Search Results (197)

The objective of this study was to investigate the influence of the lignocellulose filler originating in wood and non-wood raw materials, alone or together with collagen hydrolysate, on the properties and biodegradation ability of natural rubber latex. The different hydrophobicity of the polymer matrix and natural filler makes it difficult to obtain a homogenous structure of the composite. However, the easy biodegradation of the natural filler is a sufficient reason to seek a compromise between its useful properties and the environmental safety of the material. The composites were filled with lignocellulose filler: pine, spruce, and birch wood flour or willow, raspberry, and mallow non-wood flour. Collagen hydrolysate was used as a substitute for lignocellulosic filler, together or alone. The mechanical properties of the composites, their hardness, and equilibrium swelling were studied. In order to determine the morphology and interactions between filler and latex, scanning electron microscopy together with infrared spectroscopy were engaged. The results revealed that after the incorporation of 4 phr of the filler, the increase in mechanical strength was observed even despite the lack of compatibility between the filler and polymer matrix. The lignocellulose filler is a promising agent because its biodegradability contributes to the overall environmental safety of the polymer material. Full article

Forests are considered one of the most valuable natural areas in metropolitan region landscapes. Considering the sensitivity and ecosystem services provided by trees, the definition of urban forest ecosystems is nowadays based on a comprehensive understanding of the entire urban ecosystem. The effective capturing of particulate matter is one of the ecosystem services provided by urban forests. These ecosystems function as efficient biological filters. Plants accumulate pollutants passively via their leaves. Therefore, another ecosystem service provided by city forests could be the use of tree organs as bioindicators of pollution. This paper aims to estimate differences in trace metal pollution between the wooded urban areas of Vienna and Krakow using leaves of evergreen and deciduous trees as biomonitors. An additional objective of the research was to assess the ability of the applied tree species to act as biomonitors. Plant samples of five species—Norway spruce, Scots pine, European larch, common white birch, and common beech—were collected within both areas, in seven locations: four in the “Wienerwald” Vienna forest (Austria) and three in the “Las Wolski” forest in Krakow (Poland). Concentrations of Cr, Cu, Cd, Pb, and Zn in plant material were determined. Biomonitoring studies with deciduous and coniferous tree leaves showed statistically higher heavy metal contamination in the “Las Wolski” forest compared to the “Wienerwald” forest. Based on the conducted analyses and the literature study, it can be concluded that among the analyzed tree species, only two: European beech and common white birch can be considered potential indicators in environmental studies. These species appear to be suitable bioindicators, as both are widespread in urban woodlands of Central Europe and have shown the highest accumulation levels of trace metals. Full article

This study evaluated birch and oak ash extracts as alternative extractants for isolating humic substances (HSs) from peat and lignite. The effects of ultrasound intensity, extraction time, and temperature were optimized using a Box–Behnken design and validated statistically. The highest HSs yields were obtained from peat with oak ash extract (pH 13.18), compared to birch ash extract (pH 12.09). Optimal process parameters varied by variant, falling within 309–391 mW∙cm⁻², 116–142 min, and 67–79 °C. HSs extracted under optimal conditions were fractionated into humic acids (HAs) and fulvic acids (FAs), and then analyzed by elemental analysis, Fourier Transform Infrared Spectroscopy (FTIR), and Cross-Polarization Magic Angle Spinning Carbon-13 Nuclear Magnetic Resonance Spectroscopy (CP/MAS ¹³C NMR). The main differences in HSs quality were influenced by raw material and fraction type. However, the use of birch ash extract consistently resulted in a higher proportion of carboxylic structures across all fractions. Overall, wood ash extract, especially from oak, offers a sustainable and effective alternative to conventional extractants, particularly for HSs isolation from lignite. Notably, HSs yield from lignite with oak ash extract (29.13%) was only slightly lower than that achieved with 0.5 M NaOH (31.02%), highlighting its practical potential in environmentally friendly extraction technologies. Full article

Due to increasing environmental concerns and the scarcity of high-quality hardwood resources, enhancing wood properties—such as strength, surface smoothness, and impact resistance—has become essential, especially for veneer-based products. Wood densification is a promising method for such improvements, typically involving mechanical, thermo-mechanical, or hygrothermal-mechanical processes. However, most prior studies examined only one densification parameter at a time. This study systematically investigates the combined effects of equilibrium moisture content (EMC), pressing temperature, and pressure on birch veneer densification. Birch veneers were densified radially using four temperatures (90–210 °C), three pressures (1.8–5.4 MPa), and three EMC levels (5%–20%) for a fixed pressing time of 8 min, resulting in 36 unique combinations. Results showed that higher pressing pressure and higher initial EMC consistently led to greater veneer densification. Optimal outcomes were achieved under two distinct conditions: (1) 90 °C with high EMC and high pressure, and (2) 210 °C with the same high EMC and high pressure. Intermediate temperatures (130–170 °C) were less effective. Temperatures above 200 °C were found critical due to lignin softening beyond its glass transition temperature. These findings highlight the interactive role of key parameters and provide practical guidance for upgrading low-quality veneers into high-performance engineered wood products in a sustainable and resource-efficient manner. Full article

Various pretreatment methods, often employed in wood biorefineries, aim to disrupt the wood architecture, thereby enhancing the efficiency of hemicellulose extraction for increasing the production of bio-ethanol, bio-gas, and bio-oil, as well as improving the pulping process. Pretreatment for the pulping process has advantages such as enhanced yield in biorefined products and reducing chemicals and energy consumption. This study examined the effect of an alkaline hydrolysis of birch sawdust on the chemical composition, aggregation ability, and surface activity of soda lignin obtained by soda pulping. The alkaline hydrolysis of birch sawdust led to a remarkable removal of hemicellulose and reduced its mechanical strength. The resorption of lignin fragments on the lignocellulosic matrix during the hydrolysis was observed. The soda pulping of the original and the treated sawdust was carried out under laboratory conditions at 165 °C for 90 min, using 4.5% sodium hydroxide. A higher yield of soda lignin and pulp was obtained from the treated sawdust. The reduced content of acidic and methoxyl groups in the chemical composition of the soda lignin from the hydrolyzed sawdust was explained by the predominance of polycondensation reactions in forming its primary structure. The changes in size and zeta potential values of the formed lignin particles, as well as in the modality of the size distribution with decreasing pH, were studied. The early-proposed suggestion about the existence of structural complementarity in the formation of the ordered lignin supermolecular structures has been testified. The higher surface activity at the air–water interface for the soda lignin extracted from the hydrolyzed sawdust, compared to the lignin from the original residue, was mainly attributed to a lower content of the acidic groups in its chemical composition, shifting the hydrophilic–hydrophobic balance of its structure toward hydrophobicity. Full article

The effects of produced wood particles from three wood species—alder, birch, and larch—added in various amounts in the particle mixture consisting of spruce particles and three tested wood species in a particleboard core layer on selected physical and mechanical properties of particleboard were studied. In a laboratory, 16 mm thick three-layer urea–formaldehyde (UF)-bonded particleboards were produced at 5.23 MPa, 240 °C, and with a 10 s/mm pressing factor. Two particleboard surface layers consisted of fine spruce particles. In the particleboard core layer, spruce particles were combined with particles from alder, birch, and larch. The tested particleboards containing alder, birch, and larch were characterized by approximately identical thickness swelling and they met the requirements of the conventional values stated by major particleboard manufacturers of 8–10%. The tested particleboard in all variations met the minimum strength value P2 particleboard in three-point bending, which is conventionally set at 11.0 MPa. The tested particleboard also exceeded the required values of modulus of elasticity in bending and internal bond strength. Analysis of the relationships demonstrated by the density profile confirmed that all three investigated wood species are usable in a mixture of core particles of high-quality particleboard in the recommended amounts (10, 15, 20%). Full article

The use of non-wood forest products plays a significant role in sustainable development, especially in the context of regional development. One of the most important and promising raw materials is birch sap, which in European conditions is obtained mainly from silver birch (Betula pendula Roth). Research on the utility value of birch sap and the influence of a number of factors on its efficiency and quality has been carried out in many research centers, but so far, there are not many studies on the variability of such parameters as a function of time, taking into account the entire period of sap leakage. This research was carried out in birch stands of approximately 80 years in three forest site types: mixed coniferous forest, mixed broadleaved forest, and broadleaved forest. In each site, nine sample trees were selected using Hartig’s method. The daily and all-season sap yield obtained from individual trees was statistically characterized. The relationship between birch sap yield and select quantitative (tree height, absolute and relative crown length, and slenderness) and qualitative (forest site type, tree thickness class, and sap harvesting period) variables was examined. For the first time in the literature on the subject, there is a proposal to distinguish the phases of obtaining birch sap, which may bring new knowledge, both in relation to daily productivity and the quality of the sap. As a result, the smallest amount of sap was found in the initial leak phase, a slightly higher amount was found in the final phase, and the largest amount was found in the main phase. Regarding the forest site type and the interaction between the collection phase and forest site type, no statistically significant relationship with the average amount of obtained sap was found. Full article

This study evaluates the potential of various hardwood combinations in plywood production in response to increasing wood demand and a changing roundwood supply in Central Europe. Six different combinations of nine-layer plywood were produced using 2 mm rotary-cut veneers from lime (Tilia spp.), Norway maple (Acer platanoides), European hornbeam (Carpinus betulus), Sycamore maple (Acer pseudoplatanus), mountain ash (Sorbus aucuparia), and European beech (Fagus sylvatica) with phenol–formaldehyde adhesive, and they were compared to silver birch (Betula pendula) plywood as a reference. The raw densities of the test panels varied between 0.85 and 1.04 times the reference density (795 kg m⁻³). Flexural strengths (the modulus of rupture, MOR) ranged from 68 N mm⁻² to 104 N mm⁻² for a parallel fibre orientation and 44 N mm⁻² to 61 N mm⁻² for a perpendicular fibre orientation of the top layers. The modulus of elasticity (MOE) ranged from 7160 N mm⁻² to 11,737 N mm⁻² for the parallel fibre orientation and from 4366 N mm⁻² to 5575 N mm⁻² for the perpendicular orientation. The tensile shear strength varied between 0.91 and 1.69 times the reference (1.49 N mm⁻²). The thickness swelling after 24 h was higher in all variants than the reference (6.4%), with factors between 1.39 and 1.64. A significant effect was observed when layers with a lower density were arranged on the outside and those with a higher density in the core, resulting in a more uniform density distribution across the cross-section after hot pressing. This created a levelling effect on mechanical and physical properties, especially the modulus of rupture (MOR) and the modulus of elasticity (MOE). Overall, the evaluated hardwood combinations demonstrated comparable properties to the birch reference and industrially produced birch plywood. Full article

This work aimed at replacing per- or poly-fluoroalkyl substance (PFAS)-based food-serving containers with wood-based, oil- and grease-resistant food-serving containers. A novel container was developed by laminating wet cellulose nanofibril (CNF) films to both sides of yellow birch wood veneer using a food-grade polyamide–epichlorohydrin additive (PAE) as an adhesive. CNFs significantly improved the wood veneer container’s mechanical strength and barrier properties. The container’s mechanical testing results showed significant increases in flexural strength and modulus of elasticity (MOE) values in both parallel and perpendicular directions to the grain. All formulations of the container showed excellent oil and grease resistance properties by passing “kit” number 12 based on the TAPPI T 559 cm-12 standard. The water absorption tendency of the formulation treated at higher temperature, pressure, and longer press time showed similar performance to commercial paper plates containing PFASs. The developed composite demonstrates superior flexural strength and barrier properties, presenting a sustainable alternative to PFASs in food-serving containers. Both wood and CNFs stand out for their remarkable eco-friendliness, as they are biodegradable and naturally compostable. This unique characteristic not only helps minimize waste but also promotes a healthier environment. If scaled up, these novel containers may present a solution to the oil/grease resistance of bio-based food containers. Full article

Five series of rigid polyurethane–polyisocyanurate (RPU/PIR) foams were obtained. They were modified by ashes from burning paper (P) and wood: conifers (pine—S, spruce—S’) and deciduous trees (oak—D, birch—B). The ash was added to rigid polyurethane–polyisocyanurate foams (PU/PIR). In this way, five series of foams with different ash contents (from 1 to 9% wt.) were obtained: PP, PS, PD, PS’, PB. The model foam (reference—W) was obtained without filler. The basic properties, physico-mechanical, and thermal properties of the ashes and obtained foams were examined. It was specified, among other things, the cellular structure by scanning electron microscopy (SEM), and changes in chemical structure by Fourier-transform infrared spectroscopy (FTIR) were compared. The obtained foams were also subjected to thermostating in a circulating air dryer in increased temperature (120 °C) for 48 h. Ash tests showed that their skeletal density is about 2.9 g/cm³, and the pH of their solutions ranges from 9 to 13. The varied color of the ashes affected the color of the foams. SEM-EDS tests showed the presence of magnesium, calcium, silicon, potassium, aluminum, phosphorus, sodium, and sulfur in the ashes. Foam tests showed that pine ash is the most beneficial for foams, because it increases their compressive strength three times compared to W foam and improves their thermal stability. All ashes cause the residue after combustion of the foams (retention) to increase and the range of combustion of the samples to decrease. Full article

This study investigated the effect of using juvenile pine and birch wood for the production of particleboards with lowered density, glued with urea-formaldehyde (UF) resin. The wood used was characterized by a number of annual rings ranging from 5 to 13, which ensured that only juvenile wood was used in the study. In addition to the basic characteristics of the wood particles obtained from this type of raw material, the density profiles of the manufactured particleboards, the internal bond, bending strength, modulus of elasticity, swelling, and water absorption after short-term water exposure (2 h) were also investigated. The results were compared to particleboards made from industrial wood particles from mature wood. It was found that particleboards made from juvenile pine wood exhibited higher internal bond than those made from juvenile birch wood. The bending strength of boards made from both types of juvenile wood was comparable to that of industrial particleboards; however, the modulus of elasticity of the particleboards made from juvenile pine was lower, which indicates reduced stiffness. These particleboards also showed higher swelling and water absorption, which may limit their durability under humid conditions. In contrast, birch boards exhibited lower internal bond, but their bending strength and modulus of elasticity were similar to those of industrial particles-based particleboards. Birch boards also showed slightly better water resistance than pine particleboards made from juvenile wood. However, their swelling remained higher than that of industrial particleboards. Overall, particleboards made from juvenile wood, especially birch, show good potential for further research. Full article

The use of a novel chrono-potentiometry method (abbreviated as “CP”) in the determination of the moisture content in wood (abbreviated as “MC”) above the FSP is a practical application of the electrical charging effect (or ECE). In the specific case of this CP method, the ECE consists of an electrical charging phase for the wood and a discharge phase following the interruption of the charging current. The electrical resistance, R, and the electrical chargeability, Cha(E), of three hardwood species were determined from the final potential, E1, of the charging phase and the initial potential, E2, of the discharge phase, with the three hardwood species being birch (Betula spp.), aspen (Populus spp.), and black alder (Alnus glutinosa (L.) Gaertn). An auxiliary variable in the form of U (E1; E2) was defined as a function of E1 and E2. This was used as an independent electrical variable in the calibration model for a CP moisture meter for the three tree species when it came to the moisture content (MC) region above the FSP (fibre saturation point). It was found that upon a determination of the MC in the wood, the traditional calibration model (the R-model), which uses the electrical resistance of wood, was able to predict a single-measurement precision level of +/−10% for the MC while the U-model predicted a precision level of +/−1.75% for the MC over a single MC measurement in the wood. Full article

The eco-friendly lifestyle has gained traction at individual and industrial levels, especially following Europe’s “Green Deal”. While the woodworking industry in Latvia has made strides toward waste-free production, wood processing still produces by-products that require effective utilization. Instead of burning these residues for energy, a sustainable option is repurposing birch bark into suberinic acids adhesive, which is environmentally friendly and safe for humans. Research shows that thermally modified aspen, birch, and poplar veneers treated using the Termovuoto process at 160 °C/50 min, 204 °C/120 min, 214 °C/120 min, 217 °C/180 min, and 218 °C/30 min can be bonded with this adhesive and meet the EN 314-2:1993 standard for outdoor applications classified as Class 3 bonding. However, hydrothermally modified veneers treated at 160 °C 50 min do not bond successfully, failing to meet Class 3 requirements. Full article

Forest biomass is a renewable source of environmentally friendly material—wood. However, wood processing generates large amounts of by-products, including branches. These byproducts are often used as firewood; however, they can be used much more effectively. In this study, the pyrolysis of two woods, namely birch and pine, was proposed. The liquid products of pyrolysis were studied by FTIR spectroscopy, and the heating value of these products was evaluated. In order to find the optimal pyrolysis temperature from the point of view of the calorific value of the product, the process was carried out at four temperatures: 450, 500, 550, and 600 °C. The liquid product yielded three fractions, from which two were analyzed, namely the dense tar fraction and light liquid fraction. FTIR analysis results clearly demonstrated that samples from different fractions differ from one another, yet the results within the same fraction are remarkably similar. The tar fraction was characterized with a higher gross calorific value between 42 to 50 MJ/kg, while the liquid fraction gross calorific value was between 29 and 39 MJ/kg; in general, pine wood yielded products with higher calorific values. The pyrolysis of small wood industry by-products is an interesting method of utilization, yielding not only a liquid product with good calorific properties, but also a solid product, namely biochar, which may be used in carbon storage or used as a soil amendment. Full article

Coarse woody debris (CWD) is an essential component in forest ecosystems, playing a significant role in enhancing biodiversity, soil formation, and nutrient cycling through decomposition processes. CWD also contributes to greenhouse gas fluxes, particularly through CO₂ emissions. This study investigated the physical and chemical properties of CWD and the CO₂ effluxes from CWD of different decay classes. For this study, a range of CWD—from recently dead to highly decomposed wood—of native tree species such as silver birch (Betula pendula Roth), black alder (Alnus glutinosa (L.) Gaertn.), and Norway spruce (Picea abies (L.) H. Karst.) in hemiboreal forests were investigated. The findings showed that CWD properties significantly differed among tree species and CWD decay classes. Significant variations in wood density and total nitrogen (N) were observed in the early stages of CWD decay, with the highest values found for the deciduous tree species. The concentration of organic carbon (C) increased throughout the decomposition. The lowest CO₂ efflux from CWD was found for spruce CWD from all decay classes and it was the highest for black alder and silver birch, especially for the 3rd and 4th decay classes. CO₂ efflux was mainly influenced by the degree of decomposition, which was represented by the CWD decay class, followed by wood density and C content. Full article