadyrbolat
Appl. Sci. 2025, 15(15), 8288; https://doi.org/10.3390/app15158288 - 25 Jul 2025
Viewed by 120
Abstract
This study investigates the thermal response and surface modification of low-carbon manganese-alloyed 20GL steel during electrolytic plasma hardening. The objective was to evaluate the feasibility of surface hardening 20GL steel—traditionally considered difficult to quench—by combining high-rate surface heating with rapid cooling in an [...] Read more.
This study investigates the thermal response and surface modification of low-carbon manganese-alloyed 20GL steel during electrolytic plasma hardening. The objective was to evaluate the feasibility of surface hardening 20GL steel—traditionally considered difficult to quench—by combining high-rate surface heating with rapid cooling in an electrolyte medium. To achieve this, a transient two-dimensional heat conduction model was developed to simulate temperature evolution in the steel sample under three voltage regimes. The model accounted for dynamic thermal properties and non-linear boundary conditions, focusing on temperature gradients across the thickness. Experimental temperature measurements were obtained using a K-type thermocouple embedded at a depth of 2 mm, with corrections for sensor inertia based on exponential response behavior. A comparison between simulation and experiment was conducted, focusing on peak temperatures, heating and cooling rates, and the effective thermal penetration depth. Microhardness profiling and metallographic examination confirmed surface strengthening and structural refinement, which intensified with increasing voltage. Importantly, the study identified a critical cooling rate threshold of approximately 50 °C/s required to initiate martensitic transformation in 20GL steel. These findings provide a foundation for future optimization of quenching strategies for low-carbon steels by offering insight into the interplay between thermal fluxes, surface kinetics, and process parameters. Full article
(This article belongs to the Section Materials Science and Engineering)
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13 pages, 1895 KiB  
Article
Class-Dependent Solar Flare Effects on Mars’ Upper Atmosphere: MAVEN NGIMS Observations of X8.2 and M6.0 from September 2017
by Junaid Haleem and Shican Qiu
Universe 2025, 11(8), 245; https://doi.org/10.3390/universe11080245 - 25 Jul 2025
Viewed by 238
Abstract
Transient increments of X-ray radiation and extreme ultraviolet (EUV) during solar flares are strong drivers of thermospheric dynamics on Mars, yet their class-dependent impacts remain poorly measured. This work provides the first direct, side-by-side study of Martian thermospheric reactions to flares X8.2 on [...] Read more.
Transient increments of X-ray radiation and extreme ultraviolet (EUV) during solar flares are strong drivers of thermospheric dynamics on Mars, yet their class-dependent impacts remain poorly measured. This work provides the first direct, side-by-side study of Martian thermospheric reactions to flares X8.2 on 10 September 2017 and M6.0 on 17 September 2017. This study shows nonlinear, class-dependent effects, compositional changes, and recovery processes not recorded in previous investigations. Species-specific responses deviated significantly from irradiance proportionality, even though the soft X-ray flux in the X8.2 flare was 13 times greater. Argon (Ar) concentrations rose 3.28× (compared to 1.13× for M6.0), and radiative cooling led CO2 heating to approach a halt at ΔT = +40 K (X8.2) against +19 K (M6.0) at exobase altitudes (196–259 km). N2 showed the largest class difference, where temperatures rose by +126 K (X8.2) instead of +19 K (M6.0), therefore displaying flare-magnitude dependent thermal sensitivity. The 1.95× increase in O concentrations during X8.2 and the subsequent decrease following M6.0 (−39 K cooling) illustrate the contradiction between photochemical production and radiative loss. The O/CO2 ratio at 225 km dropped 46% during X8.2, revealing compositional gradients boosted by flares. Recovery timeframes varied by class; CO2 quickly re-equilibrated because of effective cooling, whereas inert species (Ar, N2) stabilized within 1–2 orbits after M6.0 but needed >10 orbits of the MAVEN satellite after the X8.2 flare. The observations of the X8.2 flare came from the western limb of the Sun, but the M6.0 flare happened on the far side. The CME shock was the primary driver of Mars’ EUV reaction. These findings provide additional information on atmospheric loss and planetary habitability by indicating that Mars’ thermosphere has a saturation threshold where strong flares induce nonlinear energy partitioning that encourages the departure of lighter species. Full article
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13 pages, 5115 KiB  
Article
Study the Effect of Heat Treatment on the Corrosion Resistance of AISI 347H Stainless Steel
by Yunyan Peng, Bo Zhao, Jianhua Yang, Fan Bai, Hongchang Qian, Bingxiao Shi and Luntao Wang
Materials 2025, 18(15), 3486; https://doi.org/10.3390/ma18153486 - 25 Jul 2025
Viewed by 236
Abstract
AISI 347H stainless steel is widely used in high-temperature environments due to its excellent creep strength and oxidation resistance; however, its corrosion performance remains highly sensitive to thermal oxidation, and the effects of thermal history on its passive film stability are not yet [...] Read more.
AISI 347H stainless steel is widely used in high-temperature environments due to its excellent creep strength and oxidation resistance; however, its corrosion performance remains highly sensitive to thermal oxidation, and the effects of thermal history on its passive film stability are not yet fully understood. This study addresses this knowledge gap by systematically investigating the influence of solution treatment on the corrosion and oxidation resistance of AISI 347H stainless steel. The specimens were subjected to solution heat treatment at 1050 °C, followed by air cooling, and then evaluated through electrochemical testing, high-temperature oxidation experiments at 550 °C, and multiscale surface characterization techniques. The solution treatment refined the austenitic microstructure by dissolving coarse Nb-rich precipitates, as confirmed by SEM and EBSD, and improved passive film integrity. The stabilizing effect of Nb also played a critical role in suppressing sensitization, thereby enhancing resistance to intergranular attack. Electrochemical measurements and EIS analysis revealed a lower corrosion current density and higher charge transfer resistance in the treated samples, indicating enhanced passivation behavior. ToF-SIMS depth profiling and oxide thickness analysis confirmed a slower parabolic oxide growth rate and reduced oxidation rate constant in the solution-treated condition. At 550 °C, oxidation was suppressed by the formation of compact, Cr-rich scales with dual-distributed Nb oxides, effectively limiting diffusion pathways and stabilizing the protective layer. These findings demonstrate that solution treatment is an effective strategy to improve the long-term corrosion and oxidation performance of AISI 347H stainless steel in harsh service environments. Full article
(This article belongs to the Section Metals and Alloys)
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18 pages, 5558 KiB  
Article
Microclimate Variability in a Highly Dynamic Karstic System
by Diego Gil, Mario Sánchez-Gómez and Joaquín Tovar-Pescador
Geosciences 2025, 15(8), 280; https://doi.org/10.3390/geosciences15080280 - 24 Jul 2025
Viewed by 163
Abstract
In this study, we examined the microclimates at eight entrances to a karst system distributed between an elevation of 812 and 906 m in Southern Spain. The karst system, characterised by subvertical open tectonic joints that form narrow shafts, developed on the slope [...] Read more.
In this study, we examined the microclimates at eight entrances to a karst system distributed between an elevation of 812 and 906 m in Southern Spain. The karst system, characterised by subvertical open tectonic joints that form narrow shafts, developed on the slope of a mountainous area with a Mediterranean climate and strong chimney effect, resulting in an intense airflow throughout the year. The airflows modify the entrance temperatures, creating a distinctive pattern in each opening that changes with the seasons. The objective of this work is to characterise the outflows and find simple temperature-based parameters that provide information about the karst interior. The entrances were monitored for five years (2017–2022) with temperature–humidity dataloggers at different depths. Other data collected include discrete wind measurements and outside weather data. The most significant parameters identified were the characteristic temperature (Ty), recorded at the end of the outflow season, and the rate of cooling/warming, which ranges between 0.1 and 0.9 °C/month. These parameters allowed the entrances to be grouped based on the efficiency of heat exchange between the outside air and the cave walls, which depends on the rock-boundary geometry. This research demonstrates that simple temperature studies with data recorded at selected positions will allow us to understand geometric aspects of inaccessible karst systems. Dynamic high-airflow cave systems could become a natural source of evidence for climate change and its effects on the underground world. Full article
(This article belongs to the Section Climate and Environment)
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