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Keywords = bandgap grading

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24 pages, 1069 KB  
Article
Is GaN the Enabler of High-Power-Density Converters? An Overview of the Technology, Devices, Circuits, and Applications
by Paul-Catalin Medinceanu, Alexandru Mihai Antonescu and Marius Enachescu
Electronics 2026, 15(3), 510; https://doi.org/10.3390/electronics15030510 - 25 Jan 2026
Viewed by 489
Abstract
The growing demand for electric vehicles, renewable energy systems, and portable electronics has led to the widespread adoption of power conversion systems. Although advanced structures like the superjunction MOSFET have prolonged the viability of silicon in power applications, maintaining its dominance through cost [...] Read more.
The growing demand for electric vehicles, renewable energy systems, and portable electronics has led to the widespread adoption of power conversion systems. Although advanced structures like the superjunction MOSFET have prolonged the viability of silicon in power applications, maintaining its dominance through cost efficiency, Si-based technology is ultimately constrained by its intrinsic limitations in critical electric fields. To address these constraints, research into wide bandgap semiconductors aims to minimize system footprint while maximizing efficiency. This study reviews the semiconductor landscape, demonstrating why Gallium Nitride (GaN) has emerged as the most promising technology for next-generation power applications. With a critical electric field of 3.75MV/cm (12.5× higher than Si), GaN facilitates power devices with lower conduction loss and higher frequency capability when compared to their Si counterpart. Furthermore, this paper surveys the GaN ecosystem, ranging from device modeling and packaging to monolithic ICs and switching converter implementations based on discrete transistors. While existing literature primarily focuses on discrete devices, this work addresses the critical gap regarding GaN monolithic integration. It synthesizes key challenges and achievements in the design of GaN integrated circuits, providing a comprehensive review that spans semiconductor technology, monolithic circuit architectures, and system-level applications. Reported data demonstrate monolithic stages reaching 30mΩ and 25MHz, exceeding Si performance limits. Additionally, the study reports on high-density hybrid implementations, such as a space-grade POL converter achieving 123.3kW/L with 90.9% efficiency. Full article
(This article belongs to the Section Microelectronics)
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22 pages, 5572 KB  
Review
Bandgap Engineering of CIGS: Active Control of Composition Gradient
by Zhihao Wu, Shengye Tao, Mengyao Jia, Junsu Han, Jihui Zhou, Maria Baranova, Qianming Gong, Daming Zhuang and Ming Zhao
Energies 2025, 18(23), 6089; https://doi.org/10.3390/en18236089 - 21 Nov 2025
Cited by 1 | Viewed by 734
Abstract
The tunable bandgap of CIGSe has established bandgap engineering as a pivotal research direction for advancing the efficiency frontiers of solar cells. In particular, the proposal of the V-shaped bandgap gradient has motivated extensive efforts to achieve precise control over elemental composition and [...] Read more.
The tunable bandgap of CIGSe has established bandgap engineering as a pivotal research direction for advancing the efficiency frontiers of solar cells. In particular, the proposal of the V-shaped bandgap gradient has motivated extensive efforts to achieve precise control over elemental composition and spatial distribution within the absorber layer. Against this backdrop, this review systematically classifies active control strategies—such as surface sulfurization, Ga grading, and Ag alloying—according to their doping mechanisms and the resulting bandgap profiles. It further evaluates emerging profiles, including the “hockey-stick” distribution, against the conventional V-shaped benchmark, and explores future pathways for bandgap engineering in next-generation, high-efficiency photovoltaic devices. Further improvements in photovoltaic efficiency can effectively boost power generation and lower solar power costs, providing a practical solution to future energy and environmental challenges. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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22 pages, 9030 KB  
Article
Seismic Isolation Performance of Seismic Metamaterials Based on Embedded Dual-Resonator Coupled Auxetic Materials
by Liuchang Zhang, Yue Meng, Shuliang Cheng, Shuo Zhang, Yajun Xin, Yongtao Sun and Qingxin Zhao
Materials 2025, 18(22), 5124; https://doi.org/10.3390/ma18225124 - 11 Nov 2025
Viewed by 834
Abstract
Due to their long wavelengths and low attenuation characteristics, seismic waves pose serious threats to engineering structures, resulting in an urgent need to develop effective vibration mitigation strategies. Locally resonant phononic crystals provide a novel approach to controlling seismic wave propagation, while auxetic [...] Read more.
Due to their long wavelengths and low attenuation characteristics, seismic waves pose serious threats to engineering structures, resulting in an urgent need to develop effective vibration mitigation strategies. Locally resonant phononic crystals provide a novel approach to controlling seismic wave propagation, while auxetic materials have attracted considerable attention for their excellent energy absorption capabilities. To achieve broadband low-frequency seismic isolation, this study proposes a seismic metamaterial composed of embedded dual resonators combined with auxetic materials. The bandgap characteristics of the structure are calculated using the finite element method, and the mechanism of bandgap formation is elucidated through vibrational mode analysis. A parametric study is conducted to investigate the influence of mass block substitution on bandgap tunability, and complex band analysis is employed to evaluate seismic wave attenuation within the bandgap range. Furthermore, a graded composite structure is designed, and its seismic isolation performance is validated through frequency- and time-domain simulations. The results show that the proposed composite structure exhibits significant isolation effects within the 2.7–5 Hz bandgap range. Even under excitation with the Chi-Chi earthquake, whose dominant frequency lies outside the bandgap, the peak ground acceleration is reduced by approximately 42%, and the overall acceleration response is effectively suppressed. These findings provide a promising new design strategy for achieving broadband and low-frequency seismic protection in engineering applications. Full article
(This article belongs to the Section Construction and Building Materials)
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21 pages, 6518 KB  
Article
Topological Rainbow Trapping in One-Dimensional Magnetoelastic Phononic Crystal Slabs
by Wen Xiao, Fuhao Sui, Jiujiu Chen, Hongbo Huang and Tao Luo
Magnetochemistry 2025, 11(10), 83; https://doi.org/10.3390/magnetochemistry11100083 - 25 Sep 2025
Viewed by 812
Abstract
We design a one-dimensional magnetoelastic phononic crystal slab composed of the smart magnetostrictive material Terfenol-D and pure tungsten. Band inversion and topological phase transitions are achieved by modifying the geometric parameters of the non-magnetic medium within the unit cell. The emergence of topological [...] Read more.
We design a one-dimensional magnetoelastic phononic crystal slab composed of the smart magnetostrictive material Terfenol-D and pure tungsten. Band inversion and topological phase transitions are achieved by modifying the geometric parameters of the non-magnetic medium within the unit cell. The emergence of topological interface states within overlapping bandgaps, exhibiting distinct topological properties, along with their robustness against interfacial structural defects, is confirmed. The coupling effects between adjacent topological interface states in a sandwich-like supercell configuration are investigated, and their tunability under external magnetic fields is demonstrated. A Su-Schrieffer-Heeger (SSH) phononic crystal slab system under gradient magnetic fields is proposed. Critically, and in stark contrast to previous static or structurally graded designs, we achieve reconfigurable rainbow trapping of topological interface states solely by reprogramming the gradient magnetic field, leaving the physical structure entirely unchanged. This highly localized, compact, and broadband-tunable topological rainbow trapping system design holds significant promise for applications in elastic energy harvesting, wave filtering, and multi-frequency signal processing. Full article
(This article belongs to the Special Issue Advances in Low-Dimensional Magnetic Materials)
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46 pages, 3434 KB  
Review
System-Level Compact Review of On-Board Charging Technologies for Electrified Vehicles: Architectures, Components, and Industrial Trends
by Pierpaolo Dini, Sergio Saponara, Sajib Chakraborty and Omar Hegazy
Batteries 2025, 11(9), 341; https://doi.org/10.3390/batteries11090341 - 17 Sep 2025
Cited by 1 | Viewed by 3401
Abstract
The increasing penetration of electrified vehicles is accelerating the evolution of on-board and off-board charging systems, which must deliver higher efficiency, power density, safety, and bidirectionality under increasingly demanding constraints. This article presents a system-level review of state-of-the-art charging architectures, with a focus [...] Read more.
The increasing penetration of electrified vehicles is accelerating the evolution of on-board and off-board charging systems, which must deliver higher efficiency, power density, safety, and bidirectionality under increasingly demanding constraints. This article presents a system-level review of state-of-the-art charging architectures, with a focus on galvanically isolated power conversion stages, wide-bandgap-based switching devices, battery pack design, and real-world implementation trends. The analysis spans the full energy path—from grid interface to battery terminals—highlighting key aspects such as AC/DC front-end topologies (Boost, Totem-Pole, Vienna, T-Type), high-frequency isolated DC/DC converters (LLC, PSFB, DAB), transformer modeling and optimization, and the functional integration of the Battery Management System (BMS). Attention is also given to electrochemical cell characteristics, pack architecture, and their impact on OBC design constraints, including voltage range, ripple sensitivity, and control bandwidth. Commercial solutions are examined across Tier 1–3 suppliers, illustrating how technical enablers such as SiC/GaN semiconductors, planar magnetics, and high-resolution BMS coordination are shaping production-grade OBCs. A system perspective is maintained throughout, emphasizing co-design approaches across hardware, firmware, and vehicle-level integration. The review concludes with a discussion of emerging trends in multi-functional power stages, V2G-enabled interfaces, predictive control, and platform-level convergence, positioning the on-board charger as a key node in the energy and information architecture of future electric vehicles. Full article
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11 pages, 4382 KB  
Communication
High-Speed and Broadband InGaAs/InP Photodiode with InGaAsP Graded Bandgap Layers
by Guohao Yang, Tianhong Liu, Jinping Li, Baile Chen and Cunzhu Tong
Sensors 2025, 25(9), 2841; https://doi.org/10.3390/s25092841 - 30 Apr 2025
Cited by 4 | Viewed by 2825
Abstract
This study presents the development of a high-speed, broadband InGaAs/InP photodiode suitable for advanced sensing and optical detection applications across the critical wavelength range of 850–1550 nm. By employing an InAlAs window layer to replace conventional InP, the device significantly improves sensitivity at [...] Read more.
This study presents the development of a high-speed, broadband InGaAs/InP photodiode suitable for advanced sensing and optical detection applications across the critical wavelength range of 850–1550 nm. By employing an InAlAs window layer to replace conventional InP, the device significantly improves sensitivity at 850 nm. Additionally, the substitution of traditional GaAs-based materials with InGaAs enhances responsivity and reduces carrier transit times, enabling precise, high-speed signal detection. The introduction of InGaAsP graded bandgap layers (GBLs) further improves device reliability and reduces absorption losses associated with defects, thus enhancing overall sensing performance. The fabricated photodiode, featuring an active area diameter of 35 µm, achieves high bandwidths of 20 GHz, 15 GHz, and 15.5 GHz at 850 nm, 1310 nm, and 1550 nm, respectively, along with responsivities of 0.5 A/W, 0.72 A/W, and 0.64 A/W. These characteristics make the device well suited for integration into multi-wavelength optical sensing systems, broadband photonic sensors, and high-speed optical communication platforms. Full article
(This article belongs to the Section Optical Sensors)
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15 pages, 3122 KB  
Article
Strain-Compensated Quantum Well Asymmetric Waveguide Edge-Emitting Laser Operating at 730 nm
by Lutai Fan, Lijie Cao, Peng Jia, Qian Liu, Baiheng Liu, Haofei Chen, Yongyi Chen, Li Qin, Lei Liang, Yuxin Lei, Cheng Qiu, Yue Song, Yubing Wang, Yongqiang Ning and Lijun Wang
Sensors 2025, 25(4), 1173; https://doi.org/10.3390/s25041173 - 14 Feb 2025
Cited by 1 | Viewed by 1488
Abstract
Semiconductor lasers operating at the 730 nm peak wavelength have diverse applications, including biomedical diagnostics, agricultural lighting, and high-precision sensing. However, quantum well (QW) materials, commonly employed at this wavelength, often fail to simultaneously meet the dual requirements of lattice matching and bandgap [...] Read more.
Semiconductor lasers operating at the 730 nm peak wavelength have diverse applications, including biomedical diagnostics, agricultural lighting, and high-precision sensing. However, quantum well (QW) materials, commonly employed at this wavelength, often fail to simultaneously meet the dual requirements of lattice matching and bandgap alignment. In this study, GaAsP/AlGaInP large strain compensation QW with lattice mismatches of −7.533‰ and 1.112‰ was developed. Strain compensation was utilized to address the lattice mismatch while ensuring lasing action at 730 nm. Based on this, the impact of waveguide design, particularly graded and asymmetric waveguides, on the power output was explored. Additionally, the relationship between the doping profile of the device and lasing efficiency was investigated. The completed 100 μm wide semiconductor edge-emitting laser (EEL) achieved 730 nm continuous wave laser with 1 W output power at 2 A current. This study proposes an approach to enhance the lasing power and optoelectronic conversion efficiency of lasers and provide valuable solutions for their practical applications. Full article
(This article belongs to the Section Optical Sensors)
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15 pages, 9141 KB  
Article
A Comparative Analysis of Efficiency and Losses in a 5 kW Hybrid and Full-SiC Converter, for PV Applications in Austria
by Rupak Chakraborty, Troy Eskilson, Sumanta Biswas and Markus Makoschitz
Energies 2024, 17(22), 5600; https://doi.org/10.3390/en17225600 - 9 Nov 2024
Cited by 2 | Viewed by 4700
Abstract
Wide Bandgap (WBG) devices like SiC-MOSFETs have become quite popular in recent times due to their superior switching characteristics, high current carrying capability and temperature stability. They are being adopted for many different applications and for a wide range of power levels. For [...] Read more.
Wide Bandgap (WBG) devices like SiC-MOSFETs have become quite popular in recent times due to their superior switching characteristics, high current carrying capability and temperature stability. They are being adopted for many different applications and for a wide range of power levels. For the case of PV applications, manufacturers are considering moving to SiC-based topologies due to higher converter efficiencies and improved power density. However, the present industry largely uses hybrid approaches (IGBT + SiC-diode) to optimize system cost. The aim of this paper is to present a fair comparison of an industry-grade hybrid converter with another similar counterpart where only the Si device has been replaced with the SiC device. The effects of such a direct replacement on the efficiency and losses of the converter are studied under various power ratings. Both converters consist of two stages—a boost converter and a three-phase three-level DC to AC converter. Simulation and experimental results comprehensively indicate a higher efficiency (improvements of up to 8 percent points) for the full-SiC converter, and this is more prominent at low input voltages, where the boost converter is active. However, the gains in efficiency are moderate for high input voltages (1 percent point at nominal voltage), where the boost converter is bypassed, and the losses are almost entirely attributed to the inverter. When set in the backdrop of the Austrian inverter market, the use of SiC devices in PV inverters has the potential for an estimated savings of 37.5 GWh/year in terms of loss reduction. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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16 pages, 7713 KB  
Article
Degradation of Malachite Green Dye by Solar Irradiation Assisted by TiO2 Biogenic Nanoparticles Using Vaccinium corymbosum Extract
by Iván Balderas-León, Jorge Manuel Silva-Jara, Miguel Ángel López-Álvarez, Pedro Ortega-Gudiño, Arturo Barrera-Rodríguez and Cristina Neri-Cortés
Sustainability 2024, 16(17), 7638; https://doi.org/10.3390/su16177638 - 3 Sep 2024
Cited by 9 | Viewed by 3291
Abstract
The green synthesis of metal oxide nanoparticles (NPs) offers an alternative to chemical procedures, which can be harmful to human health due to exposure to hazardous substances and harsh synthesis conditions. The following work synthesized titanium dioxide nanoparticles (TiO2 NPs) using a [...] Read more.
The green synthesis of metal oxide nanoparticles (NPs) offers an alternative to chemical procedures, which can be harmful to human health due to exposure to hazardous substances and harsh synthesis conditions. The following work synthesized titanium dioxide nanoparticles (TiO2 NPs) using a green synthesis method. As a precursor, food-grade TiO2 was used with blueberry extract. This approach makes the process safer, cheaper, and simpler, requiring minimal effort to achieve effective TiO2 NP synthesis. The TiO2 NP characterization was performed by solid-state techniques, such as Ultraviolet-visible (UV-Vis) spectroscopy, X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). According to the XRD diffractograms, TiO2 NPs were obtained in the anatase phase with incidence peaks of 25.28 (101). TEM confirmed their pseudo-spherical shape with an average size of 170 nm. The 3.2 eV bandgap of TiO2 NPs enables UV absorption, making them ideal for efficient photocatalytic degradation under sunlight. On the other hand, the photocatalytic activity of TiO2 NPs was examined using malachite green (MG) dye as a pollutant model under direct sunlight. After 30 min, a degradation of 94% was achieved. The kinetic analysis identified parabolic diffusion and modified-Freundlich kinetics as primary mechanisms, emphasizing diffusion and adsorption in electron transfer. The main reactive oxygen species (ROS) involved in the photodegradation of MG dye were h+ and OH. Full article
(This article belongs to the Section Sustainable Water Management)
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62 pages, 16763 KB  
Review
Epitaxial Growth of Ga2O3: A Review
by Imteaz Rahaman, Hunter D. Ellis, Cheng Chang, Dinusha Herath Mudiyanselage, Mingfei Xu, Bingcheng Da, Houqiang Fu, Yuji Zhao and Kai Fu
Materials 2024, 17(17), 4261; https://doi.org/10.3390/ma17174261 - 28 Aug 2024
Cited by 29 | Viewed by 10832
Abstract
Beta-phase gallium oxide (β-Ga2O3) is a cutting-edge ultrawide bandgap (UWBG) semiconductor, featuring a bandgap energy of around 4.8 eV and a highly critical electric field strength of about 8 MV/cm. These properties make it highly suitable for next-generation power [...] Read more.
Beta-phase gallium oxide (β-Ga2O3) is a cutting-edge ultrawide bandgap (UWBG) semiconductor, featuring a bandgap energy of around 4.8 eV and a highly critical electric field strength of about 8 MV/cm. These properties make it highly suitable for next-generation power electronics and deep ultraviolet optoelectronics. Key advantages of β-Ga2O3 include the availability of large-size single-crystal bulk native substrates produced from melt and the precise control of n-type doping during both bulk growth and thin-film epitaxy. A comprehensive understanding of the fundamental growth processes, control parameters, and underlying mechanisms is essential to enable scalable manufacturing of high-performance epitaxial structures. This review highlights recent advancements in the epitaxial growth of β-Ga2O3 through various techniques, including Molecular Beam Epitaxy (MBE), Metal-Organic Chemical Vapor Deposition (MOCVD), Hydride Vapor Phase Epitaxy (HVPE), Mist Chemical Vapor Deposition (Mist CVD), Pulsed Laser Deposition (PLD), and Low-Pressure Chemical Vapor Deposition (LPCVD). This review concentrates on the progress of Ga2O3 growth in achieving high growth rates, low defect densities, excellent crystalline quality, and high carrier mobilities through different approaches. It aims to advance the development of device-grade epitaxial Ga2O3 thin films and serves as a crucial resource for researchers and engineers focused on UWBG semiconductors and the future of power electronics. Full article
(This article belongs to the Section Electronic Materials)
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17 pages, 5768 KB  
Article
One Stone, Three Birds: Feasible Tuning of Barrier Heights Induced by Hybridized Interface in Free-Standing PEDOT@Bi2Te3 Thermoelectric Films
by Li Feng, Fen Wang, Hongjie Luo, Yajuan Zhang, Jianfeng Zhu and Yi Qin
Polymers 2024, 16(14), 1979; https://doi.org/10.3390/polym16141979 - 11 Jul 2024
Viewed by 1663
Abstract
Converting low-grade thermal energy into electrical energy is crucial for the development of modern smart wearable energy technologies. The free-standing films of PEDOT@Bi2Te3 prepared by tape-casting hold promise for flexible thermoelectric technology in self-powered sensing applications. Bi2Te3 [...] Read more.
Converting low-grade thermal energy into electrical energy is crucial for the development of modern smart wearable energy technologies. The free-standing films of PEDOT@Bi2Te3 prepared by tape-casting hold promise for flexible thermoelectric technology in self-powered sensing applications. Bi2Te3 nanosheets fabricated by the solvothermal method are tightly connected with flat-arranged PEODT molecules, forming an S-Bi bonded interface in the composite materials, and the bandgap is reduced to 1.63 eV. Compared with the PEDOT film, the mobility and carrier concentration of the composite are significantly increased at room temperature, and the conductivity reaches 684 S/cm. Meanwhile, the carrier concentration decreased sharply at 360 K indicating the creation of defect energy levels during the interfacial reaction of the composites, which increased the Seebeck coefficient. The power factor was improved by 68.9% compared to PEDOT. In addition, the introduction of Bi2Te3 nanosheets generated defects and multidimensional interfaces in the composite film, which resulted in weak phonon scattering in the conducting polymer with interfacial scattering. The thermal conductivity of the film is decreased and the ZT value reaches 0.1. The composite film undergoes 1500 bending cycles with a 14% decrease in conductivity and has good flexibility. This self-supporting flexible thermoelectric composite film has provided a research basis for low-grade thermal energy applications. Full article
(This article belongs to the Section Polymer Membranes and Films)
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23 pages, 8869 KB  
Article
Performance Signature of the Best Candidate-Graded Bandgap Materials for Solar Cells with Steady-State Conversion Efficiency
by Hazem M. El-Hageen, Ahmed Nabih Zaki Rashed, Hani Albalawi, Mohammed A. Alhartomi, Yousef H. Alfaifi, Madhi Tarikham Alsubaie and Mohamed A. Mead
Energies 2023, 16(19), 7001; https://doi.org/10.3390/en16197001 - 9 Oct 2023
Cited by 7 | Viewed by 2360
Abstract
This is a comprehensive research endeavor focused on enhancing the efficiency of the proposed solar cell design. The integration of the simulation techniques, judicious material selection, and meticulous performance metrics showcase a methodical approach toward creating a solar cell capable of achieving high [...] Read more.
This is a comprehensive research endeavor focused on enhancing the efficiency of the proposed solar cell design. The integration of the simulation techniques, judicious material selection, and meticulous performance metrics showcase a methodical approach toward creating a solar cell capable of achieving high efficiency across a wide spectrum of light in the AM 1.5 G1 sun solar cell illumination spectrum. Having said this, many researchers are still working on the efficiency potential—based on external radiative efficiency (ERE), open-circuit voltage loss, and fill factor loss—of high-efficiency solar cells. The solar cell is built on aluminum-doped zinc oxide (ZnO) as a transparent conductive oxide layer; aluminum nitride (AlN) as the window layer (emitter); an SWCNT layer as the absorber layer; gallium phosphide (GaP) as the contact layer; and silicon as the substrate. The proposed solar cell transmission, reflection, and absorption relative to the variations in wavelength band spectrum are studied. The conduction and valence band energy diagrams of the solar cell design structure are simulated against the layer thickness variations for the suggested solar cell structure. Short-circuit current density and maximum power variations are clarified versus the bias voltage. Light current density is simulated versus the bias voltage (J/V characteristics curve) of the suggested solar cell design structure. The carrier generation–recombination rate is also simulated by the COMSOL simulation program versus the layer thickness of the suggested solar cell structure. The solar cell circuit design has a fill factor (FF) value of 74.31% and a power conversion efficiency value of 29.91%. Full article
(This article belongs to the Special Issue Renewable Energy Systems (Solar, Wind) and Grid Integration)
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13 pages, 4588 KB  
Article
Performance Improvement of Perovskite Solar Cell Design with Double Active Layer to Achieve an Efficiency of over 31%
by Sagar Bhattarai, Mustafa K. A. Mohammed, Jaya Madan, Rahul Pandey, Mohd Zahid Ansari, Ahmed Nabih Zaki Rashed, Mongi Amami and M. Khalid Hossain
Sustainability 2023, 15(18), 13955; https://doi.org/10.3390/su151813955 - 20 Sep 2023
Cited by 35 | Viewed by 3752
Abstract
This research aims to optimize the efficiency of the device structures by introducing the novel double perovskite absorber layer (PAL). The perovskite solar cell (PSC) has higher efficiency with both lead perovskite (PVK), i.e., methylammonium tin iodide (MASnI3) and Caseium tin [...] Read more.
This research aims to optimize the efficiency of the device structures by introducing the novel double perovskite absorber layer (PAL). The perovskite solar cell (PSC) has higher efficiency with both lead perovskite (PVK), i.e., methylammonium tin iodide (MASnI3) and Caseium tin germanium iodide (CsSnGeI3). The current simulation uses Spiro-OMeTAD as the hole transport layer (HTL) and TiO2 as an electron transport layer (ETL) to sandwich the PVK layers of MASnI3 and CsSnGeI3, which have precise bandgaps of 1.3 eV and 1.5 eV. The exclusive results of the precise modeling technique for organic/inorganic PVK-based photovoltaic solar cells under the illumination of AM1.5 for distinctive device architectures are shown in the present work. Influence of defect density (DD) is also considered during simulation that revealed the best PSC parameters with JSC of 31.41 mA/cm2, VOC of 1.215 V, FF of nearly 82.62% and the highest efficiency of 31.53% at the combined DD of 1.0 × 1014 cm−3. The influence of temperature on device performance, which showed a reduction in PV parameters at elevated temperature, is also evaluated. A steeper temperature gradient with an average efficiency of −0.0265%/K for the optimized PSC is observed. The novel grading technique helps in achieving efficiency of more than 31% for the optimized device. As a result of the detailed examination of the total DD and temperature dependency of the simulated device, structures are also studied simultaneously. Full article
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13 pages, 2594 KB  
Article
Influence of Al Doping on the Physical Properties of CuO Thin Films
by Radouane Daira, Bouzid Boudjema, Mohamed Bououdina, Mohamed Salah Aida and Catalin-Daniel Constantinescu
Appl. Sci. 2023, 13(14), 8193; https://doi.org/10.3390/app13148193 - 14 Jul 2023
Cited by 14 | Viewed by 3145
Abstract
The synthesis of cupric oxide (CuO) films on cost-efficient, optical grade borosilicate-crown glass substrates (BK7) via chemical spray pyrolysis (CSP), either in pure form or with a low concentration of Al doping (below 1%), is presented and discussed. As a non-toxic p-type [...] Read more.
The synthesis of cupric oxide (CuO) films on cost-efficient, optical grade borosilicate-crown glass substrates (BK7) via chemical spray pyrolysis (CSP), either in pure form or with a low concentration of Al doping (below 1%), is presented and discussed. As a non-toxic p-type semiconductor, exhibiting monoclinic crystal structure and widely tuneable band gap (Eg), it is used in various applications. The optical properties, morphology and crystalline phases of CuO films are influenced by substrate temperature during thin film growth (annealing) and also by chemical doping very often introduced to modify grain boundary energy. The importance of our research subject is therefore perfectly justified and is essentially based on the fact that the potential fields of application are wide. Thus, herein we emphasize impact of the annealing stage and Al doping upon the structural, optical and electrical properties of the resulting product. Raman spectroscopy analysis confirms the presence of vibrational bands characteristic of a CuO phase, while X-ray diffraction (XRD) confirms the polycrystalline nature of the pure films. The thickness of the CuO films grown at 350 °C over three annealing intervals is proportional to the annealing time, while the crystallite phase in the films is proportional with the annealing temperature. Furthermore, XRD analysis of the Al:CuO films indicates the formation of a monoclinic-type structure (CuO phase) exhibiting a preferred orientation along the (002) plane, together with a significant grain size reduction from ~88 to ~45 nm as Al content increases. The transmittance spectra (between 400 and 800 nm) reveal a decrease in the transmittance from 48% to 15% with as the Al doping ratio increases. Additionally, the bandgap energy of the films is measured, modelled and discussed, using data from an ultraviolet–visible (UV-Vis) spectrophotometer. The calculated Eg is approximately 3.5 eV, which decreases with respect to the increasing annealing temperature, while the electrical resistivity varies from ~19 to ~4.6 kOhm.cm. Finally, perspectives and applications of CuO films are suggested, since the films are found to have a remarkable improvement in their structure and optical properties when doped with Al. Full article
(This article belongs to the Special Issue Advances in Surface Science and Thin Films)
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13 pages, 5818 KB  
Communication
Design of a Functionally Graded Material Phonon Crystal Plate and Its Application in a Bridge
by Shuqin Li, Jing Song and Jingshun Ren
Appl. Sci. 2023, 13(13), 7677; https://doi.org/10.3390/app13137677 - 29 Jun 2023
Cited by 3 | Viewed by 1899
Abstract
In order to alleviate the structural vibrations induced by traffic loads, in this paper, a phonon crystal plate with functionally graded materials is designed based on local resonance theory. The vibration damping performance of the phonon crystal plate is studied via finite element [...] Read more.
In order to alleviate the structural vibrations induced by traffic loads, in this paper, a phonon crystal plate with functionally graded materials is designed based on local resonance theory. The vibration damping performance of the phonon crystal plate is studied via finite element numerical simulation and the band gap is verified via vibration transmission response analysis. Finally, the engineering application mode is simulated to make it have practical engineering application value. The results show that the phonon crystal plate has two complete bandgaps within 0~150 Hz, the initial bandgap frequency is 0.00 Hz, the cut-off frequency is 128.32 Hz, and the internal ratio of 0~100 Hz is 94.13%, which can effectively reduce the structural vibration caused by traffic loads. Finally, stress analysis of the phonon crystal plate is carried out. The results show that phonon crystals of functionally graded materials can reduce stress concentration through adjusting the band gap. The phonon crystal plate designed in this paper can effectively suppress the structural vibration caused by traffic loads, provides a new method for the vibration reduction of traffic infrastructure, and can be applied to the vibration reduction of bridges and their auxiliary facilities. Full article
(This article belongs to the Special Issue Advance of Structural Health Monitoring in Civil Engineering)
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