Search Results (1,288)

Microplastics (MPs) and Antifouling Paint Particles (APPs) are pervasive anthropogenic pollutants that threaten global ecosystems, with distinct yet overlapping environmental behaviors and toxic impacts. MPs disperse widely in aquatic systems via runoff and wastewater; their toxicity stems from physical, chemical, and synergistic effects. APPs are concentrated in coastal zones, estuaries, and shipyard areas, and are acutely toxic due to their high metal and biocide content. This study systematically characterized the composition, concentration, and size distribution of common MPs and APPs in ship-hull derusting wastewater produced by ultra-high-pressure water jetting, using pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) coupled with particle size analysis. The wastewater exhibited a total suspended solids (TSS) concentration of 20.04 g·L⁻¹, within which six types of MPs were identified at 3.29 mg·L⁻¹ in total and APPs were quantified at 330.25 mg·L⁻¹, representing 1.65% of TSS. The residual fraction primarily consisted of algae, biological debris, and inorganic particles. Particle size distribution ranged from 3.55 to 111.47 μm, with a median size (D50) of 31 μm, while APPs were mainly 5–100 μm, with 81.4% < 50 μm. Extrapolation to the annual treated ship-hull surface area in 2024 indicated the generation of ~57,440 m³ wastewater containing ~0.2 tons of MPs and ~19 tons of APPs. These findings highlight the magnitude of pollutant release from ship maintenance activities and underscore the urgent need for targeted treatment technologies and regulatory policies to mitigate microplastic pollution in marine environments. Full article

Long-term wind speed changes over the Yangtze River waterway have critical implications for inland shipping efficiency, emission dispersion, and renewable energy potential. This study utilizes a high-resolution 5 km gridded reanalysis dataset spanning 1979–2018 to conduct a comprehensive spatiotemporal analysis of surface wind climatology, variability, and trends along China’s primary inland waterway. A pivotal regime shift was identified around 2000, marking a transition from terrestrial stilling to a recovery phase characterized by wind speed intensification. Multiple change-point detection algorithms consistently identify 2000 as a pivotal turning point, marking a transition from the late 20th century “terrestrial stilling” to a recovery phase characterized by wind speed intensification. Post-2000 trends reveal pronounced spatial heterogeneity: the upstream section exhibits sustained strengthening (+0.02 m/s per decade, p = 0.03), the midstream shows weak or non-significant trends with localized afternoon stilling in complex terrain (−0.08 m/s per decade), while the downstream coastal zone demonstrates robust intensification exceeding +0.10 m/s per decade during spring–autumn daytime hours. Three distinct wind regimes emerge along the 3000 km corridor: a high-energy maritime-influenced downstream sector (annual means > 3.9 m/s, diurnal peaks > 6.0 m/s) dominated by sea breeze circulation, a transitional midstream zone (2.3–2.7 m/s) exhibiting bimodal spatial structure and unique summer-afternoon thermal enhancement, and a topographically suppressed upstream region (<2.0 m/s) punctuated by pronounced channeling effects through the Three Gorges constriction. Critically, the observed recovery contradicts widespread basin greening (97.9% of points showing significant positive NDVI trends), which theoretically should enhance surface roughness and suppress wind speeds. Correlation analysis reveals that wind variability is systematically controlled by large-scale atmospheric circulation patterns, including the Northern Hemisphere Polar Vortex (r ≈ 0.35), Western Pacific Subtropical High (r ≈ 0.38), and East Asian monsoon systems (r > 0.60), with distinct seasonal phase-locking between baroclinic spring dynamics and monsoon-thermal summer forcing. These findings establish a comprehensive, fine-scale climatological baseline essential for optimizing pollutant dispersion modeling, and evaluating wind-assisted propulsion feasibility to support shipping decarbonization goals along the Yangtze Waterway. Full article

This study focuses on the diversity of phytoplankton in the Koh Yaa region of Thailand and their relationship with environmental variables, aiming to assess whether human activities (primarily tourism) pose potential threats to the marine ecosystem and provide scientific support for eco-sustainable tourism management decisions in the region. In April, August, and December 2024, corresponding to peak season, off-season, and shoulder season, a total of 156 discrete samples were collected from four coastal sites to analyze water quality parameters such as temperature, pH, total nitrogen (TN), and total phosphorus (TP), along with plankton diversity and abundance. Statistical analyses including two-way ANOVA with Duncan’s Multiple Range Test (DMRT), Pearson correlation analysis, and principal component analysis (PCA) were applied. The results showed a declining trend in plankton abundance over time, peaking at 1009 × 10⁶ cells/m³ in April and dropping to 281 × 10⁶ cells/m³ by December. A total of 15 types of phytoplankton were identified across four phyla: Bacillariophyta, Cyanobacteria, Dinoflagellata, and Chlorophyta. Notably, Chaetoceros from Bacillariophyta accounted for 47% of phytoplankton, while Oscillatoria from Cyanobacteria made up 29.6%. The diversity index and evenness index improved from 1.34 and 0.46 in April to 1.88 and 0.64 in December, respectively. Environmental factors like pH, temperature, and TP significantly affected phytoplankton abundance (p < 0.01), with TP levels ranging from 0.27 to 0.69 mg/L. These results indicate possible pollution in this region, and changes in phytoplankton abundance were linked to seasonal climate variations—especially during peak tourist seasons—which may exacerbate eutrophication affecting community structures. Full article

The seasonal dynamics, sources, and ecological risks of polycyclic aromatic hydrocarbons (PAHs) in inland freshwater ports remain largely limited, despite extensive research on coastal port PAH pollution. Here, we investigated sixteen U.S. EPA priority PAHs in surface waters of Jiujiang Port, a major inland hub along the Yangtze River, China. Total PAH concentrations ranged from 21.8 to 121.0 ng·L⁻¹ (mean: 65.0 ng L⁻¹), which represents relatively low levels compared with coastal ports worldwide. In this study, significant seasonal variations were also observed, with higher concentrations during the dry season than the wet season. Diagnostic ratios and multivariate analyses indicated petroleum combustion as the dominant source, while PAH levels showed positive correlations with turbidity and COD_Mn, underscoring the role of suspended particulates and organic load. Ecological risk assessment revealed low to moderate risks, with elevated risks in the dry season. These findings provide novel insights into PAH pollution in inland port systems and offer a scientific basis for pollution control and ecological management under the Yangtze River Protection framework. Full article

The Santos Estuarine System, one of the most anthropogenically impacted coastal regions in Brazil, was studied using benthic foraminiferal assemblages to determine four distinct stages of organic pollution. Predictive models combined with the Ecological Quality Status (EcoQs) index were applied to relate pollution stages to abiotic parameters (total organic carbon, mud content, and salinity variability) and organic contaminants, including aliphatic (AHs) and aromatic hydrocarbons (PAHs), linear alkylbenzenes (LABs), and coprostanol. The pollution gradient ranged from low (São Vicente Channel and Santos Bay, characterized by Ammonia tepida and medium coprostanol concentrations), to moderate (Santos Channel, with Bulimina elongata and Triloculina sp.1), high (Bertioga Channel, showing Cribroelphidium poeyanum, Paratrochammina sp.1, high levels of LABs, and TOC), and severe (Upper Estuary, marked by Ammonia sp.1 and high concentrations of PAHs and coprostanol). A linear discriminant analysis (LDA) demonstrated an overall accuracy of 70%, suggesting that the discriminant model performs reasonably well in predicting the predictive ability of foraminifera species to distinguish between areas with varying pollution status based on organic pollutants. Also, the potential use of the EcoQs index in assessing the environmental quality of a subtropical estuary subjected to organic pollution was demonstrated. Full article

The coexistence of plastics and metal-based materials in aquatic systems introduces complex interfacial processes that influence pollutant speciation and mobility. This study investigates the role of polystyrene (PS) in promoting UV-induced dissolution of ZnO and Cu₂O in aqueous media, revealing a plastic-mediated pathway for metal ion mobilization. Post-use expanded PS fragments were co-dispersed with the oxides and irradiated at 254 nm for 24 h. Ion concentrations were quantified by ICP-MS, while PS morphology and chemistry were characterized by SEM, EDX, FTIR, Raman, and DSC. The presence of PS markedly enhanced metal release, bringing Zn²⁺ from 29.9 to 50.6 ppm and Cu²⁺ from 1.1 to 26.5 ppm under irradiation, compared to minimal dissolution in the dark. Spectroscopic analyses indicated negligible polymer degradation, suggesting that enhanced dissolution arises from interfacial photooxidation and associated redox/pH microgradients at the polymer–oxide boundary. These findings demonstrate that PS may serve as a catalytic interface that accelerates UV-driven dissolution of otherwise poorly soluble metal oxides. This mechanism expands current understanding of plastic–pollutant interactions and has implications for predicting metal bioavailability and designing strategies to mitigate pollutant release in sunlit marine and coastal environments. Full article

This study investigated the site-specific ionic composition and wet deposition loads of rainwater collected from eight actively cultivated agricultural regions across South Korea, with the aim of quantifying spatial and seasonal variability and interpreting how regional agricultural characteristics and surrounding site conditions influence major ion concentrations and deposition patterns. Rainfall samples were obtained using automated samplers and analyzed via high-performance ion chromatography for major cations (Na⁺, $\mathrm{N}{\mathrm{H}}_4^{+}$, K⁺, Ca²⁺, Mg²⁺) and anions (Cl⁻, $\mathrm{N}{\mathrm{O}}_3^{-}$, $\mathrm{S}{\mathrm{O}}_4^{2-}$, $\mathrm{N}{\mathrm{O}}_2^{-}$). The results revealed significant seasonal fluctuations in ion loads, with $\mathrm{N}{\mathrm{H}}_4^{+}$ (peak 1.13 kg/ha) and K⁺ (peak 0.25 kg/ha) reaching their highest levels during summer due to increased fertilizer use and crop activity. Conversely, Cl⁻ peaked in winter (2.11 kg/ha in December), particularly in coastal regions, likely influenced by de-icing salts and sea-salt aerosols. Correlation analysis showed a strong positive association among $\mathrm{N}{\mathrm{H}}_4^{+}$, $\mathrm{N}{\mathrm{O}}_3^{-}$, and $\mathrm{S}{\mathrm{O}}_4^{2-}$ (r = 0.89 and r = 0.84, respectively), indicating shared atmospheric transformation pathways from agricultural emissions. Ternary diagram analysis further revealed regional distinctions: coastal regions such as Gimhae and Muan exhibited Na⁺ and Cl⁻ dominance, while inland areas like Danyang and Hongcheon showed higher proportions of Ca²⁺ and Mg²⁺, reflecting differences in aerosol sources, land use, and local meteorological conditions. These findings underscore the complex interactions between agricultural practices, atmospheric processes, and local geography in shaping rainwater chemistry. The study provides quantitative baseline data for evaluating non-point source pollution and developing region-specific nutrient and soil management strategies in agricultural ecosystems. Full article

Anthropogenic increases in nitrogen and phosphorus inputs have intensified coastal water pollution, leading to economic losses and even threats to human health. Dissolved Inorganic Nitrogen (DIN) and Dissolved Inorganic Phosphorus (DIP), as key indicators of water quality, are essential for formulating environmental protection strategies. While deep learning has advanced the retrieval of these nutrients in coastal waters, existing models remain constrained by limited accuracy, insufficient interpretability, and poor regional transferability. To address these issues, we developed a Transformer-based model for retrieving DIN and DIP in the Jiangsu-Zhejiang-Shanghai (JZS) Offshore, integrating satellite observations with reanalysis data. Our model outperformed previous studies in this region, achieving high retrieval accuracy for DIN (R² = 0.88, RMSE = 0.16 mg/L, and MAPE = 33.69%) and DIP (R² = 0.85, RMSE = 0.007 mg/L, and MAPE = 31.59%) with strong interpretability. Based on this model, we generated a long-term (2005–2024) dataset, revealing clear seasonality and spatial patterns of DIN and DIP. Specifically, the concentrations have a distinct seasonal cycle with winter minima and autumn maxima, as well as estuarine-to-offshore decreasing gradient. Water quality assessment further showed that the areal extent of medium-to-high eutrophic waters increased by 3.94 × 10² km²/yr (2005–2016) but decreased by 4.45 × 10² km²/yr (2016–2024). Overall, the proposed Transformer-based framework provided a robust, accurate, and interpretable tool for nitrogen and phosphorus nutrient retrieval, supporting sustainable management of marine water quality in the JZS coastal ecosystems. Full article

The mangrove ecosystems in Muara Angke, Jakarta, serve as a national benchmark for sustainable mangrove management in Indonesia, yet face significant urban pressures threatening their long-term viability. This study evaluates the ecological integrity and governance effectiveness of this critical ecosystem, covering Wildlife Reserve, Nature Park, Protected Forest, and Production Forest areas totaling 327.7 hectares. An exploratory mixed-methods approach was employed over four months (June–September 2025), integrating vegetation diversity assessments through plot sampling, avifauna surveys via point count methods, herpetofauna identification using Visual Encounter Surveys, water quality assessments through systematic literature review, geospatial analysis of mangrove dynamics using Sentinel-2A imagery (2015–2025), and social-governance evaluation using close-ended questionnaires and One Score One Criteria Scoring System. Results revealed moderate to severe water pollution with phosphate and nitrate exceeding standards, moderate vegetation diversity (13 species; Shannon-Wiener H′ = 1.466–1.728), high avifaunal diversity (55 species; H′ = 3.54) confirming significance along the East Asian-Australasian Flyway, and significant sediment accretion (32 hectares) attributed to coastal reclamation. Management evaluation identified critical conservation compliance deficiencies (score 1.43/7). The findings indicate urgent need for integrated interventions including pollution control, ecosystem-based restoration, enhanced monitoring, and cross-sector policy integration to prevent rapid mangrove degradation and ensure sustainability of this ecologically significant urban mangrove ecosystem. Full article

The problem of adequate quantitative analysis of anthropogenic film pollution of water areas according to synthetic aperture radar (SAR) satellite imagery is addressed here. A quantitative analysis of anthropogenic film pollution (AFP) in the studied coastal water areas of the north sector of the Black Sea and Avacha Gulf has been conducted. The analysis utilized a method that involved the statistical processing of data related to AFP identified within the cells of a regular spatial grid. Time series of Sentinel-1 SAR satellite imagery were used as initial data. Spatiotemporal distributions of the proposed quantitative criterion (e_AFP, ppm) have been calculated and analyzed. This criterion characterizes the intensity of AFP impact within the selected regions of marine waters based on measuring the relative frequency of an AFP event. Among them, the area of the emergency fuel oil spill that occurred in 2024–2025 near the Kerch Strait was investigated (e_AFP values near the wreckage of tankers reached ~13,000 ppm), as well as the area of the emergency oil spill near the Novorossiysk terminal that occurred in 2021 (e_AFP ≤ 6000 ppm). Accidents led to an approximately 3–6-fold increase in e_AFP values against the background level of 0–2000 ppm. The spatiotemporal variability of e_AFP across various water areas and under different conditions has been demonstrated and discussed. Full article

This study investigates the atmospheric corrosion behavior of zinc in tropical marine environments affected by hydrogen sulfide (H₂S), particularly from the decomposition of stranded Sargassum algae. Four exposure sites in Martinique with varying levels of H₂S and marine chlorides were selected. Gravimetric analysis showed that zinc thickness loss reached up to 45 µm after one year at the most impacted site (Frégate Est), compared to only 3–10 µm at less contaminated locations. This degradation level classifies the site as “extremely corrosive” according to ISO 9223. Electrochemical impedance spectroscopy (EIS) and linear polarization measurements revealed distinct corrosion behaviors. After 12 months of exposure, the polarization resistance and corrosion current density reached R_p = 916 Ω·cm² and I_corr = 28 µA·cm² at the Frégate Est site and R_p = 1835 Ω·cm² and I_corr = 6 µA·cm² at the Vauclin site. In H₂S-poor environments (Diamant, Vert-Pré, Vauclin), corrosion resistance increased over time due to the formation of protective layers such as hydrozincite and simonkolleite. In contrast, H₂S-rich environments favored the formation of sulfur-based compounds like elemental sulfur and zinc sulfide (ZnS), which exhibit poor protective properties and result in lower polarization resistance and higher corrosion current densities. Polarization curves confirmed a general decrease in anodic and cathodic currents over time, with less significant improvements in passivation at H₂S-impacted sites. The corrosion mechanism is influenced by both pollutant type and exposure duration. Overall, this study highlights the synergistic effect of H₂S and chlorides on accelerating zinc corrosion and underscores the need for adapted protection strategies in tropical coastal zones affected by Sargassum proliferation. Full article

This study investigates the effectiveness of cold atmospheric plasma (CAP) treatment for improving the microbiological and physicochemical quality of wastewater generated in tourism-affected coastal regions. Experiments were performed on influent and effluent samples from the Ravda Wastewater Treatment Plant (WWTP) collected in April, August, and November 2024, representing different seasonal loading conditions. The plasma pre-treatment of influent aimed to minimize toxic micropollutants that inhibit activated sludge activity, reduce pathogenic and opportunistic microorganisms, and enhance oxidative potential before biological processing. The post-treatment of effluent focused on the elimination of residual pathogens, mainly Enterobacteriaceae, and the oxidative degradation of xenobiotics resistant to conventional treatment. Combined fluorescent (CTC/DAPI) and culture-based analyses were used to assess microbial viability and activity. Plasma exposure (1, 3 and 5 min) caused measurable changes in metabolic potential and bacterial abundance across all sampling periods. The results demonstrate that 1 min CAP treatment does not increase pathogen removal, but enhances oxidation capacity of the influent, while 3 min of CAP treatment ensures the disinfection of the effluent. Both can be combined to improve the effluent safety prior to Black Sea discharge. CAP is showing strong potential as a sustainable technology for wastewater management in tourism-intensive coastal zones. Full article

Air pollution from ship operations can pose a significant challenge for coastal cities, particularly where ports are closely integrated into the urban fabric. This study examines the influence of ship docking on PM_2.5 concentrations in Chios, Greece, a medium size island city where the port directly borders densely populated neighbourhoods. Calibrated PurpleAir sensors were installed at urban and suburban sites to measure PM_2.5, with data analysed alongside ship call records and meteorological observations. An event-based concentration enhancement metric (%ΔC) was estimated to compare PM_2.5 during docking with the preceding 3 h background for 170 ship arrivals in February and August 2022. The results showed that under prevailing northerly winds in August, PM_2.5 at the downwind urban site increased on average by 5.0 µg m⁻³ (48%), whereas winter increments were smaller (6.1%) due to higher background variability. When both seasons and all wind directions were pooled, the urban site exhibited a mean enhancement of 1.7 µg m⁻³ (19%), while impacts at the suburban site remained minor (3%). Median-based uncertainty analysis confirmed robust enhancements under northerly winds only. Wind direction and wind speed were the primary controls on %ΔC, whereas ship engine power and time at berth had limited influence. The results suggest that ship-related PM_2.5 impacts are detectable but remain spatially and temporally limited in coastal urban environments, including medium-sized islands characterised by relatively low shipping activity. Full article

This study examines the occurrence of bacteria resistant to antibiotics and heavy metals in Terra Nova Bay, a coastal area of the Ross Sea in Antarctica that is increasingly recognised as vulnerable to human influence. During the 37th Italian Antarctic Expedition (2021–2022), researchers collected seawater, sediment, and fish samples from the notothenioid species Trematomus bernacchii to evaluate microbial resistance in an environment once considered largely pristine. Fifty heterotrophic bacterial isolates were obtained and tested against twenty-eight antibiotics, revealing a notable presence of multidrug resistance. These multidrug-resistant isolates were then assessed for their tolerance to eight heavy metal salts to understand whether resistance traits extended beyond antimicrobials. Twelve isolates showing resistance to both antibiotics and metals were selected for further genetic screening, targeting key resistance genes linked to tetracycline, vancomycin, sulphonamides, and other antimicrobial classes. The detection of multiple resistance genes in genera such as Pseudomonas, Pseudoalteromonas, and Psychrobacter indicates that both natural selective pressures and local, human-related contamination may be shaping resistance patterns in this region. Overall, the study demonstrates that even remote Antarctic marine ecosystems can host bacteria with complex resistance profiles. While these ecosystems are largely isolated, human activities such as scientific research, tourism, and the introduction of pollutants may contribute to the dissemination of antibiotic resistance genes, raising important ecological and potential public health considerations regarding the spread of resistance in polar environments. Full article

The Xiaohai Lagoon is a vital coastal ecosystem that has faced decades of significant natural and anthropogenic pressures. This study investigated the spatio-temporal dynamics its phytoplankton communities through quarterly sampling from 2024 to 2025. Significant spatial and seasonal variations (p < 0.05) in physicochemical parameters were observed. The concentrations of various physicochemical parameters were highest at the lagoon mouth and decreased inwards. In contrast, sites inside the lagoon experienced elevated nutrient and organic matter indicators. Seasonally, the highest temperatures were recorded in Summer. However, Autumn recorded the highest NH₃-N and NO₂-N levels, while Winter recorded the highest NO₃-N levels. The findings generally suggest minimal pollution, as key physicochemical parameters, met the China water quality standard for environmental protection (GB 3838–2002). Overall, 109 phytoplankton species belonging to 38 genera and 5 phyla, including Cyanophyta, Bacillariophyta, Chlorophyta, Cryptophyta, and Dinophyta, were identified. The phytoplankton average density was 1.65 × 10³ Ind L⁻¹ with insignificant differences both spatially and seasonally (p > 0.05). One-way ANOSIM indicated significant seasonal dissimilarity in phytoplankton community composition (R = 0.828, p < 0.001), with SIMPER results revealing that Ceratocorys sp., Chaetoceros sp., Coscinodiscus subtilis, Oscillatoria princes, and Thalassionema nitzschioides contributed to the seasonal difference. CCA indicated phytoplankton composition and abundance were influenced by COD, TN, TDS, salinity, oxidation-reduction potential, EC, water temperature, NH₃-N, and NO₃-N. This study highlights the critical need for effective management strategies to protect and preserve the ecological integrity of Xiaohai Lagoon. Full article