Search Results (79)

This study investigated the effect of in situ polymerization on the compressive strength of demolition-derived Scots pine, European beech, and black alder wood. The treatment applied was based on previously confirmed in situ polymerization systems in wood, which are known to lead to polymer formation and composite-like structures. In this study, we assumed similar behavior and focused on a mechanical evaluation of the modified wood. Three different polymer systems were applied to evaluate differences in performance. After modification, the compressive strength levels increased by 60% in beech, 119% in alder, and 150% in pine, with corresponding increases in density and weight percent gain (WPG). The highest relative improvement was observed in the least dense species, pine. The findings suggest that polymer treatment can significantly enhance the mechanical properties, likely due to the incorporation of polymer into the wood matrix; however, this inference is based on indirect physical evidence. Full article

Wood is a green and renewable bio-based building material, but its hygroscopicity affects its dimensional stability, limiting its use in construction. Chemical modification can improve its properties, yet its effectiveness depends on wood permeability and traditional modifiers. This study first used a deep eutectic solvent (DES) to boost the permeability of North American alder wood. Then, methyl trimethoxysilane was impregnated under supercritical carbon dioxide (SCI), pressure (PI), vacuum (VI), and atmospheric pressure (AI) conditions. DES treatment damaged the cell structure, increasing wood permeability. Silane was deposited and polymerized in the cell lumen, chemically bonding with cell-wall components, filling walls and pits, and thickening walls. The VI group had the highest absolute density (0.59 g/cm³, +36.6%) and the lowest moisture absorption (4.4%, −33.3%). The AI group had the highest ASE (25%). The PI group showed the highest surface hardness (RL, 2592 N) and a water contact angle of 131.9°, much higher than natural wood. Overall, the VI group had the best performance. Silane reacts with cellulose, hemicellulose, and lignin in wood via hydrolysis and hydroxyl bonding, forming stable bonds that enhance the treated wood’s hydrophobicity, dimensional stability, and surface hardness. Full article

Pellets can be produced not only from forest dendromass but also from agricultural dendromass derived from short rotation coppice (SRC) plantations, as well as surplus straw from cereal and oilseed crops. This study aimed to determine the thermophysical properties and elemental composition of 16 types of pellets produced from four types of forest biomass (Scots pine I, alder, beech, and Scots pine II), four types of agricultural biomass (SRC willow, SRC poplar, wheat straw, and rapeseed straw), and eight types of pellets from mixtures of wood biomass and straw. Another aim of the study was to demonstrate which pellet types met the parameters specified in three standards, categorizing pellets into thirteen different classes. As expected, pellets produced from pure Scots pine sawdust exhibited the best quality. The quality of the pellets obtained from mixtures of dendromass and straw deteriorated with an increase in the proportion of cereal straw or rapeseed straw in relation to pure Scots pine sawdust and SRC dendromass. The bulk density of the pellets ranged from 607.9 to 797.5 kg m⁻³, indicating that all 16 pellet types met the requirements of all six classes of the ISO standard. However, it was determined that four types of pellets (rapeseed, wheat, and two others from biomass mixtures) did not meet the necessary requirements of the Premium and Grade 1 classes. The ash content ranged from 0.44% DM in pellets from pure Scots pine sawdust to 5.00% DM in rapeseed straw pellets. Regarding ash content, only the pellets made from pure Scots pine sawdust met the stringent requirements of the highest classes, A1, Premium, and Grade 1. In contrast, all 16 types of pellets fulfilled the criteria for the lower classes, i.e., Utility and Grade 4. Concerning the nitrogen (N) content, seven types of pellets met the strict standards of classes A1 and Grade 1, while all the pellets satisfied the less rigorous requirements of classes B and Grade 4. Full article

This article sheds light on the historical dyeing traditions of rural inhabitants of the Eastern Baltic region. The 19th- and early 20th-century Estonian archival sources mention that rotted alder buckthorn (Frangula alnus Mill.) bark was used to dye woollen yarn red. The bark was rotted by leaving it outside for weeks or months before dyeing. Although dyeing red with alder buckthorn bark by fermenting it in wood ash lye is well known, the combination of rotting the bark and using the boiling method to dye red has not been reported. Practical experiments testing shorter and longer-term rotting of alder buckthorn bark both on and under the ground were conducted. Woollen yarns were dyed with rotted bark using the boiling method and were tested for lightfastness and alkaline pH sensitivity, and analysed using HPLC-DAD. The results show that rotting alder buckthorn bark has a strong effect on the achievable colours and that woollen yarns can be dyed different shades of red. The colours were sensitive to alkaline pH and their light fastness varied from very low to good. HPLC-DAD analysis showed that the pretreatment of the bark affected not only the colour but also the dye composition of the dyed wool. Full article

The effects of produced wood particles from three wood species—alder, birch, and larch—added in various amounts in the particle mixture consisting of spruce particles and three tested wood species in a particleboard core layer on selected physical and mechanical properties of particleboard were studied. In a laboratory, 16 mm thick three-layer urea–formaldehyde (UF)-bonded particleboards were produced at 5.23 MPa, 240 °C, and with a 10 s/mm pressing factor. Two particleboard surface layers consisted of fine spruce particles. In the particleboard core layer, spruce particles were combined with particles from alder, birch, and larch. The tested particleboards containing alder, birch, and larch were characterized by approximately identical thickness swelling and they met the requirements of the conventional values stated by major particleboard manufacturers of 8–10%. The tested particleboard in all variations met the minimum strength value P2 particleboard in three-point bending, which is conventionally set at 11.0 MPa. The tested particleboard also exceeded the required values of modulus of elasticity in bending and internal bond strength. Analysis of the relationships demonstrated by the density profile confirmed that all three investigated wood species are usable in a mixture of core particles of high-quality particleboard in the recommended amounts (10, 15, 20%). Full article

In this study we present an application of wood biomass—alder wood char—as the carbon precursor for the synthesis of novel and sustainable nitrogen-doped activated-carbon-supported nickel nanoparticle catalyst (AWC-Ni-N) for hydrazine oxidation. For comparison, the wood-based carbon material doped with nitrogen only (AWC-N) was also synthesized. Extensive characterization, including SEM, Raman spectroscopy, XPS, and XRD revealed the catalysts’ microstructure and properties. Electrochemical testing demonstrated that the AWC-Ni-N catalyst significantly enhanced the efficiency of the hydrazine oxidation reaction. In addition, direct N₂H₄-H₂O₂ single-fuel-cell tests were conducted using the prepared AWC-N and AWC-Ni-N catalysts as the anodes and cathodes. Peak power densities of up to 10.8 mW cm⁻² were achieved at 25 °C, corresponding to a current density of 27 mA cm⁻² and a cell voltage of 0.4 V when the AWC-Ni-N catalyst was used as both the anode and cathode. Furthermore, the peak power density increased by approximately 1.6 and 2.9 times, respectively, when the operating temperature was raised from 25 °C to 55 °C for the AWC-N and AWC-Ni-N catalysts. Overall, the AWC-N and AWC-Ni-N catalysts demonstrated significant potential as anode and cathode materials in direct N₂H₄-H₂O₂ fuel cells. Full article

The use of a novel chrono-potentiometry method (abbreviated as “CP”) in the determination of the moisture content in wood (abbreviated as “MC”) above the FSP is a practical application of the electrical charging effect (or ECE). In the specific case of this CP method, the ECE consists of an electrical charging phase for the wood and a discharge phase following the interruption of the charging current. The electrical resistance, R, and the electrical chargeability, Cha(E), of three hardwood species were determined from the final potential, E1, of the charging phase and the initial potential, E2, of the discharge phase, with the three hardwood species being birch (Betula spp.), aspen (Populus spp.), and black alder (Alnus glutinosa (L.) Gaertn). An auxiliary variable in the form of U (E1; E2) was defined as a function of E1 and E2. This was used as an independent electrical variable in the calibration model for a CP moisture meter for the three tree species when it came to the moisture content (MC) region above the FSP (fibre saturation point). It was found that upon a determination of the MC in the wood, the traditional calibration model (the R-model), which uses the electrical resistance of wood, was able to predict a single-measurement precision level of +/−10% for the MC while the U-model predicted a precision level of +/−1.75% for the MC over a single MC measurement in the wood. Full article

Coarse woody debris (CWD) is an essential component in forest ecosystems, playing a significant role in enhancing biodiversity, soil formation, and nutrient cycling through decomposition processes. CWD also contributes to greenhouse gas fluxes, particularly through CO₂ emissions. This study investigated the physical and chemical properties of CWD and the CO₂ effluxes from CWD of different decay classes. For this study, a range of CWD—from recently dead to highly decomposed wood—of native tree species such as silver birch (Betula pendula Roth), black alder (Alnus glutinosa (L.) Gaertn.), and Norway spruce (Picea abies (L.) H. Karst.) in hemiboreal forests were investigated. The findings showed that CWD properties significantly differed among tree species and CWD decay classes. Significant variations in wood density and total nitrogen (N) were observed in the early stages of CWD decay, with the highest values found for the deciduous tree species. The concentration of organic carbon (C) increased throughout the decomposition. The lowest CO₂ efflux from CWD was found for spruce CWD from all decay classes and it was the highest for black alder and silver birch, especially for the 3rd and 4th decay classes. CO₂ efflux was mainly influenced by the degree of decomposition, which was represented by the CWD decay class, followed by wood density and C content. Full article

This study aimed to evaluate the bondability of beech and alder wood modified through styrene polymerization within the wood lumen. Unmodified wood samples served as the reference material. Bondability was tested using four adhesive types commonly used in wood technology: polyvinyl acetate (PVAc), urea-formaldehyde (UF), phenol-resorcinol-formaldehyde (PRF), and epoxy resin. In addition to shear strength measurements, the adhesive density profile was also assessed. Results indicated that styrene modification generally reduced wood bondability, with reductions in shear strength ranging from 8% to 23% for beech wood and 1.6% to 29% for alder wood, depending on the adhesive type. The only exception was observed with the epoxy adhesive, which showed a 13% improvement in bonding quality for modified wood. These findings suggest that while styrene modification may enhance specific properties of wood, it can adversely affect its adhesion performance with some adhesive systems, except epoxy, which displayed improved compatibility with styrene-modified wood. The study offers insights for selecting suitable adhesives when using modified wood in structural applications. Full article

Problems with the availability of raw materials on the Polish market have forced wood industry producers to search for new, previously unused species of wood that meet the functional requirements of the target products. Therefore, it is necessary to conduct research on products whose structure is different from the popular offerings on the market. The goal of this study was to analyze the influence of the thickness of Scots pine veneers, also with Alder interlayer variants, on Young’s modulus and stiffness values of plywood-like composites dedicated to flooring applications regarding statistically based quality control of the products. The variables in this research are the thickness of the veneer, which creates the structure of the base layer of flooring materials, and the kind of wood used. This research looked at basic mechanical properties determining the suitability of flooring materials: modulus of elasticity and stiffness. Because both these parameters describe the product quality, the analyses were based on the normal distribution (containing kurtosis) and the creation of Shewart Control Charts for each parameter. Analyses of control charts provide information on whether the projected production process is stable and is able to give predictable results. In turn, the analysis of the kurtosis value allows us to determine whether Young’s modulus and stiffness values obtained for the products are as close as possible to the values assumed by the manufacturers. The thickness of veneers in the base layer of flooring composites can be enlarged, allowing production to be simplified and more environmentally friendly. New types of layered composites for flooring, manufactured by rotary cutting, without the need for quality assessment, with a minimum number of layers, and additionally verified with Shewart Control Charts, may be applied to production. Presented studies show that veneers of different quality classes, having plywood-like structures, can be used for flooring materials and that the thickness of the veneers in the base layer can be increased. In this way, wood can be used without the need for quality classification and with fewer production processes. Full article

Over the last 50 years, groundwater levels have been decreasing and air temperatures have been increasing in Poland. Maintaining this trend may make it impossible to maintain hydrogenic habitats in good condition. Reactions to ongoing climate change recorded in tree rings may be a good indicator describing the degree of this threat. The aim of this study was to determine the influence of climatic and hydrological changes on the growth of scotch pine (Pinus sylvestris L.) and black alder (Alnus glutinosa (L.) Gaertn) in the Narew National Park over past 50 years. The research was based on tree increment cores extracted from 42 pine trees and 57 alder trees that were randomly selected and ranged in age from 25 to 88 years, as well as climatic and hydrological data. Standardised data (5-year index) were analysed by species, generation (Y—21–40 years, M—41–60, O—61–90), and decade using correlation analysis. The results of the study show that pine responded more strongly to changes in air temperature and changes in precipitation totals, while alder growth was more strongly related to fluctuations in the water level of the Narew River and changes in precipitation totals. Our research showed that differences in response to environmental factors also occur between tree generations. The decrease in the water level of the Narew River that occurred over the last 50 years did not adversely affect the condition of the trees. Analysis of DBH growth rates showed that the younger generations (Y, M) grow faster than the older generation (O). This is positive news for managers of commercial and protected forests, but accelerated tree growth may be associated with specific consequences, such as increased wind damage as a result of reduced wood density or reduced sensitivity of trees to climate and hydrological changes. Full article

Increasing environmental awareness and the carbon-storing capability of wood have amplified its relevance as a building material. The demand for high-quality wood species necessitates exploring alternative, underutilized wood sources due to limited forest areas and premium wood volume. Consequently, the veneer-based industry is considering lower-value hardwood species like grey alder (Alnus Incania), black alder (Alnus glutinosa), and aspen (Populus tremula) as substitutes for high-quality birch (Betula pendula). Initially less appealing due to their lower density and mechanical properties, these species show promise through densification, which enhances their density, strength, and hardness. This study aims to enhance plywood screw withdrawal capacity and surface hardness by densifying low-density wood species and using them in plywood face-veneer layers, or in all layers. The relationship between the wood density, surface hardness, and screw withdrawal capacity of plywood made of low-value species like aspen and black alder is examined. Experimental work with a pilot-scale veneer and plywood production line demonstrates improved surface hardness (65% and 93% for aspen and black alder, respectively) and screw withdrawal capacity (16% and 35% for aspen and black alder, respectively) in densified face veneer plywood. This research highlights the potential of densified low-value wood species to meet construction requirements, expanding their practical applications. Full article

Residential wood combustion (RWC) is a significant source of gaseous and particulate emissions causing adverse health and environmental effects. Several factors affect emissions, but the effects of the fuel wood species on emissions are currently not well understood. In this study, the Nordic wood species (named BirchA, BirchB, Spruce, SpruceDry, Pine and Alder) were combusted in a modern stove, and the emissions were studied. The lowest emissions were obtained from the combustion of BirchA and the highest from Spruce and Alder. The fine particle mass (PM_2.5) was mainly composed of elemental carbon (50–70% of PM_2.5), which is typical in modern appliances. The lowest PAH concentrations were measured from BirchA (total PAH 107 µg/m³) and Pine (250 µg/m³). In the ignition batch, the PAH concentration was about 4-fold (416 µg/m³). The PAHs did not correlate with other organic compounds, and thus, volatile organic compounds (VOCs) or organic carbon (OC) concentrations cannot be used as an indicator of PAH emissions. Two birch species from different origins with a similar chemical composition but different density produced partially different emission profiles. This study indicates that emission differences may be due more to the physical properties of the wood and the combustion conditions than to the wood species themselves. Full article

The goal of this study is to comprehensively evaluate the natural weathering performance of three wood species representing hardwood and softwood modified with the acetylation process. Alder (Alnus glutinosa L.), beech (Fagus sylvatica L.), and radiata pine (Pinus radiata D. Don) were characterised by various techniques to determine the aesthetical, chemical, and physical changes. The overall aesthetic performance of the investigated species was similar, with all showing a change in appearance after 9 months of exposure. However, the multi-sensor approach used for characterisation revealed differences in weathering behaviour related to surface erosion, wettability, and changes in chemical composition between the investigated species. An increase in the surface roughness observed for both hardwoods was associated with the erosion of the wood surface and the leaching of photodegraded chemical components. On the contrary, values of Sa remained relatively constant for acetylated radiata pine. Acetylated pine wood exhibited lower susceptibility to bleaching at the initial stage of the weathering process (3 months) and represented a more constant CIE L* compared to the investigated hardwood species. The contact angle measured with water gradually decreased in the case of acetylated radiata pine for up to six months, then it plateaued with a slight oscillation around 15°. For both hardwood species, the big drop was observed already after three months, followed by rather similar values. The PCA of IR spectra highlighted different mechanisms in the weathering of acetylated softwood and hardwood. The acetylated hardwood samples showed higher thermal stability than acetylated radiata pine. Experimental findings provide a comprehensive understanding of the long-term performance of acetylated wood, which directly influences its practical applications by enhancing design strategies, maintenance planning, product development, market acceptance, and overall sustainability. Performed tests have demonstrated the potential of underutilised hardwood species, enhanced through the acetylation process, to serve as alternative cladding materials to commonly used acetylated radiata pine. Full article

Particleboard, engineered wood products as part of a large family of wood composite materials, developed in use mainly in the 1950s and 1960s to utilize inferior wood and wood waste when good-quality wood was in short supply; the annual production capacity worldwide is over 100 million m³. It is also necessary to have a lot of wood raw material for its production, although raw material resources are limited on our planet. In addition to the main wood species, it is therefore possible to think about the wider use of alternative, lesser-known European species of alder, larch, and birch in particleboard production. These three wood species represent an eco-friendly and sustainable wood alternative to the conventional wood raw materials used. This review confirms the diversity of the use of these three species in different fields and proves their suitability in relation to particleboard production. Fundamental research is ongoing in certain universities to determine the proportional shares of use of these tree species in particleboard (in a certain weight proportion in their core layers) for the purpose of formulating the correct technology shares and rules for their application in the wood-based panel industry. Full article