Implications of THMC Processes on Long-Term Safety of Geological Disposal of Radioactive Waste, 2nd Edition

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Clays and Engineered Mineral Materials".

Deadline for manuscript submissions: 31 December 2025 | Viewed by 681

Special Issue Editors


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Guest Editor
Canadian Nuclear Safety Commission (CNSC), Ottawa, ON K1P 5S9, Canada
Interests: geomechanics; contaminant hydrogeology; coupled THMC processes in geomaterials; deep geological disposal
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Guest Editor
Department of Civil Engineering, University of Ottawa, 161 Louis Pasteur, Ottawa, ON K1N 6N5, Canada
Interests: geotechnical engineering; deep geological disposal; THMC processes in geosystems; mining geotechnics
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Geological disposal consists in placing waste in a repository at depths of hundreds of meters in a suitable rock formation. It is considered in many countries for the long-term management of radioactive waste.  A deep geological repository (DGR) relies on a multiple-redundant-barrier system, with engineered and natural components that act together to contain and isolate the waste for tens of thousands to millions of years. The engineered barrier components are typically the waste container and the bentonite sealing system which surrounds the container in the emplacement room; the host rock formation is the natural component. The primary type of waste considered for deep geological disposal is high-level radioactive waste, such as used fuel from nuclear power plants. High-level waste (HLW) generates heat and would substantially raise the ambient temperature in the DGR and host rock for tens of thousands of years. This heat results in complex coupled processes that perturb the thermal–mechanical–hydraulic–chemical regime in the multiple-barrier system and impact its long-term performance.

Research in coupled THMC processes has been active for the last few decades, resulting in ever-improving capabilities of mathematical models for THMC processes to predict experiments conducted at different research institutions and underground research facilities. At present, many countries have moved past the stage of concept development and fundamental research and have started or are close to implementing geological disposal. Therefore, we believe it is timely to consider the following questions:

  1. How do coupled THMC processes impact the containment and isolation of a DGR? When do they need to be considered and when can they be neglected?
  2. How confident are we that coupled THMC models could be used to evaluate the long-term evolution of a DGR (up to 1 million years) while they are typically developed and validated using short-term experiments?

The editors therefore invite contributions, either in the form of a thematic review or the reporting of original research that can shed some light on the above two questions. Although the focus of this call for papers is on geological disposal of radioactive waste, coupled THMC processes are important in many other underground engineering applications, such as carbon sequestration, petroleum extraction using hot water injection, geothermal energy, and mine backfilling. Therefore, contributions from these other fields that shed light on the second question above are particularly welcome.

Dr. Thanh Son Nguyen
Prof. Dr. Mamadou Fall
Guest Editors

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Keywords

  • coupled thermal–hydrological–mechanical–chemical processes
  • geological disposal of radioactive waste
  • long-term safety
  • geomaterials
  • geotechnical
  • barrier

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Published Papers (1 paper)

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Research

24 pages, 5892 KB  
Article
Reactive Transport Model of Steel/Bentonite Interactions in the FEBEX In Situ Test
by Javier Samper, Alba Mon and Luis Montenegro
Minerals 2025, 15(9), 940; https://doi.org/10.3390/min15090940 - 3 Sep 2025
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Abstract
Steel corrosion plays a major role in the geochemical evolution at the canister/bentonite interface of the engineered barrier systems of geological radioactive waste repositories. The interactions between corrosion products and bentonite can significantly affect bentonite properties and performance. These interactions have been investigated [...] Read more.
Steel corrosion plays a major role in the geochemical evolution at the canister/bentonite interface of the engineered barrier systems of geological radioactive waste repositories. The interactions between corrosion products and bentonite can significantly affect bentonite properties and performance. These interactions have been investigated by resorting to in situ tests conducted in underground laboratories, such as the FEBEX (Full-scale Engineered Barrier Experiment) test. The FEBEX in situ test, which was conducted at the Grimsel underground research laboratory in Switzerland from 1997 to 2015, demonstrated substantial corrosion of the steel liner in areas without a heater, primarily due to the presence of O2. Here we report a reactive transport model that simulates steel corrosion products and their interactions with bentonite. The model builds on a previously published conceptual geochemical model and addresses its limitations by integrating a more detailed representation of temperature and unsaturated flow conditions, leveraging prior thermo–hydrodynamic–mechanical–chemical (THMC) models. Given the prevailing uncertainties in O2 and redox conditions during the test and the limited data on liner corrosion and gas conditions at the liner–bentonite interface, liner corrosion was modeled by using a prescribed time-dependent function for the corrosion rate. Goethite, hematite, and magnetite were the Fe minerals allowed to precipitate in the model. The corrosion rate and the specific surface area of the hematite and magnetite were calibrated based on the profiles of goethite, hematite, and total Fe (including dissolved, exchanged and sorbed forms) observed at the post mortem analysis of the FEBEX in situ test. The model reproduces the observed goethite and hematite precipitation near the liner but underestimates the measured values at greater distances from the liner. The pattern of total calculated Fe concentrations reproduce the measured values except at a distance between 15 and 50 mm from the liner. Goethite is the predominant corrosion product in the model results, even under reducing conditions, owing to kinetic constraints on magnetite and hematite precipitation and to the enhanced stability of goethite driven by pH increase and thermal evolution. Full article
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