Search Results (150)

Thermoplastic polyurethane (TPU) combines elastomeric and thermoplastic properties but suffers from insufficient rigidity and strength for structural applications. Herein, we developed novel carbon fiber-reinforced TPU (CF/TPU) composites filaments and utilize melt extrusion for 3D printing to maintain elasticity, while achieving enhanced stiffness and strength through multi scale-the control of fiber content and optimization of printing parameters, reaching a rigid–elastic balance. A systematic evaluation of CF content (0–25%) and printing parameters revealed optimal performance to be at 220–230 °C and 40 mm/s for ensuring proper flow to wet fibers without polymer degradation. Compared with TPU, 20% CF/TPU exhibited 63.65%, 105.51%, and 93.69% improvements in tensile, compressive, and impact strength, respectively, alongside 70.88% and 72.92% enhancements in compression and impact energy absorption. This work establishes a fundamental framework for developing rigid–elastic hybrid materials with tailored energy absorption capabilities through rational material design and optimized additive manufacturing processes. Full article

Carbon fiber-reinforced composites (CFRCs) have attracted considerable attention in recent years due to their excellent properties, enabling their use across various sectors. However, their application at high temperatures is limited by the fibers’ lack of oxidation resistance. This study demonstrates a significant advancement in enhancing the oxidation stability performance of carbon fiber-reinforced composites (CFRCs) by developing a silicon carbide (SiC) coating through the ceramization of carbon fibers using silicon (Si) powder. For the first time, this method was applied to recycled carbon fibers from CF thermoplastic composites. The key findings include the successful formation of a uniform SiC coating, with coating thickness increasing with process duration and decreasing at higher temperatures. The treated fibers exhibited substantially improved oxidation resistance, maintaining structural stability above 700 °C—markedly better than that of their uncoated counterparts. Thermogravimetric analysis confirmed that oxidation resistance varied depending on the CF/Si ratio, highlighting this parameter’s critical role. Overall, this study offers a viable pathway to enhance the thermal durability of recycled carbon fibers for high-temperature applications. Full article

Thermoplastic carbon fiber/aluminum alloy hybrid composite laminates fully integrate the advantages of fiber-reinforced composites and metallic materials, exhibiting high fatigue resistance and impact resistance, with broad applications in fields such as national defense, aerospace, automotive engineering, and marine engineering. In this paper, thermoplastic carbon fiber/aluminum alloy hybrid composite laminates were first prepared using a hot-press machine; then, high-velocity impact tests were conducted on the specimens using a first-stage light gas gun test system. Comparative experimental analyses were performed to evaluate the energy absorption performance of laminates with different ply thicknesses and layup configurations. High-speed cameras and finite element analysis software were employed to analyze the failure process and modes of the laminates under impact loading. The results demonstrate that fiber–metal laminates exhibit higher specific energy absorption than carbon fiber composite laminates. Meanwhile, the numerical simulation results can effectively reflect the experimental outcomes in terms of the velocity–time relationship, failure modes during the laminate impact process, and failure patterns after the laminate impact. Full article

In recent years, the rapid development of three-dimensional (3D)-printed continuous fiber-reinforced polymer (CFRP) technology has provided novel strategies for customized manufacturing of high-performance composites. This review systematically summarizes research advancements in material systems, processing methods, mechanical performance regulation, and functional applications of this technology. Material-wise, the analysis focuses on the performance characteristics and application scenarios of carbon fibers, glass fibers, and natural fibers, alongside discussions on the processing behaviors of thermoplastic matrices such as polyetheretherketone (PEEK). At the process level, the advantages and limitations of fused deposition modeling (FDM) and photopolymerization techniques are compared, with emphasis on their impact on fiber–matrix interfaces. The review further examines the regulatory mechanisms of fiber orientation, volume fraction, and other parameters on mechanical properties, as well as implementation pathways for functional designs, such as electrical conductivity and self-sensing capabilities. Application case studies in aerospace lightweight structures and automotive energy-absorbing components are comprehensively analyzed. Current challenges are highlighted, and future directions proposed, including artificial intelligence (AI)-driven process optimization and multi-material hybrid manufacturing. This review aims to provide a comprehensive assessment of the current achievements in 3D printing CFRP technology and a forward-looking analysis of existing challenges, offering a systematic reference for accelerating the transformation of 3D printing CFRP technology from laboratory research to industrial-scale implementation. Full article

High-performance discontinuous carbon-fiber-reinforced thermoplastics (CFRTPs) offer promising manufacturing flexibility and recyclability for advanced composite applications. However, their mechanical performance and reliability strongly depend on the internal fiber architecture, which is largely determined by the molding process. In this study, three distinct compression molding approaches—CFRTP sheet molding compounds (SMCs), bulk molding compounds (BMCs), and free-edge molding compounds (FMCs)—were systematically evaluated to investigate how processing parameters affect fiber orientation, tape deformation, and impregnation quality. X-ray micro-computed tomography (XCT) was employed to visualize and quantify the internal structures of each material, focusing on the visualization and quantification of in-plane and out-of-plane fiber alignment and other internal structure features. The results indicate that CFRTP-SMC retains largely intact tape layers and achieves better impregnation, leading to more uniform and predictable internal geometry. Although CFRTP-BMC exhibits greater tape deformation and splitting due to increased flow, its simpler molding process and better tolerance for tape shape distortion suggest potential advantages for recycled applications. In contrast, CFRTP-FMC shows significant tape fragmentation and poor impregnation, particularly near free edges. These findings underscore the critical role of a controlled molding process in achieving a consistent internal structure for these materials for the first time. This study highlights the utility of advanced XCT methods for optimizing process design and advancing the use of high-performance discontinuous CFRTP in industry. Full article

To address the insufficient bonding performance between TC4 (Ti-6Al-4V) coating and carbon fiber-reinforced thermoplastic (CFRP) matrices that limits engineering applications of composite structures, TC4 coatings were fabricated on CFRP polymer composites via laser cladding and analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) to examine the interface morphology, microstructure, and phase composition. The influence of laser processing parameters on the cladding quality was assessed based on the mechanical performance of the TC4 coating. The findings revealed that insufficient laser power (<230 W) or excessive scanning speed (>1.4 m/min) led to incomplete melting of TC4 powder, preventing the formation of intermetallic compound (IMC) layers. Conversely, excessive laser power (>270 W) or a low scanning speed (<1.0 m/min) caused thermal decomposition of the CFRP due to its limited thermal resistance, leading to interfacial defects such as cracks and pores. The interface between the CFRP and TC4 coating primarily comprised granular TiC and acicular α′ martensite, with minor TiS₂ detected. Optimal mechanical performance was achieved at a laser power of 250 W and a scanning speed of 1.2 m/min, yielding a maximum interfacial shear strength of 18.5 MPa. These findings provide critical insights for enhancing the load-bearing capacity of TC4/CFRP aeronautical composites, enabling their reliable operation in extreme aerospace environments. Full article

Polyether ether ketone (PEEK) is a high-performance thermoplastic widely used in aerospace, automotive, and medical applications due to its exceptional strength, heat resistance, and chemical stability. However, warpage and mechanical property variations remain significant challenges in 3D printing PEEK parts. This study investigates the effect of key printing parameters, including nozzle temperature, layer thickness, platform temperature, and infill rate, on the mechanical properties and warpage of 3D-printed PEEK components. By systematically analyzing tensile and compressive loading conditions, this research aims to optimize printing settings to improve dimensional accuracy and structural integrity. The experimental results indicate that mechanical properties, such as tensile and compressive stress at break, vary significantly with printing conditions. The highest tensile strength and compressive strength achieved were 71.4 MPa and 167 MPa, respectively. Meanwhile, the lowest tensile (45.36 MPa) and compressive strengths (72.5 MPa) were also recorded. Higher nozzle and platform temperatures, coupled with increased infill rates, enhance layer adhesion, leading to improved tensile and compressive strength. However, a nozzle temperature of 400 °C, platform temperature of 130 °C, and 60% infill rate lead to optimal bonding between layers and thus a reduction in warpage. Considering warpage in all four corners and mechanical properties, a 400 °C nozzle temperature, 0.16 mm layer thickness, and 130 °C platform temperature, coupled with a 60% infill rate, provide optimal printing conditions. The 10% carbon fiber-reinforced PEEK composites exhibit an improved tensile strength that is 1.68 times higher compared to pure PEEK. To emphasize the importance of thermal and structural settings, the findings highlight the crucial role of printing parameters in minimizing warpage and enhancing mechanical properties in 3D-printed PEEK parts, which were analyzed by the multi-objective optimization method. Scanning electron microscopy analyses were carried out to analyze fracture morphology and printing layer orientation. Full article

Polycarbonate (PC) is a highly recyclable thermoplastic with high impact strength that bodes well to re-melting extrusion and shredding for positive environmental impact. For the goal of improving impact strength further, layered carbon fiber (CF) reinforcement has been added between PC sheets by hot pressing at 6.0 MPa and 537 K for 8 min. An addition of cross-weave CF layer reinforcement to PC increased Charpy impact value, a_uc of the untreated [PC]₄[CF]₃ composite over that of untreated PC resin reported at all accumulative probabilities, P_f. At medial-P_f of 0.50, a_uc was increased 3.13 times (213%), while statistically lowest impact value a_s at P_f = 0 calculated by 3-parameter Weibull equation was boosted 2.64 times (164%). To optimize a_uc, effect of homogeneous electron beam irradiation (HLEBI) treatment of 43.2, 129, 216, 302, or 432 kGy at 170 kV acceleration voltage to the CF plies before assembly with PC then hot press was also investigated. The 216 kGy HLEBI dose appears to be optimum, raising a_s at P_f = 0 about 6.5% over that of untreated [PC]₄[CF]₃ and agrees with a previous study that showed 216 kGy to be optimum for static 3-point bending strength, when quality can be controlled. Electron spin resonance (ESR) data confirms 216 kGy HLEBI generates strong peaks in CF and PC indicating dangling bond (DB) generation. Bending strength increase was higher than that of impact due to lower test velocity and higher deformation area spreading along specimen length, allowing more DBs to take on the load. X-ray photoelectron spectroscopy (XPS) data of CF top ~10 nm surface layer in the sizing confirms C–O–H, C–H, and C–O peak height from 216 kGy exhibited little or no change compared with untreated. However, 432 kGy increased the peak heights indicating enhanced adhesion to PC. However, 432 kGy degraded a_s at P_f = 0 of the [PC]₄[CF]₃, and is reported to decrease impact strength of PC itself by excess dangling bond formation. Thus, the 432 kGy created increased PC/CF adhesion, but degraded the PC resin. Therefore, 216 kGy of 170 kV-HLEBI appeared to be a well-balanced condition between the PC-cohesive force and PC/CF interface adhesive force when fabricating [PC]₄[CF]₃. Full article

The aim of this work is to study the effect of high-temperature compaction (HTC) upon the polymorphism and the mechanical behavior of an additively manufactured (AM) carbon fiber-reinforced polyamide (PA6). Different pressure and temperature levels during HTC were tested to determine the overall effect on the mechanical behavior and material crystalline composition. Treated, carbon fiber-reinforced PA6 samples were analyzed using differential scanning calorimetry, X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, and three-point bending testing. When considered with respect to as-printed samples, an HTC temperature of 190 °C combined with 80 psi pressure resulted in an increased flexural modulus and strength of 47% and 58%, respectively. This increase was attributed to the decrease in AM-induced cracking, voids (both inside and between the beads), and crystalline solid-state transition in the PA6. The effect of pressure and temperature on the crystalline structure was discussed in terms of an increased degree of crystallinity and the amount of α-phase. Therefore, HTC can help overcome some limitations of traditional annealing, which can result in recrystallization-induced cracking which can lead to material embrittlement. The proposed HTC method demonstrates the potential in improving the mechanical behavior of AM thermoplastic composites. Full article

Innovative structures technologies can contribute to increasing the sustainability of next-generation aircraft. Advanced multi-disciplinary physics models, combined with data-based models, are needed to obtain optimized structures with maximum contributions to sustainability throughout the life cycle. Such models are needed for next-generation aircraft products, for better production of their parts, and for representative testing of their innovative systems. Modeling challenges addressed recently will be presented and illustrated in their industrial context. In particular, fast in-line detection of defects in large composite aircraft parts during their high-rate production, induction welding of thermoplastic carbon-fiber reinforced parts, and accurate design of composite fan blades for wind tunnel testing of fuel-efficient Ultra-High Bypass Ratio (UHBR) turbofan engines will be presented. Full article

The growing demand for high-performance and cost-effective composite materials necessitates advanced computational approaches for optimizing their composition and properties. This study aimed at the application of machine learning for the prediction and optimization of the functional properties of composites based on a thermoplastic matrix with various fillers (two types of fibrous, four types of dispersed, and two types of nano-dispersed fillers). The experimental methods involved material production through powder metallurgy, further microstructural analysis, and mechanical and tribological testing. The microstructural analysis revealed distinct structural modifications and interfacial interactions influencing their functional properties. The key findings indicate that optimal filler selection can significantly enhance wear resistance while maintaining adequate mechanical strength. Carbon fibers at 20 wt. % significantly improved wear resistance (by 17–25 times) while reducing tensile strength and elongation. Basalt fibers at 10 wt. % provided an effective balance between reinforcement and wear resistance (by 11–16 times). Kaolin at 2 wt. % greatly enhanced wear resistance (by 45–57 times) with moderate strength reduction. Coke at 20 wt. % maximized wear resistance (by 9−15 times) while maintaining acceptable mechanical properties. Graphite at 10 wt. % ensured a balance between strength and wear, as higher concentrations drastically decreased mechanical properties. Sodium chloride at 5 wt. % offered moderate wear resistance improvement (by 3–4 times) with minimal impact on strength. Titanium dioxide at 3 wt. % enhanced wear resistance (by 11–12.5 times) while slightly reducing tensile strength. Ultra-dispersed PTFE at 1 wt. % optimized both strength and wear properties. The work analyzed in detail the effect of PTFE content and filler content on composite properties based on machine learning-driven prediction. Regression models demonstrated high R-squared values (0.74 for density, 0.67 for tensile strength, 0.80 for relative elongation, and 0.79 for wear intensity), explaining up to 80% of the variability in composite properties. Despite its efficiency, the limitations include potential multicollinearity, a lack of consideration of external factors, and the need for further validation under real-world conditions. Thus, the machine learning approach reduces the need for extensive experimental testing, minimizing material waste and production costs, contributing to SDG 9. This study highlights the potential use of machine learning in polymer composite design, offering a data-driven framework for the rational choice of fillers, thereby contributing to sustainable industrial practices. Full article

3D-printed short-carbon-fiber-reinforced thermoplastic composites have attracted significant attention from both the academic and industrial communities due to their remarkable advantages such as lightweight, high strength, and recyclability. However, in most of the current 3D-printing-related nylon composites, the content of short carbon fibers is generally low, and the influence laws of short carbon fibers on the mechanical properties of the composites have not been fully explored. This paper focuses on short-carbon-fiber-reinforced nylon (SCF/PA) composites with short-carbon-fiber contents of 15 wt%, 25 wt%, and 35 wt%, respectively. It studies in depth their mechanical properties and related characteristics. The research results show that with the increase in the short-carbon-fiber content, the melt flow rate of the SCF/PA composites shows a downward trend. In terms of mechanical properties, when the short-carbon-fiber content is 25 wt%, the tensile strength and flexural strength of the composite reach their maximum values, which are 101.43 MPa and 173.16 MPa, respectively. Compared with pure nylon, the improvement ranges are 17.01% and 21.4%, respectively. When the short-carbon-fiber content is 35 wt%, the impact resistance of the material reaches its optimal value, which is 6.02 KJ/m², an increase of 38.1% compared with pure nylon. At the same time, when the short-carbon-fiber content is 35 wt%, the thermal deformation temperature of the material also shows a certain degree of slight increase. In summary, the research results of this paper will provide more abundant and detailed experimental data support for 3D-printed short-carbon-fiber-reinforced nylon composites in various different application scenarios, facilitating further exploration and application in related fields. Full article

This study focuses on reducing the weight of oxygen respirators in firefighters’ personal protective equipment (PPE), which currently accounts for about 56% of the total weight. The heavy PPE, weighing between 20 and 25 kg, restricts movement and can lead to musculoskeletal injuries. To address this, the study investigates using a carbon fiber-reinforced composite for the backrest of the oxygen respirator to reduce weight while maintaining strength. The backrest was fabricated using a long-fiber thermoplastic (LFT) composite made with PA66 resin and 30wt.% carbon fiber content. Initially, the injection-molding process conditions were identified to achieve a tensile strength of 85 MPa or higher. Additionally, flame retardants were added to improve fire resistance, with AF-480 at 5 wt.% found to be the best option. Subsequently, optimal injection conditions were set by fabricating the back rest with the composite by applying the Taguchi method to satisfy the required tensile strength. As a result, the composite material achieved a 12.8% weight reduction while maintaining the required strength. This development is expected to significantly improve firefighter safety, leading to more effective firefighting and reduced human and property damage. Full article

Short fiber-reinforced thermoplastic composites (SFRTPs) have excellent recyclability and processability, but their mechanical properties are weak compared to continuous fiber products. Various studies have reported that the addition of GNPs improves the mechanical properties of SFRTPs, but it is unclear what effect different types of reinforcing fibers have on a hybrid composite system. In this study, the effect of adding a small amount (1 wt%) of graphene nanoplatelets (GNPs) to fiber-reinforced polypropylene composites on their mechanical properties was investigated from a crystallinity perspective. GNPs were mixed with polypropylene (PP)/carbon fiber (CF) or PP/glass fiber (GF) using a melt blending process, and composites were molded by injection molding. The results of mechanical property characterization showed no significant effect when GNPs were added to PP/CF, but when GNPs were added to PP/GF, this increased the composite’s tensile strength and Young’s modulus by approximately 20% and 10%, respectively. The interfacial shear strength (IFSS) predicted using the modified Kelly–Tyson equation did not change much before and after the addition of GNPs to PP/CF. On the other hand, the IFSS increased from 10.8 MPa to 19.2 MPa with the addition of GNPs to PP/GF. The increase in IFSS led to an increase in the tensile strength of PP/GF with the incorporation of GNPs. Differential scanning calorimetry (DSC) indicated that GNPs accelerated the crystallization rate, and the X-ray diffraction (XRD) results confirmed that GNPs acted as a crystal nucleating agent. However, CF was also shown to be a nucleating agent, limiting the effect of GNP addition. In other words, it can be said that the addition of GNPs to PP/GF is more effective than their addition to PP/CF due to the differential crystallization effects of each fiber. Full article

This study investigates carbon fabric-reinforced thermoplastic composites produced via hot pressing, using Polyamide PA6 and Polybutylene Terephthalate (PBT) as matrix materials. These materials are increasingly utilized in the development of lightweight, high-performance, multilayer structures, such as aluminum-reinforced laminates, for automotive and aerospace applications. The mechanical properties, including tensile strength and stiffness, were systematically evaluated under varying loading conditions. The PBT-CF composite exhibited a 17% higher tensile strength and stiffness compared to the PA6-CF composite, despite the low carbon fiber content. This highlights the critical role of uniform fiber distribution in enhancing material performance. Slower loading speeds (1 mm/min) resulted in higher strength, emphasizing the influence of process parameters on mechanical behavior. Cyclic loading tests showed a gradual reduction in stiffness with increasing strain range, particularly for the CF-45° configuration. The warp and weft arrangement of the carbon fabric contributed to structural inhomogeneity but did not significantly affect the global mechanical properties. These findings demonstrate the suitability of PBT as a matrix material alongside PA6 for carbon fiber-reinforced thermoplastics, offering new possibilities for the design of advanced composite materials with tailored properties. Full article