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Keywords = competitive sustainability

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19 pages, 1835 KiB  
Article
Methods for Enhancing Energy and Resource Efficiency in Sunflower Oil Production: A Case Study from Bulgaria
by Penka Zlateva, Angel Terziev, Nikolay Kolev, Martin Ivanov, Mariana Murzova and Momchil Vasilev
Eng 2025, 6(8), 195; https://doi.org/10.3390/eng6080195 - 6 Aug 2025
Abstract
The rising demand for energy resources and industrial goods presents significant challenges to sustainable development. Sunflower oil, commonly utilized in the food sector, biofuels, and various industrial applications, is notably affected by this demand. In Bulgaria, it serves as a primary source of [...] Read more.
The rising demand for energy resources and industrial goods presents significant challenges to sustainable development. Sunflower oil, commonly utilized in the food sector, biofuels, and various industrial applications, is notably affected by this demand. In Bulgaria, it serves as a primary source of vegetable fats, ranking second to butter in daily consumption. The aim of this study is to evaluate and propose methods to improve energy and resource efficiency in sunflower oil production in Bulgaria. The analysis is based on data from an energy audit conducted in 2023 at an industrial sunflower oil production facility. Reconstruction and modernization initiatives, which included the installation of high-performance, energy-efficient equipment, led to a 34% increase in energy efficiency. The findings highlight the importance of adjusting the technological parameters such as temperature, pressure, grinding level, and pressing time to reduce energy use and operational costs. Additionally, resource efficiency is improved through more effective raw material utilization and waste reduction. These strategies not only enhance the economic and environmental performance of sunflower oil production but also support sustainable development and competitiveness within the industry. The improvement reduces hexane use by approximately 2%, resulting in energy savings of 12–15 kWh/t of processed seeds and a reduction in CO2 emissions by 3–4 kg/t, thereby improving the environmental profile of sunflower oil production. Full article
(This article belongs to the Special Issue Interdisciplinary Insights in Engineering Research)
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18 pages, 313 KiB  
Article
Sustainability and Profitability of Large Manufacturing Companies
by Iveta Mietule, Rasa Subaciene, Jelena Liksnina and Evalds Viskers
J. Risk Financial Manag. 2025, 18(8), 439; https://doi.org/10.3390/jrfm18080439 - 6 Aug 2025
Abstract
This study explores whether sustainability achievements—proxied through ESG (environmental, social, and governance) reporting—are associated with superior financial performance in Latvia’s manufacturing sector, where ESG maturity remains low and institutional readiness is still emerging. Building on stakeholder, legitimacy, signal, slack resources, and agency theories, [...] Read more.
This study explores whether sustainability achievements—proxied through ESG (environmental, social, and governance) reporting—are associated with superior financial performance in Latvia’s manufacturing sector, where ESG maturity remains low and institutional readiness is still emerging. Building on stakeholder, legitimacy, signal, slack resources, and agency theories, this study applies a mixed-method approach (that consists of two analytical stages) suited to the limited availability and reliability of ESG-related data in the Latvian manufacturing sector. Financial indicators from three large firms—AS MADARA COSMETICS, AS Latvijas Finieris, and AS Valmiera Glass Grupa—are compared with industry averages over the 2019–2023 period using independent sample T-tests. ESG integration is evaluated through a six-stage conceptual schema ranging from symbolic compliance to performance-driven sustainability. The results show that AS MADARA COSMETICS, which demonstrates advanced ESG integration aligned with international standards, significantly outperforms its industry in all profitability metrics. In contrast, the other two companies remain at earlier ESG maturity stages and show weaker financial performance, with sustainability disclosures limited to general statements and outdated indicators. These findings support the synergy hypothesis in contexts where sustainability is internalized and operationalized, while also highlighting structural constraints—such as resource scarcity and fragmented data—that may limit ESG-financial alignment in post-transition economies. This study offers practical guidance for firms seeking competitive advantage through strategic ESG integration and recommends policy actions to enhance ESG transparency and performance in Latvia, including performance-based reporting mandates, ESG data infrastructure, and regulatory alignment with EU directives. These insights contribute to the growing empirical literature on ESG effectiveness under constrained institutional and economic conditions. Full article
(This article belongs to the Section Business and Entrepreneurship)
20 pages, 312 KiB  
Article
Pimelea and Its Toxicity: A Survey of Landholder Experiences and Management Practices
by Rashid Saleem, Shane Campbell, Mary T. Fletcher, Sundaravelpandian Kalaipandian and Steve W. Adkins
Toxins 2025, 17(8), 393; https://doi.org/10.3390/toxins17080393 - 6 Aug 2025
Abstract
Pimelea is one of the highly toxic plants in Australia, particularly affecting cattle. It contains simplexin, a potent toxin that can cause Pimelea poisoning (St. George Disease) in livestock. A survey was conducted to assess the current impact of Pimelea on livestock production, [...] Read more.
Pimelea is one of the highly toxic plants in Australia, particularly affecting cattle. It contains simplexin, a potent toxin that can cause Pimelea poisoning (St. George Disease) in livestock. A survey was conducted to assess the current impact of Pimelea on livestock production, pasture systems, and financial losses among agricultural producers. In addition, information was also sought about the environmental conditions that facilitate its growth and the effectiveness of existing management strategies. The survey responses were obtained from producers affected by Pimelea across nine different Local Government Areas, through three States, viz., Queensland, New South Wales, and South Australia. Pimelea was reported to significantly affect animal production, with 97% of producers surveyed acknowledging its detrimental effects. Among livestock, cattle were the most severely affected (94%), when compared to sheep (13%), goats (3%), and horses (3%). The presence of Pimelea was mostly observed in spring (65%) and winter (48%), although 29% of respondents indicated that it could be present all year-round under favorable rainfall conditions. Germination was associated with light to moderate rainfall (52%), while only 24% linked it to heavy rainfall. Pimelea simplex F. Muell. was the most frequently encountered species (71%), followed by Pimelea trichostachya Lindl. (26%). Infestations were reported to occur annually by 47% of producers, with 41% noting occurrences every 2 to 5 years. Financially, producers estimated average annual losses of AUD 67,000, with 50% reporting an average of 26 cattle deaths per year, reaching up to 105 deaths in severe years. Some producers were spending up to AUD 2100 per annum to manage Pimelea. While chemical and physical controls were commonly employed, integrating competitive pastures and alternative livestock, such as sheep and goats, was considered as a potential management strategy. This study reiterates the need for further research on sustainable pasture management practices to reduce Pimelea-related risks to livestock and agricultural production systems. Full article
(This article belongs to the Special Issue Plant Toxin Emergency)
26 pages, 3368 KiB  
Article
Effective Ciprofloxacin Removal from Deionized and Salt Water by Sulfonated Pentablock Copolymer (NexarTM)
by Simona Filice, Simona Crispi, Viviana Scuderi, Daniela Iannazzo, Consuelo Celesti and Silvia Scalese
Molecules 2025, 30(15), 3275; https://doi.org/10.3390/molecules30153275 - 5 Aug 2025
Abstract
The presence of ciprofloxacin antibiotic in water is a threat to humans and aquatic life since antibiotics are currently regarded as emerging contaminants of major concern. This work reported the use of NexarTM film, a sulfonated pentablock copolymer, to effectively remove ciprofloxacin [...] Read more.
The presence of ciprofloxacin antibiotic in water is a threat to humans and aquatic life since antibiotics are currently regarded as emerging contaminants of major concern. This work reported the use of NexarTM film, a sulfonated pentablock copolymer, to effectively remove ciprofloxacin antibiotic from water in a sustainable approach. The removal efficiency of Nexar film was evaluated in aqueous or salty (NaCl 0.5 M) ciprofloxacin solutions as a function of contact time and the initial ciprofloxacin concentration. In the investigated conditions, the polymeric film totally removed ciprofloxacin in MilliQ solution while its removal efficiency in salty solution was approximately 73%. This lower value is due to the presence of Na+ ions that compete with antibiotic molecules for adsorption on active surface sites of the polymeric film. No further release of adsorbed antibiotic molecules occurred. The kinetic studies, conducted for ciprofloxacin adsorption on Nexar film in both MilliQ and salty solutions, revealed that the overall sorption process is controlled by the rate of surface reaction between ciprofloxacin molecules and active sites on Nexar surface. Furthermore, at equilibrium conditions, the isotherm model that best fits experimental parameters was not linear. This indicates that the competition between the solute and the solvent for binding sites on the adsorbent should be considered to describe adsorption processes in both MilliQ and salty solutions. Full article
(This article belongs to the Special Issue Materials for Environmental Remediation and Catalysis)
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19 pages, 1495 KiB  
Review
Computer Vision for Low-Level Nuclear Waste Sorting: A Review
by Tianshuo Li, Danielle E. Winckler and Zhong Li
Environments 2025, 12(8), 270; https://doi.org/10.3390/environments12080270 - 5 Aug 2025
Abstract
Nuclear power is a low-emission and economically competitive energy source, yet the effective disposal and management of its associated radioactive waste can be challenging. Radioactive waste can be categorised as high-level waste (HLW), intermediate-level waste (ILW), and low-level waste (LLW). LLW primarily comprises [...] Read more.
Nuclear power is a low-emission and economically competitive energy source, yet the effective disposal and management of its associated radioactive waste can be challenging. Radioactive waste can be categorised as high-level waste (HLW), intermediate-level waste (ILW), and low-level waste (LLW). LLW primarily comprises materials contaminated during routine clean-up, such as mop heads, paper towels, and floor sweepings. While LLW is less radioactive compared to HLW and ILW, the management of LLW poses significant challenges due to the large volume that requires processing and disposal. The volume of LLW can be significantly reduced through sorting, which is typically performed manually in a labour-intensive way. Smart management techniques, such as computer vision (CV) and machine learning (ML), have great potential to help reduce the workload and human errors during LLW sorting. This paper provides a comprehensive review of previous research related to LLW sorting and a summative review of existing applications of CV in solid waste management. It also discusses state-of-the-art CV and ML algorithms and their potential for automating LLW sorting. This review lays a foundation for and helps facilitate the applications of CV and ML techniques in LLW sorting, paving the way for automated LLW sorting and sustainable LLW management. Full article
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38 pages, 2949 KiB  
Article
Modeling the Evolutionary Mechanism of Multi-Stakeholder Decision-Making in the Green Renovation of Existing Residential Buildings in China
by Yuan Gao, Jinjian Liu, Jiashu Zhang and Hong Xie
Buildings 2025, 15(15), 2758; https://doi.org/10.3390/buildings15152758 - 5 Aug 2025
Abstract
The green renovation of existing residential buildings is a key way for the construction industry to achieve sustainable development and the dual carbon goals of China, which makes it urgent to make collaborative decisions among multiple stakeholders. However, because of divergent interests and [...] Read more.
The green renovation of existing residential buildings is a key way for the construction industry to achieve sustainable development and the dual carbon goals of China, which makes it urgent to make collaborative decisions among multiple stakeholders. However, because of divergent interests and risk perceptions among governments, energy service companies (ESCOs), and owners, the implementation of green renovation is hindered by numerous obstacles. In this study, we integrated prospect theory and evolutionary game theory by incorporating core prospect-theory parameters such as loss aversion and perceived value sensitivity, and developed a psychologically informed tripartite evolutionary game model. The objective was to provide a theoretical foundation and analytical framework for collaborative governance among stakeholders. Numerical simulations were conducted to validate the model’s effectiveness and explore how government regulation intensity, subsidy policies, market competition, and individual psychological factors influence the system’s evolutionary dynamics. The findings indicate that (1) government regulation and subsidy policies play central guiding roles in the early stages of green renovation, but the effectiveness has clear limitations; (2) ESCOs are most sensitive to policy incentives and market competition, and moderately increasing their risk costs can effectively deter opportunistic behavior associated with low-quality renovation; (3) owners’ willingness to participate is primarily influenced by expected returns and perceived renovation risks, while economic incentives alone have limited impact; and (4) the evolutionary outcomes are highly sensitive to parameters from prospect theory, The system’s evolutionary outcomes are highly sensitive to prospect theory parameters. High levels of loss aversion (λ) and loss sensitivity (β) tend to drive the system into a suboptimal equilibrium characterized by insufficient demand, while high gain sensitivity (α) serves as a key driving force for the system’s evolution toward the ideal equilibrium. This study offers theoretical support for optimizing green renovation policies for existing residential buildings in China and provides practical recommendations for improving market competition mechanisms, thereby promoting the healthy development of the green renovation market. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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19 pages, 3110 KiB  
Article
Integrated Environmental–Economic Assessment of Small-Scale Natural Gas Sweetening Processes
by Qing Wen, Xin Chen, Xingrui Peng, Yanhua Qiu, Kunyi Wu, Yu Lin, Ping Liang and Di Xu
Processes 2025, 13(8), 2473; https://doi.org/10.3390/pr13082473 - 5 Aug 2025
Viewed by 65
Abstract
Effective in situ H2S removal is essential for the utilization of small, remote natural gas wells, where centralized treatment is often unfeasible. This study presents an integrated environmental–economic assessment of two such processes, LO-CAT® and triazine-based absorption, using a scenario-based [...] Read more.
Effective in situ H2S removal is essential for the utilization of small, remote natural gas wells, where centralized treatment is often unfeasible. This study presents an integrated environmental–economic assessment of two such processes, LO-CAT® and triazine-based absorption, using a scenario-based framework. Environmental impacts were assessed via the Waste Reduction Algorithm (WAR), considering both Potential Environmental Impact (PEI) generation and output across eight categories, while economic performance was analyzed based on equipment, chemical, energy, environmental treatment, and labor costs. Results show that the triazine-based process offers superior environmental performance due to lower toxic emissions, whereas LO-CAT® demonstrates better economic viability at higher gas flow rates and H2S concentrations. An integrated assessment combining monetized environmental impacts with economic costs reveals that the triazine-based process becomes competitive only if environmental impacts are priced above specific thresholds. This study contributes a practical evaluation framework and scenario-based dataset that support sustainable process selection for decentralized sour gas treatment applications. Full article
(This article belongs to the Section Chemical Processes and Systems)
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31 pages, 6551 KiB  
Article
Optimization Study of the Electrical Microgrid for a Hybrid PV–Wind–Diesel–Storage System in an Island Environment
by Fahad Maoulida, Kassim Mohamed Aboudou, Rabah Djedjig and Mohammed El Ganaoui
Solar 2025, 5(3), 39; https://doi.org/10.3390/solar5030039 - 4 Aug 2025
Viewed by 311
Abstract
The Union of the Comoros, located in the Indian Ocean, faces persistent energy challenges due to its geographic isolation, heavy dependence on imported fossil fuels, and underdeveloped electricity infrastructure. This study investigates the techno-economic optimization of a hybrid microgrid designed to supply electricity [...] Read more.
The Union of the Comoros, located in the Indian Ocean, faces persistent energy challenges due to its geographic isolation, heavy dependence on imported fossil fuels, and underdeveloped electricity infrastructure. This study investigates the techno-economic optimization of a hybrid microgrid designed to supply electricity to a rural village in Grande Comore. The proposed system integrates photovoltaic (PV) panels, wind turbines, a diesel generator, and battery storage. Detailed modeling and simulation were conducted using HOMER Energy, accompanied by a sensitivity analysis on solar irradiance, wind speed, and diesel price. The results indicate that the optimal configuration consists solely of PV and battery storage, meeting 100% of the annual electricity demand with a competitive levelized cost of energy (LCOE) of 0.563 USD/kWh and zero greenhouse gas emissions. Solar PV contributes over 99% of the total energy production, while wind and diesel components remain unused under optimal conditions. Furthermore, the system generates a substantial energy surplus of 63.7%, which could be leveraged for community applications such as water pumping, public lighting, or future system expansion. This study highlights the technical viability, economic competitiveness, and environmental sustainability of 100% solar microgrids for non-interconnected island territories. The approach provides a practical and replicable decision-support framework for decentralized energy planning in remote and vulnerable regions. Full article
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14 pages, 379 KiB  
Essay
Is Platform Capitalism Socially Sustainable?
by Andrea Fumagalli
Sustainability 2025, 17(15), 7071; https://doi.org/10.3390/su17157071 - 4 Aug 2025
Viewed by 158
Abstract
This theoretical essay aims to analyze some of the socio-economic innovations introduced by Platform Capitalism Specifically, it focuses on two main aspects: first, the digital platform as a radical organizational innovation. Digital platforms represent a structural novelty in the market economy, signaling a [...] Read more.
This theoretical essay aims to analyze some of the socio-economic innovations introduced by Platform Capitalism Specifically, it focuses on two main aspects: first, the digital platform as a radical organizational innovation. Digital platforms represent a structural novelty in the market economy, signaling a new organization of production and labor. Second, the essay examines the role of platforms in directly generating value through the concept of “network value”. To this end, it explores the function of “business intelligence” as a strategic and competitive tool. Finally, the paper discusses the key issues associated with platform capitalism, which could threaten its social sustainability and contribute to economic and financial instability. These issues include the increasing commodification of everyday activities, the devaluation of paid labor in favor of free production driven by platform users (the so-called prosumers), and the emergence of proprietary and financial monopolies. Hence, digital platforms do not inherently ensure comprehensive social and environmental sustainability unless supported by targeted economic policy interventions. Conclusively, it is emphasized that defining robust social welfare frameworks—which account for emerging value creation processes—is imperative. Simultaneously, policymakers must incentivize the proliferation of cooperative platforms capable of fostering experimental circular economy models aligned with ecological sustainability. Full article
(This article belongs to the Section Economic and Business Aspects of Sustainability)
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25 pages, 30553 KiB  
Article
Optimizing Multi-Cluster Fracture Propagation and Mitigating Interference Through Advanced Non-Uniform Perforation Design in Shale Gas Horizontal Wells
by Guo Wen, Wentao Zhao, Hongjiang Zou, Yongbin Huang, Yanchi Liu, Yulong Liu, Zhongcong Zhao and Chenyang Wang
Processes 2025, 13(8), 2461; https://doi.org/10.3390/pr13082461 - 4 Aug 2025
Viewed by 225
Abstract
The persistent challenge of fracture-driven interference (FDI) during large-scale hydraulic fracturing in the southern Sichuan Basin has severely compromised shale gas productivity, while the existing research has inadequately addressed both FDI risk reductions and the optimization of reservoir stimulation. To bridge this gap, [...] Read more.
The persistent challenge of fracture-driven interference (FDI) during large-scale hydraulic fracturing in the southern Sichuan Basin has severely compromised shale gas productivity, while the existing research has inadequately addressed both FDI risk reductions and the optimization of reservoir stimulation. To bridge this gap, this study developed a mechanistic model of the competitive multi-cluster fracture propagation under non-uniform perforation conditions and established a perforation-based design methodology for the mitigation of horizontal well interference. The results demonstrate that spindle-shaped perforations enhance the uniformity of fracture propagation by 20.3% and 35.1% compared to that under uniform and trapezoidal perforations, respectively, with the perforation quantity (48) and diameter (10 mm) identified as the dominant control parameters for balancing multi-cluster growth. Through a systematic evaluation of the fracture communication mechanisms, three distinct inter-well types of FDI were identified: Type I (natural fracture–stress anisotropy synergy), Type II (natural-fracture-dominated), and Type III (stress-anisotropy-dominated). To mitigate these, customized perforation schemes coupled with geometry-optimized fracture layouts were developed. The surveillance data for the offset well show that the pressure interference decreased from 14.95 MPa and 6.23 MPa before its application to 0.7 MPa and 0 MPa, achieving an approximately 95.3% reduction in the pressure interference in the application wells. The expansion morphology of the inter-well fractures confirmed effective fluid redistribution across clusters and containment of the overextension of planar fractures, demonstrating this methodology’s dual capability to enhance the effectiveness of stimulation while resolving FDI challenges in deep shale reservoirs, thereby advancing both productivity and operational sustainability in complex fracturing operations. Full article
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25 pages, 1294 KiB  
Article
Achieving Optimal Distinctiveness in Green Innovation: The Role of Pressure Congruence
by Rong Cong, Hongyan Gao, Liya Wang, Bo Liu and Ya Wang
Systems 2025, 13(8), 657; https://doi.org/10.3390/systems13080657 - 4 Aug 2025
Viewed by 174
Abstract
As a critical external mechanism driving green innovation, institutional and competitive pressure often coexist and jointly shape firms’ strategic responses. However, existing studies primarily focus on the individual effects of these pressures, with limited attention to their interactive impacts on green innovation. Drawing [...] Read more.
As a critical external mechanism driving green innovation, institutional and competitive pressure often coexist and jointly shape firms’ strategic responses. However, existing studies primarily focus on the individual effects of these pressures, with limited attention to their interactive impacts on green innovation. Drawing on optimal distinctiveness theory, this study proposes a “pressure–response” analytical framework that classifies institutional and competitive pressure combinations into congruent (i.e., high–high or low–low) and incongruent (i.e., high–low or low–high) pressure contexts based on their relative intensities. It further examines how these distinct configurations affect two types of green innovation: strategic green innovation (StrGI) and substantive green innovation (SubGI). Using panel data from Chinese A-share listed firms between 2010 and 2022, the empirical results reveal that under congruent pressure contexts, the alignment of institutional and competitive pressures tends to suppress green innovation. In contrast, under incongruent contexts, the misalignment between the two pressures significantly promotes green innovation. Regarding innovation motivation, the high institutional–low competitive pressure context more significantly promotes StrGI, while the low institutional–high competitive pressure context has a more prominent effect on SubGI. In addition, this study also investigates the mediating roles of StrGI and SubGI on ESG performance. The findings provide theoretical support and policy implications for improving green transition policies and institutional frameworks, as well as promoting sustainable corporate development. Full article
(This article belongs to the Section Systems Practice in Social Science)
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15 pages, 428 KiB  
Article
Biodiversity Patterns and Community Construction in Subtropical Forests Driven by Species Phylogenetic Environments
by Pengcheng Liu, Jiejie Jiao, Chuping Wu, Weizhong Shao, Xuesong Liu and Liangjin Yao
Plants 2025, 14(15), 2397; https://doi.org/10.3390/plants14152397 - 2 Aug 2025
Viewed by 487
Abstract
To explore the characteristics of species diversity and phylogenetic diversity, as well as the dominant processes of community construction, in different forest types (deciduous broad-leaved forest, mixed coniferous and broad-leaved forest, and Chinese fir plantation) in subtropical regions, analyze the specific driving patterns [...] Read more.
To explore the characteristics of species diversity and phylogenetic diversity, as well as the dominant processes of community construction, in different forest types (deciduous broad-leaved forest, mixed coniferous and broad-leaved forest, and Chinese fir plantation) in subtropical regions, analyze the specific driving patterns of soil nutrients and other environmental factors on the formation of forest diversity in different forest types, and clarify the differences in response to environmental heterogeneity between natural forests and plantation forests. Based on 48 fixed monitoring plots of 50 m × 50 m in Shouchang Forest Farm, Jiande City, Zhejiang Province, woody plants with a diameter at breast height ≥5 cm were investigated. Species diversity indices (Margalef index, Shannon–Wiener index, Simpson index, and Pielou index), phylogenetic structure index (PD), and environmental factors were used to analyze the relationship between diversity characteristics and environmental factors through variance analysis, correlation analysis, and generalized linear models. Phylogenetic structural indices (NRI and NTI) were used, combined with a random zero model, to explore the mechanisms of community construction in different forest types. Research has found that (1) the deciduous broad-leaved forest had the highest species diversity (Margalef index of 4.121 ± 1.425) and phylogenetic diversity (PD index of 21.265 ± 7.796), significantly higher than the mixed coniferous and broad-leaved forest and the Chinese fir plantation (p < 0.05); (2) there is a significant positive correlation between species richness and phylogenetic diversity, with the best fit being AIC = 70.5636 and R2 = 0.9419 in broad-leaved forests; however, the contribution of evenness is limited; (3) the specific effects of soil factors on different forest types: available phosphorus (AP) is negatively correlated with the diversity of deciduous broad-leaved forests (p < 0.05), total phosphorus (TP) promotes the diversity of coniferous and broad-leaved mixed forests, while the diversity of Chinese fir plantations is significantly negatively correlated with total nitrogen (TN); (4) the phylogenetic structure of three different forest types shows a divergent pattern in deciduous broad-leaved forests, indicating that competition and exclusion dominate the construction of deciduous broad-leaved forests; the aggregation mode of Chinese fir plantation indicates that environmental filtering dominates the construction of Chinese fir plantation; the mixed coniferous and broad-leaved forest is a transitional model, indicating that the mixed coniferous and broad-leaved forest is influenced by both stochastic processes and ecological niche processes. In different forest types in subtropical regions, the species and phylogenetic diversity of broad-leaved forests is significantly higher than in other forest types. The impact of soil nutrients on the diversity of different forest types varies, and the characteristics of community construction in different forest types are also different. This indicates the importance of protecting the original vegetation and provides a scientific basis for improving the ecological function of artificial forest ecosystems through structural adjustment. The research results have important practical guidance value for sustainable forest management and biodiversity conservation in the region. Full article
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16 pages, 1504 KiB  
Article
Tuning the Activity of NbOPO4 with NiO for the Selective Conversion of Cyclohexanone as a Model Intermediate of Lignin Pyrolysis Bio-Oils
by Abarasi Hart and Jude A. Onwudili
Energies 2025, 18(15), 4106; https://doi.org/10.3390/en18154106 - 2 Aug 2025
Viewed by 172
Abstract
Catalytic upgrading of pyrolysis oils is an important step for producing replacement hydrocarbon-rich liquid biofuels from biomass and can help to advance pyrolysis technology. Catalysts play a pivotal role in influencing the selectivity of chemical reactions leading to the formation of main compounds [...] Read more.
Catalytic upgrading of pyrolysis oils is an important step for producing replacement hydrocarbon-rich liquid biofuels from biomass and can help to advance pyrolysis technology. Catalysts play a pivotal role in influencing the selectivity of chemical reactions leading to the formation of main compounds in the final upgraded liquid products. The present work involved a systematic study of solvent-free catalytic reactions of cyclohexanone in the presence of hydrogen gas at 160 °C for 3 h in a batch reactor. Cyclohexanone can be produced from biomass through the selective hydrogenation of lignin-derived phenolics. Three types of catalysts comprising undoped NbOPO4, 10 wt% NiO/NbOPO4, and 30 wt% NiO/NbOPO4 were studied. Undoped NbOPO4 promoted both aldol condensation and the dehydration of cyclohexanol, producing fused ring aromatic hydrocarbons and hard char. With 30 wt% NiO/NbOPO4, extensive competitive hydrogenation of cyclohexanone to cyclohexanol was observed, along with the formation of C6 cyclic hydrocarbons. When compared to NbOPO4 and 30 wt% NiO/NbOPO4, the use of 10 wt% NiO/NbOPO4 produced superior selectivity towards bi-cycloalkanones (i.e., C12) at cyclohexanone conversion of 66.8 ± 1.82%. Overall, the 10 wt% NiO/NbOPO4 catalyst exhibited the best performance towards the production of precursor compounds that can be further hydrodeoxygenated into energy-dense aviation fuel hydrocarbons. Hence, the presence and loading of NiO was able to tune the activity and selectivity of NbOPO4, thereby influencing the final products obtained from the same cyclohexanone feedstock. This study underscores the potential of lignin-derived pyrolysis oils as important renewable feedstocks for producing replacement hydrocarbon solvents or feedstocks and high-density sustainable liquid hydrocarbon fuels via sequential and selective catalytic upgrading. Full article
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14 pages, 253 KiB  
Article
Marketing and Perceived Value of Differentiated Quality Labels in Extremadura’s Agri-Food Sector
by Alejandro Maya Reyes, Elena Muñoz-Muñoz, Carlos Díaz Caro and Ángel-Sabino Mirón Sanguino
Foods 2025, 14(15), 2707; https://doi.org/10.3390/foods14152707 - 1 Aug 2025
Viewed by 721
Abstract
The present study focuses on the attractiveness and perceived value of differentiated quality labels, such as the Protected Designation of Origin (PDO) and Protected Geographical Indication (PGI), for agri-food products from Extremadura (Spain). In doing so, it addresses a gap in the scientific [...] Read more.
The present study focuses on the attractiveness and perceived value of differentiated quality labels, such as the Protected Designation of Origin (PDO) and Protected Geographical Indication (PGI), for agri-food products from Extremadura (Spain). In doing so, it addresses a gap in the scientific literature concerning consumer behavior toward products bearing these certifications. The results show that awareness of these quality schemes is significantly higher among middle-aged and older individuals, underscoring the need for more modern and targeted communication strategies. The findings highlight the strategic role of agri-food marketing in promoting certified products and emphasize the importance of bridging the generational gap in consumer education. Overall, differentiated quality schemes are perceived as strategic tools to enhance the competitiveness of local products, strengthen cultural identity, and foster sustainable rural economies. Furthermore, this study identifies a negative relationship between the consumption of certified products and the awareness of certification and a positive relationship with the willingness to pay a premium. Consumers with greater awareness tend consume these products less, although they are more willing to pay higher prices for items bearing quality labels. Full article
(This article belongs to the Section Sensory and Consumer Sciences)
17 pages, 5553 KiB  
Article
Effects of Interspecific Competition on Habitat Shifts of Sardinops melanostictus (Temminck et Schlegel, 1846) and Scomber japonicus (Houttuyn, 1782) in the Northwest Pacific
by Siyuan Liu, Hanji Zhu, Jianhua Wang, Famou Zhang, Shengmao Zhang and Heng Zhang
Biology 2025, 14(8), 968; https://doi.org/10.3390/biology14080968 (registering DOI) - 1 Aug 2025
Viewed by 183
Abstract
As economically important sympatric species in the Northwest Pacific, the Japanese sardine (Sardinops melanostictus) and Chub mackerel (Scomber japonicus) exhibit significant biological interactions. Understanding the impact of interspecies competition on their habitat dynamics can provide crucial insights for the [...] Read more.
As economically important sympatric species in the Northwest Pacific, the Japanese sardine (Sardinops melanostictus) and Chub mackerel (Scomber japonicus) exhibit significant biological interactions. Understanding the impact of interspecies competition on their habitat dynamics can provide crucial insights for the sustainable development and management of these interconnected species resources. This study utilizes fisheries data of S. melanostictus and S. japonicus from the Northwest Pacific, collected from June to November between 2017 and 2020. We integrated various environmental parameters, including temperature at different depths (0, 50, 100, 150, and 200 m), eddy kinetic energy (EKE), sea surface height (SSH), chlorophyll-a concentration (Chl-a), and the oceanic Niño index (ONI), to construct interspecific competition species distribution model (icSDM) for both species. We validated these models by overlaying the predicted habitats with fisheries data from 2021 and performing cross-validation to assess the models’ reliability. Furthermore, we conducted correlation analyses of the habitats of these two species to evaluate the impact of interspecies relationships on their habitat dynamics. The results indicate that, compared to single-species habitat models, the interspecific competition species distribution model (icSDM) for these two species exhibit a significantly higher explanatory power, with R2 values increasing by up to 0.29; interspecific competition significantly influences the habitat dynamics of S. melanostictus and S. japonicus, strengthening the correlation between their habitat changes. This relationship exhibits a positive correlation at specific stages, with the highest correlations observed in June, July, and October, at 0.81, 0.80, and 0.88, respectively; interspecific competition also demonstrates stage-specific differences in its impact on the habitat dynamics of S. melanostictus and S. japonicus, with the most pronounced differences occurring in August and November. Compared to S. melanostictus, interspecific competition is more beneficial for the expansion of the optimal habitat (HIS ≥ 0.6) for S. japonicus and, to some extent, inhibits the habitat expansion of S. melanostictus. The variation in migratory routes and predatory interactions (with larger individuals of S. japonicus preying on smaller individuals of S. melanostictus) likely constitutes the primary factors contributing to these observed differences. Full article
(This article belongs to the Special Issue Adaptation of Living Species to Environmental Stress)
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