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Keywords = cement manufacturing

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12 pages, 3874 KiB  
Article
Comparison of the Marginal Integrity of Sectional Non-Invasive Laminate Veneers Versus Sectional Minimally Invasive Laminate Veneers Under Artificial Aging
by Polykarpos Papanagiotou, Phophi Kamposiora, George Papavasiliou and Spiros Zinelis
Dent. J. 2025, 13(8), 358; https://doi.org/10.3390/dj13080358 - 7 Aug 2025
Abstract
Background/Objectives: To compare the marginal integrity of sectional non-invasive laminate veneers versus sectional minimally invasive laminate veneers. Methods: A total of eighty (80) intact maxillary and mandibular frontal teeth (central incisors) were randomly divided into four groups (n = 20). [...] Read more.
Background/Objectives: To compare the marginal integrity of sectional non-invasive laminate veneers versus sectional minimally invasive laminate veneers. Methods: A total of eighty (80) intact maxillary and mandibular frontal teeth (central incisors) were randomly divided into four groups (n = 20). Two groups received non-invasive veneers made of feldspathic porcelain (Feldspathic Non-Invasive—FNI) and lithium disilicate (Lithium Disilicate Non-Invasive—LNI) accordingly. Groups FP and LP received minimally invasive veneers manufactured by feldspathic porcelain and lithium disilicate, respectively. Following cementation, three grooves with mesio-distal orientation on the labial surface of teeth of each sample, at the incisal, middle, and cervical third, were made. Before and after artificial aging, the mesio-distal distance between the end of the groove on the tooth and the edge of each veneer was measured in micrometers (μm) employing an SEM immediately after cementation (T0), after simulated artificial aging equivalent to four months of everyday brushing (T1), and after twelve months of everyday brushing (2 times per day) (T2) to identify the wear of veneers. In the same manner, the horizontal dimension of the cement layer extending from its edge till the margin of the veneer was measured for all the groups at T0, T1, and T2, respectively. The statistical analysis was performed employing non-parametric Kruskal–Wallis ANOVA and Dunn’s test. Results: No significant differences from T0 to T1 and from T1 to T2, as well as from T0 to T2, were identified for all the groups tested. No significant differences were allocated among all groups for the dimensional changes in the cement. Conclusions: All the groups responded similarly to aging factors, regardless of the non-invasive or minimally invasive approach, or the material used to fabricate the veneers. Full article
(This article belongs to the Special Issue Dental Materials Design and Innovative Treatment Approach)
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14 pages, 10994 KiB  
Article
Novel Cemented Carbide Inserts for Metal Grooving Applications
by Janusz Konstanty, Albir Layyous and Łukasz Furtak
Materials 2025, 18(15), 3674; https://doi.org/10.3390/ma18153674 - 5 Aug 2025
Abstract
Although cemented carbides have been manufactured by the powder metallurgy (P/M) technology for over a century now, systematic developmental efforts are still underway. In the present study, tool life improvements in metal grooving applications are the key objective. Four PVD-coated cemented carbides compositions, [...] Read more.
Although cemented carbides have been manufactured by the powder metallurgy (P/M) technology for over a century now, systematic developmental efforts are still underway. In the present study, tool life improvements in metal grooving applications are the key objective. Four PVD-coated cemented carbides compositions, dedicated to groove steel, stainless steel, cast iron, and aluminium alloys, have been newly designed, along with their manufacturing conditions. Physical, mechanical and chemical characteristics—such as sintered density, modulus of elasticity, hardness, fracture toughness, WC grain size, and the chemical composition of the substrate material, as well as the chemical composition, microhardness, structure, and thickness of the coatings—have been studied. A series of grooving tests have also been conducted to assess whether modifications to the thus far marketed tool materials, tool geometries, and coatings can improve cutting performance. In order to compare the laboratory and application properties of the investigated materials with currently produced by reputable companies, commercial inserts have also been tested. The experimental results obtained indicate that the newly developed grooving inserts exhibit excellent microstructural characteristics, high hardness, fracture toughness, and wear resistance and that they show slightly longer tool life compared to the commercial ones. Full article
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6 pages, 1231 KiB  
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A Personalized 3D-Printed CAD/CAM Functional Space Maintainer Following the Premature Loss of a Primary First Molar in a Five-Year-Old Child
by Rasa Mladenovic, Andrija Nedeljkovic, Ljiljana Vujacic, Marko Stevanovic, Vladan Djordjevic, Srbislav Pajic and Kristina Mladenovic
Reports 2025, 8(3), 125; https://doi.org/10.3390/reports8030125 - 29 Jul 2025
Viewed by 286
Abstract
Primary teeth play a crucial role in a child’s development, particularly in maintaining space for permanent teeth. The premature loss of a primary tooth can lead to orthodontic issues, making the use of space maintainers essential to ensure proper growth and development of [...] Read more.
Primary teeth play a crucial role in a child’s development, particularly in maintaining space for permanent teeth. The premature loss of a primary tooth can lead to orthodontic issues, making the use of space maintainers essential to ensure proper growth and development of permanent teeth. To preserve space, the fabrication of a space maintainer is necessary. Since conventional space maintainers do not restore masticatory function, this study presents an innovative solution for space preservation following the extraction of the first primary molar through the design of the functional space maintainer KOS&MET (Key Orthodontic System and Materials Enhanced Therapy). The space maintainer was designed using the 3Shape Dental Designer 2023 version software tool and manufactured via additive 3D printing, utilizing a metal alloy with high resistance to masticatory forces. The crown is supported by the primary canine, while an intraoral window is created to monitor the eruption of the successor tooth. This design does not interfere with occlusion and enables bilateral chewing. Masticatory performance was assessed using two-color chewing gum, and the results showed improvement after cementing the space maintainer. This innovative approach not only preserves space for permanent teeth but also enhances masticatory function, contributing to the proper growth and development of the jaws and teeth. Full article
(This article belongs to the Special Issue Oral Disorders in the Pediatric Population)
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15 pages, 2645 KiB  
Article
Carbon Footprint and Uncertainties of Geopolymer Concrete Production: A Comprehensive Life Cycle Assessment (LCA)
by Quddus Tushar, Muhammed A. Bhuiyan, Ziyad Abunada, Charles Lemckert and Filippo Giustozzi
C 2025, 11(3), 55; https://doi.org/10.3390/c11030055 - 28 Jul 2025
Viewed by 756
Abstract
This study aims to estimate the carbon footprint and relative uncertainties for design components of conventional and geopolymer concrete. All the design components of alkaline-activated geopolymer concrete, such as fly ash, ground granulated blast furnace slag, sodium hydroxide (NaOH), sodium silicate (Na2 [...] Read more.
This study aims to estimate the carbon footprint and relative uncertainties for design components of conventional and geopolymer concrete. All the design components of alkaline-activated geopolymer concrete, such as fly ash, ground granulated blast furnace slag, sodium hydroxide (NaOH), sodium silicate (Na2SiO3), superplasticizer, and others, are assessed to reflect the actual scenarios of the carbon footprint. The conjugate application of the life cycle assessment (LCA) tool SimPro 9.4 and @RISK Monte Carlo simulation justifies the variations in carbon emissions rather than a specific determined value for concrete binders, precursors, and filler materials. A reduction of 43% in carbon emissions has been observed by replacing cement with alkali-activated binders. However, the associative uncertainties of chemical admixtures reveal that even a slight increase may cause significant environmental damage rather than its benefit. Pearson correlations of carbon footprint with three admixtures, namely sodium silicate (r = 0.80), sodium hydroxide (r = 0.52), and superplasticizer (r = 0.19), indicate that the shift from cement to alkaline activation needs additional precaution for excessive use. Therefore, a suitable method of manufacturing chemical activators utilizing renewable energy sources may ensure long-term sustainability. Full article
(This article belongs to the Section Carbon Cycle, Capture and Storage)
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25 pages, 528 KiB  
Review
Life Cycle Assessment and Environmental Load Management in the Cement Industry
by Qiang Su, Ruslan Latypov, Shuyi Chen, Lei Zhu, Lixin Liu, Xiaolu Guo and Chunxiang Qian
Systems 2025, 13(7), 611; https://doi.org/10.3390/systems13070611 - 20 Jul 2025
Viewed by 519
Abstract
The cement industry is a significant contributor to global environmental impacts, and Life Cycle Assessment (LCA) has emerged as a critical tool for evaluating and managing these burdens. This review uniquely synthesizes recent advancements in the LCA methodology and provides a detailed comparison [...] Read more.
The cement industry is a significant contributor to global environmental impacts, and Life Cycle Assessment (LCA) has emerged as a critical tool for evaluating and managing these burdens. This review uniquely synthesizes recent advancements in the LCA methodology and provides a detailed comparison of cement production impacts across major producing regions, notably highlighting China’s role as the largest global emitter. It covers the core LCA phases, including goal and scope definition, inventory analysis, impact assessment, and interpretation, and emphasizes the role of LCA in quantifying cradle-to-gate impacts (typically around 0.9–1.0 t CO2 per ton of cement), evaluating the emissions reductions provided by alternative cement types (such as ~30–45% lower emissions using limestone calcined clay cements), informing policy frameworks like emissions trading schemes, and guiding sustainability certifications. Strategies for environmental load reduction in cement manufacturing are quantitatively examined, including technological innovations (e.g., carbon capture technologies potentially cutting plant emissions by up to ~90%) and material substitutions. Persistent methodological challenges—such as data quality issues, scope limitations, and the limited real-world integration of LCA findings—are critically discussed. Finally, specific future research priorities are identified, including developing country-specific LCI databases, integrating techno-economic assessment into LCA frameworks, and creating user-friendly digital tools to enhance the practical implementation of LCA-driven strategies in the cement industry. Full article
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24 pages, 2639 KiB  
Review
Cement Industry Pollution and Its Impact on the Environment and Population Health: A Review
by Alina Bărbulescu and Kamal Hosen
Toxics 2025, 13(7), 587; https://doi.org/10.3390/toxics13070587 - 14 Jul 2025
Viewed by 1276
Abstract
The cement industry, a foundation of global infrastructure development, significantly contributes to environmental pollution. Key sources of pollution include dust emissions; greenhouse gases, particularly carbon dioxide; and the release of toxic substances such as heavy metals and particulate matter. These pollutants contribute to [...] Read more.
The cement industry, a foundation of global infrastructure development, significantly contributes to environmental pollution. Key sources of pollution include dust emissions; greenhouse gases, particularly carbon dioxide; and the release of toxic substances such as heavy metals and particulate matter. These pollutants contribute to air, water, and soil degradation and are linked to severe health conditions in nearby populations, including respiratory disorders, cardiovascular diseases, and increased mortality rates. Noise pollution is also a significant issue, inducing auditory diseases that affect most workers in cement plants, and disturbing the population living in the neighborhoods and fauna behavior. This review explores the pollution paths and the multifaceted impacts of cement production on the environment. It also highlights the social challenges faced by communities, underscoring the urgent need for stricter environmental policies and the adoption of greener technologies to mitigate the adverse effects of cement production on both the environment and human health. Full article
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29 pages, 13314 KiB  
Article
Development of Unfired Clay Bricks with Alumina Waste from Liquid Nitrogen Production: A Sustainable Alternative for Construction Materials
by Noppadol Sangiamsak, Nopanom Kaewhanam, Meesakthana Puapitthayathorn, Seksan Numsong, Kowit Suwannahong, Sukanya Hongthong, Torpong Kreetachat, Sompop Sanongraj and Surachai Wongcharee
Sustainability 2025, 17(14), 6424; https://doi.org/10.3390/su17146424 - 14 Jul 2025
Viewed by 417
Abstract
A major breakthrough in environmentally friendly building materials is the development of sustainable unfired clay bricks including alumina waste produced during liquid nitrogen generation. Though used extensively, conventional fired clay bricks require energy-intensive manufacturing techniques that produce significant amounts of CO2 and [...] Read more.
A major breakthrough in environmentally friendly building materials is the development of sustainable unfired clay bricks including alumina waste produced during liquid nitrogen generation. Though used extensively, conventional fired clay bricks require energy-intensive manufacturing techniques that produce significant amounts of CO2 and aggravate environmental damage. By removing the need for high-temperature firing and allowing for the valorization of industrial byproducts including alumina waste and lateritic soil, unfired clay bricks offer a reasonable low-carbon alternative. High silica and alumina contents define the alumina waste, which shows pozzolanic reactivity, thus improving the physicomechanical performance of the bricks. With alumina waste substituting 0–8.57% of the cement content, seven different formulations showed improvements in compressive strength, reduced water absorption, and optimal thermal conductivity. Especially, the mechanical performance was much enhanced with alumina waste inclusion up to 30%, without sacrificing thermal insulation capacity or moisture resistance. Further supporting the environmental and financial sustainability of the suggested brick compositions is the economic viability of using industrial waste and regionally derived soils. A comparative analysis of the conventional fired bricks shows that the unfired substitutes have a much lower environmental impact and show better mechanical properties, including greater compressive strength and modulus of rupture. These results support the more general goals of circular economy systems and low-carbon urban development by highlighting the feasibility of including alumina waste and lateritic soil into sustainable building materials. Using such waste-derived inputs in building fits world initiatives to lower resource consumption, lower greenhouse gas emissions, and build strong infrastructure systems. Full article
(This article belongs to the Special Issue Solid Waste Management and Sustainable Environmental Remediation)
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24 pages, 3139 KiB  
Article
Alternative Materials for Interior Partitions in Construction
by Bruna Resende Fagundes Pereira, Carolina Rezende Pinto Narciso, Gustavo Henrique Nalon, Juliana Farinassi Mendes, Lívia Elisabeth Vasconcellos de Siqueira Brandão Vaz, Raphael Nogueira Rezende and Rafael Farinassi Mendes
Sustainability 2025, 17(14), 6341; https://doi.org/10.3390/su17146341 - 10 Jul 2025
Viewed by 390
Abstract
The significant waste generated by construction has increased interest in sustainable solutions, including prefabricated interior partition panels. Although different types of alternative panels have been proposed, their performance as interior partitions remains underexplored in systematic comparative studies. To narrow this knowledge gap, this [...] Read more.
The significant waste generated by construction has increased interest in sustainable solutions, including prefabricated interior partition panels. Although different types of alternative panels have been proposed, their performance as interior partitions remains underexplored in systematic comparative studies. To narrow this knowledge gap, this paper presents a comprehensive evaluation and classification of drywall, OSB (Oriented Strand Board), cement–wood, and honeycomb panels, regarding physical, mechanical, microstructural, thermal, acoustic, and combustibility characteristics, in addition to conducting a cost evaluation. The results indicated that the OSB panels exhibited superior results for interior partition applications, showing notable advantages in physical strength, mechanical performance, and thermal insulation, while offering acoustic properties comparable to those of drywall panels. Nevertheless, OSB panels showed lower fire resistance and were associated with the highest cost among the materials analyzed in the present research. Drywall panels, on the other hand, provided the most favorable fire resistance but exhibited the least effective thermal insulation. The findings also indicated that both wood–cement and honeycomb panels require further improvements in their manufacturing processes to meet performance standards suitable for interior partition. Full article
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28 pages, 2882 KiB  
Article
Additive Manufacturing as an Alternative to Core Sampling in Concrete Strength Assessment
by Darya Anop, Marzhan Sadenova, Nail Beisekenov, Olga Rudenko, Zulfiya Aubakirova and Assel Jexembayeva
Appl. Sci. 2025, 15(14), 7737; https://doi.org/10.3390/app15147737 - 10 Jul 2025
Viewed by 292
Abstract
Additive manufacturing reshapes concrete construction, yet routine strength verification of printed elements still depends on destructive core sampling. This study evaluates whether standard 70 mm cubes—corrected by a single factor—can provide an equally reliable measure of in situ compressive strength. Five Portland-cement mixes, [...] Read more.
Additive manufacturing reshapes concrete construction, yet routine strength verification of printed elements still depends on destructive core sampling. This study evaluates whether standard 70 mm cubes—corrected by a single factor—can provide an equally reliable measure of in situ compressive strength. Five Portland-cement mixes, with and without ash-slag techno-mineral filler, were extruded into wall blocks on a laboratory 3D printer. For each mix, the compressive strengths of the cubes and ∅ 28 mm drilled cores were measured at 7, 14 and 28 days. The core strengths were consistently lower than the cube strengths, but their ratios remained remarkably stable: the transition coefficient clustered between 0.82 and 0.85 (mean 0.83). Ordinary least-squares regression of the pooled data produced the linear relation R^core [MPa] = 0.97 R^cube − 4.9, limiting the prediction error to less than 2 MPa (under 3% across the 40–300 MPa range) and outperforming more complex machine-learning models. Mixtures containing up to 30% ash-slag filler maintained structural-grade strength while reducing clinker demand, underscoring their sustainability potential. The results deliver a simple, evidence-based protocol for non-destructive strength assessment of 3D-printed concrete and provide quantitative groundwork for future standardisation of quality-control practices in additive construction. Full article
(This article belongs to the Special Issue Sustainable Concrete Materials and Resilient Structures)
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51 pages, 8938 KiB  
Review
Sustainability of Recycling Waste Ceramic Tiles in the Green Concrete Industry: A Comprehensive Review
by Ghasan Fahim Huseien, Zahraa Hussein Joudah, Mohammad Hajmohammadian Baghban, Nur Hafizah A. Khalid, Iman Faridmehr, Kaijun Dong, Yuping Li and Xiaobin Gu
Buildings 2025, 15(14), 2406; https://doi.org/10.3390/buildings15142406 - 9 Jul 2025
Viewed by 687
Abstract
Ceramic tiles classified as non-biodegradable are made from fired clay, silica, and other natural materials for several construction applications. Waste ceramic tiles (WCTs) are produced from several sources, including manufacturing defects; surplus, broken, or damaged tiles resulting from handling; and construction and demolition [...] Read more.
Ceramic tiles classified as non-biodegradable are made from fired clay, silica, and other natural materials for several construction applications. Waste ceramic tiles (WCTs) are produced from several sources, including manufacturing defects; surplus, broken, or damaged tiles resulting from handling; and construction and demolition debris. WCTs do not decompose easily, leading to long-term accumulation in landfills and occupying a significant amount of landfill space, which has substantial environmental impacts. Recycling WCTs offers several critical ecological benefits, including reducing landfill waste and pollution, conserving natural resources, lowering energy consumption, and supporting the circular economy, which in turn contributes to sustainable construction and waste management practices. In green concrete manufacturing, WCTs are widely utilized as replacements for cement, fine, and coarse aggregates, and the recycling level in the concrete industry is an increasingly explored practice aimed at promoting sustainability and reducing construction waste. From this view, this paper reports the innovative technologies, advancements in green concrete performance, and development trends in the reuse of WCTs in the production of systems. The effects of WCTs on fresh, engineering, microstructural, and durable properties, as well as their environmental performance, are reviewed. In conclusion, the use of technologies for recycling WCTs has demonstrated potential in promoting sustainability and supporting the transition toward a more environmentally friendly construction industry. This approach offers a practical contribution to sustainable development and represents significant progress in closing the recycling loop within the construction sector. Full article
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19 pages, 6342 KiB  
Article
Innovative Use of UHPC and Topology Optimization in Permeable Interlocking Pavers: Advancing Sustainable Pavement Solutions
by Fernanda Gadler, José Augusto Ferreira Sales de Mesquita, Francisco Helio Alencar Oliveira, Liedi Legi Bariani Bernucci, Rafael Giuliano Pileggi, Emilio Carlos Nelli Silva and Diego Silva Prado
Sustainability 2025, 17(13), 6039; https://doi.org/10.3390/su17136039 - 1 Jul 2025
Viewed by 402
Abstract
The rapid expansion of urban areas has increased the prevalence of impermeable surfaces, intensifying flooding risks by disrupting natural water infiltration. Permeable pavements have emerged as a sustainable alternative, capable of reducing stormwater runoff, improving surface friction, and mitigating urban heat island effects. [...] Read more.
The rapid expansion of urban areas has increased the prevalence of impermeable surfaces, intensifying flooding risks by disrupting natural water infiltration. Permeable pavements have emerged as a sustainable alternative, capable of reducing stormwater runoff, improving surface friction, and mitigating urban heat island effects. Nevertheless, their broader implementation is often hindered by issues such as clogging and limited mechanical strength resulting from high porosity. This study examines the design of interlocking permeable blocks utilizing ultra-high-performance concrete (UHPC) to strike a balance between enhanced drainage capacity and high structural performance. A topology optimization (TO) strategy was applied to numerically model the ideal block geometry, incorporating 105 drainage channels with a diameter of 6 mm—chosen to ensure manufacturability and structural integrity. The UHPC formulation was developed using particle packing optimization with ordinary Portland cement (OPC), silica fume, and limestone filler to reduce binder content while achieving superior strength and workability, guided by rheological assessments. Experimental tests revealed that the perforated UHPC blocks reached compressive strengths of 87.8 MPa at 7 days and 101.0 MPa at 28 days, whereas the solid UHPC blocks achieved compressive strengths of 125.8 MPa and 146.2 MPa, respectively. In contrast, commercial permeable concrete blocks reached only 28.9 MPa at 28 days. Despite a reduction of approximately 30.9% in strength due to perforations, the UHPC-105holes blocks still far exceed the 41 MPa threshold required for certain structural applications. These results highlight the mechanical superiority of the UHPC blocks and confirm their viability for structural use even with enhanced permeability features. The present research emphasizes mechanical and structural performance, while future work will address hydraulic conductivity and anticlogging behavior. Overall, the findings support the use of topology-optimized UHPC permeable blocks as a resilient solution for sustainable urban drainage systems, combining durability, strength, and environmental performance. Full article
(This article belongs to the Special Issue Green Infrastructure and Sustainable Stormwater Management)
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22 pages, 2576 KiB  
Article
Multi-Indicator Environmental Impact Assessment of Recycled Aggregate Concrete Based on Life Cycle Analysis
by Heng Zhang, Xiaochu Wang, Peng Ren and Linlin Yang
Buildings 2025, 15(13), 2301; https://doi.org/10.3390/buildings15132301 - 30 Jun 2025
Viewed by 374
Abstract
With the ongoing acceleration in urban development, the volume of construction and demolition waste continues to rise, while the availability of natural aggregates is steadily declining. Utilizing recycled aggregates in concrete has become a vital approach to fostering sustainability within the construction sector. [...] Read more.
With the ongoing acceleration in urban development, the volume of construction and demolition waste continues to rise, while the availability of natural aggregates is steadily declining. Utilizing recycled aggregates in concrete has become a vital approach to fostering sustainability within the construction sector. This research develops a life cycle-based environmental impact evaluation model for recycled aggregate concrete, applying the Life Cycle Assessment (LCA) framework. Through the eFootprint platform, a quantitative evaluation is carried out for C30-grade concrete containing varying levels of recycled aggregate replacement. Four replacement ratios of recycled coarse aggregate (30%, 50%, 70%, and 100%) were evaluated. The assessment includes six key environmental indicators: Global Warming Potential (GWP), Primary Energy Demand (PED), Abiotic Depletion Potential (ADP), Acidification Potential (AP), Eutrophication Potential (EP), and Respiratory Inorganics (RI). The findings reveal that higher substitution rates of recycled aggregate lead to noticeable reductions in RI, EP, and AP, indicating improved environmental performance. Conversely, slight increases are observed in GWP and PED, especially under long transport distances. Analysis of contributing factors and sensitivity indicates that cement manufacturing is the principal driver of these increases, contributing over 80% of the total GWP, PED, and ADP impacts, with aggregate transport as the next major contributor. This study offers methodological insights into the environmental evaluation of recycled aggregate concrete and supports the green design and development of low-carbon strategies in construction. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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11 pages, 2164 KiB  
Article
Study of Corrosion Characteristics of AlMg3.5 Alloy by Hydrogen-Induced Pressure and Mass Loss Evaluation Under Simulated Cementitious Repository Conditions
by Marvin Schobel, Christian Ekberg, Teodora Retegan Vollmer, Fredrik Wennerlund, Svante Hedström and Anders Puranen
Corros. Mater. Degrad. 2025, 6(3), 27; https://doi.org/10.3390/cmd6030027 - 30 Jun 2025
Viewed by 410
Abstract
The decommissioning and dismantling of nuclear research reactors can lead to a large amount of low- and intermediate-level radioactive waste. For repositories, the materials must be kept confined and safety must be ensured for extended time spans. Waste is encapsulated in concrete, which [...] Read more.
The decommissioning and dismantling of nuclear research reactors can lead to a large amount of low- and intermediate-level radioactive waste. For repositories, the materials must be kept confined and safety must be ensured for extended time spans. Waste is encapsulated in concrete, which leads to alkaline conditions with pH values of 12 and higher. This can be advantageous for some radionuclides due to their precipitation at high pH. For other materials, such as reactive metals, however, it can be disadvantageous because it might foster their corrosion. The Studsvik R2 research reactor contained an AlMg3.5 alloy with a composition close to that of commercial Al5154 for its core internals and the reactor tank. Aluminum corrosion is known to start rapidly due to the formation of an oxidation layer, which later functions as natural protection for the surface. The corrosion can lead to pressure build-up through the accompanied production of hydrogen gas. This can lead to cracks in the concrete, which can be pathways for radioactive nuclides to migrate and must therefore be prevented. In this study, unirradiated rod-shaped samples were cut from the same material as the original reactor tank manufacture. They were embedded in concrete with elevated water–cement ratios of 0.7 compared to regular commercial concrete (ca. 0.45) to ensure water availability throughout all of the experiments. The sample containers were stored in pressure vessels with attached high-definition pressure gauges to read the hydrogen-induced pressure build-up. A second set of samples were exposed in simplified artificial cement–water to study similarities in corrosion characteristics between concrete and cement–water. Additionally, the samples were exposed to concrete and cement–water in free-standing sample containers for deconstructive examinations. In concrete, the corrosion rates started extremely high, with values of more than 10,000 µm/y, and slowed down to less than 500 µm/y after 2000 h, which resulted in visible channels inside the concrete. In the cement–water, the samples showed similar behavior after early fluctuations, most likely caused by the surface coverage of hydrogen bubbles. These trends were further supported by mass loss evaluations. Full article
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12 pages, 4460 KiB  
Article
Influence of Laser Energy Variation on the Composition and Properties of Gradient-Structured Cemented Carbide Layers Produced by LP-DED
by Yorihiro Yamashita, Kenta Kawabata, Hayato Mori, Eito Ose and Takahiro Kunimine
J. Manuf. Mater. Process. 2025, 9(7), 218; https://doi.org/10.3390/jmmp9070218 - 27 Jun 2025
Viewed by 330
Abstract
In this study, graded cemented carbide layers were fabricated using Laser Powder-Directed Energy Deposition (LP-DED) to investigate the effects of laser input energy and WC content on crack formation, compositional distribution, and hardness. Two-layer structures were formed, with the first layer containing either [...] Read more.
In this study, graded cemented carbide layers were fabricated using Laser Powder-Directed Energy Deposition (LP-DED) to investigate the effects of laser input energy and WC content on crack formation, compositional distribution, and hardness. Two-layer structures were formed, with the first layer containing either 30.5 wt.% or 42.9 wt.% WC and the second layer containing 63.7 wt.% WC. Crack formation was evaluated in situ using acoustic emission (AE) sensors, and elemental composition and Vickers hardness were measured across the cross-section of the deposited layers. The results showed that crack formation increased with higher laser power and higher WC content in the first layer. Elemental analysis revealed that higher laser input led to greater Co enrichment and reduced W content near the surface. Additionally, the formation of brittle structures was observed under high-energy conditions, contributing to increased hardness but decreased toughness. These findings indicate that both WC content and laser energy strongly influence the microstructural evolution and mechanical properties of graded cemented carbide layers. Optimizing the balance between WC content and laser parameters is essential for improving the crack resistance and performance of cemented carbide layers in additive manufacturing applications. Full article
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16 pages, 550 KiB  
Article
Evaluating the Use of Alternative Fuels in Cement Production for Environmental Sustainability
by Taj Wali, Azmat Qayum, Fahad Algarni, Fazle Malik and Saeed Ullah Jan
Sustainability 2025, 17(13), 5924; https://doi.org/10.3390/su17135924 - 27 Jun 2025
Viewed by 809
Abstract
This study empirically examines the impact of 30% alternative fuel (AF) adoption on the emission of CO2 to the environment in the UAE cement industry. The researchers employed a quantitative method to robustly analyze secondary data obtained from the 12 cement manufacturing [...] Read more.
This study empirically examines the impact of 30% alternative fuel (AF) adoption on the emission of CO2 to the environment in the UAE cement industry. The researchers employed a quantitative method to robustly analyze secondary data obtained from the 12 cement manufacturing units of the UAE, the International Energy Agency (IEA), the United States Geological Survey (USGS), and peer-reviewed published papers. The researcher’s main focus was on data from 2018 to 2024 and aligned that with the UAE Green Agenda 2030. The data analysis was conducted through a well-known software, the Statistical Package for Social Sciences (SPSS), and tests like descriptive statistics, correlation, and regression were employed. The correlation analysis showed that there is a strong negative relationship between AF adoption and CO2 emissions. The test also showed that the relationship is inverse, that is, increasing the adoption rate of AF lowers CO2 emissions and thus positively impacts the environment. The Pearson correlation analysis (r = −0.82) showed a strong inverse relationship between the independent and dependent variables. This strong relationship was further revealed and confirmed by the regression analysis, and AF as an individual independent variable explained a 67% reduction in CO2 emission (R2 = 0.67), while a combination with mediating variables, such as economic incentives and the integration of advanced technologies, further increased the impact to 83%, where the explanatory power jumped to R2 = 0.83 (p < 0.001). As the relationship is strongly inverse between the independent and dependent variables, this reinforces the hypothesis that AF adoption is a good strategy to decarbonize the production of cement and make the operations sustainable. Full article
(This article belongs to the Section Air, Climate Change and Sustainability)
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