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13 pages, 4282 KiB  
Article
Cerium Addition Enhances Impact Energy Stability in S355NL Steel by Tailoring Microstructure and Inclusions
by Jiandong Yang, Bijun Xie and Mingyue Sun
Metals 2025, 15(7), 802; https://doi.org/10.3390/met15070802 - 16 Jul 2025
Viewed by 260
Abstract
S355NL structural steel is extensively employed in bridges, ships, and power station equipment owing to its excellent tensile strength, weldability, and low-temperature toughness. However, pronounced fluctuations in its Charpy impact energy at low temperatures significantly compromise the reliability and service life of critical [...] Read more.
S355NL structural steel is extensively employed in bridges, ships, and power station equipment owing to its excellent tensile strength, weldability, and low-temperature toughness. However, pronounced fluctuations in its Charpy impact energy at low temperatures significantly compromise the reliability and service life of critical components. In this study, vacuum-induction-melted ingots of S355NL steel containing 0–0.086 wt.% rare earth cerium were prepared. The effects of Ce on microstructures, inclusions, and impact toughness were systematically investigated using optical microscopy (OM), scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), and Charpy V-notch testing. The results indicate that appropriate Ce additions (0.0011–0.0049 wt.%) refine the average grain size from 5.27 μm to 4.88 μm, reduce the pearlite interlamellar spacing from 204 nm to 169 nm, and promote the transformation of large-size Al2O3-MnS composite inclusions into fine, spherical, Ce-rich oxysulfides. Charpy V-notch tests at –50 °C reveal that 0.0011 wt.% Ce enhances both longitudinal (269.7 J) and transverse (257.4 J) absorbed energies while minimizing anisotropy (E_t/E_l  =  1.01). Conversely, excessive Ce addition (0.086 wt.%) leads to coarse inclusions and deteriorates impact performance. These findings establish an optimal Ce window (0.0011–0.0049 wt.%) for microstructural and inclusion engineering to enhance the low-temperature impact toughness of S355NL steel. Full article
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19 pages, 1214 KiB  
Article
Physical and Chemical Characteristics of Different Aerosol Fractions in the Southern Baikal Region (Russia) During the Warm Season
by Liudmila P. Golobokova, Tamara V. Khodzher, Vladimir A. Obolkin, Vladimir L. Potemkin and Natalia A. Onischuk
Atmosphere 2025, 16(7), 829; https://doi.org/10.3390/atmos16070829 - 8 Jul 2025
Viewed by 266
Abstract
The Baikal region, including areas with poor environmental conditions, has significant clean background zones. In the summer of 2023, we analyzed the physical and chemical parameters of aerosol particles with different size fractions at Irkutsk and Listvyanka monitoring stations. Reduced wildfires and minimal [...] Read more.
The Baikal region, including areas with poor environmental conditions, has significant clean background zones. In the summer of 2023, we analyzed the physical and chemical parameters of aerosol particles with different size fractions at Irkutsk and Listvyanka monitoring stations. Reduced wildfires and minimal impact from fuel and energy industries allowed us to observe regional and transboundary pollution transport. A large data array indicated that, during the shift of cyclones from Mongolia to the south of the Baikal region, the concentrations of Na+, Ca2+, Mg2+, K+, and Cl ions increased at the Irkutsk station, dominated by NH4+ and SO42−. The growth of the ionic concentrations at the Listvyanka station was observed in aerosol particles during the northwesterly transport. When air masses arrived from the southerly direction, the atmosphere was the cleanest. The analysis of 27 elements in aerosols revealed that Al, Fe, Mn, Cu, and Zn made the greatest contribution to air pollution at the Irkutsk station, while Fe, Al, Cu, Cr, Mn, and Ni made the greatest contribution to air pollution at the Listvyanka station. The dynamics of the investigated elements were mainly due to natural processes in the air under various synoptic situations and weather conditions in the region, although anthropogenic factors also affected the formation of aerosol composition wth certain directions of air mass transport. Full article
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16 pages, 2989 KiB  
Article
Unraveling Zooplankton Trophic Dynamics: Insights from Stable Isotope Analysis in the Eastern Mediterranean (Aegean, Cretan and Ionian Seas)
by Maria Protopapa and Soultana Zervoudaki
Water 2025, 17(8), 1187; https://doi.org/10.3390/w17081187 - 15 Apr 2025
Viewed by 472
Abstract
Understanding the trophic interactions and community structure of zooplankton is essential for assessing energy transfer in marine ecosystems. This study investigates the spatial and seasonal variations in stable carbon (δ13C) and nitrogen (δ15N) isotopes of dominant mesozooplankton groups across [...] Read more.
Understanding the trophic interactions and community structure of zooplankton is essential for assessing energy transfer in marine ecosystems. This study investigates the spatial and seasonal variations in stable carbon (δ13C) and nitrogen (δ15N) isotopes of dominant mesozooplankton groups across three sub-basins of the Eastern Mediterranean (North Aegean, Cretan, and South Ionian Seas) during two seasonal surveys (October 2014 and May 2015). Zooplankton samples were collected using a WP-2 net and analyzed for taxonomic composition, abundance, biomass, and stable isotopic signatures to assess trophic positioning. The results indicate that copepods dominated the zooplankton community at all stations, with Clausocalanus and Oithona juveniles being the most abundant taxa. Salps contributed significantly at certain stations, reflecting regional variations in the planktonic food web structure. Zooplankton δ15N values exhibited pronounced spatial and seasonal differences, with higher enrichment observed in 2014 compared to 2015. The calculated trophic positions highlight the variability in feeding strategies among copepod species, with Calanus helgolandicus occupying the highest trophic position (TP = 3.34) and Lucicutia spp. the lowest (TP = 1.22). Isotopic niche analysis identified two distinct feeding guilds: a group relying on phytoplankton and microzooplankton and another exhibiting broader trophic plasticity, including omnivorous and carnivorous taxa. These findings underscore the complexity of zooplankton trophic interactions in the Eastern Mediterranean and the role of regional hydrographic conditions in shaping the food web structure. This study provides essential baseline data for future research on the impacts of climate change and nutrient variability on Mediterranean marine ecosystems. Full article
(This article belongs to the Special Issue The Study of Plankton in the Mediterranean Sea)
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26 pages, 1158 KiB  
Article
Simultaneously Transmitting and Reflecting Reconfigurable Intelligent Surface-Assisted Non-Orthogonal Multiple Access Wireless Education Network Under Multiple Interference Devices
by Ziyang Zhang
Symmetry 2025, 17(4), 491; https://doi.org/10.3390/sym17040491 - 25 Mar 2025
Viewed by 609
Abstract
Reconfigurable Intelligent Surfaces (RISs) and Non-Orthogonal Multiple Access (NOMA) have emerged as key technologies for next-generation (6G) wireless networks, attracting significant attention from researchers. As an advanced extension of RISs, Simultaneously Transmitting and Reflecting Reconfigurable Intelligent Surfaces (STAR-RISs) offer superior geometric and functional [...] Read more.
Reconfigurable Intelligent Surfaces (RISs) and Non-Orthogonal Multiple Access (NOMA) have emerged as key technologies for next-generation (6G) wireless networks, attracting significant attention from researchers. As an advanced extension of RISs, Simultaneously Transmitting and Reflecting Reconfigurable Intelligent Surfaces (STAR-RISs) offer superior geometric and functional symmetry due to their capability to simultaneously reflect and transmit signals, thereby achieving full 360° spatial coverage. This symmetry not only ensures balanced energy distribution between the Transmission (T) and Reflection (R) regions but also facilitates interference cancellation through phase alignment. Furthermore, in NOMA networks, the symmetric allocation of power coefficients and the tunable transmission and reflection coefficients of STAR-RIS elements aligns with the principle of resource fairness in multi-user systems, which is crucial for maintaining fairness under asymmetric channel conditions. In this study, key factors, such as interference sources and distance effects, are considered in order to conduct a detailed analysis of the performance of STAR-RIS-assisted NOMA wireless education networks under multiple interference devices. Specifically, a comprehensive analysis of the Signal-to-Interference-plus-Noise Ratio (SINR) for both near-end and far-end devices is conducted, considering various scenarios, such as whether or not the direct communication link exists between the base station and the near-end device, and whether or not the near-end device is affected by interference. Based on these analyses, closed-form approximate expressions for the outage probabilities of the near-end and far-end devices, as well as the closed-form approximation for the system’s Spectral Efficiency (SE), are derived. Notably, the Gamma distribution is used to approximate the square of the composite channel amplitude between the base station and the near-end device, effectively reducing computational complexity. Finally, simulation results validate the accuracy of our analytical results. Both numerical and simulation results show that adjusting the base station’s power allocation, and the transmission and reflection coefficients of the STAR-RIS, can effectively mitigate the impact of interference devices on the near-end device and enhance the communication performance of receiving devices. Additionally, increasing the number of STAR-RIS elements can effectively improve the overall performance of the near-end device, far-end device, and the entire system. Full article
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20 pages, 19989 KiB  
Article
The Icing Characteristics of Post Insulators in a Natural Icing Environment
by Zhijin Zhang, Jiahui Tu, Yuanpeng Zhang, Xingliang Jiang and Zhenbing Zhu
Atmosphere 2025, 16(1), 64; https://doi.org/10.3390/atmos16010064 - 9 Jan 2025
Cited by 1 | Viewed by 772
Abstract
Icing significantly reduces the electrical performance of insulators, and grid failures caused by insulator icing are common. Currently, most research on the flashover characteristics of insulators under icing conditions focuses on artificially iced suspension insulators, with limited studies on post insulators under natural [...] Read more.
Icing significantly reduces the electrical performance of insulators, and grid failures caused by insulator icing are common. Currently, most research on the flashover characteristics of insulators under icing conditions focuses on artificially iced suspension insulators, with limited studies on post insulators under natural icing conditions. The shed spacing of post insulators is smaller, making them more prone to bridging by icicles in the same icing environment, which exacerbates insulation problems. Therefore, investigating the icing characteristics of post insulators is crucial. In this study, natural icing growth was observed on seven different types of post insulators at the Xuefeng Mountain Energy Equipment Safety National Observation and Research Station. The icing morphology and characteristics of these insulators were examined. The main conclusions are as follows: (1) the icing type and morphology of post insulators are influenced by meteorological conditions, with more severe icing observed on the windward side. (2) The icing mass and icicle length of the insulator increase nonlinearly with icing time. Specifically, during the glaze icing period from 0 to 8 h, the ice mass on the Type V composite post insulator was 3.89 times greater than that during the 13-to-18 h period. (3) Within the same icing cycle, the icing growth rate on composite post insulators is faster than on porcelain post insulators. (4) Compared to suspension insulators, the sheds of post insulators are more easily bridged by icicles. Notably, when the sheds of post insulators are bridged by icicles, the length of icicles on suspension insulators is only half of the gap size. Full article
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22 pages, 3167 KiB  
Article
The Composite Spectral Energy Distribution of Quasars Is Surprisingly Universal Since Cosmic Noon
by Zhenyi Cai
Universe 2024, 10(11), 431; https://doi.org/10.3390/universe10110431 - 19 Nov 2024
Cited by 1 | Viewed by 1139
Abstract
Leveraging the photometric data of the Sloan Digital Sky Survey and the Galaxy Evolution Explorer (GALEX), we construct mean/median spectral energy distributions (SEDs) for unique bright quasars in redshift bins of 0.2 and up to z3, after taking the GALEX [...] Read more.
Leveraging the photometric data of the Sloan Digital Sky Survey and the Galaxy Evolution Explorer (GALEX), we construct mean/median spectral energy distributions (SEDs) for unique bright quasars in redshift bins of 0.2 and up to z3, after taking the GALEX non-detection into account. Further correcting for the absorption of the intergalactic medium, these mean/median quasar SEDs constitute a surprisingly redshift-independent mean/median composite SED from the rest-frame optical down to ≃500 A˚ for quasars with bolometric luminosity brighter than 1045.5ergs1. Moreover, the mean/median composite quasar SED is plausibly also independent of black hole mass and Eddington ratio, and suggests similar properties of dust and gas in the quasar host galaxies since cosmic noon. Both the mean and median composite SEDs are nicely consistent with previous mean composite quasar spectra at wavelengths beyond ≃1000 A˚, but at shorter wavelengths, are redder, indicating, on average, less ionizing radiation than previously expected. Through comparing the model-predicted to the observed composite quasar SEDs, we favor a simply truncated disk model, rather than a standard thin disk model, for the quasar central engine, though we request more sophisticated disk models. Future deep ultraviolet facilities, such as the China Space Station Telescope and the Ultraviolet Explorer, would prompt revolutions in many aspects, including the quasar central engine, production of the broad emission lines in quasars, and cosmic reionization. Full article
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25 pages, 3366 KiB  
Review
An Overview of the R&D of Flywheel Energy Storage Technologies in China
by Xingjian Dai, Xiaoting Ma, Dongxu Hu, Jibing Duan and Haisheng Chen
Energies 2024, 17(22), 5531; https://doi.org/10.3390/en17225531 - 5 Nov 2024
Cited by 5 | Viewed by 3039
Abstract
The literature written in Chinese mainly and in English with a small amount is reviewed to obtain the overall status of flywheel energy storage technologies in China. The theoretical exploration of flywheel energy storage (FES) started in the 1980s in China. The experimental [...] Read more.
The literature written in Chinese mainly and in English with a small amount is reviewed to obtain the overall status of flywheel energy storage technologies in China. The theoretical exploration of flywheel energy storage (FES) started in the 1980s in China. The experimental FES system and its components, such as the flywheel, motor/generator, bearing, and power electronic devices, were researched around thirty years ago. About twenty organizations devote themselves to the R&D of FES technology, which is developing from theoretical and laboratory research to the stage of engineering demonstration and commercial application. After the research and accumulation in the past 30 years, the initial FES products were developed by some companies around 10 years ago. Today, the overall technical level of China’s flywheel energy storage is no longer lagging behind that of Western advanced countries that started FES R&D in the 1970s. The reported maximum tip speed of the new 2D woven fabric composite flywheel arrived at 900 m/s in the spin test. A steel alloy flywheel with an energy storage capacity of 125 kWh and a composite flywheel with an energy storage capacity of 10 kWh have been successfully developed. Permanent magnet (PM) motors with power of 250–1000 kW were designed, manufactured, and tested in many FES assemblies. The lower loss is carried out through innovative stator and rotor configuration, optimizing magnetic flux and winding arrangement for harmonic magnetic field suppression. Permanent magnetic bearings with high load ability up to 50–100 kN were developed both for a 1000 kW/16.7 kWh flywheel used for the drilling practice application in hybrid power of an oil well drilling rig and for 630 kW/125 kWh flywheels used in the 22 MW flywheel array applied to the flywheel and thermal power joint frequency modulation demonstration project. It is expected that the FES demonstration application power stations with a total cumulative capacity of 300 MW will be built in the next five years. Full article
(This article belongs to the Special Issue Flywheel Energy Storage Systems and Applications Ⅱ)
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29 pages, 4444 KiB  
Article
A Stochastic Approach to the Power Requirements of the Electric Vehicle Charging Infrastructure: The Case of Spain
by Oscar Castillo, Roberto Álvarez Fernández and Mario Porru
Energies 2024, 17(21), 5314; https://doi.org/10.3390/en17215314 - 25 Oct 2024
Cited by 1 | Viewed by 1110
Abstract
Battery electric vehicles represent a technological pathway for reducing carbon emissions in personal road transport. However, for the widespread adoption of this type of vehicle, the user experience should be similar to that of combustion engine vehicles. To achieve this objective, a robust [...] Read more.
Battery electric vehicles represent a technological pathway for reducing carbon emissions in personal road transport. However, for the widespread adoption of this type of vehicle, the user experience should be similar to that of combustion engine vehicles. To achieve this objective, a robust and reliable public charging infrastructure is essential. In Spain, the electric recharging infrastructure is growing quickly in metropolitan areas but much more slowly on roads and highways. The upcoming charging stations must be located along high-volume traffic corridors and in proximity to the Trans-European Transport Network. The main contribution of this research is to offer a method for examining the essential electricity infrastructure investments required in scenarios involving substantial electric vehicle adoption. The methodology includes a sensitivity analysis of fleet composition and market share, recharging user behavior, charging station density, and vehicle efficiency improvements. To this end, the authors have developed a simplified probabilistic model, addressing the effect of the involved parameters through a comprehensive scenario analysis. The results show that the actual number of high-capacity charging plugs on Spanish roads is significantly lower than the European regulation requirements for the year 2030 considering an electric vehicle market share according to the Spanish Integrated National Energy and Climate Plan 2021–2030 objectives and it is far from the necessary infrastructure to cover the expected demand according to the traffic flow. Under these circumstances, the charging peak power demand reaches over 7.4% of the current Spanish total power demand for an electric vehicle fleet, which corresponds to only 12% of the total. Full article
(This article belongs to the Section E: Electric Vehicles)
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15 pages, 4416 KiB  
Article
Polymer Boron-Containing Composite for Protecting Astronauts of Manned Orbital Stations from Secondary Neutron Radiation
by Roman Nikolaevich Yastrebinsky, Anna Viktorovna Yastrebinskaya, Andrey Ivanovich Gorodov and Anastasia Vladislavovna Akimenko
J. Compos. Sci. 2024, 8(9), 372; https://doi.org/10.3390/jcs8090372 - 21 Sep 2024
Viewed by 1091
Abstract
This article considers the prospects of using heat-resistant polyimide boron-containing composites to protect astronauts of manned orbital stations from secondary neutron radiation. Variant calculations are performed regarding neutron and gamma-quanta flux distributions in a polyimide composite material with different boron content used to [...] Read more.
This article considers the prospects of using heat-resistant polyimide boron-containing composites to protect astronauts of manned orbital stations from secondary neutron radiation. Variant calculations are performed regarding neutron and gamma-quanta flux distributions in a polyimide composite material with different boron content used to reduce capture radiation. The dependences of spatial distributions of thermal neutron flux density and the gamma-quanta dose rate in a polyimide composite layer with a boron content of 0 to 5% are obtained. An experimental assessment of the energy distribution of neutron and gamma radiation behind the protective polyimide composite is carried out. The introduction of boron atoms in an amount of 3.0 wt.% shows the absence of bursts of secondary gamma radiation energy in the composite, which is due to the high cross-section of thermal neutron absorption by boron atoms. As a result, with a material layer thickness of 3–10 cm, the gamma-quanta dose rate decreases by 2–3 times. The differential thermal analysis method showed that the upper limit of the working temperature of the polyimide composite is 500 °C. The polyimide matrix filled with boron atoms can find effective application in the development of new radiation-protective polymer materials used in manned orbital stations. Full article
(This article belongs to the Section Polymer Composites)
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25 pages, 8614 KiB  
Article
Techno-Economic Analysis of Combined Production of Wind Energy and Green Hydrogen on the Northern Coast of Mauritania
by Varha Maaloum, El Moustapha Bououbeid, Mohamed Mahmoud Ali, Kaan Yetilmezsoy, Shafiqur Rehman, Christophe Ménézo, Abdel Kader Mahmoud, Shahab Makoui, Mamadou Lamine Samb and Ahmed Mohamed Yahya
Sustainability 2024, 16(18), 8063; https://doi.org/10.3390/su16188063 - 14 Sep 2024
Cited by 5 | Viewed by 3120
Abstract
Green hydrogen is becoming increasingly popular, with academics, institutions, and governments concentrating on its development, efficiency improvement, and cost reduction. The objective of the Ministry of Petroleum, Mines, and Energy is to achieve a 35% proportion of renewable energy in the overall energy [...] Read more.
Green hydrogen is becoming increasingly popular, with academics, institutions, and governments concentrating on its development, efficiency improvement, and cost reduction. The objective of the Ministry of Petroleum, Mines, and Energy is to achieve a 35% proportion of renewable energy in the overall energy composition by the year 2030, followed by a 50% commitment by 2050. This goal will be achieved through the implementation of feed-in tariffs and the integration of independent power generators. The present study focused on the economic feasibility of green hydrogen and its production process utilizing renewable energy resources on the northern coast of Mauritania. The current investigation also explored the wind potential along the northern coast of Mauritania, spanning over 600 km between Nouakchott and Nouadhibou. Wind data from masts, Lidar stations, and satellites at 10 and 80 m heights from 2022 to 2023 were used to assess wind characteristics and evaluate five turbine types for local conditions. A comprehensive techno-economic analysis was carried out at five specific sites, encompassing the measures of levelized cost of electricity (LCOE) and levelized cost of green hydrogen (LCOGH), as well as sensitivity analysis and economic performance indicators. The results showed an annual average wind speed of 7.6 m/s in Nouakchott to 9.8 m/s in Nouadhibou at 80 m. The GOLDWIND 3.0 MW model showed the highest capacity factor of 50.81% due to its low cut-in speed of 2.5 m/s and its rated wind speed of 10.5 to 11 m/s. The NORDEX 4 MW model forecasted an annual production of 21.97 GWh in Nouadhibou and 19.23 GWh in Boulanoir, with the LCOE ranging from USD 5.69 to 6.51 cents/kWh, below the local electricity tariff, and an LCOGH of USD 1.85 to 2.11 US/kg H2. Multiple economic indicators confirmed the feasibility of wind energy and green hydrogen projects in assessed sites. These results boosted the confidence of the techno-economic model, highlighting the resilience of future investments in these sustainable energy infrastructures. Mauritania’s north coast has potential for wind energy, aiding green hydrogen production for energy goals. Full article
(This article belongs to the Special Issue Renewable Energy, Electric Power Systems and Sustainability)
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12 pages, 1598 KiB  
Article
An Analysis of the Physicochemical and Energy Parameters of Briquettes Manufactured from Sewage Sludge Mixtures and Selected Organic Additives
by Sebastian Kujawiak, Małgorzata Makowska, Damian Janczak, Wojciech Czekała, Włodzimierz Krzesiński, Ariel Antonowicz and Karol Kupryaniuk
Energies 2024, 17(18), 4573; https://doi.org/10.3390/en17184573 - 12 Sep 2024
Cited by 3 | Viewed by 1320
Abstract
As a by-product of wastewater treatment, sewage sludge can be used for natural, agricultural, or energy purposes. One method of preparing sludge for management and use is solar drying. To intensify the drying process, natural additives can be used to alter the structure [...] Read more.
As a by-product of wastewater treatment, sewage sludge can be used for natural, agricultural, or energy purposes. One method of preparing sludge for management and use is solar drying. To intensify the drying process, natural additives can be used to alter the structure of the sludge and accelerate the evaporation of water. This research aimed to evaluate the influences of different organic additives in sewage sludge mixtures on the physicochemical and energy parameters of briquettes. This research was carried out without thermal boosting in a 4 × 2.5 × 2 m plastic tunnel. The tunnel was equipped with three drying stations and control and measuring equipment. In two test series, sludge additives in the form of straw and lignocellulosic materials, sawdust, bark, woodchips, and walnut shells, were used. Briquettes were made from the resulting mixtures and then subjected to physical and chemical analyses. This research showed high variability in the contents of trace elements, nitrogen, and sulphur in relation to an increase in the amount of sludge in the briquettes, which, for the briquettes made from sewage sludge, was nearly twice as high as for the briquettes made from the mixtures. The results of the flue gas analysis for the briquettes with sawdust and wood chip additives were very similar. The briquettes made from sewage sludge with lignocellulosic materials (bark and wood chips) had fuel properties similar to woody biomass, with a calorific value and heat of combustion of 15–16 MJ/kg. Fibrous additives (straw) significantly increased the strength parameters of the briquettes, by more than 50% of the value. The compositions and properties of the mixtures affected the following briquetting parameters: temperature and compressive force. The briquettes made from sewage sludge and additives can be classified according to ISO 21640 as SRFs (solid recovered fuels). In most of the results, the net calorific value (NCV) was 3 to 4; the chlorine content (CL) was 2 to 1; and the mercury content (Hg) was 1. The sewage sludge mixtures facilitated the agricultural and energy use of the briquettes. Full article
(This article belongs to the Special Issue Biofuel Production and Bio-Waste Management)
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17 pages, 5119 KiB  
Article
Fabrication of Active Z-Scheme Sr2MgSi2O7: Eu2+, Dy3+/COF Photocatalyst for Round-the-Clock Efficient Removal of Total Cr
by Meng Xu, Junshu Wu, Mupeng Zheng and Jinshu Wang
Molecules 2024, 29(18), 4327; https://doi.org/10.3390/molecules29184327 - 12 Sep 2024
Viewed by 986
Abstract
Photoreduction is recognized as a desirable treatment method for hexavalent chromium (Cr(VI)). However, it has been limited by the intermittent solar flux and limited light absorption. In this work, a novel Z-scheme photocatalyst combining a covalent organic framework (COF) with Eu2+, [...] Read more.
Photoreduction is recognized as a desirable treatment method for hexavalent chromium (Cr(VI)). However, it has been limited by the intermittent solar flux and limited light absorption. In this work, a novel Z-scheme photocatalyst combining a covalent organic framework (COF) with Eu2+, Dy3+ co-doped Sr2MgSi2O7 (Sr2MgSi2O7:Eu2+, Dy3+) is synthesized, which shows the high spectral conversion efficiency and works efficiently in both light irradiation and dark for Cr(VI) reduction. Sr2MgSi2O7:Eu2+, Dy3+ serves as both an electron transfer station and active sites for COF molecule activation, thus resulting in 100% photoreduction of Cr(VI) (50 mL, 10 mg/L) with high light stability and over 1 h dark activity. Moreover, the XPS and FT-IR analyses reveal the existence of functional groups (Si-OH on Sr2MgSi2O7:Eu2+, Dy3+, and -NH- on COFTP-TTA) on the composited catalyst as active sites to adsorb the resultant Cr(III) species, demonstrating a synergistic effect for total Cr removal. This work provides an alternative method for the design of a round-the-clock photocatalyst for Cr(VI) reduction, allowing a versatile solid surface activation for establishing a more energy efficient and robust photocatalysis process for Cr pollution cleaning. Full article
(This article belongs to the Special Issue Advances in Composite Photocatalysts)
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17 pages, 5007 KiB  
Article
The Effect of Fly Ash Additive on the Thermal Conductivity of Polystyrene Concrete
by Rassul B. Tlegenov, Rimma K. Niyazbekova, Assel E. Jexembayeva, Kinga Korniejenko, Lyazat B. Aruova, Saule S. Aldabergenova and Aslan S. Maykonov
Buildings 2024, 14(9), 2850; https://doi.org/10.3390/buildings14092850 - 10 Sep 2024
Cited by 2 | Viewed by 1884
Abstract
The use of fly ash in compositions as a substitute for a part of cement is economically favorable and ecologically feasible in connection with large accumulations of waste at the enterprises of the energy sector. In addition, the technology of cement production provides [...] Read more.
The use of fly ash in compositions as a substitute for a part of cement is economically favorable and ecologically feasible in connection with large accumulations of waste at the enterprises of the energy sector. In addition, the technology of cement production provides high-temperature treatment of mineral substances in kilns with significant emissions of carbon dioxide. One of the most effective directions of the utilization of fly ash is their use in concrete composites. The use of this material will provide the required temperature and humidity conditions in residential premises, solve the problem of “cold bridges” in structures, minimize heat losses of the structure, and increase the energy efficiency of buildings in general. At the same time, polystyrene concrete, due to its structural structure and the presence of thermally conductive concrete, has limited opportunities for thermal and physical–mechanical properties. To improve the operational properties of polystyrene concrete, it is proposed to use composite binders, including fly ash from the thermal power station of Astana. The main aim of this study is to develop compositions of polystyrene concrete with reduced thermal conductivity and improved physical and mechanical properties. The objectives of this study include the determination of characteristics of fly ash from Astana, formulation of polystyrene concrete mixtures with different proportions of fly ash, and evaluation of their thermal conductivity properties. These tasks are in line with the objectives of the ISO 50001 standard to improve energy efficiency and reduce environmental impact. The results showed that the addition of fly ash from Astana to polystyrene concrete leads to a marked reduction in thermal conductivity, contributing to improved energy efficiency of the building envelope. Optimal results were achieved by using 15% of Astana fly ash as an additive in polystyrene concrete, which led to a significant reduction in thermal conductivity of 51.47%. This reduction is in line with improving the energy efficiency of building materials, especially in cold climates. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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21 pages, 2125 KiB  
Article
Adaptive Charging Simulation Model for Different Electric Vehicles and Mobility Patterns
by Bruno Knevitz Hammerschmitt, Clodomiro Unsihuay-Vila, Jordan Passinato Sausen, Marcelo Bruno Capeletti, Alexandre Rasi Aoki, Mateus Duarte Teixeira, Carlos Henrique Barriquello and Alzenira da Rosa Abaide
Energies 2024, 17(16), 4032; https://doi.org/10.3390/en17164032 - 14 Aug 2024
Cited by 3 | Viewed by 1465
Abstract
Electric mobility is a sustainable alternative for mitigating carbon emissions by replacing the conventional fleet. However, the low availability of data from charging stations makes planning energy systems for the integration of electric vehicles (EVs) difficult. Given this, this work focuses on developing [...] Read more.
Electric mobility is a sustainable alternative for mitigating carbon emissions by replacing the conventional fleet. However, the low availability of data from charging stations makes planning energy systems for the integration of electric vehicles (EVs) difficult. Given this, this work focuses on developing an adaptive computational tool for charging simulation, considering many EVs and mobility patterns. Technical specifications data from many EVs are considered for charging simulation, such as battery capacity, driving range, charging time, charging standard for each EV, and mobility patterns. Different simulations of charging many EVs and analyses of weekly charging load profiles are carried out, portraying the characteristics of the different load profiles and the challenges that system planners expect. The research results denote the importance of considering different manufacturers and models of EVs in the composition of the aggregate charging load profile and mobility patterns of the region. The developed model can be adapted to any system, expanded with new EVs, and scaled to many EVs, supporting different research areas. Full article
(This article belongs to the Section E: Electric Vehicles)
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22 pages, 13498 KiB  
Article
Experimental Research on Thermal-Venting Characteristics of the Failure 280 Ah LiFePO4 Battery: Atmospheric Pressure Impacts and Safety Assessment
by Yu Wang, Yan Wang, Jingyuan Zhao, Hongxu Li, Chengshan Xu, Yalun Li, Hewu Wang, Languang Lu, Feng Dai, Ruiguang Yu and Feng Qian
Batteries 2024, 10(8), 270; https://doi.org/10.3390/batteries10080270 - 29 Jul 2024
Cited by 3 | Viewed by 2754
Abstract
With the widespread application of lithium-ion batteries (LIBs) energy storage stations in high-altitude areas, the impact of ambient pressure on battery thermal runaway (TR) behavior and venting flow characteristics have aroused wide research attention. This paper conducts a lateral heating experiment on 280 [...] Read more.
With the widespread application of lithium-ion batteries (LIBs) energy storage stations in high-altitude areas, the impact of ambient pressure on battery thermal runaway (TR) behavior and venting flow characteristics have aroused wide research attention. This paper conducts a lateral heating experiment on 280 Ah lithium iron phosphate batteries (LFPs) and proposes a method for testing battery internal pressure using an embedded pressure sensor. This paper analyzes the battery characteristic temperature, internal pressure, chamber pressure, and gas components under different chamber pressures. The experiment is carried out in a N2 atmosphere using a 1000 L insulated chamber. At 40 kPa, the battery experiences two instances of venting, with a corresponding peak in temperature on the battery’s side of 136.3 °C and 302.8 °C, and gas generation rates of 0.14 mol/s and 0.09 mol/s, respectively. The research results indicate that changes in chamber pressure significantly affect the center temperature of the battery side (Ts), the center temperature of the chamber (Tc), the opening time of the safety valve (topen), the triggering time of TR (tTR), the time difference (Δt), venting velocity, gas composition, and flammable limits. However, the internal pressure and gas content of the battery are apparently unaffected. Considering the TR characteristics mentioned above, a safety assessment method is proposed to evaluate the TR behavior and gas hazard of the battery. The results indicate that the risk at 40 kPa is much higher than the other three chamber pressures. This study provides theoretical references for the safe use and early warning of energy storage LIBs in high-altitude areas. Full article
(This article belongs to the Special Issue Thermal Safety of Lithium Ion Batteries)
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