Search Results (81)

All-solid-state lithium–sulfur batteries (ASSLSBs) couple the high theoretical energy density of sulfur (2600 Wh kg⁻¹) with the safety and polysulfide-shuttle suppression advantages of solid electrolytes (SEs). In practice, however, sluggish solid-state conversion kinetics, chemo-mechanical degradation in composite cathodes, and large solid–solid interfacial resistance remain the principal barriers to practical implementation. This review systematically examines recent progress across the three key components of ASSLSBs: cathodes, solid electrolytes, and interfaces. For cathodes, S/C composite design strategies and alternative active materials—including Li₂S, metal sulfides, and organosulfur compounds—are discussed. For solid electrolytes, inorganic (sulfide, oxide, halide, and hydride), polymer, and hybrid composite systems are compared. For interfaces, physical strategies (stack pressure, compliant interlayers, three-dimensional cathode architectures) and chemical strategies (cathode–SE and Li metal–SE interphase engineering, in situ stabilization) are evaluated. Outstanding challenges and design guidelines for next-generation ASSLSBs are discussed. Full article

The UHV dry-type bushing plays a critical role in power transmission by enabling electrical connection, electrical insulation, and mechanical support, making it a core component for ensuring the safe and stable operation of UHV direct current (DC) transmission projects. Epoxy resin, serving as the fundamental insulating material for the bushing core, undergoes significant residual strain during high-temperature curing due to chemical shrinkage and thermal strain, which directly affects the molding quality and service reliability of the component. This paper investigates the curing process of a large-thickness epoxy material, which is on the same scale as a UHV bushing. An in situ monitoring system combining fiber Bragg grating (FBG) sensors and thermocouples, together with COMSOL Multiphysics simulations, is employed to systematically study the evolution of the temperature field and residual strain throughout the entire curing process, considering the demolding effect. The results show that during the curing stage, the internal temperature distribution is non-uniform, with a maximum temperature difference of 65 °C between the center and the edge. The residual strain is dominated by chemical shrinkage (accounting for 73.25%) and exhibits a pronounced radial gradient. Mold constraint and demolding cause abrupt changes in the strain. The developed thermo-chemo-mechanical coupled model shows good agreement between simulations and experimental measurements. Thermal cycling relaxes the residual stress, achieving a reduction of 3.89–5.77%. This study provides support for process optimization and defect prevention in large-scale epoxy insulation components. Full article

Cementitious materials in the fresh state are commonly regarded as viscoplastic. That is, below a given yield stress, they exhibit solid-like behavior, whereas above this threshold, they behave as fluids. In this context, the shear strength of such materials has traditionally been analyzed from a rheological standpoint, considering them as fluids and using time as the primary state variable. From a structural perspective, however, relatively few studies have treated the material as a solid. With the advent of 3D printing technology, this trend has persisted. Within this framework, the present research aims to evaluate the shear strength of a structural mortar for 3D printing in its solid-like regime, by applying the Mohr–Coulomb failure criterion. Furthermore, in a novel approach, the degree of hydration of Portland cement is proposed as a state variable to replace time, enabling a more comprehensive and objective description of the material’s mechanical evolution. Thus, addressing this gap in the state of the art, a chemo-mechanical coupling is developed. To obtain the necessary data, direct shear, uniaxial compression, and isothermal calorimetry tests are performed. The results indicate that the friction angle remains constant, at approximately 33°, and that cohesion, the parameter governing strength gain, exhibits the same linear rate of increase with hydration in both mechanical tests, indicating an intrinsic relationship within the material. Full article

The sealing behavior of fracture-filling minerals in the near-field of the deep geological repository (DGR) is critical for the safe disposal of high-level radioactive waste (HLW). In granite host rocks, natural fractures are often filled with polymineralic assemblages of calcite, quartz, and clay minerals; however, their coupled compaction–pressure solution mechanisms under thermal–hydraulic–mechanical–chemical (THMC) conditions remain poorly understood. In this study, 12 fracture sealing tests were conducted on Beishan granite and its typical fracture fillings at 90 °C and 15 MPa effective stress, using different pore fluids and systematically varying grain size (75–250 μm), mineral proportions, and clay content. The results indicate that stress-assisted dissolution–precipitation of calcite in saturated CaCO₃ solution is a key process contributing to porosity reduction and chemo-mechanical densification of the fracture filling, achieving a compaction strain of 24.6%—substantially higher than those obtained in deionized water (20.6%) and under dry conditions (14.8%). Fine-grained calcite compacts more effectively than its coarse-grained counterpart, reaching a porosity as low as 4.8%; rigid quartz locally redistributes contact stress at quartz–calcite interfaces, promoting preferential deformation or dissolution of adjacent calcite, although increasing quartz abundance reduces the bulk compaction efficiency. A moderate amount of clay minerals (~20 wt%) further reduces porosity to 2.1% through lubrication and micropore filling. The study reveals a multi-stage process transitioning from mechanical compaction to chemo-mechanical sealing, and a synergistic mechanism dominated by calcite compaction–pressure solution, augmented by quartz stress redistribution and clay lubrication. These findings provide direct experimental evidence for the progressive chemo-mechanical densification of mineral-filled granite fractures, and offer quantitative constraints for long-term THMC modeling of fracture sealing behavior in HLW repositories. Full article

Reinjection represents a fundamental strategy for sustainable geothermal reservoir development. During reinjection, reservoirs are subjected to pronounced physicochemical disequilibrium, under which complex water–rock interactions render long–term behavior difficult to predict. This review synthesizes mineral reactions and reservoir dynamic responses from a geochemical perspective. The interplay between reaction kinetics and fluid transport is examined using the Damköhler number, elucidating the spatiotemporal evolution of reactive transport. The dissolution–precipitation behaviors of silicate, carbonate, and sulfate minerals are evaluated, highlighting their distinct roles in governing long–term structural reorganization, short–term permeability variability, and rapid clogging. The influence of mineral reactions on pore structure evolution and the development of nonlinear porosity–permeability relationships is examined, alongside commonly used constitutive models and their inherent limitations. Multiscale characterization approaches for porosity–permeability evolution and the distinct responses of different reservoir types are reviewed. The chemo–mechanical coupling induced by water–rock interactions and its implications for reservoir stability are addressed. This work establishes a unified conceptual framework linking mineral reactions, fluid transport, and reservoir evolution, providing a basis for optimizing reinjection strategies and improving long–term geothermal system performance. Full article

Robotic tactile interfaces involving artificial skins often experience sliding contact conditions. At sliding interfaces, frictional loading, tangential stress, and impending slip dominate sensing behavior. This work demonstrates three-dimensional finite element (3D-FE) and Poisson–Nernst–Planck (PNP) modeling of layered ionic polymer–metal composite (IPMC) artificial skin under finger-like reciprocating sliding contact. The layered structure consists of a Nafion-based IPMC core sandwiched between thin upper and lower electrodes. A rigid acrylic slider is used to simulate reciprocating finger motion relative to the surface of the IPMC skin. A time-dependent contact mechanics model is first utilized to simulate temporal variations in normal and tangential contact fields for various coefficients of friction. Electrochemical response is then determined in COMSOL Multiphysics by coupling ion transport and electrostatics in a PNP framework to predict the output sliding current. Parametric studies are used to investigate the dependence of sensor response on the coefficient of friction, reciprocating history, layer geometry, and transport parameters. From the results, it can be noted that the resulting parameter offers a robust and physically meaningful description of the magnitude of contact-induced shear stress under multi-mode loadings, yet retaining the capability of responding to the presence of friction-induced mechanical excitation. The current model is aimed at dynamic shear sensitivity detection in sliding contacts. It is not designed for texture discrimination or fragment identification tasks. Thus, the current study demonstrates an important coupling parameter for 3D IPMC sensor models under contact and sets up a framework for enhanced electro-chemo-mechanical modeling of soft ionic tactile sensors. Full article

Polyamide (PA) is widely used as a high-performance engineering thermoplastic in automotive components and textiles, due to its superior mechanical strength and chemical resistance. However, the increase in PA waste has posed significant challenges to resource sustainability and environmental protection. Despite breakthrough development achieved in PA recycling, key barriers remain in process scale-up and high-value recovery. This review examines the current state of PA recycling, analyzing the research prospects of mechanical and chemical recycling from economic feasibility and environmental impact. We present discussions on innovative recycling approaches for PA, including upcycling, molecular design of novel PA derivatives, chemo-biological coupling and solvent-based recovery, offering potential solutions to the sustainable circular economy and green cycles. Finally, by presenting case studies, we highlight pathways toward future innovation that inform industrial-scale implementation. Full article

High-temperature Solid Oxide Fuel Cells (SOFCs) typically operate under conditions involving repeated thermal cycling. The transient temperature rise during thermal cycling directly affects the stress distribution within the SOFC structure, particularly inducing non-uniform thermal stresses in the electrolyte layer. This can readily lead to cracking and fracture of the SOFCs, potentially degrading overall system performance. Therefore, investigating the effects of cyclic thermal loading on structural stress distribution is essential for optimizing SOFC design. To this end, this study developed a coupled thermo-chemo-mechanical finite element analysis for a planar tubular SOFC. The model is employed to analyze the influence of thermal impact on the thermal stress distribution within the cell structure under multiple thermal cycling conditions. The results indicate that both the transient temperature rise during SOFC operation and the number of thermal cycles significantly affect the peak stress in the electrolyte layer and the overall performance stability of the cell. By optimizing the geometric configuration of the flat-tubular and the transient temperature rise during thermal cycling, the thermal stress field distribution in the electrolyte can be improved. These findings provide theoretical guidance for optimizing the design and engineering application of high-temperature SOFCs. Full article

Deep-sea gear transmission systems encounter critical lubrication challenges arising from the synergistic coupling of extreme hydrostatic pressure and cryogenic temperatures. These environmental stressors induce exponential viscosity escalation in lubricants, precipitating severe fluidity degradation, elevated startup resistance, and lubrication starvation. Concurrently, seawater intrusion triggers lubricant emulsification, additive deactivation, and electrochemical corrosion at meshing interfaces, collectively escalating the risk of catastrophic lubrication failure and compromising long-term operational reliability. This study systematically elucidates the lubrication degradation mechanisms inherent to deep-sea environments and proposes targeted mitigation strategies. Through comprehensive characterization of deep-sea environmental parameters and their impact on lubricant rheological behavior, we critically evaluate the applicability and inherent limitations of conventional Thermal Elasto-Hydrodynamic Lubrication (TEHL) theory under extreme conditions. Our analysis reveals that established TEHL frameworks necessitate substantial modification to accurately capture pressure-viscosity-temperature coupling phenomena and seawater contamination kinetics. Meshing interface texturing, as an effective anti-friction and wear-mitigation strategy, is investigated to delineate its mechanistic pathways for enhancing lubricant film formation and tribological performance under starved lubrication regimes. Key findings demonstrate that optimized micro-texture architectures can effectively compensate for viscosity-induced fluidity deficits and attenuate the deleterious effects of seawater ingress. Critical knowledge gaps are identified, and future research trajectories are charted: (i) multiphysics coupling models integrating thermo-hydrodynamic, chemo-physical, and mechanical degradation processes; (ii) synergistic texture-coating design paradigms; (iii) high-pressure low-temperature experimental validation protocols; and (iv) engineering implementation frameworks for deep-sea gear transmission systems. This review establishes theoretical foundations and provides technical guidelines for robust lubrication design and long-term operational stability of deep-sea transmission equipment. Full article

Module- and pack-level mechanical design of lithium-ion batteries in electric vehicles is a primary driver of swelling-induced stack pressure and spatially varying ageing. Current practice remains largely empirical or data-driven and configuration-specific, limiting the ability to predict how design changes translate into local pressure heterogeneity and state-of-health (SOH) loss. This motivates a compact chemo-mechanical model that maps packaging boundary conditions to pressure, swelling, and SOH evolution with few interpretable parameters. This study introduces finite-element-ready constitutive laws that couple reversible and irreversible swelling to SOH and through-thickness pressure, covering three boundary cases reported in literature: constant pressure, thickness clamp after an initial preload, and flexible support. Parameters are identified from different published datasets, and the model is validated against independent constraint scenarios. Good quantitative agreement is shown with averaged RMSE of 1.16% for SOH and 0.16 [MPa] for pressure evolution. Variance-based sensitivity analysis shows SOH uncertainty dominated by the damage-law parameters of the proposed constitutive relationship, whereas pressure evolution is primarily controlled by irreversible swelling and the non-linear through-thickness stiffness, indicating calibration priorities for engineering design studies. The framework is intended for fast comparative analyses of individual cells under a controlled environment. Further extensions, including SOC-dependent mechanics, refined hysteresis, temperature, and C-rate variations require dedicated datasets and are left for future work. Full article

Land degradation in drylands increasingly threatens infrastructure and the performance of renewable energy (RE) systems through coupled hydro-chemo-mechanical changes in soil fabric, density, matric suction, and pore–water chemistry. A key gap is the limited integration of unsaturated soil mechanics with practical indicator sets used in engineering screening and operations. This narrative review synthesizes evidence from targeted searches of Scopus, Web of Science, and Google Scholar. Searches are complemented by key organizational reports and standards, as well as citation tracking. Priority is given to sources that report mechanisms linked to measurable indicators, thresholds, tests, or models relevant to dryland infrastructure. The synthesis uses the soil-water characteristic curve (SWCC) and hydraulic conductivity k(θ) to connect hydraulic state to strength and deformation and couples these with chemical indices, including electrical conductivity (EC), exchangeable sodium percentage (ESP), and sodium adsorption ratio (SAR). Practical diagnostics include the dynamic cone penetrometer (DCP) and California Bearing Ratio (CBR) tests, infiltration and crust-strength tests, monitoring with unmanned aerial vehicles (UAVs), geophysics, and in situ moisture and suction sensing. The contribution is an indicator-driven, practice-oriented framework linking mechanisms, monitoring, and mitigation for photovoltaic (PV), concentrating solar power (CSP), wind, transmission, and well-pad corridors. This framework is implemented by consistently linking unsaturated soil state (SWCC, k(θ), and matric suction) to degradation processes, measurable indicator/test sets, and trigger-based interventions across the review. Full article

Spontaneous liquefaction in the Lusatian lignite dump sites has raised significant geotechnical and environmental concerns. While mechanical influences have been extensively studied, hydrochemical investigations suggest an inner initial that is highly correlated to CO₂ generation, attributed to buffering reactions, which lays the foundation for this study. This study aims to understand the process behind and to quantify the transient evolution of excess pore-pressure induced by CO₂ accumulation, both dissolved and as free gas, in saturated medium using a series of column experiments. Excess pore-pressures up to 7.7 kPa were recorded following a period of buffering reaction, with discharged gas confirmed as CO₂. The results demonstrate that the buffering process strongly influences the elevated pressure, while, in turn, elevated pressures affect the chemical conditions within the column. Secondary mineral precipitation, as one of the effects, was observed to reduce buffering reactivity and modify pore structure, thereby altering pore-pressure response. These findings highlight hydrochemical feedback as critical internal triggers and amplifiers in liquefaction events, complementing mechanical explanations and advancing understanding of coupled hydro-chemo-mechanical processes in dump site stability. Full article

Improving the energy efficiency of advanced ultra-supercritical (USC) power plants by increasing steam operating temperature up to 700 °C can be achieved, at reduced cost, by using novel engineering design concepts, such as coated steam pipe systems manufactured from high temperature materials commonly used in current operational power plants. The durability of thermal barrier coatings (TBC) in advanced USC coal power systems is critically influenced by thermally grown oxide (TGO) evolution and interfacial stress under thermo-chemo-mechanical coupling. This study investigates a novel dual-pipe coating system comprising an inner P91 steel pipe with dual coatings and external cooling, designed to mitigate thermal mismatch stresses while operating at 700 °C. A finite element framework integrating thermo-chemo-mechanical coupling theory is developed to analyze TGO growth kinetics, oxygen diffusion, and interfacial stress evolution. Results reveal significant thermal gradients across the coating, reducing the inner pipe surface temperature to 560 °C under steady-state conditions. Oxygen diffusion and interfacial curvature drive non-uniform TGO thickening, with peak regions exhibiting 23% greater thickness than troughs after 500 h of oxidation. Stress analysis identifies axial stress dominance at top coat/TGO and TGO/bond coat interfaces, increasing from 570 MPa to 850 MPa due to constrained volumetric changes and incompatible growth strains. The parabolic TGO growth kinetics and stress redistribution mechanisms underscore the critical role of thermo-chemo-mechanical interactions in interfacial degradation. These research findings will facilitate the optimization of coating architectures and the enhancement of structural integrity in high-temperature energy systems. Meanwhile, clarifying the stress evolution within the coating can improve the ability to predict failures in USC coal power technology. Full article

In lithium-ion battery electrodes, repeated lithium insertion and extraction generate compositional gradients and volumetric changes that produce evolving stress fields and eigenstrains, accelerating mechanical degradation. While existing diffusion-induced stress models often capture only elastic behavior, they rarely provide a closed-form analytical treatment of irreversible deformation or its connection to cyclic degradation. In this work, a transparent analytical framework is developed for a planar electrode that explicitly couples lithium diffusion with elastic-plastic deformation, eigenstrain formation, and fracture-aware stress relaxation. The framework provides a means to quantitatively model the evolution of residual stress gradients, revealing the formation of a damaging tensile state at the electrode surface after delithiation and demonstrating how path-dependent irreversible deformation establishes a degradation memory. A parametric study is used to demonstrate the framework’s capability to clarify the influence of diffusivity and yield strength on residual stress development. This framework, which unifies diffusion, plasticity, and fracture in closed-form mechanical relations, provides new physical insight into the origins of chemo-mechanical degradation and offers a computationally efficient tool for guiding the design of durable next-generation electrode materials where chemo-mechanical strains are moderate. Full article

This work investigates the role of preload pressure in governing the electro-chemo-mechanical (ECM) behavior of lithium iron phosphate (LFP)/graphite pouch cells during calendar aging. Cells aged at 60 °C under different preload levels were systematically evaluated through in situ monitoring of force evolution and capacity retention. To interpret these behaviors, a coupled model was developed that integrates solid electrolyte interphase (SEI)-induced electrode expansion, viscoelastic relaxation, and stiffness evolution, and it was validated against multi-rate discharge experiments, showing excellent agreement with measured voltage and force responses. The results reveal that higher preload amplifies internal pressure fluctuations, prolongs viscoelastic relaxation, and delays irreversible force recovery, while the overall capacity fade remains largely unaffected. A slight mitigation in capacity loss is observed at high preload, primarily due to suppressed SEI growth resulting from reduced electrode porosity and a decrease in active surface area available for interfacial reactions. Fitting parameters for stiffness correction, relaxation amplitude, and relaxation time exhibited systematic preload dependence. By decoupling irreversible and relaxation forces, the framework enables quantitative analysis of aging-induced pressure accumulation. Overall, this study underscores the critical role of mechanical constraints in long-term battery degradation and demonstrates the predictive capability of the proposed ECM model for guiding preload design in practical modules. Full article