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Keywords = biaxial stretching

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19 pages, 1883 KB  
Article
Validation of Soft Wearable Sensors for Wrist and Elbow Kinematics During Simulated Industrial Tasks
by Purva Talegaonkar, David Saucier, Laith Bani Khaled, Erin Tillery, Alana J. Turner, Russell Lowell, James Weinstein, John E. Ball, Harish Chander, Brian K. Smith and Reuben F. Burch V
Electronics 2026, 15(11), 2453; https://doi.org/10.3390/electronics15112453 - 3 Jun 2026
Viewed by 696
Abstract
Accurate and unobtrusive measurement of upper-limb kinematics is critical for advancing wearable sensing technologies used in industrial ergonomics, human–machine interaction, and real-time biomechanics monitoring. This study evaluates the performance of two soft, flexible wearable sensors—BendLabs biaxial angular displacement sensors and StretchSense capacitive stretch [...] Read more.
Accurate and unobtrusive measurement of upper-limb kinematics is critical for advancing wearable sensing technologies used in industrial ergonomics, human–machine interaction, and real-time biomechanics monitoring. This study evaluates the performance of two soft, flexible wearable sensors—BendLabs biaxial angular displacement sensors and StretchSense capacitive stretch sensors—for quantifying wrist and elbow motions during simulated dynamic industrial tasks. Wrist flexion–extension and radial–ulnar deviation were measured using BendLabs sensors mounted on the dorsal hand, while elbow flexion–extension was captured using StretchSense sensors positioned along the elbow joint. A multi-camera optical motion capture system served as the reference standard. Sensor data were preprocessed using baseline correction, smoothing, denoising, and normalized cross-correlation techniques to support temporal alignment with motion-capture recordings. Across all activities, the BendLabs sensors demonstrated moderate agreement with motion capture for wrist kinematics, with generally better performance for radial–ulnar deviation than for flexion–extension. StretchSense sensors demonstrated stronger agreement with motion capture for elbow flexion–extension, with performance that was generally consistent across task types. These findings support the feasibility of soft wearable sensors for capturing upper-limb kinematics during simulated occupational tasks and highlight their potential for integration into ergonomic assessment, occupational monitoring systems, and future industrial wearable platforms. Full article
(This article belongs to the Special Issue New Insights Into Smart and Intelligent Sensors)
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21 pages, 4041 KB  
Article
Multi-Parameter Effects on Equi-Biaxially Pre-Stretched Dielectric Elastomer Actuators for Dynamic Design
by Song Wu, Matthew O. T. Cole and Theeraphong Wongratanaphisan
Actuators 2026, 15(5), 252; https://doi.org/10.3390/act15050252 - 1 May 2026
Cited by 1 | Viewed by 665
Abstract
Due to the strong nonlinearity and large deformation characteristics of dielectric elastomer actuators (DEAs), the dynamic performance design of their actuators faces the challenge of complex multi-parameter coupling. This paper establishes a unified parameterized dynamic equation based on analytical mechanics, focusing on the [...] Read more.
Due to the strong nonlinearity and large deformation characteristics of dielectric elastomer actuators (DEAs), the dynamic performance design of their actuators faces the challenge of complex multi-parameter coupling. This paper establishes a unified parameterized dynamic equation based on analytical mechanics, focusing on the influence of electric field, excitation frequency, driving waveform, material properties, geometric dimensions, and pre-stretch ratio on their dynamic performance indicators. The study finds that the pre-stretch ratio, by changing the system’s potential energy and stiffness, not only directly affects the system’s dynamic performance. More importantly, throughout a complete driving voltage waveform cycle, the DEA exhibits alternating compression and expansion—a phenomenon rarely reported in existing studies. Accordingly, this study defines two new performance indicators: maximum stretch ratio (characterizing expansion) and minimum stretch ratio (characterizing compression). Based on this, the paper proposes a visualization design method using radar charts. By normalizing the performance indicators and plotting performance indicator radar charts, the interaction of various parameters can be intuitively presented, providing a new approach for the customized dynamic design of DEAs. Full article
(This article belongs to the Section Actuator Materials)
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21 pages, 1760 KB  
Article
Wrinkling Simulations of Fiber-Reinforced Elastomer Sheets Under Global Tensile Loading
by Marius M. Schasching, Robert Duy, Heinz E. Pettermann and Melanie Todt
J. Compos. Sci. 2026, 10(4), 192; https://doi.org/10.3390/jcs10040192 - 1 Apr 2026
Viewed by 554
Abstract
Numerical predictions of the wrinkling behavior of biaxially fiber-reinforced elastomer sheets are carried out under consideration of finite deformations. The Holzapfel–Gasser–Ogden material model is used to account for the anisotropic hyperelastic material behavior of the sheets, where material parameters are identified based on [...] Read more.
Numerical predictions of the wrinkling behavior of biaxially fiber-reinforced elastomer sheets are carried out under consideration of finite deformations. The Holzapfel–Gasser–Ogden material model is used to account for the anisotropic hyperelastic material behavior of the sheets, where material parameters are identified based on experimental data of tensile tests from literature. A Finite Element Method-based simulation strategy is presented to extract critical loading conditions and to access the postbuckling response using geometrical imperfections. Depending on the layup and aspect ratio of the sheets, wrinkling onset was predicted for global stretches between 10% and 25%. For sheets with fiber orientations [±45°] wrinkling is predicted at larger global stretches than for sheets with fiber orientations of [+30/60] for the same aspect ratio. Furthermore, it is shown that short sheets have a tendency towards symmetric wrinkling patterns whereas for long sheets asymmetric wrinkles are more likely to occur. Comparison of the numerical predictions with experiments from the literature shows that the geometrical characteristics of the wrinkles, such as wavelengths and amplitudes, can be well predicted. Far into the postbuckling regime, the deviations of the predicted wrinkling amplitudes and their experimental counterparts are around 30% or less. Full article
(This article belongs to the Section Composites Modelling and Characterization)
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14 pages, 5354 KB  
Article
Synergistic Mechanical Enhancement and Surface Treatment for Superior Tribological Performance of Ultra-High Molecular Weight Polyethylene (UHMWPE) Films
by Qiao Gu, Yuchen Feng and Lingxiang Jiang
Polymers 2026, 18(5), 603; https://doi.org/10.3390/polym18050603 - 28 Feb 2026
Viewed by 656
Abstract
This study systematically investigates a novel two-step approach to enhance the tribological performance of ultra-high molecular weight polyethylene (UHMWPE) by combining biaxial stretching with a subsequent hot pressing treatment. The significance of this work lies in developing a continuous, high-efficiency process that allows [...] Read more.
This study systematically investigates a novel two-step approach to enhance the tribological performance of ultra-high molecular weight polyethylene (UHMWPE) by combining biaxial stretching with a subsequent hot pressing treatment. The significance of this work lies in developing a continuous, high-efficiency process that allows for decoupled control of bulk mechanical properties and surface tribological characteristics. The material’s evolution was comprehensively characterized using Differential Scanning Calorimetry (DSC), Scanning Electron Microscopy (SEM), tensile testing, and a Taber Abraser. Results show that biaxial stretching significantly enhanced the film’s bulk mechanical strength and thermal stability, creating a wider processing window for subsequent surface treatment. A subsequent hot pressing step was then applied to refine the surface characteristics, yielding an optimal wear rate of 0.002 g/1000 cycles and a kinetic coefficient of friction (µk) of 0.106. Achieving such a concurrent optimization of high wear resistance and low friction is crucial in materials processing. The study demonstrates that the synergistic effect of biaxial orientation and hot pressing-induced crystal perfection provides a powerful and previously unreported pathway to achieving a superior balance of low wear and low friction in UHMWPE. Full article
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18 pages, 7234 KB  
Article
Preparation and Material–Structure–Performance Relationships of Biaxially Stretched Polytetrafluoroethylene (PTFE) Membranes for Air Filtration
by Chunxing Zhou, Haiqin Mo, Yiqin Shao, Parpiev Khabibulla, Juramirza Abdiramatovich Kayumov and Guocheng Zhu
Polymers 2026, 18(2), 199; https://doi.org/10.3390/polym18020199 - 11 Jan 2026
Viewed by 1168
Abstract
Biaxially stretched polytetrafluoroethylene (PTFE) membranes are promising media for high-efficiency air filtration because of their stable node–fiber microstructure and environmental durability. To clarify how resin properties and microstructure govern filtration behavior, ten PTFE resins with different average molecular weights (Mn) and particle size [...] Read more.
Biaxially stretched polytetrafluoroethylene (PTFE) membranes are promising media for high-efficiency air filtration because of their stable node–fiber microstructure and environmental durability. To clarify how resin properties and microstructure govern filtration behavior, ten PTFE resins with different average molecular weights (Mn) and particle size characteristics were processed into membranes under essentially identical biaxial stretching and sintering conditions. Resin particle size, fiber diameter and pore size distributions were quantified, and coefficients of variation (CVs), together with Spearman rank correlations, were used to analyze material–structure–performance links. Filtration efficiency, pressure drop and quality factor (QF) were measured according to ISO 29463-3 using 0.1–0.3 μm aerosols. Higher Mn combined with lower particle-size dispersion favored finer fibers and narrower pores, yielding efficiencies close to 100%, but increased pressure drop and slightly reduced QF, indicating a trade-off between efficiency and flow resistance. The sample with the lowest Mn in its group and a high machine-direction draw ratio (12×), showed pronounced fibril breakage, node coalescence, broadened pore-size distribution and degraded QF, illustrating the sensitivity of structure and performance to resin-process mismatch. Overall, the study establishes a hierarchical material–fiber–pore–performance relationship that can guide resin selection, structural tuning and process optimization of biaxially stretched PTFE membranes. Full article
(This article belongs to the Section Polymer Membranes and Films)
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12 pages, 4359 KB  
Article
Highly Selective Laser Ablation for Thin-Film Electronics: Overcoming Variations Due to Minute Optical Path Length Differences in Plastic Substrates
by Ahmed Fawzy, Henri Fledderus, Jie Shen, Wiel H. Manders, Emile Verstegen and Hylke B. Akkerman
J. Exp. Theor. Anal. 2025, 3(4), 38; https://doi.org/10.3390/jeta3040038 - 14 Nov 2025
Viewed by 1725
Abstract
Roll-to-roll production of thin organic and large-area electronic (TOLAE) devices often involves a two-step process per functional layer: a continuous, un-pattered deposition of the film and subsequent structuring process, such as laser ablation. Thin-film organic devices should be protected using ultra-barrier films. To [...] Read more.
Roll-to-roll production of thin organic and large-area electronic (TOLAE) devices often involves a two-step process per functional layer: a continuous, un-pattered deposition of the film and subsequent structuring process, such as laser ablation. Thin-film organic devices should be protected using ultra-barrier films. To perform laser ablation of functional layers on top of such barrier films, in particular that of transparent electrodes, highly selective laser ablation is required to completely remove the layers without damaging the thin-film barrier layers underneath. When targeting highly selective laser ablation of indium tin oxide (ITO) on top of silicon nitride (SiN) barrier layers with a 1064 nm picosecond or 1030 nm femtosecond laser, we observed the emergence of visible large-scale patterns due to local variations in ablation quality. Our investigations using a very sensitive Raman spectroscopy setup show that the observed ablation variations stem from subtle differences in optical path length within the heat-stabilized plastic substrates. These variations are likely caused by minute, localized changes in the refractive index, introduced during the bi-axial stretching process used in film fabrication. Depending on the optical path length, these variations lead to either constructive or destructive interference between the incoming laser beam and the light reflected from the back surface of the substrate. By performing laser ablation under an angle such that the reflected and incoming laser beam do not spatially overlap, highly selective uniform laser ablation can be performed, even for two stacked optically transparent layers. Full article
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17 pages, 3529 KB  
Article
Achieving High-Performance Polypropylene-Based Synthetic Paper with High-Modulus Organic Oligomer and Biaxial Stretching Force Field
by Zhenkun Wang, Quanjia Du, Weiyouran Hong, Guiying Yu, Haoran Wang, Yanshan Feng, Xinyu Chen, Hongrun Li, Shaoyun Guo and Chunhai Li
Polymers 2025, 17(21), 2951; https://doi.org/10.3390/polym17212951 - 5 Nov 2025
Cited by 2 | Viewed by 1340
Abstract
The widespread replacement of cellulose paper with polypropylene (PP)-based synthetic paper has been hindered by the relatively low stiffness and modulus of PP. Conventional approaches that incorporate rigid inorganic fillers can enhance the modulus but typically compromise processability and mechanical performance. In this [...] Read more.
The widespread replacement of cellulose paper with polypropylene (PP)-based synthetic paper has been hindered by the relatively low stiffness and modulus of PP. Conventional approaches that incorporate rigid inorganic fillers can enhance the modulus but typically compromise processability and mechanical performance. In this work, we propose a dual strategy by introducing high-modulus organic hydrogenated resin fillers (C9) and applying a biaxial stretching force field. The biaxial stretching process not only promotes PP crystallization but also significantly improves the uniform dispersion of C9 fillers. As a result, a composite paper with ultrafine C9 dispersion and a crystalline self-reinforced structure was successfully fabricated. The composite exhibits a modulus that is 38% higher than that of biaxially stretched neat PP and 218% higher than that of unstretched neat PP. Furthermore, under biaxial stretching, the C9 fillers impart a toughening effect, effectively overcoming the conventional stiffness–toughness trade-off. This work therefore provides a promising strategy for the scalable fabrication of high-performance PP-based synthetic paper. Full article
(This article belongs to the Special Issue Advanced Polymer Composites: Structure and Mechanical Properties)
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24 pages, 3215 KB  
Article
Biaxial Stretching of PBAT/PLA Blends for Improved Mechanical Properties
by Nikki Rodriguez, Osnat Gillor, Murat Guvendiren and Lisa Axe
Polymers 2025, 17(19), 2651; https://doi.org/10.3390/polym17192651 - 30 Sep 2025
Cited by 6 | Viewed by 2355
Abstract
Biodegradable polymers offer a promising solution to the growing issue of global microplastic pollution. To effectively replace conventional plastics, it is essential to develop strategies for tuning the properties of biodegradable polymers without relying on additives. Biaxial stretching promotes anisotropic crystallization in polymer [...] Read more.
Biodegradable polymers offer a promising solution to the growing issue of global microplastic pollution. To effectively replace conventional plastics, it is essential to develop strategies for tuning the properties of biodegradable polymers without relying on additives. Biaxial stretching promotes anisotropic crystallization in polymer domains, thereby altering the mechanical performance of polymer blends. In this study, we employed a design of experiment (DoE) approach to investigate the effects of biaxial stretching at three drawing temperatures (Tds) and draw ratios (λs) on a biodegradable blend of poly(lactic acid) (PLA) and poly(butylene adipate-co-terephthalate) (PBAT), aiming to optimize both the strength and ductility. The DoE analysis revealed that the composition, the λ, the interaction between the λ and composition, and the interaction between the Td and composition significantly affect the elongation at break (εBreak). For the stress at break (σBreak), the most influential factors were the interaction between the λ and PLA concentration; a three-way interaction among the λ, PLA, and Td; the Td; the λ; and finally the PLA concentration alone. The optimal εBreak and σBreak were achieved at a λ = 5 × 5 and Td = 110 °C, with a composition of 10% PLA and 90% PBAT. The stretched samples exhibited higher crystallinity compared to the pressed samples across all compositions. This work demonstrates that in addition to the composition, the processing parameters, such as the λ and Td, critically influence the mechanical properties, enabling performance enhancements without the need for compatibilizers or toxic additives. Full article
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20 pages, 12005 KB  
Article
In Situ Constructing Highly Aligned Ribbon-like PHBV Lamellae in PBAT: Towards Strong, Ductile and High-Barrier PBAT/PHBV Films
by Yaqiao Wang, Jun Xu and Baohua Guo
Materials 2025, 18(17), 3947; https://doi.org/10.3390/ma18173947 - 22 Aug 2025
Cited by 4 | Viewed by 1790
Abstract
This study presents a facile approach to fabricate PBAT/PHBV films with superior mechanical and barrier properties by in situ forming ribbon-like lamellae, achieving a PHBV platelet-reinforced PBAT films. The fabrication involves melt blending of PBAT and PHBV, where styrene–methyl methacrylate–glycidyl methacrylate copolymer as [...] Read more.
This study presents a facile approach to fabricate PBAT/PHBV films with superior mechanical and barrier properties by in situ forming ribbon-like lamellae, achieving a PHBV platelet-reinforced PBAT films. The fabrication involves melt blending of PBAT and PHBV, where styrene–methyl methacrylate–glycidyl methacrylate copolymer as a multifunctional reactive compatibilizer (RC) regulates PHBV domain size by forming a branched/cross-linked PBAT-B-PHBV structure. The introduction of a compatibilizer into the PBAT/PHBV system can reduce domain size and improve interfacial adhesion, thereby elevating PBAT’s storage modulus and complex viscosity for optimized blow-molding processability. During blow-molding, biaxial stretching with rapid cooling transforms PHBV sea–island structures into well-aligned ribbon-like lamellae. Notably, when PHBV content is ≤30 wt.%, lamellae form in the PBAT matrix, significantly enhancing both mechanical and barrier properties. The addition of RC reduces the lateral dimensions of PHBV lamellae while increasing PHBV number density. The introduction of 0.2 wt.% RC optimizes lamellar dimensions and density to maximize permeation pathway tortuosity. Ultimately, the lamellae in the PBAT matrix yield remarkable property enhancements: yield strength increased by >600%, elastic modulus by >200%, and water vapor/oxygen transmission rate reduced by ~81% and ~85%, respectively. Full article
(This article belongs to the Section Thin Films and Interfaces)
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17 pages, 3907 KB  
Review
Polyamide 6 as a Liner Material for Type IV Hydrogen Storage Cylinders: Performance Challenges and Modification Strategies
by Wenyan Wang, Guanxi Zhao, Xiao Ma, Dengxun Ren, Min Nie and Rui Han
Polymers 2025, 17(13), 1848; https://doi.org/10.3390/polym17131848 - 1 Jul 2025
Cited by 12 | Viewed by 2845
Abstract
Type IV hydrogen storage cylinders are pivotal for high-pressure hydrogen storage and transportation, offering advantages such as lightweight design, high hydrogen storage density, and cost efficiency. Polyamide 6 (PA6) has emerged as a promising liner material due to its excellent mechanical strength, chemical [...] Read more.
Type IV hydrogen storage cylinders are pivotal for high-pressure hydrogen storage and transportation, offering advantages such as lightweight design, high hydrogen storage density, and cost efficiency. Polyamide 6 (PA6) has emerged as a promising liner material due to its excellent mechanical strength, chemical resistance, and gas barrier properties. However, challenges remain, including high hydrogen permeability and insufficient mechanical performance under extreme temperature and pressure conditions. This review systematically summarizes recent advances in modification strategies to enhance PA6’s suitability for Type IV hydrogen storage cylinders. Incorporating nanofillers (e.g., graphene, montmorillonite, and carbon nanotubes) significantly reduces hydrogen permeability. In situ polymerization and polymer blending techniques improve toughness and interfacial adhesion (e.g., ternary blends achieve a special increase in impact strength). Multiscale structural design (e.g., biaxial stretching) and process optimization further enhance PA6’s overall performance. Future research should focus on interdisciplinary innovation, standardized testing protocols, and industry–academia collaboration to accelerate the commercialization of PA6-based composites for hydrogen storage applications. This review provides theoretical insights and engineering guidelines for developing high-performance liner materials. Full article
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33 pages, 2465 KB  
Article
A Unified Size-Dependent Theory for Analyzing the Free Vibration Behavior of an FG Microplate Under Fully Simply Supported Conditions and Magneto-Electro-Thermo-Mechanical Loads Considering Couple Stress and Thickness Stretching Effects
by Chih-Ping Wu and Cheng-Dao Hsu
J. Compos. Sci. 2025, 9(5), 201; https://doi.org/10.3390/jcs9050201 - 24 Apr 2025
Cited by 5 | Viewed by 1379
Abstract
This work develops a unified size-dependent shear deformation theory (SDSDT) to analyze the free vibration behavior of a functionally graded (FG) magneto-electro-elastic (MEE) microplate under fully simply supported conditions, open- or closed-circuit surface conditions, biaxial compression, magnetic and electric potentials, and uniform temperature [...] Read more.
This work develops a unified size-dependent shear deformation theory (SDSDT) to analyze the free vibration behavior of a functionally graded (FG) magneto-electro-elastic (MEE) microplate under fully simply supported conditions, open- or closed-circuit surface conditions, biaxial compression, magnetic and electric potentials, and uniform temperature changes based on consistent couple stress theory (CCST). The FG-MEE microplate is composed of BaTiO3 (a piezoelectric material) and CoFe2O4 (a magnetostrictive material). Various CCST-based SDSDTs, considering couple stress and thickness stretching effects, can be reproduced by employing a generalized shape function that characterizes shear deformation distributions along the thickness direction within the unified SDSDT. These CCST-based SDSDTs encompass the size-dependent classical plate theory (CPT), first-order shear deformation theory (SDT), Reddy’s refined SDT, exponential SDT, sinusoidal SDT, and hyperbolic SDT. The unified SDSDT is validated by comparing its solutions with relevant three-dimensional solutions available in the literature. After validation and comparison studies, we conduct a parametric study, whose results indicate that the effects of thickness stretching, material length-scale parameter, inhomogeneity index, and length-to-thickness ratio, as well as the magnitude of biaxial compressive forces, electric potential, magnetic potential, and uniform temperature changes significantly impact the microplate’s natural frequency. Full article
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17 pages, 12970 KB  
Article
Design of Dielectric Elastomer Actuator and Its Application in Flexible Gripper
by Xiaoyu Meng, Jiaqing Xie, Haoran Pang, Wenchao Wei, Jiping Niu, Mingqiang Zhu, Fang Gu, Xiaohuan Fan and Haiyan Fan
Micromachines 2025, 16(1), 107; https://doi.org/10.3390/mi16010107 - 19 Jan 2025
Cited by 10 | Viewed by 4561
Abstract
Dielectric elastomer actuators (DEAs) are difficult to apply to flexible grippers due to their small deformation range and low output force. Hence, a DEA with a large bending deformation range and output force was designed, and a corresponding flexible gripper was developed to [...] Read more.
Dielectric elastomer actuators (DEAs) are difficult to apply to flexible grippers due to their small deformation range and low output force. Hence, a DEA with a large bending deformation range and output force was designed, and a corresponding flexible gripper was developed to realize the function of grasping objects of different shapes. The relationship between the pre-stretch ratio and DEA deformation degree was tested by experiments. Based on the performance test results of the dielectric elastomer (DE), the bending deformation process of DEAs with different shapes was simulated by Finite Element Method (FEM) simulation. DEAs with different shapes were prepared through laser cutting and the relationship between the voltage and the bending angle, and the output force of the DEAs was measured. The result shows that under uniaxial stretching, the deformation of the DEA in the stretching direction gradually increases and decreases in the unstretched direction with the increase in the pre-stretch ratio. Under biaxial stretching, DEA deformation increases with the increase in the pre-stretch ratio. The shape of the DEA has a certain influence on the bending deformation range under the same conditions, and the elliptical DEA has a larger bending deformation range and higher output force compared with the rectangular DEA and the trapezium DEA. The elliptical DEA can produce a bending deformation of 40° and an output force of 37.2 mN at a voltage of 24 kV. The three-finger flexible gripper composed of an elliptical DEA can realize the grasping of a paper cup. Full article
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12 pages, 2446 KB  
Article
Deformation-Induced Electromagnetic Reconfigurable Square Ring Kirigami Metasurfaces
by Xuanqing Fan, Zijian Pan, Yunfan Zhu, Min Li, Yunpeng Ma and Yuhang Li
Micromachines 2024, 15(12), 1493; https://doi.org/10.3390/mi15121493 - 13 Dec 2024
Cited by 6 | Viewed by 1995
Abstract
The continuous expansion of wireless communication application scenarios demands the active tuning of electromagnetic (EM) metamaterials, which is essential for their flexible adaptation to complex EM environments. However, EM reconfigurable systems based on intricate designs and smart materials often exhibit limited flexibility and [...] Read more.
The continuous expansion of wireless communication application scenarios demands the active tuning of electromagnetic (EM) metamaterials, which is essential for their flexible adaptation to complex EM environments. However, EM reconfigurable systems based on intricate designs and smart materials often exhibit limited flexibility and incur high manufacturing costs. Inspired by mechanical metastructures capable of switching between multistable configurations under repeated deformation, we propose a planar kirigami frequency selective surface (FSS) that enables mechanical control of its resonant frequency. This FSS is composed of periodically arranged copper square-ring resonators embedded in a kirigami-structured ecoflex substrate. Through simple tensile deformation, the shapes and positions of the square-ring resonators on the kirigami substrate are altered, resulting in changes to the coupling between capacitance and inductance, thereby achieving active tuning. Combining EM finite element simulations and transmittance measurements, we demonstrate that biaxial mechanical stretching allows for continuous adjustment of the FSS resonant frequency and −10 dB bandwidth. Additionally, the FSS exhibits excellent polarization and incident angle stability. Structural parameterization of the square-ring kirigami FSS was conducted to elucidate the deformation–electromagnetic coupling mechanism underlying the active tuning. These insights provide a foundation for guiding the application of square-ring kirigami FSS in various practical engineering domains. Full article
(This article belongs to the Special Issue Metamaterials for Sensing Applications)
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21 pages, 8085 KB  
Article
Enhanced Impact Resistance, Oxygen Barrier, and Thermal Dimensional Stability of Biaxially Processed Miscible Poly(Lactic Acid)/Poly(Butylene Succinate) Thin Films
by Piyawanee Jariyasakoolroj, Pramote Kumsang, Supanut Phattarateera and Noppadon Kerddonfag
Polymers 2024, 16(21), 3033; https://doi.org/10.3390/polym16213033 - 29 Oct 2024
Cited by 10 | Viewed by 3436
Abstract
This study investigates the crystallization, microstructure, and performance of poly(lactic acid)/poly(butylene succinate) (PLA/PBS) thin films processed through blown film extrusion and biaxial orientation (BO) at various blend ratios. Succinic anhydride (SA) was used to enhance interfacial adhesion in PLA-rich blends, while blends near [...] Read more.
This study investigates the crystallization, microstructure, and performance of poly(lactic acid)/poly(butylene succinate) (PLA/PBS) thin films processed through blown film extrusion and biaxial orientation (BO) at various blend ratios. Succinic anhydride (SA) was used to enhance interfacial adhesion in PLA-rich blends, while blends near 50/50 formed co-continuous phases without SA. Biaxial stretching and annealing, adjusted according to the crystallization behavior of PLA and PBS, significantly influenced crystallinity, crystallite size, and molecular orientation. Biaxial stretching induced crystallization and ordered chain alignment, particularly at the cold crystallization temperature (Tcc), leading to a 70–80-fold increase in impact resistance compared to blown films. Annealing further enhanced crystallinity, especially at the Tcc of PLA, resulting in larger crystallite sizes. BO films demonstrated reduced thermal shrinkage due to improved PLA crystalline structure, whereas PLA-rich blown films showed higher shrinkage due to PLA’s lower thermal resistance. The SA-miscibilized phase reduced oxygen transmission in blown films, while BO films exhibited higher permeability due to anisotropic crystal orientation. However, the annealing of BO films, especially at high temperature (Tcc of PLA), further lowered oxygen permeability by promoting the crystallization of both PLA and PBS phases. Overall, the combination of SA compatibilization, biaxial stretching, and annealing resulted in substantial improvements in mechanical strength, dimensional stability, and oxygen barrier properties, highlighting the potential of these films for packaging applications. Full article
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14 pages, 9101 KB  
Article
Mimicking Polymer Processing Conditions on the Meso-Scale: Relaxation and Crystallization in Polyethylene Systems after Uni- and Biaxial Stretching
by Dirk Grommes, Olaf Bruch and Dirk Reith
Molecules 2024, 29(14), 3391; https://doi.org/10.3390/molecules29143391 - 18 Jul 2024
Cited by 2 | Viewed by 2054
Abstract
Highly varying process conditions drive polymers into nonequilibrium molecular conformations. This has direct implications for the resulting structural and mechanical properties. This study rigorously investigated processing-property relations from a microscopic perspective. The corresponding models use a mesoscale molecular dynamics (MD) approach. Different loading [...] Read more.
Highly varying process conditions drive polymers into nonequilibrium molecular conformations. This has direct implications for the resulting structural and mechanical properties. This study rigorously investigated processing-property relations from a microscopic perspective. The corresponding models use a mesoscale molecular dynamics (MD) approach. Different loading conditions, including uniaxial and biaxial stretching, along with various cooling conditions, were employed to mimic process conditions on the micro-scale. The resulting intricate interplay between equi-biaxial stretching, orientation, and crystallization behavior in long polyethylene chains was reviewed. The study reveals notable effects depending on different cooling and biaxial stretching procedures. The findings emphasize the significance of considering distributions and directions of chain ordering. Local inspections of trajectories unveil that crystal growth predominantly occurs in regions devoid of entanglements. Full article
(This article belongs to the Section Computational and Theoretical Chemistry)
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