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24 pages, 3803 KB  
Article
Surface Runoff Responses to Forest Thinning in Semi-Arid Oak–Pine Micro-Catchments of Northern Mexico
by Gabriel Sosa-Pérez, Argelia E. Rascón-Ramos, David E. Hermosillo-Rojas, Alfredo Pinedo Alvarez, Eduardo Santellano-Estrada, Raúl Corrales-Lerma, Sandra Rodríguez-Piñeros and Martín Martínez-Salvador
Hydrology 2026, 13(1), 27; https://doi.org/10.3390/hydrology13010027 - 9 Jan 2026
Viewed by 81
Abstract
Hydrological behavior plays a critical role in seasonally dry forest ecosystems, as it underpins water availability for multiple productive activities, including forestry, agriculture, grazing, and urban supply. This study evaluated the hydrological effects of thinning treatments in a semi-arid oak–pine forest of Chihuahua, [...] Read more.
Hydrological behavior plays a critical role in seasonally dry forest ecosystems, as it underpins water availability for multiple productive activities, including forestry, agriculture, grazing, and urban supply. This study evaluated the hydrological effects of thinning treatments in a semi-arid oak–pine forest of Chihuahua, Mexico, using a Before–After–Control–Impact (BACI) design. Three Micro-catchments (MC) with initially comparable tree density and canopy cover were monitored during the rainy seasons of 2018 (pre-thinning) and 2019 (post-thinning). Thinning treatments were applied at 20% and 60% canopy cover in two MC, while a third remained unthinned as a 100% control. Precipitation and surface runoff were recorded at the event scale, and data were analyzed using Weibull probability models with a log link to capture the frequency and magnitude of runoff events. Precipitation patterns were broadly comparable across years, although 2018 included an extreme storm event (59 mm). In contrast, runoff volumes in 2019 were lower despite marginally higher seasonal rainfall, reflecting the absence of large storms. Statistical modeling indicated that for each additional millimeter of precipitation, mean runoff increased by approximately 12%, although thinning significantly altered baseline conditions. Relative to 2018, mean runoff ratios were 0.087 in the 100% canopy catchment, 0.296 in the 60% treatment, and 0.348 in the 20% treatment, suggesting that reduced canopy cover retained proportionally more runoff than the control. BACI contrasts confirmed that thinned catchments maintained higher proportions of runoff than the unthinned control, although statistical significance was marginal for the 20% canopy treatment. Overall, the study provides ecohydrological insights relevant to the management of semi-arid forest ecosystems. Full article
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18 pages, 2276 KB  
Article
Eutrophication Risk Assessment vs. Trophic Status: Concordances and Discrepancies in the Trophic Characterization of Ebro Basin Reservoirs
by Juan Víctor Molner, Elena Arnau-López, Noelia Campillo-Tamarit, Rebeca Pérez-González, Manuel Muñoz-Colmenares, María José Rodríguez and Juan M. Soria
Environments 2026, 13(1), 39; https://doi.org/10.3390/environments13010039 - 8 Jan 2026
Viewed by 185
Abstract
The vulnerability of reservoirs in Mediterranean regions to eutrophication is attributable to two key factors: strong seasonal hydrological variability and intensive agricultural activity. The present study evaluated the trophic state of 47 reservoirs in the Ebro Basin in Spain using two complementary approaches: [...] Read more.
The vulnerability of reservoirs in Mediterranean regions to eutrophication is attributable to two key factors: strong seasonal hydrological variability and intensive agricultural activity. The present study evaluated the trophic state of 47 reservoirs in the Ebro Basin in Spain using two complementary approaches: the Organisation for Economic Co-operation and Development (OECD) classification system and the criteria set out in Royal Decree (RD) 47/2022. Chlorophyll-a, total phosphorus and transparency data were monitored from 2023 to 2024. While most of reservoirs were classified as oligotrophic to mesotrophic under the OECD thresholds, the RD 47/2022 identified 87% as being at risk of eutrophication. A significant variation in transparency was observed among the different reservoir types (p < 0.05), with high-altitude systems showing higher levels of water transparency. However, chlorophyll-a and total phosphorus had a significant spatial variability, exhibiting only modest correlations. Chlorophyll-a was weakly but significantly correlated to transparency (r = −0.21), while total phosphorus was not significantly associated with either variable, suggesting a decoupling between nutrient availability and phytoplankton biomass. The observed discrepancy between the two classification frameworks is indicative of divergent conceptual approaches (ecological condition versus management risk). It underscores the requirement for integrated monitoring that incorporates chemical, biological and catchment-scale indicators. These findings offer new insight into the trophic dynamics of Mediterranean reservoirs and highlights the importance of adapting regulatory assessment methods to region-specific climatic and hydrological contexts. Full article
(This article belongs to the Special Issue Monitoring of Contaminated Water and Soil, 2nd Edition)
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16 pages, 2459 KB  
Article
Hydrochemical Evolution and Pollution Source Apportionment of Groundwater in Arid Regions: A Case Study of the Datong River Basin, Northwest China
by Tao Liu, Jian Kang, Youwei Yu, Yue Qi and Zizhao Zhang
Water 2026, 18(1), 105; https://doi.org/10.3390/w18010105 - 1 Jan 2026
Viewed by 202
Abstract
Understanding hydrochemical evolution and apportioning pollution sources are prerequisites for effective groundwater protection at the regional scale; nevertheless, the governing processes and anthropogenic drivers in arid regions remain poorly constrained. Here, we present a comprehensive geochemical survey of the Datong River Basin, a [...] Read more.
Understanding hydrochemical evolution and apportioning pollution sources are prerequisites for effective groundwater protection at the regional scale; nevertheless, the governing processes and anthropogenic drivers in arid regions remain poorly constrained. Here, we present a comprehensive geochemical survey of the Datong River Basin, a representative arid catchment in north-western China. Thirty-seven groundwater samples were analyzed with hydrochemical methods and Positive-Matrix Factorization (PMF) to delineate natural controls and contaminant sources. Results showed that the aquifer is dominated by HCO3–Ca(Mg) water controlled predominantly by silicate and carbonate weathering, modified locally by evapo-concentration and human activities. Water-quality indices classify 70.3% of the samples as excellent, but spatially restricted degradation is evident. PMF resolved three independent sources: a natural end-member enriched in Mn, Na+ and Cl; a mixed source reflecting domestic wastewater, agricultural fertilizers and rock weathering; and an industrial source dominated by Fe. The mixed source contributes most major ions and chemical oxygen demand (COD), whereas the industrial source accounts for 75.7% of total Fe. These findings provide a robust scientific basis for groundwater management and pollution mitigation in arid regions under similar hydrogeological settings. Full article
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15 pages, 1819 KB  
Article
Application of a Parsimonious Phosphorus Model (SimplyP) to Two Hydrologically Contrasting Agricultural Catchments
by Daniel Hawtree, Per-Erik Mellander, Russell Adams, Golnaz Ezzati, Leah Jackson-Blake, Ognjen Zurovec, Magnus Norling and Jason Galloway
Water 2026, 18(1), 6; https://doi.org/10.3390/w18010006 - 19 Dec 2025
Viewed by 332
Abstract
Understanding how water-quality models perform across different hydrological and biogeochemical contexts is essential for managing nutrient losses in agricultural catchments. This study evaluated SimplyP, a parsimonious phosphorus model, adapted to better represent Irish agricultural catchments and implemented within the flexible Mobius2 framework. Long-term, [...] Read more.
Understanding how water-quality models perform across different hydrological and biogeochemical contexts is essential for managing nutrient losses in agricultural catchments. This study evaluated SimplyP, a parsimonious phosphorus model, adapted to better represent Irish agricultural catchments and implemented within the flexible Mobius2 framework. Long-term, high-frequency monitoring data from the Agricultural Catchments Programme (ACP) were used for two sites: Ballycanew, a grassland catchment dominated by surface runoff, and Castledockrell, an arable, groundwater-driven catchment. Model calibration and validation were performed for streamflow (Q), suspended sediment (SS), and multiple phosphorus (P) fractions, with performance assessed using Kling–Gupta efficiency (KGE). In Ballycanew, the model reproduced Q, SS, and total P load well, with weaker agreement for total reactive phosphorus (TRP), likely reflecting unaccounted point sources during low flows. In Castledockrell, performance was moderate for Q and SS, but TRP and other P fractions were not adequately captured, highlighting the need for more detailed representation of subsurface P pathways in groundwater-dominated systems. Overall, SimplyP is well-suited to surface-runoff-dominated catchments with conventional phosphorus mobilisation. Its flexible implementation in Mobius2 allows relatively straightforward modifications, such as including groundwater-mediated P processes, to extend applicability to more complex systems. High-resolution ACP datasets were crucial for identifying model strengths and limitations, supporting refinement for improved nutrient management across diverse agricultural landscapes. Full article
(This article belongs to the Special Issue New Technologies for Hydrological Forecasting and Modeling)
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25 pages, 4630 KB  
Article
Landslide Occurrence and Mitigation Strategies: Exploring Community Perception in Kivu Catchment of Rwanda
by Ma-Lyse Nema, Bachir Mahaman Saley, Arona Diedhiou and Assiel Mugabe
GeoHazards 2026, 7(1), 1; https://doi.org/10.3390/geohazards7010001 - 19 Dec 2025
Viewed by 754
Abstract
Landslides are among the most significant disasters that threaten communities worldwide. This study sampled 384 respondents, using standardized interviews and field observations, to analyze how they perceived the factors influencing the incidence of landslides in the Kivu catchment of Rwanda, especially in landslide-prone [...] Read more.
Landslides are among the most significant disasters that threaten communities worldwide. This study sampled 384 respondents, using standardized interviews and field observations, to analyze how they perceived the factors influencing the incidence of landslides in the Kivu catchment of Rwanda, especially in landslide-prone areas. This study employs a mixed-methods approach that combines household surveys and interviews with key informants to assess how residents perceive landslide causes, warning signs, and impacts, which were analyzed statistically using SPSS. For further analysis, a binary logistic regression model and chi-square tests were used. The chi-square test findings highlighted that heavy rainfall, inappropriate agricultural practices, steep slopes, deforestation, road construction, earthquakes, and climate change were strongly correlated with landslide occurrence, with a p < 0.05 level of significance, while mining activities were not correlated with landslides. On the other hand, a binary logistic regression model revealed that, among the selected factors influencing landslide occurrence in the Kivu catchment, road construction (B = −0.644; p = 0.014), inappropriate agriculturalpractices (−1.177; p = 0.000), steep slopes (B = −0.648; p = 0.018), deforestation (B = −0.854; p = 0.007), and earthquakes (B = −1.59; p = 0.008) were negatively correlated, while heavy rainfall (B = 1.686; p = 0.000) and climate change (B = 1.784; p = 0.001) were positively correlated, and this was statistically significant for landslide occurrence at a p-value < 0.05. In contrast, mining activities (B = −0.065; p = 0.917) showed a negative coefficient that was statistically insignificant with respect to landslide occurrence in the study area. Future studies should integrate surveys with landslide hazard modeling tools for better spatial prediction of vulnerability and economic losses. Therefore, the findings from this study will contribute to sustainable natural disaster management planning in the western region of Rwanda. Full article
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27 pages, 5123 KB  
Article
Projections of Hydrological Droughts in Northern Thailand Under RCP Scenarios Using the Composite Hydrological Drought Index (CHDI)
by Duangnapha Lapyai, Chakrit Chotamonsak, Somporn Chantara and Atsamon Limsakul
Water 2025, 17(24), 3568; https://doi.org/10.3390/w17243568 - 16 Dec 2025
Viewed by 578
Abstract
Hydrological droughts represent a growing challenge for northern watersheds in Thailand, where climate change is projected to intensify seasonal water stress and destabilize agricultural productivity and water resource management. This study employed the Composite Hydrological Drought Index (CHDI) to evaluate the spatiotemporal characteristics [...] Read more.
Hydrological droughts represent a growing challenge for northern watersheds in Thailand, where climate change is projected to intensify seasonal water stress and destabilize agricultural productivity and water resource management. This study employed the Composite Hydrological Drought Index (CHDI) to evaluate the spatiotemporal characteristics of future droughts under representative concentration pathway (RCP) scenarios. The findings revealed a pronounced seasonal contrast: under RCP8.5, the CHDI values indicated more severe drought conditions during the dry season and greater flood potential during the wet season. Consequently, the region faces dual hydrological threats: prolonged water deficits and increased flood exposure within the same annual cycle. Drought persistence is expected to intensify, with maximum consecutive drought runs extending up to 10–11 months in future projections. The underlying mechanisms include increased actual evapotranspiration, which accelerates soil moisture depletion, enhanced rainfall variability, which drives the sequencing of floods and droughts, and catchment storage properties, which govern hydrological resilience. These interconnected processes alter the timing and clustering of drought events, concentrating hydrological stress during periods that are sensitive to agriculture. Overall, drought behavior in northern Thailand is projected to intensify in a spatially heterogeneous pattern, emphasizing the need for localized, integrated adaptation measures and flexible water management strategies to mitigate future risks of drought. Full article
(This article belongs to the Section Hydrology)
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18 pages, 6338 KB  
Article
Runoff and Sediment Responses to Snowmelt in a Gully-Dominated Agricultural Catchment in Northeast China
by Qingnan Yang, Anshuang Su, Shijun Gao, Zhuoxin Chen, Mingming Guo and Jinzhong Xu
Hydrology 2025, 12(12), 327; https://doi.org/10.3390/hydrology12120327 - 11 Dec 2025
Viewed by 353
Abstract
Gully is the most visible sign of land degradation, but its effects on runoff and sediment dynamics during snowmelt conditions remain poorly understood. This study monitored a typical gully in the Mollisols region of Northeast China to investigate runoff and sediment transport at [...] Read more.
Gully is the most visible sign of land degradation, but its effects on runoff and sediment dynamics during snowmelt conditions remain poorly understood. This study monitored a typical gully in the Mollisols region of Northeast China to investigate runoff and sediment transport at the Gully Head (GH) and Gully Tail (GT) during spring snowmelt. Results showed that gully significantly influenced snow distribution, with deeper snow accumulation than on slopes. Runoff at the GH lasted 9 days, while gully connectivity extended catchment runoff by 10 additional days. Runoff temporal variation at GH and GT was broadly consistent, with GH contributing 7.4% of the total runoff at GT. Peak runoff discharge and sediment concentration occurred on the sixth day after snowmelt onset, driven by snow cover and air temperature. Gully significantly increased the sediment concentration from the upslope runoff. Runoff responses to temperature varied by melt stage, with GT showing higher sensitivity, especially under high-runoff conditions. High sediment yield was linked not to snow depth, but to late-stage snowmelt and soil thawing, when erosion sensitivity peaked. Hysteresis analysis revealed dominant clockwise loops during this phase, contrasting with figure-eight and counterclockwise patterns in other stages. These findings highlight the importance of targeting erosion control during late snowmelt when runoff intensifies and soils thaw. Full article
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10 pages, 4187 KB  
Data Descriptor
Early-Season Field Reference Dataset of Croplands in a Consolidated Agricultural Frontier in the Brazilian Cerrado
by Ana Larissa Ribeiro de Freitas, Fábio Furlan Gama, Ivo Augusto Lopes Magalhães and Edson Eyji Sano
Data 2025, 10(12), 204; https://doi.org/10.3390/data10120204 - 10 Dec 2025
Viewed by 621
Abstract
This dataset presents field observations collected in the municipality of Goiatuba, Goiás State, Brazil, a consolidated and representative agricultural frontier of the Brazilian Cerrado biome. The region presents diverse land use dynamics, including annual cropping systems, irrigated fields with up to three harvests [...] Read more.
This dataset presents field observations collected in the municipality of Goiatuba, Goiás State, Brazil, a consolidated and representative agricultural frontier of the Brazilian Cerrado biome. The region presents diverse land use dynamics, including annual cropping systems, irrigated fields with up to three harvests per year, and pasturelands. We conducted a field campaign from 3 to 7 November 2025, corresponding to the beginning of the 2025/2026 Brazilian crop season, when crops were at distinct early phenological stages. To ensure representativeness, we delineated 117 reference fields prior to the field campaign, and an additional 463 plots were surveyed during work. Geographic coordinates, crop types, and photographic records were obtained using the GPX Viewer application, a handheld GPS receiver, and the QField 3.7.9 mobile GIS application running on a tablet uploaded with Sentinel-2 true-color imagery and the municipal road network. Plot boundaries were subsequently digitized in QGIS Desktop 3.34.1 software, following a conservative mapping strategy to minimize edge effects and internal heterogeneity associated with trees and water catchment basins. In total, more than 26,000 hectares of agricultural fields were mapped, along with additional land use and land cover polygons representing water bodies, urban areas, and natural vegetation fragments. All reference fields were labeled based on in situ observations and linked to Sentinel-2 mosaics downloaded via the Google Earth Engine platform. This dataset is well-suited for training, testing, and validation of remote sensing classifiers, benchmarking studies, and agricultural mapping initiatives focused on the beginning of the agricultural season in the Brazilian Cerrado. Full article
(This article belongs to the Special Issue New Progress in Big Earth Data)
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17 pages, 1815 KB  
Article
Assessing Climate and Watershed Controls on Rain-on-Snow Runoff Using XGBoost-SHAP Explainable AI (XAI)
by Yog Aryal
Geosciences 2025, 15(12), 467; https://doi.org/10.3390/geosciences15120467 - 9 Dec 2025
Viewed by 424
Abstract
Rain-on-snow (ROS) events significantly impact hydrological processes in snowy regions, yet their seasonal drivers remain poorly understood, particularly in low-elevation and low-gradient catchments. This study uses an XGBoost-SHAP explainable artificial intelligence (XAI) model to analyze meteorological and watershed controls on ROS runoff in [...] Read more.
Rain-on-snow (ROS) events significantly impact hydrological processes in snowy regions, yet their seasonal drivers remain poorly understood, particularly in low-elevation and low-gradient catchments. This study uses an XGBoost-SHAP explainable artificial intelligence (XAI) model to analyze meteorological and watershed controls on ROS runoff in the Laurentian Great Lakes region. We used daily discharge, precipitation, temperature, and snow depth data from 2000 to 2023, available from HYSETS, to identify ROS runoff. The XGBoost model’s performance for predicting ROS runoff was higher in winter (R2 = 0.65, Nash–Sutcliffe = 0.59) than in spring (R2 = 0.56, Nash–Sutcliffe = 0.49), indicating greater predictability in colder months. The results reveal that rainfall and temperature dominated ROS runoff generation, jointly explaining more than 60% of total model importance, while snow depth accounted for 8–12% depending on season. Winter runoff is predominantly governed by climatic factors—rainfall, air temperature, and their interactions—with soil permeability and slope orientation playing secondary roles. In contrast, spring runoff shows increased sensitivity to land cover characteristics, particularly agricultural and shrub cover, as vegetation-driven processes become more influential. Snow depth effects shift from predominantly negative in winter, where snow acts as storage, to positive contributions in spring at shallow to moderate depths. ROS runoff responded positively to air temperatures exceeding approximately 2.5 °C in both winter and spring. Land cover influences on ROS runoff differ by vegetation type and season. Agricultural areas consistently increase runoff in both seasons, likely due to limited infiltration, whereas shrub-dominated regions exhibit stronger runoff enhancement in spring. The seasonal shift in dominant controls underscores the importance of accounting for land–climate interactions in predicting ROS runoff under future climate scenarios. These insights are essential for improving flood forecasting, managing water resources, and developing adaptive strategies. Full article
(This article belongs to the Section Cryosphere)
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15 pages, 2312 KB  
Article
Study on the Source and Microbial Mechanisms Influencing Heavy Metals and Nutrients in a Subtropical Deep-Water Reservoir
by Gaoyang Cui, Jiaoyan Cui, Mengke Zhang, Boning Zhang, Yingying Huang, Yiheng Wang, Wanfu Feng, Jiliang Zhou, Yong Liu and Tao Li
Microorganisms 2025, 13(12), 2750; https://doi.org/10.3390/microorganisms13122750 - 3 Dec 2025
Viewed by 397
Abstract
Reservoirs are hotspots for the coupling of nutrients and heavy metals, and they substantially modify the compositions and spatiotemporal distributions of microorganisms in fluvial systems. However, relatively few studies have been performed that investigate the microbial mechanisms driving interactions among heavy metals and [...] Read more.
Reservoirs are hotspots for the coupling of nutrients and heavy metals, and they substantially modify the compositions and spatiotemporal distributions of microorganisms in fluvial systems. However, relatively few studies have been performed that investigate the microbial mechanisms driving interactions among heavy metals and nutrients in reservoirs. The Goupitan Reservoir, a seasonal stratified reservoir located within the Wujiang River catchment, was chosen as the research subject. The temporal and spatial variations in heavy metals and nutrients, and the metagenomic composition of the reservoir water were analyzed in January, April, July, and October 2019. The results revealed that As, Ni, Co, and Mn were derived primarily from mine wastewater, whereas Zn, Pb, Cd, and Cr were related to domestic and agricultural wastewater discharge. The study area was dominated by Proteobacteria, Actinobacteria, Cyanobacteria, and Bacteroidetes, with the proportion of dominant phyla reaching 90%. Decreases in the dissolved oxygen (DO) concentration and pH in the bottom water during July and October were conducive to increases in the abundance of the anaerobic bacterial groups Planctomycetes and Acidobacteria. The functional genes norBC and nosZ associated with denitrification (DNF), the key gene nrfAH involved in the dissimilatory nitrate reduction to ammonium (DNRA) process, the functional genes aprAB and dsrAB responsible for sulfate reduction/sulfide oxidation, as well as the thiosulfate oxidation complex enzyme system SOX, all exhibit high abundance in hypoxic water bodies and peak in the redoxcline, highlighting the significance of related nitrogen (N) and sulfur (S) metabolic processes. In addition, the concentrations of heavy metals significantly affected the spatial differentiation of the planktonic bacterial community structure, with Mn, Co, Fe, Ni, As, and Cu making relatively high individual contributions (p < 0.01). This study is important for elucidating the sources and microbiological mechanisms influencing heavy metals and nutrients in seasonally stratified subtropical reservoirs. Full article
(This article belongs to the Special Issue Microbes, Society and Sustainable Solutions)
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22 pages, 2685 KB  
Article
Resolving Nitrate Sources in Rivers Through Dual Isotope Analysis of δ15N and δ18O
by Shuai Wang, Heng Li, Tao Kang, Ruixin Li and Chengzhong Zhang
Water 2025, 17(23), 3370; https://doi.org/10.3390/w17233370 - 26 Nov 2025
Viewed by 616
Abstract
Nitrate (NO3) pollution in rivers within agricultural regions has become a global issue that cannot be ignored. Identifying the sources and transformation processes of NO3 is crucial for safeguarding water quality in agricultural catchment areas. This study traces [...] Read more.
Nitrate (NO3) pollution in rivers within agricultural regions has become a global issue that cannot be ignored. Identifying the sources and transformation processes of NO3 is crucial for safeguarding water quality in agricultural catchment areas. This study traces the sources and transformation processes of NO3 in the Songhua River basin of Northeast China by analysing hydrochemical parameters and NO3 dual isotopes (δ15N and δ18O) in river water. It estimates the proportional contributions of NO3 sources using Bayesian modelling via the MixSIAR package (3.1.12) in the R programming language. (1) The relatively low NO3/Cl ratio and high chloride concentrations in the upstream section indicate that the primary sources of NO3 in this area are manure and sewage (M&S). (2) Dual isotope analysis of NO3 indicates that the primary sources of NO3 in the Songhua River basin are M&S, soil nitrogen (SN), and chemical fertilizers (CF). (3) Nitrification occurs throughout the entire watershed. (4) Model estimation results indicate that SN constitutes the primary source of NO3 throughout the entire watershed (48%), with no significant variation observed across the studied river sections. However, other major NO3 sources exhibit spatially significant differences, primarily manifested as follows: M&S constitute the primary upstream source of NO3 (39%), whilst downstream contributions are predominantly attributable to CF (20%). Intermediate regions experience combined impacts from both MS and CF sources. Full article
(This article belongs to the Special Issue Advanced Research in Non-Point Source Pollution of Watersheds)
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18 pages, 2852 KB  
Article
Permeable Organic Barriers as Effective Tools for Reducing Emissions of Nitrogen Compounds and PCBs from Manure to Groundwater
by Jerzy Mirosław Kupiec, Sebastian Szklarek, Magdalena Urbaniak, Arnoldo Font-Nájera, Elżbieta Mierzejewska-Sinner, Agnieszka Bednarek, Jakub Wójcik and Joanna Mankiewicz-Boczek
Nitrogen 2025, 6(4), 105; https://doi.org/10.3390/nitrogen6040105 - 20 Nov 2025
Viewed by 441
Abstract
Agricultural pollution, such as contamination from manure storage or leaking livestock buildings, often spreads through the catchment, affecting groundwater and surface water. An effective solution is the construction of permeable organic barriers. This study evaluates the efficiency of an innovative bioactive barrier in [...] Read more.
Agricultural pollution, such as contamination from manure storage or leaking livestock buildings, often spreads through the catchment, affecting groundwater and surface water. An effective solution is the construction of permeable organic barriers. This study evaluates the efficiency of an innovative bioactive barrier in removing nitrogen compounds (NO3 and NH4+) and polychlorinated biphenyls (PCBs). Two types of barriers were tested: a horizontal deposit under a manure storage point and a vertical deposit in the leachate flow path. The bioactivity of the barrier was confirmed by the presence of bacterial genes involved in nitrogen transformation and PCB degradation. Results showed a 70% reduction in NO3 (368.4 mg·L−1) and 43% reduction in NH4+ (42.4 mg·L−1). Genetic analysis identified bacteria capable of complete denitrification, resembling Pseudomonas stutzeri. The analysis also indicated that higher summer temperatures and pH levels fostered microbial communities capable of nitrogen transformation. Cluster analysis revealed that the vertical deposit zone was crucial for nitrogen removal. Additionally, the vertical barrier achieved a 53% reduction in PCBs, with Pseudomonas aeruginosa-like bacteria identified as PCB degraders. Full article
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19 pages, 6401 KB  
Article
Holocene and Late Pleistocene Flood Events in Central Europe Reconstructed from Eifel Maar Lake Sediments
by Johannes Albert and Frank Sirocko
Quaternary 2025, 8(4), 69; https://doi.org/10.3390/quat8040069 - 18 Nov 2025
Viewed by 770
Abstract
Severe floods such as in the Ahr valley in July 2021 are one of the leading causes of fatalities from natural disaster. Riverine and lacustrine floods are caused by a sudden flux of water masses from heavy rainfall or snowmelts. These surface water [...] Read more.
Severe floods such as in the Ahr valley in July 2021 are one of the leading causes of fatalities from natural disaster. Riverine and lacustrine floods are caused by a sudden flux of water masses from heavy rainfall or snowmelts. These surface water runoff events significantly enhance erosion of detrital material in the catchment, which is then deposited in natural sinks such as lakes. We reconstructed flood phases from Eifel maar lakes over the last 60,000 years and compared flood behavior with regional riverine flood data covering the past 1000 years. Multi-centennial flood cycles persisted throughout the Holocene with durations of flood-poor periods significantly decreasing around 3700 years ago due to human activity in the Eifel region. Holocene flood frequency peaked in the 13th and 14th centuries during the medieval agricultural revolution. Late Pleistocene flood phases occurred during the Younger Dryas and Heinrich stadials and represent surface runoff events in cold and dry climates. As flood behavior is strongly affected not only by increased water supply but also by soil stability and erosion processes in the catchment area, flood phases reflect shifts in the prevailing climate conditions and vegetation cover, either through natural steppe formation or human impact. Full article
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30 pages, 10234 KB  
Article
GIS-Based Site Selection for Agricultural Water Reservoirs: A Case Study of São Brás de Alportel, Portugal
by Olga Dziuba, Cláudia Custódio, Carlos Otero Silva, Fernando Miguel Granja-Martins, Rui Lança and Helena Maria Fernandez
Sustainability 2025, 17(22), 10276; https://doi.org/10.3390/su172210276 - 17 Nov 2025
Cited by 1 | Viewed by 554
Abstract
In the São Brás de Alportel municipality, water scarcity poses a significant constraint on agricultural activities. This study utilises Remote Sensing (RS) and Geographical Information Systems (GISs) to identify existing irrigated areas, delineate catchment basins, and select the most suitable sites for the [...] Read more.
In the São Brás de Alportel municipality, water scarcity poses a significant constraint on agricultural activities. This study utilises Remote Sensing (RS) and Geographical Information Systems (GISs) to identify existing irrigated areas, delineate catchment basins, and select the most suitable sites for the installation of new surface water reservoirs. First, the principal territorial components were characterised, including physical elements (climate, geology, soils, and hydrography) and anthropogenic infrastructure (road network and high-voltage power lines). Summer Sentinel-2 satellite imagery was then analysed to calculate the Normalised Difference Vegetation Index (NDVI), enabling the identification and classification of irrigated agricultural parcels. Flow directions and accumulations derived from Digital Elevation Models (DEMs) facilitated the characterisation of 38 micro-catchments and the extraction of 758 km of the drainage network. The siting criteria required a minimum setback of 100 m from roads and high-voltage lines, excluded farmland currently in use, and favoured mountainous areas with low permeability. Only 18.65% (2854 ha) of the municipality is agricultural land, of which just 4% (112 ha) currently benefits from irrigation. The NDVI-based classification achieved a Kappa coefficient of 0.88, indicating high reliability. Three sites demonstrated adequate storage capacity, with embankments measuring 8 m, 10 m, and 12 m in height. At one of these sites, two reservoirs arranged in a cascade were selected as an alternative to a single structure exceeding 12 m in height, thereby reducing environmental and landscape impact. The reservoirs fill between October and November in an average rainfall year and between October and January in a dry year, maintaining a positive annual water balance and allowing downstream plots to be irrigated by gravity. The methodology proved to be objective, replicable, and essential for the sustainable expansion of irrigation within the municipality. Full article
(This article belongs to the Section Sustainable Water Management)
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16 pages, 2103 KB  
Article
Hydrological and Geochemical Responses to Agricultural Activities in a Karst Catchment: Insights from Spatiotemporal Dynamics and Source Apportionment
by Le Cao, Qianyun Cheng, Shangqing Wang, Shaoqiang Xu, Qirui He, Yanqiu Li, Tao Peng and Shijie Wang
Water 2025, 17(22), 3264; https://doi.org/10.3390/w17223264 - 15 Nov 2025
Viewed by 509
Abstract
Karst aquifers, vital freshwater resources, are highly vulnerable to agricultural pollution, yet their hydro-geochemical responses remain poorly understood due to high spatial heterogeneity. This study aimed to unravel these complex responses in a subtropical karst agricultural catchment to provide a basis for its [...] Read more.
Karst aquifers, vital freshwater resources, are highly vulnerable to agricultural pollution, yet their hydro-geochemical responses remain poorly understood due to high spatial heterogeneity. This study aimed to unravel these complex responses in a subtropical karst agricultural catchment to provide a basis for its sustainable management. We employed high-frequency monitoring at a headwater spring (background), a depression well (hotspot), and the catchment outlet (integrated) in Southwest China. Using hydrological and geochemical data from 2017, we applied Principal Component Analysis (PCA) to apportion natural and anthropogenic sources. The main findings revealed significant spatial heterogeneity, with the depression well acting as a contamination hotspot characterized by rapid hydrological responses and elevated SO42− and Cl concentrations. PCA successfully decoupled an “anthropogenic factor” (PC1, 40.5%) from a “natural weathering factor” (PC2, 25.2%). Critically, agricultural SO42− at the hotspot was counter-intuitively higher during the wet season than the dry season, opposing the typical dilution pattern of background ions and revealing that depressions act as contaminant-concentrating pathways, whose risks are severely underestimated by traditional outlet monitoring. The anomalous sulfate dynamics reveal a cross-seasonal “storage-and-release” mechanism (legacy effect) within the karst Critical Zone, demonstrating that these systems can buffer and “remember” contaminants. Full article
(This article belongs to the Section Hydrogeology)
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