Search Results (161)

In the preparation of rubber-recycled cement mortar (RRCM), recycled fine aggregates (RFA) were used to replace 95% of natural fine aggregates (NFA) by mass, with an additional 5% of NFA replaced by rubber particles (RP). Additionally, nano-silica (NS) was incorporated to replace ordinary Portland cement (OPC) by mass at a replacement of 0%, 1%, 2%, 3%, and 4%. The study aimed to investigate the effects of NS on the mechanical properties, freeze–thaw resistance, and microstructure of RRCM, using techniques such as X-ray diffraction (XRD), thermogravimetric analysis (TG-DTG), and scanning electron microscopy (SEM) to reveal the enhancement mechanisms. The results indicated that the compressive strength and flexural strength of RRCM at 28 days decreased by 10.3% and 10.1%, respectively, compared to NCM. After adding 1–3% NS, the mechanical properties of RRCM were improved, with the enhancements increasing as the NS content increased. Specifically, RRCM3 exhibited a 7.7% and 7.6% improvement in compressive and flexural strength, respectively, compared to RRCM0. After 30 freeze–thaw cycles, the strength loss rate of RCM was 27.51%, whereas the strength loss rate of RRCM3 was reduced to 20.13%, with better overall appearance integrity. Moreover, NS promoted the hydration of cement; reduced the contents of tricalcium silicate (C₃S), and dicalcium silicate (C₂S) and calcium hydroxide (CH); and facilitated the formation of additional hydration products that filled the interfacial transition zone (ITZ). The incorporation of 3% NS was found to provide the optimal improvement in RRCM. Full article

This study investigates the impact of particle size in fly ash derived from different coal sources on the performance of fly ash–cement systems. Utilizing a newly developed flotation classification method, physical properties of fly ash were examined to reveal variations among different particle sizes and coal sources. Thermal analysis was employed to analyze the calcium hydroxide content’s effect on the cement system, while selective dissolution methods were used to assess reaction rates. XRD analysis confirmed particle size effects. Results indicate that flotation classification optimizes the properties of fly ash, enhancing activity and flow values, where some of the ash fractions exhibit overall superior properties. The use of high-volume fly ash (50% fly ash replacement) promotes continued pozzolanic reactions, especially with smaller particle sizes. Reaction rates decrease with larger particle sizes, emphasizing the importance of classification. XRD analysis further supports these findings, revealing that smaller particle sizes favor cement hydration and pozzolanic reactions. Overall, this study provides insights into optimizing fly ash properties for enhanced concrete performance. Full article

To address the issues of numerous influencing factors on material quality, difficulty in determining the optimal mix proportion, and the need to clarify the formation mechanism when foam concrete is used as an internal mold for prefabricated components, this study conducted orthogonal tests to investigate the influence laws of fly ash content, foam content, foaming agent dilution ratio, and water–binder ratio on the dry density and compressive strength of foam concrete, and determined the optimal mix proportion via analysis of variance (ANOVA). Additionally, scanning electron microscopy (SEM) tests were performed to analyze the effects of these four factors on the microscopic pore morphology of foam concrete from a microscopic perspective, thereby revealing its formation mechanism, and engineering applications were carried out. The results show that the primary-to-secondary order of factors affecting the dry density and compressive strength of foam concrete is as follows: foam content (B) > water–binder ratio (D) > foaming agent dilution ratio (C) > fly ash content (A). The optimal mix proportion is 5% fly ash content, 18% foam content, a 30-fold foaming agent dilution ratio, and a water–binder ratio of 0.55. Under this mix proportion, the pore size of foam concrete ranges from 200 μm to 500 μm with uniform distribution, and the pore spacing is between 20 μm and 30 μm, with almost no connected pores. When the foam concrete slurry sets and hardens, hydration products such as calcium silicate hydrate (C-S-H) gel, calcium hydroxide, ettringite (AFt), and monosulfate aluminate (AFm) are generated around the bubbles. The mechanical properties of foam concrete are afforded by the combined action of these hydration products and the pore structure. Full article

The incorporation of fly ash into concrete reduces cement consumption by 10–30%, lowers CO₂ emissions by 30–50%, cuts costs by 15–25%, and enhances durability, thus reducing maintenance expenses. However, the predictive model for the elastic modulus of fly ash concrete subjected to calcium leaching is still lacking. Regarding the theoretical method, the content of calcium hydroxide and calcium silicate hydrate in fly ash–cement systems is quantitatively calculated according to the hydration reaction relationship between cement, fly ash, and water, and then the porosity of the fly ash–cement matrix and interface transition zone (ITZ) after calcium leaching can be obtained. Based on the theory of two-phase composite spheres and the non-uniform ITZ model, the prediction method for the elastic modulus of leached fly ash concrete can be constructed, which comprehensively considers key parameters such as fly ash content, non-uniform characteristics of the ITZ, and the water–binder ratio (w/b). Additionally, the corresponding experimental investigation is also designed to study the variation regulation of the leaching depth, leaching extent, and elastic modulus of fly ash concrete with leaching time. The prediction method for the elastic modulus of leached fly ash concrete is validated via self-designed experimental methods and third-party experiments. This study further delves into the specific effects of w/b, aggregate volume fraction (f_a), fly ash content, and ITZ thickness (h_ITZ) on the elastic modulus of leached concrete (E). The research findings indicate that an appropriate amount of fly ash can effectively enhance the leaching resistance of concrete. For a leaching degree of 10.0%, 30.0%, and 50.0%, E at w/b = 0.40 exceeds that of w/b = 0.60 by 26.71%, 28.43%, and 30.28%, respectively; E at h_ITZ = 10 μm exceeds that of h_ITZ = 50 μm by 16.96%, 15.80%, and 15.11%, respectively; and E at f_a = 65% is 39.82%, 43.15%, and 46.12% higher, respectively, than that of concrete with f_a = 45%. Furthermore, a linear correlation exists between the elastic modulus and the degree of leaching. The prediction method for the elastic modulus offers a theoretical foundation for in-depth exploration of the durability of leached mineral admixture concrete and its scientific application in practical engineering. Full article

Agriculture is one of the most important sectors of the global economy, but it increasingly faces sustainability challenges in meeting rising food demands. The intensive use of mineral fertilizers not only improves yields, but also causes negative environmental impacts such as increasing greenhouse gas emissions, water eutrophication, and soil degradation. To develop more sustainable solutions, the focus is on organic fertilizers, which are produced using waste and biostimulants such as amino acids. The aim of this study was to develop and characterize liquid nitrogen–calcium–magnesium fertilizers produced by decomposing dolomite with nitric acid followed by further processing and to enrich them with a powdered amino acid concentrate Naturamin-WSP and liquid extracts from digestate, a by-product of biogas production. Nutrient-rich extracts were obtained using water and potassium hydroxide solutions, with the latter proving more effective by yielding a higher organic carbon content (4495 ± 0.52 mg/L) and humic substances, which can improve soil structure. The produced fertilizers demonstrated favourable physical properties, including appropriate viscosity and density, as well as low crystallization temperatures (eutectic points from –3 to –34 °C), which are essential for storage and application in cold climates. These properties were achieved by adjusting the content of nitrogenous compounds and bioactive extracts. The results of the study show that liquid fertilizers enriched with organic matter can be an effective and more environmentally friendly alternative to mineral fertilizers, contributing to the development of the circular economy and sustainable agriculture. Full article

This study investigates the feasibility of using volcanic lapillus as a supplementary cementitious material (SCM) in mortar production to improve the sustainability of the cement industry. Cement production is one of the main sources of CO₂ emissions, mainly due to clinker production. Replacing clinker with SCMs, such as volcanic lapillus, can reduce the environmental impact while maintaining adequate mechanical properties. Experiments were conducted to replace up to 20 wt% of limestone Portland cement with volcanic lapillus. Workability, compressive strength, microstructure, resistance to alkali-silica reaction (ASR), sulfate, and chloride penetration were analyzed. The results showed that up to 10% replacement had a minimal effect on mechanical properties, while higher percentages resulted in reduced strength but still improved some durability features. The control sample cured 28 days showed a compressive strength of 43.05 MPa compared with 36.89 MPa for the sample containing 10% lapillus. After 90 days the respective values for the above samples were 44.76 MPa and 44.57 MPa. Scanning electron microscopy (SEM) revealed good gel–aggregate adhesion, and thermogravimetric analysis (TGA) confirmed reduced calcium hydroxide content, indicating pozzolanic activity. Overall, volcanic lapillus shows promise as a sustainable SCM, offering CO₂ reduction and durability benefits, although higher replacement rates require further optimization. Full article

This research focuses on improving the characteristics of recycled concrete and utilizing solid waste resources through the combination of industrial waste pre-impregnation and the carbonation process. A novel pre-impregnation–carbonation aggregate method is proposed to increase the content of carbonatable components in the surface-bonded mortar of recycled coarse aggregate by pre-impregnating it with carbide slag slurry (CSS). This approach enhances the subsequent carbonation effect and thus the properties of recycled aggregates. The experimental results showed that the method significantly improved the water absorption, crushing value, and apparent density of the recycled aggregate. Additionally, it enhanced the compressive strength, split tensile strength, and flexural strength of the recycled concrete produced using the aggregate improved by this method. Microanalysis revealed that CO₂ reacts with calcium hydroxide and hydrated calcium silicate (C-S-H) to produce calcite-type calcium carbonate and amorphous silica gel. These reaction products fill microcracks and pores on the aggregate and densify the aggregate–paste interfacial transition zone (ITZ), thereby improving the properties of recycled concrete. This study presents a practical approach for the high-value utilization of construction waste and the production of low-carbon building materials by enhancing the quality of recycled concrete. Additionally, carbon sequestration demonstrates broad promise for engineering applications. Full article

Rare earth elements (REEs) have garnered significant global attention due to their essential role in advanced technologies. Sri Lanka is endowed with various REE-bearing minerals, including the apatite-rich deposit in the Eppawala area, commonly known as Eppawala rock phosphate (ERP). However, direct extraction of REEs from ERP is technically challenging and economically unfeasible. This study introduces a novel, integrated approach for recovering REEs from ERP as a by-product of nitrophosphate fertilizer production. The process involves nitric acid-based acidolysis of apatite, optimized at 10 M nitric acid for 2 h at 70 °C with a pulp density of 2.4 mL/g. During cooling crystallization, 42 wt% of calcium was removed as Ca(NO₃)₂.4H₂O while REEs remained in the solution. REEs were then selectively precipitated as REE phosphates via pH-controlled addition of ammonium hydroxide, minimizing the co-precipitation with calcium. Further separation was achieved through selective dissolution in a sulfuric–phosphoric acid mixture, followed by precipitation as sodium rare earth double sulfates. The process achieved over 90% total REE recovery with extraction efficiencies in the order of Pr > Nd > Ce > Gd > Sm > Y > Dy. Samples were characterized for their phase composition, elemental content, and morphology. The fertilizer results confirmed the successful production of a nutrient-rich nitrophosphate (NP) with 18.2% nitrogen and 13.9% phosphorus (as P₂O₅) with a low moisture content (0.6%) and minimal free acid (0.1%), indicating strong agronomic value and storage stability. This study represents one of the pioneering efforts to valorize Sri Lanka’s apatite through a novel, dual-purpose, and circular approach, recovering REEs while simultaneously producing high-quality fertilizer. Full article

In order to address a challenging issue in the recycling of construction debris, the impact of carbonization treatment on the characteristics of recycled aggregates (RCAs) was experimentally examined in this work. Both direct carbonization and carbonization following calcium hydroxide pretreatment were used in the study to assess the impact of carbonization on the physical characteristics of recycled aggregates. According to the findings, carbonization raised the recycled aggregates’ apparent density while drastically lowering their porosity and water absorption (by as much as 20–30%). Although the recycled aggregate’s crushing index marginally increased with age, its overall physical qualities remained excellent. Pretreatment with calcium hydroxide can improve the physical characteristics of recycled aggregates, further optimize their pore structure, and efficiently encourage the carbonation process. Furthermore, recycled aggregate’s crushing index can be considerably decreased and its quality much enhanced by the ultrasonic cavitation treatment. According to the study, the carbonation-treated recycled aggregate’s microstructure was denser in the interfacial transition zone and had a stronger link with the cement paste, improving the recycled aggregate concrete’s overall performance. XRD, infrared spectral analysis, and SEM scanning were used to determine the increased calcium carbonate content in the recycled aggregate following carbonation treatment as well as its microstructure improvement process. The findings offer fresh concepts for achieving resource efficiency and environmental preservation through the use of recycled aggregates in concrete, as well as theoretical backing for their use. Full article

This study explores the impact of thermal cycling and rubber particle content on the static and dynamic compressive properties of rubber–polyethylene fiber-reinforced engineered cementitious composites (RPECC). Through static and dynamic compression tests, supplemented by scanning electron microscopy and energy-dispersive X-ray spectroscopy, the mechanical behavior and microstructural evolution of RPECC under thermal cycling were analyzed. Results indicate that increasing rubber content from 10% to 30% enhances toughness and strain capacity but reduces the static compressive strength of ECC by up to 17.9% at 30%. Thermal cycling reduced strength: static and dynamic compressive strengths decreased by 18.0% and 41.2%, respectively, after 270 cycles. Dynamic tests demonstrated that RPECC is sensitive to strain rate. For example, C-20 specimens exhibited increases in dynamic strength of 6.9% and 9.9% as strain rate rose from 60.2 s⁻¹ to 77.4 s⁻¹ and 110.8 s⁻¹, respectively, and the dynamic increase factor correlated linearly with strain rate. By contrast, excessive rubber content (30%) diminishes dynamic strengthening, indicating that 20% rubber is optimal for enhancing strain rate sensitivity. Thermal cycling facilitates the formation of hydration products, such as calcium hydroxide, and creates interfacial defects, further deteriorating mechanical performance. These findings provide a reliable foundation for optimizing RPECC mix design and ductility in environments subject to temperature fluctuations and dynamic loading. Full article

Treating poultry manure with calcium compounds is the primary technique for inactivating toxic pathogens such as bacteria, fungi, or viruses and decreasing the risk of biological contaminant release into the environment. On the other hand, the preferable method for reducing its volume is incineration with the aim of obtaining highly concentrated fertilizer. This paper presents the optimization of the biological deactivation of fresh poultry manure using calcium hydroxide via central composite design and response surface methodology. The results revealed that the optimum parameters required to decrease the number of E. coli bacteria to below the acceptable level (1000 CFU/g) were 5.0 wt% Ca(OH)₂ at 22 °C and an exposure time of 209 h. A regression analysis showed a good fit of the approximated parameters to the experimental data (R² = 98%, R_adj.² = 97%). Additionally, laboratory tests involving ash samples obtained from the incineration of poultry manure with the addition of 5 wt% calcium hydroxide (T = 500 °C, t = 5 h) intended as a fertilizer for degraded soils were performed. The analysis revealed that the content of pure manure ash in the sample incinerated with Ca(OH)₂ was approximately 47.5%. An X-ray diffraction analysis of the ash sample revealed that the main crystalline component was calcite (67.5 wt% CaCO₃), the phases containing phosphorus were apatite (3 wt%) and hydroxyapatite (3 wt%), whereas the source of the bioavailable form of phosphorus was the amorphous phase (15.5 wt%). An analysis of the ash extracts in a 2% citric acid solution revealed that the phosphorus concentration (287 mg/L) was two times lower than that of potassium (661 mg/L). The best results of phytotoxicity tests with Sinapis alba were obtained for soils containing no more than 1.0 wt% ash with calcium hydroxide. Full article

Milk of lime (MOL), a suspension of calcium oxide and calcium hydroxide, is vital in the purification of sugar beet and cane juices. This study evaluates the application of Fourier Transform Near-Infrared (FT-NIR) spectroscopy combined with chemometric models—Partial Least Squares (PLS) and Principal Component Regression (PCR)—for rapid, non-destructive assessment of key MOL parameters: density, total lime content, calcium oxide availability, and sucrose content. Ninety samples were analyzed using both wet chemistry and FT-NIR. The predictive performance was assessed using the coefficient of determination (R²). High predictive accuracy was observed for density (PLS: R² = 0.8274; PCR: R² = 0.8795) and calcium oxide availability (PLS: R² = 0.9035; PCR: R² = 0.9115). Total lime content showed moderate accuracy (PLS: R² = 0.7748; PCR: R² = 0.7983), while sucrose content exhibited low predictive power (PLS: R² = 0.2312; PCR: R² = 0.3747). The weak performance was noted for %CaO (PLS: R² = 0.4893; PCR: R² = 0.2409), likely due to spectral overlap and matrix complexity. Despite these challenges, FT-NIR remains a viable, reagent-free method for monitoring MOL, with the potential to enhance process control in the sugar industry. Future work should focus on refining calibration strategies and addressing spectral interferences to improve predictive accuracy for complex matrices. Full article

To study the chloride transport properties of urban rail transit structures under the action of stray currents, electrochemical tests were employed as part of this paper to investigate the impact of stray currents on cementitious materials and pore structure and further analyze the chloride distribution of specimens in different conditions. Results show that a stray current accelerates calcium ion precipitation in chloride solutions, reducing calcium hydroxide content compared to unelectrified specimens. This dissolution alters the concrete pore structure, increasing porosity by 26.3%, 31.2%, and 36.1% for specimens electrified at 50 mA, 100 mA, and 150 mA, respectively, after 28 days. The effect coefficient k_p of stray currents on the porosity of concrete is given with the test results. Electrified specimens have a higher chloride content compared to unelectrified specimens, with free chloride increasing more than bound chloride as current and time increase. The chloride ion binding capacity of concrete electrified at 150 mA is only 60% that of unelectrified, indicating the significant weakening effect of stray currents on it. Full article

Alkali-activated slag-like powder (AASP) materials are a novel type of binder prepared by activating slag-like powder (SP) with alkaline activators, providing a sustainable alternative to traditional cement for construction in remote mountainous regions, as well as on islands and reefs far from the inland, reducing transportation costs, shortening construction timelines, and minimizing energy consumption. SP is locally produced from siliceous and calcareous materials through calcining, water quenching, and grinding, exhibiting reactivity similar to that of ground granulated blast-furnace slag. In this study, siliceous sand and ground calcium carbonate powder were utilized to produce SP, with sodium carbonate (Na₂CO₃), sodium hydroxide (NaOH), and their mixture serving as activators. The results indicated that the Ca/Si ratio in SP, along with the dosage of Na₂CO₃ (D_sc) and Na₂O content (N_c) in the activator, significantly affected the compressive strength of AASP materials at both early and late stages. The 28-day compressive strength reached up to 78.95 MPa, comparable to that of alkali-activated slag (AAS) materials. The optimum mix ratio for Na₂CO₃-NaOH based AASP materials was also determined to be 80% D_sc and 8% N_c (C8N2-8). Microscopic analyses were employed to investigate the changes in the macroscopic properties of AASP materials driven by hydration products, chemical group composition, and microstructure. Full article

To address the high carbon emissions and resource dependency associated with conventional ordinary Portland cement (OPC) production, this study systematically investigated the preparation processes, hydration mechanisms, and chemical properties of high-belite calcium sulfoaluminate (HBCSA) and calcium sulfoaluminate (CSA) cements based from industrial solid wastes. The results demonstrate that substituting natural raw materials (e.g., limestone and gypsum) with industrial solid wastes—including fly ash, phosphogypsum, steel slag, and red mud—not only reduces raw material costs but also mitigates land occupation and pollution caused by waste accumulation. Under optimized calcination regimes, clinkers containing key mineral phases (C₄A₃S⁻ and C₂S) were successfully synthesized. Hydration products, such as ettringite (AFt), aluminum hydroxide (AH₃), and C-S-H gel, were identified, where AFt crystals form a three-dimensional framework through disordered growth, whereas AH₃ and C-S-H fill the matrix to create a dense interfacial transition zone (ITZ), thereby increasing the mechanical strength. The incorporation of steel slag and granulated blast furnace slag was found to increase the setting time, with low reactivity contributing to reduced strength development in the hardened paste. In contrast, Solid-waste gypsum did not significantly differ from natural gypsum in stabilizing ettringite (AFt). Furthermore, this study clarified key roles of components in HBCSA/CSA systems; Fe₂O₃ serves as a flux but substitutes some Al₂O₃, reducing C₄A₃S⁻ content. CaSO₄ retards hydration while stabilizing strength via sustained AFt formation. CaCO₃ provides nucleation sites and CaO but risks AFt expansion, degrading strength. These insights enable optimized clinker designs balancing reactivity, stability, and strength. Full article