Search Results (30)

This study investigates the mechanical performance and blast resistance of high-performance aramid, carbon, and ultra-high molecular weight polyethylene (UHMWPE) fiber fabrics, responding to the need for lightweight and flexible materials in anti-explosion containers for aviation and critical infrastructure. The experimental methodology integrated quasi-static and dynamic tensile tests to characterize the strain-rate effect, followed by near-field air blast tests on both single-material and hybrid multi-ply fabric specimens to analyze their dynamic response, failure modes, and overpressure attenuation. Key findings revealed that carbon fabric exhibited high stiffness but was strain-rate insensitive and susceptible to brittle perforation failure, whereas aramid and UHMWPE fabrics demonstrated strain-rate sensitivity, with UHMWPE showing superior ductility and energy absorption. The hybrid multi-ply configuration (A-C-U sequence) achieved the least amount of failure, effectively utilizing the wave impedance of aramid fabric for initial shock reflection, high stiffness of carbon fabric for stress homogenization, and plasticity of UHMWPE fabric for energy dissipation. Additionally, all fabrics attenuated peak overpressure by over 80%, with enhancement observed for increased thickness. The study concludes that the strategic layering of different fabrics creates a synergistic effect, mitigating the weaknesses of individual fabrics and establishing an effective design paradigm for advanced blast-resistant structures, further enhancing the protective performance. Full article

Reinforced concrete (RC) columns, vital components of urban infrastructure, are highly vulnerable to severe damage from contact explosions, posing significant threats to structural integrity and occupant safety. This study presents a rigorous experimental investigation into the dynamic blast response of RC columns and the efficacy of externally bonded Carbon Fiber Reinforced Polymer (CFRP) wraps as a retrofitting solution. Three series of scaled RC columns were subjected to controlled contact explosions using RDX charges of 50 g, 30 g, and 20 g. For each charge level, three configurations were tested: unretrofitted, single-layer unidirectional CFRP (hoop direction), and dual-layer orthogonal CFRP (hoop and longitudinal). A comprehensive instrumentation system, including high-speed cameras, accelerometers, and pressure transducers, captured blast overpressure, crack evolution, and dynamic acceleration. The results demonstrate that CFRP retrofitting substantially enhances blast resistance and structural performance. Peak accelerations were reduced by up to 68%, with the dual-layer configuration achieving the highest mitigation across all charge levels. In terms of damage control, a single CFRP layer reduced spalling height by 65%, while the dual-layer system achieved up to a 75% reduction. Damage depth was also mitigated by up to 60%, highlighting the superior energy dissipation and containment provided by multi-layered CFRP. These findings underscore CFRP’s significant potential as a robust, practical, and scalable retrofitting solution for enhancing the blast resilience of critical infrastructure, contributing directly to improved urban safety and structural protection in blast-prone environments. Full article

To investigate the explosive characteristics of solid–liquid mixed fuels containing different types of metal powders—including hydrogen-storage metal powders—and volatile liquid fuels, explosion experiments and corresponding numerical simulations were conducted under unconstrained space conditions. The studied system consisted of Et₂O/Al/B/MgH₂ mixed fuels with varying composition ratios. Research has shown that the dispersion effect of solid–liquid mixed fuel containing metal dust under strong shock waves is higher than that of pure liquid fuel. And the explosion overpressure and temperature of solid–liquid mixed fuel are higher than that of pure liquid fuel. Under the same solid–liquid ratio, the explosive overpressure of Et₂O/Al/B/MgH₂ mixed fuel was the highest, which was 110.8% higher than that of pure liquid fuel at the 5 m position. For solid–liquid mixed fuels containing different metal powders, due to the high reaction threshold of boron powder, a high-activity MgH₂ reaction is required to drive the reaction. Therefore, the explosive strength of the mixed fuel systems follows the order Et₂O/Al/B/MgH₂ > Et₂O/Al/MgH₂ > Et₂O/Al > Et₂O/Al/B. Meanwhile, simulation models for pure liquid and solid–liquid fuel explosions were established. The discrepancy between the simulated results and the experimental data was within 10%, demonstrating that the proposed model provides an effective and reliable approach for predicting the explosive power and hazardous range of fuel–air explosions. Full article

To solve the problem of low energy release efficiency of fluoropolymer-based reactive materials, four PTFE (Polytetrafluoroethylene) -based reactive structural materials with different contents were prepared by adding traditional energetic materials (RDX, 1,3,5-Trinitrohexahydro-1,3,5-triazine) and alloy metals (aluminum magnesium, aluminum magnesium zinc). In addition, in order to reduce the high cost of the existing high-speed impact energy release testing device, the formulation optimization of PTFE-based aluminum alloy reactive material was efficiently carried out using a small-scale drop hammer impact test in this paper. The self-designed impact energy release testing device was established for the overpressure measurement of PTFE-based aluminum alloy reactive materials. The impact response processes of PTFE-based aluminum alloy reactive material were recorded with high-speed photography. The energy release characteristics were quantified using overpressure measurements. Based on the chemical reaction properties and microstructural characterization of the PTFE-based reactive materials, the ignition mechanism of aluminum alloy reactive materials was analyzed under drop hammer impact load. The results show that the quantitative characterization of the overpressure changes of reactive materials in a quasi-enclosed space before and after reaction can reflect their energy release efficiency under low-velocity impact by using the drop hammer impact energy release testing device. The order of impact response overpressure values for four PTFE-based reactive materials has been conducted. The aluminum alloy reactive material containing RDX explosive has the highest overpressure value and the highest energy release efficiency in terms of drop hammer impact response. Based on the ignition mechanism and energy release characteristics of these four PTFE-based reactive materials, it was found that the addition of alloy metal powder can reduce impact sensitivity, but when activated, it can effectively enhance the damage effect. Full article

The global shift towards cleaner energy sources is driving the adoption of hydrogen as an environmentally friendly alternative to fossil fuels. Among the forms currently available, Liquid Hydrogen (LH₂) offers high energy density and efficient storage, making it suitable for large-scale transport by rail. However, the flammability of hydrogen poses serious safety concerns, especially when transported through confined spaces such as railway tunnels. In case of an accidental LH₂ release from a freight train, the rapid accumulation and potential ignition of hydrogen could cause catastrophic consequences, especially if freight and passenger trains are present simultaneously in the same tunnel tube. In this study, a three-dimensional computational fluid dynamics model was developed to simulate the dispersion and explosion of LH₂ following an accidental leak from a freight train’s cryo-container in a single-tube double-track railway tunnel, when a passenger train queues behind it on the same track. The overpressure results were analyzed using probit functions to estimate the fatality probabilities for the passenger train’s occupants. The analysis suggests that a significant number of fatalities could be expected among the passengers. However, shorter users’ evacuation times from the passenger train’s wagons and/or longer distances between the two types of trains might reduce the number of potential fatalities. The findings, by providing additional insight into the risks associated with LH₂ transport in railway tunnels, indicate the need for risk mitigation measures and/or traffic management strategies. Full article

To improve the efficiency of aquatic environmental monitoring, an in-situ solid-phase extraction (SPE) system using amphibious (waterproof) drones was developed and validated using recovery testing with samples containing known concentrations of systemic insecticides in the laboratory and using real samples from natural water bodies. The system used a water-resistant linear actuator for continuous aspiration at 1–10 mL min⁻¹ through a pre-washed hydrophilic–lipophilic balanced SPE cartridge. The system functioned properly during field sampling using vacuum-mode filtration to avoid overpressure, overcurrent, and contamination through repeated filtration. The recovery tests using 10 ng L⁻¹ of each target analyte in ultra-pure water samples produced satisfactory recovery results of 89–96% (relative standard deviation < 10%). In the real sampling of water bodies, the developed system was able to detect target analytes of 0.9–180 ng L⁻¹. The results are comparable to those obtained using in-situ manual SPE from boat sampling, irrespective of differences in the two aspiration systems. These findings suggest that the application of the developed drone-assisted in situ SPE system can improve the efficiency of real-sample monitoring of natural water bodies. Full article

Ammonia is emerging as a promising zero-carbon marine fuel due to its high hydrogen density, low storage pressure, and long-term stability, making it well-suited for supporting sustainable maritime energy systems. However, its adoption introduces serious safety challenges, as its toxic, flammable, and corrosive properties pose greater risks than many other alternative fuels, necessitating rigorous risk assessment and safety management. This study presents a comprehensive investigation of potential ammonia leakage scenarios that may arise during the fuel gas supply process within confined compartments of marine vessels, such as the fuel preparation room and engine room. The simulations were conducted using FLACS-CFD V22.2, a validated computational fluid dynamics tool specialized for flammable gas dispersion and explosion risk analysis in complex geometries. The model enables detailed assessment of gas concentration evolution, toxic exposure zones, and overpressure development under various leakage conditions, providing valuable insights for emergency planning, ventilation design, and structural safety reinforcement in ammonia-fueled ship systems. Prolonged ammonia exposure is driven by three key factors: leakage occurring opposite the main ventilation flow, equipment layout obstructing airflow and causing gas accumulation, and delayed sensor response due to recirculating flow patterns. Simulation results revealed that within 1.675 s of ammonia leakage and ignition, critical impact zones capable of causing fatal injuries or severe structural damage were largely contained within a 10 m radius of the explosion source. However, lower overpressure zones extended much further, with slight damage reaching up to 14.51 m and minor injury risks encompassing the entire fuel preparation room, highlighting a wider threat to crew safety beyond the immediate blast zone. Overall, the study highlights the importance of targeted emergency planning and structural reinforcement to mitigate explosion risks in ammonia-fueled environments. Full article

The substitution of aluminum powder with highly reactive ultrafine aluminum-based metal fuels has a significant impact on the energy release of aluminum-containing energetic materials because of their excellent energy density and combustion performances. A series of ultrafine spherical Al-Mg alloy fuels with different contents of magnesium were prepared by close-coupled gas atomization technology. The properties of Al-Mg alloy powders of 13~15 μm were tested by SEM, TG-DSC, and laser ignition experiments. Results show that alloying with magnesium can significantly enhance thermal oxidation and combustion performance, leading to more oxidation weight gains and higher combustion heat release. HMX-based castable explosives with the same content of Al and the novel Al-Mg alloy were made and tested. Results show that the detonation performances of HMX/Al-Mg alloy/HTPB are better than HMX/Al/HTPB. Compared to the HMX/Al/HTPB explosive, the detonation heat of HMX/ Al-Mg alloy/HTPB was increased by 200 kJ/kg, the energy release efficiency was enhanced from 80.55% to 83.19%, the detonation velocity was increased by 114 m/s, and the shock wave overpressure at 5 m was increased by 83%. This research provides a new type of composite metal fuel for improving the combustion performance of Al powder. Full article

To ensure the safe utilization of hydrogen-enriched natural gas (HENG), it is essential to explore effective explosion suppressants to prevent and mitigate potential explosions. This study experimentally investigates the impact of ultrafine water mist containing K₂CO₃ additives on the explosion characteristics of methane/hydrogen/air premixed combustion. The influence of varying K₂CO₃ concentrations on pressure rise rates and flame propagation was analyzed across different hydrogen blending ratios. The results demonstrate that the addition of K₂CO₃ to ultrafine water mist significantly enhances its suppression effects. The peak overpressure decreased by 41.60%, 56.15%, 64.94%, and 72.98%, the flame speed decreased by 30.66%, 70.56%, 46.72%, and 65.65%, and the flame propagation time was prolonged by 25%, 20.83%, 22.92%, and 18.75%, respectively, for different hydrogen blending ratios, showing a similar trend. However, the suppression effectiveness diminishes under high hydrogen blending ratios and low K₂CO₃ concentrations. Further analysis using thermogravimetric infrared spectroscopy and chemical kinetics simulations revealed that the heat release rate and the generation rate of active free radicals significantly decrease after the addition of K₂CO₃ to the ultrafine water mist. The recombination cycle of KOH → K → KOH, formed by reactions (R211: K + OH + M = KOH + M) and (R259: H + KOH = K + H₂O), continuously combines active free radicals (·O, ·OH) into stable product molecules, such as H₂O. However, at low K₂CO₃ concentrations, reaction R211, which suppresses laminar combustion sensitivity and consumes a larger quantity of active free radicals, does not dominate, leading to a reduced suppression effect of K₂CO₃ ultrafine water mist. Several factors during the reaction process also adversely affect the performance of K₂CO₃-containing ultrafine water mist. These factors include the premature onset of laminar flame instability at low K₂CO₃ concentrations, the increased flame-front propagation speed due to the addition of hydrogen to methane, which shortens the residence time of K₂CO₃ in the reaction zone, and the turbulence caused by unvaporized droplets. Full article

This paper investigates the failure behavior and vulnerability of the containment structure (CS) under internal pressure according to different functional and structural failure criteria. Through nonlinear numerical analysis, the deformation of the structure, degree of concrete cracking, and the distribution of stresses and strains in the prestressing tendons and steel liner under different failure criteria are compared. Combined with probabilistic analysis methods, the vulnerability curves, HCLPF capacities, and total failure probabilities of CS determined by different failure criteria are systematically discussed. Results show that there are some differences in the failure behavior and pressure capacity of CS under different failure criteria for both functional and structural failure modes. Under the same failure mode, the variability of the pressure capacities obtained using different criteria is relatively small. Generally, the total failure probabilities of CS subjected to overpressure loads determined by different failure criteria exhibit significant differences. If it is considered that all the investigated failure criteria have a certain ability to predict containment failure, the probabilistic assessment results derived from the functional failure criterion based on the fracture strain of steel liners and the structural failure criterion based on the global strain are deemed to be more reasonable. Full article

This paper presents an investigation into the design of ammonia tanks for long-duration and high-pressure blast loads. The focus is on cylindrical steel tanks that apply as outer pressure-tight containers for double-walled tanks storing refrigerated liquefied gases. Based on limited empirical data, it is known in the tank industry that these tanks can withstand an explosion pressure up to a peak overpressure of approximately 10 kPa and 100 ms positive load duration. However, there is a growing need to design tanks for higher peak overpressures in order to establish a higher safety standard and accommodate unforeseen future requirements. This paper explores the concept of adapting established steel tank designs to handle high-pressure and long-duration overpressure due to blast events. Numerical analysis is conducted on a representative steel tank geometry subjected to a triangular blast load of 30 kPa with a 300 ms positive load duration. Various load application and calculation options are analyzed numerically. Considering the challenging nature of analyzing tank structures under blast load, the paper addresses controversial aspects discussed in the literature and presents a suitable analysis concept for a deflagration blast scenario for cylindrical tanks. The results provide insights into the expected structural behavior of the tank under high-pressure and long-duration overpressure. The main finding is that the calculation method developed in this study demonstrates the feasibility of utilizing steel tanks in scenarios involving long-duration and high-pressure blast loads. Furthermore, the paper provides recommendations to guide future studies in this area. The findings have implications for the design and construction of tanks in critical infrastructure and offer valuable insights for engineers and researchers in this field, improving safety standards and ensuring adaptability to future utilization concepts. Full article

Horizontal oil tanks, like other oil storage containers, carry the risk of explosion when gasoline–air mixtures are ignited. With the widespread application of horizontal oil tanks in the petrochemical industry, attention to safety risks is increasing. However, currently, a limited amount of experimental research on such tanks exists. To explore the characteristics of gasoline–air mixtures combustion within the confined space of horizontal oil tanks, this study constructed a medium-scale simulated horizontal oil tank (L/D = 3, V = 1.0 m³) platform. By investigating the effects of different initial gasoline–air mixture volume fractions and ignition positions on explosion overpressure characteristic parameters, an analysis of the combustion characteristics was conducted. It was found that the most dangerous gasoline–air mixture volume fraction is 1.9% when ignited at the top position and 2.1% at the middle. It was also observed that the ignition position has a significant impact on the variation in explosion overpressure characteristic parameters, with ignition at the middle position resulting having a greater explosive force compared to ignition at the top position. Furthermore, using ignition at the middle position as an example, a study was conducted on the flame morphology characteristics at initial gasoline–air mixture volume fractions of 1.1%, 1.9%, and 2.7%. The conclusions from this research deepen our understanding of the explosion characteristics of different containers, providing theoretical insights for the safe storage and transportation of oil materials in horizontal oil tanks. Full article

With the development of hydrogen energy, containerized hydrogen fuel cell systems are being used in distributed energy-supply systems. Hydrogen pipelines and electronic equipment of fuel cell containers can trigger hydrogen-explosion accidents. In the present study, Computational Fluid Dynamics (CFD) software was used to calculate the affected areas of hydrogen fuel cell container-explosion accidents with and without protective walls. The protective effects were studied for protective walls at various distances and heights. The results show that strategically placing protective walls can effectively block the propagation of shock waves and flames. However, the protective wall has a limited effect on the reduction of overpressure and temperature behind the wall when the protective wall is insufficiently high. Reflected explosion shock waves and flames will cause damage to the area inside the wall when the protective wall is too close to the container. In this study, a protective wall that is 5 m away from the container and 3 m high can effectively protect the area behind the wall and prevent damage to the container due to the reflection of shock waves and flame. This paper presents a suitable protective wall setting scheme for hydrogen fuel cell containers. Full article

Porphyry deposits are the dominant sources of copper and major sources of several base and precious metals. They are commonly formed via the repeated emplacement of hydrous magmas and associated fluid exsolution. As a result, mineralized hydrothermal veins may undergo multiple deposition and reopening processes that are not fully accounted for by existing fluid models. The Tongchang porphyry Cu deposit is a rare example of being related to a single intrusion. The simplicity in intrusive history provides an ideal starting point for studying fluid processes in more complex multi-intrusion porphyry systems. Detailed scanning electron microscope (SEM) cathodoluminescence imaging (CL) revealed rich microtextures in quartz and anhydrite that point to a fluid timeline encompassing early quartz deposition followed by fluid-aided dynamic recrystallization, which was succeeded by an intermediate stage of quartz dissolution and subsequent deposition, and ended with a late stage of continuous quartz deposition, brecciation, and fracturing. Vein reopening is more common than expected. Fifteen out of seventeen examined vein samples contained quartz and/or anhydrite that was older or younger than the vein age defined by vein sequences. Thermobarometry and solubility analysis suggests that the fluid events occurred in a general cooling path (from 650 °C to 250 °C), interspersed with two episodes of fluid pressurization. The first episode occurred at high-T (>500 °C), under lithostatic conditions alongside dynamic recrystallization, whereas the second one took place at a lower temperature (~400 °C), under lithostatic to hydrostatic transition conditions. The main episode of chalcopyrite veining took place subsequent to the second overpressure episode at temperatures of 380–300 °C. The results of this study reaffirm that thermal and hydraulic conditions are the main causative factors for vein reopening and growth in porphyry deposits. Full article

Hydrogen refueling stations are one of the key infrastructure components for the hydrogen-fueled economy. Skid-mounted hydrogen refueling stations (SHRSs) can be more easily commercialized due to their smaller footprints and lower costs compared to stationary hydrogen refueling stations. The present work modeled hydrogen explosions in a skid-mounted hydrogen refueling station to predict the overpressures for hydrogen-air mixtures and investigate the protective effects for different explosion vent layouts and protective wall distances. The results show that the explosive vents with the same vent area have similar overpressure reduction effects. The layout of the explosion vent affects the flame shape. Explosion venting can effectively reduce the inside maximum overpressure by 61.8%. The protective walls can reduce the overpressures, but the protective walls should not be too close to the SHRS because high overpressures are generated inside the walls due to the confined shock waves. The protective wall with a distance of 6 m can effectively protect the surrounding people and avoid the secondary overpressure damage to the container. Full article