Search Results (69)

A diffusion absorption heat transformer is a completely thermally driven heat upgrading technology with significant application potential in low-grade thermal energy recovery. However, existing diffusion absorption heat transformers have problems such as complex circulation processes, limited solution flow rates, and insufficient stability due to their reliance on bubble pumps. A jet pump was proposed for application in a diffusion absorption heat transformer cycle to replace the bubble pumps in the original diffusion absorption heat transformer cycle. In the novel cycle, without electricity consumption, the diffusant gas was used as the primary flow of the jet pump to transport the solution, and the diffusion generation of the refrigerant was realized in the jet pump for more efficient and stable thermal energy upgrading. The performance of the novel cycle with H₂O/LiBr/C₅H₁₀ or H₂O/HCOOK/C₅H₁₀ as working fluids was analyzed based on a constructed theoretical model validated by numerical simulation. It was found that the performance of the jet pump was sensitive to the generator temperature and the pressure difference of the cycle. Increasing the temperature of the jet pump and reducing the temperature of the absorber were conducive to improving the COP. As a potential absorbent substitute for LiBr, HCOOK also led to slightly better performance in most cases. Full article

Hydrogen (H₂) liquefaction is an energy-intensive process, and improving its efficiency is critical for large-scale deployment in H₂ infrastructure. Industrial waste heat recovery contributes to energy savings and environmental improvements in liquid H₂ processes. This study proposes a comparative framework for industrial waste heat recovery in H₂ liquefaction systems by examining three recovery cycles, including an ammonia–water absorption refrigeration (ABR) unit, a diffusion absorption refrigeration (DAR) process, and a combined organic Rankine/Kalina plant. All scenarios incorporate 2 MW of industrial waste heat to improve precooling and reduce the external power demand. The simulations were conducted using Aspen HYSYS (V10) in combination with an m-file code in MATLAB (R2022b) programming to model each configuration under consistent operating conditions. Detailed energy and exergy analyses are performed to assess performance. Among the three scenarios, the ORC/Kalina-based system achieves the lowest specific power consumption (4.306 kWh/kg LH₂) and the highest exergy efficiency in the precooling unit (70.84%), making it the most energy-efficient solution. Although the DAR-based system shows slightly lower performance, the ABR-based system achieves the highest exergy efficiency of 52.47%, despite its reduced energy efficiency. By comparing three innovative configurations using the same industrial waste heat input, this work provides a valuable tool for selecting the most suitable design based on either energy performance or thermodynamic efficiency. The proposed methodology can serve as a foundation for future system optimization and scale-up. Full article

Seeking the alternative working pairs used in absorption refrigeration cycles is one of the main issues in refrigeration fields due to the drawbacks of traditional H₂O/LiBr and NH₃/H₂O, such as corrosion, crystallization, and toxicity. The imidazolium-based ionic liquid [hmim][Tf₂N] has emerged as a promising candidate as an absorbent used in absorption refrigeration systems. In addition, due to having a higher specific heat and higher latent heat of evaporation, hydrocarbons such as HC-290 have been considered as good alternative refrigerants in compression refrigeration cycles. In order to explore the possibility of using HC-290 in the absorption refrigeration cycle, the exact phase behavior of HC-290 with absorbents should be known. Therefore, in this work, the isochoric saturation method was used to determine the solubility of HC-290 in [hmim][Tf₂N] over a temperature range of 283.15 K to 343.15 K. The experimental data were modeled using the non-random two-liquid (NRTL) activity coefficient model and the Krichevsky–Kasarnovsky (K-K) fugacity model. The average absolute relative deviations for the mole fraction of HC-290 in [hmim][Tf₂N] between this work and calculated results from the models were 0.76% (NRTL) and 0.78% (K-K), and the corresponding maximum relative deviations were 3.39% and 3.24%. Based on the NRTL model, the Gibbs free energy, enthalpy change, and entropy change in the dissolution process of HC-290 in [hmim][Tf₂N] were calculated and discussed. Furthermore, the Henry’s constants of various refrigerants in [hmim][Tf₂N] were calculated at 313.15 K and 333.15 K, and the results were systematically compared. Full article

Recent research in the liquefied natural gas (LNG) industry has concentrated on reducing specific power consumption (SPC) during production, which helps to lower operating costs and decrease the carbon footprint. Although reducing the SPC offers benefits, it can complicate the system and increase investment costs. This review investigates the thermodynamic parameters of various natural gas (NG) liquefaction technologies. It examines the cryogenic NG processes, including integrating NG liquid recovery plants, nitrogen rejection cycles, helium recovery units, and LNG facilities. It explores various approaches to improve hybrid NG liquefaction performance, including the application of optimization algorithms, mixed refrigerant units, absorption refrigeration cycles, diffusion–absorption refrigeration systems, auto-cascade absorption refrigeration processes, thermoelectric generator plants, liquid air cold recovery units, ejector refrigeration cycles, and the integration of renewable energy sources and waste heat. The review evaluates the economic aspects of hybrid LNG systems, focusing on specific capital costs, LNG pricing, and capacity. LNG capital cost estimates from academic sources (173.2–1184 USD/TPA) are lower than those in technical reports (486.7–3839 USD/TPA). LNG prices in research studies (0.2–0.45 USD/kg, 2024) are lower than in technical reports (0.3–0.7 USD/kg), based on 2024 data. Also, this review investigates LNG accidents in detail and provides valuable insights into safety protocols, risk management strategies, and the overall resilience of LNG operations in the face of potential hazards. A detailed evaluation of LNG plants built in recent years is provided, focusing on technological advancements, operational efficiency, and safety measures. Moreover, this study investigates LNG ports in the United States, examining their infrastructures, regulatory compliance, and strategic role in the global LNG supply chain. In addition, it outlines LNG’s current status and future outlook, focusing on key industry trends. Finally, it presents a market share analysis that examines LNG distribution by export, import, re-loading, and receiving markets. Full article

This study conducts a life cycle assessment and exergoenvironmental evaluation of a double-effect vapor absorption chiller (DEAC) with a cooling capacity of 352 kW, employing three different energy sources: natural gas, biomethane, and green hydrogen. The main objectives of this paper are as follows: (i) provide an exergoenvironmental model for DEAC technologies, (ii) evaluation of a case-study where a DEAC is used to cover the cooling demand of a specific university building in the Northeast of Brazil, and (iii) evaluate the scenario where the DEAC is fed by green hydrogen (GH2) and compare it with conventional energy resources (natural gas and biomethane). In order to develop the exergoenvironmental model, two methodologies are essential: a thermodynamic analysis and a Life Cycle Assessment (LCA). The thermodynamic analysis was carried out using the Engineering Equation Solver (EES: 10.998) software. The LCA has been developed through the open-source software openLCA version 1.10.3, with the Ecoinvent 3.7.1 life cycle inventory database, whereas the chosen life cycle inventory assessment (LCIA) method was the ReCiPe Endpoint LCA method (Humanitarian, medium weighting–H, A). The main results indicate that green hydrogen provides a 99.84% reduction in environmental impacts compared to natural gas during the operational phase, while biomethane reduces these impacts by 54.21% relative to natural gas. In the context of life cycle assessment (LCA), green hydrogen decreases fossil resource depletion by 18% and climate change-related emissions by 33.16% compared to natural gas. This study contributes to enhancing the understanding of the environmental and exergoenvironmental impacts of a double-effect vapor absorption chiller by varying the fuel usage during the operational phase. Full article

The accurate optimisation of absorption chillers is often impeded by idealised models that overlook system interactions and machine complexities. This study introduces a validated mathematical description for predicting the primary indicators of non-idealised absorption chillers, accounting for factors such as the electrical work of the Solution Circulation Pump, entropy changes within the refrigerant cycle, and exergy losses. Validation against 13 years of data (2008–2021) from the University of Debrecen’s absorption chiller indicated close agreement, with deviations within acceptable limits. The use of a solution heat exchanger shifted cooling indicators towards their minima. Sensitivity analyses indicated that a 2.5% reduction in condenser temperature increased COP by 41.3% and Cooling Exergetic Efficiency by 15.5%, while a 2.5% reduction in the Heat Fraction Factor improved both by 34%. Adjusting absorber temperature and Heat Fraction Factor down by 2.5%, alongside a 2.5% rise in generator temperature, resulted in a 100.8% increase in COP and a 52.8% boost in Cooling Exergetic Efficiency. These insights provide a solid foundation for future optimisation strategies in real-life absorption chiller systems. Full article

With the requirement of energy decarbonization, natural gas (NG) and hydrogen (H₂) become increasingly important in the world’s energy landscape. The liquefaction of NG and H₂ significantly increases energy density, facilitating large-scale storage and long-distance transport. However, conventional liquefaction processes mainly adopt electricity-driven compression refrigeration technology, which generally results in high energy consumption and carbon dioxide emissions. Absorption refrigeration technology (ART) presents a promising avenue for enhancing energy efficiency and reducing emissions in both NG and H₂ liquefaction processes. Its ability to utilize industrial waste heat and renewable thermal energy sources over a large temperature range makes it particularly attractive for sustainable energy practices. This review comprehensively analyzes the progress of ART in terms of working pairs, cycle configurations, and heat and mass transfer in main components. To operate under different driven heat sources and refrigeration temperatures, working pairs exhibit a diversified development trend. The environment-friendly and high-efficiency working pairs, in which ionic liquids and deep eutectic solvents are new absorbents, exhibit promising development potential. Through the coupling of heat and mass transfer within the cycle or the addition of sub-components, cycle configurations with higher energy efficiency and a wider range of operational conditions are greatly focused. Additives, ultrasonic oscillations, and mechanical treatment of heat exchanger surfaces efficiently enhance heat and mass transfer in the absorbers and generators of ART. Notably, nanoparticle additives and ultrasonic oscillations demonstrate a synergistic enhancement effect, which could significantly improve the energy efficiency of ART. For the conventional NG and H₂ liquefaction processes, the energy-saving and carbon emission reduction potential of ART is analyzed from the perspectives of specific power consumption (SPC) and carbon dioxide emissions (CEs). The results show that ART integrated into the liquefaction processes could reduce the SPC and CE by 10~38% and 10~36% for NG liquefaction processes, and 2~24% and 5~24% for H₂ liquefaction processes. ART, which can achieve lower precooling temperatures and higher energy efficiency, shows more attractive perspectives in low carbon emissions of NG and H₂ liquefaction. Full article

This article introduces a novel multiple-cycle generation system for efficient heat recovery at high and low temperatures. The system is modeled and optimized using the M2EP analysis method (mass, energy, exergy, and performance) and the particle swarm optimization algorithm. The multigeneration system produces electricity, cold, domestic hot water, and biogas by utilizing Kalina cycles, diffusion–absorption refrigeration machines, and high-performance heat exchangers by harnessing waste heat from cement kiln exhaust gases. The Kalina cycle is employed for electricity generation, wherein the H₂O+NH₃ mixture, heated by hot water, circulates through heat exchangers. Downstream of the Kalina cycle, the refrigeration machine generates cold by evaporating the strong solution of the H₂O+NH₃ mixture. Hydrogen circulates in the diffusion–absorption refrigerator (DAR) circuit, facilitating the exchange between the evaporator and the absorber. The domestic hot water and biogas production systems operate at lower temperatures (around 45 °C). The simulation results for the Kalina cycle indicate an electrical energy production of 2565.03 kW, with a release of usable energy (residual gases) estimated at 7368.20 kW and a thermal efficiency of 22.15%. Exergy destruction is highest at heat exchanger 1, accounting for 26% of the total. A coefficient of performance of 0.268 and an evaporator temperature of 10.57 °C were obtained for the DAR cycle. The absorber contributes the most to energy exchanges, comprising 37% of the entire circuit. Summarizing the potential for valorizing waste heat from cement kilns, this article lays the foundation for future research. Full article

Adopting biomass energy as an alternative to fossil fuels for electricity production presents a viable strategy to address the prevailing energy deficits and environmental concerns, although it faces challenges related to suboptimal energy efficiency levels. This study introduces a novel combined cooling and power (CCP) system, incorporating an externally fired gas turbine (EFGT), steam Rankine cycle (SRC), absorption refrigeration cycle (ARC), and organic Rankine cycle (ORC), aimed at boosting the efficiency of biomass integrated gasification combined cycle systems. Through the development of mathematical models, this research evaluates the system’s performance from both thermodynamic and exergoeconomic perspectives. Results show that the system could achieve the thermal efficiency, exergy efficiency, and levelized cost of exergy (LCOE) of 70.67%, 39.13%, and 11.67 USD/GJ, respectively. The analysis identifies the combustion chamber of the EFGT as the component with the highest rate of exergy destruction. Further analysis on parameters indicates that improvements in thermodynamic performance are achievable with increased air compressor pressure ratio and gas turbine inlet temperature, or reduced pinch point temperature difference, while the LCOE can be minimized through adjustments in these parameters. Optimized operation conditions demonstrate a potential 5.7% reduction in LCOE at the expense of a 2.5% decrease in exergy efficiency when compared to the baseline scenario. Full article

The utilization of biomass for multi-generation systems is garnering significant interest due to its potential in conserving primary energy and mitigating greenhouse gas emissions. However, enhancing its energy efficiency remains a critical challenge. This study introduces an innovative cogeneration system that combines biomass gasification with an externally fired gas turbine, organic Rankine cycle, and absorption refrigeration cycle. It undergoes thorough thermodynamic and exergoeconomic evaluations, with a dual-objective optimization conducted to identify the optimal operational conditions that achieve the highest exergy efficiency while minimizing product cost. The findings reveal that, in the base case, the thermal efficiency, exergy efficiency, and sum unit cost of the product (SUCP) of the system are 66.36%, 32.04%, and 8.71 USD/GJ, respectively. A parametric study illustrates that elevating the air compressor pressure ratio or the temperature difference at the cold end enhances thermal efficiency but reduces exergy efficiency. Additionally, the lowest unit cost of the product is attainable by optimizing the gas turbine inlet temperature. The performance of the system shows negligible sensitivity to the turbine inlet pressure of a bottoming organic Rankine cycle. Finally, optimization demonstrates a 9.7% increase in exergy efficiency and a 1.8% rise in the SUCP compared to the baseline scenario. The study suggests integrating with other energy sources for diversified product outputs and conducting environmental analyses in future research. Full article

The supercritical CO₂ power cycle driven by solar as a new generation of solar thermal power generation technology has drawn significant attention worldwide. In this paper, a cogeneration system derived from a supercritical CO₂ recompression Brayton cycle is proposed, by considering the recovery of waste heat from the turbine outlet. The absorption refrigeration cycle is powered by the medium-temperature waste heat from the turbine outlet, while the low-temperature waste heat is employed for heating, achieving the cascaded utilization of the heat from the turbine outlet. As for the proposed combined cooling, heating, and power (CCHP) system, a dynamic model was built and verified in MATLAB R2021b/Simulink. Under design conditions, values for the energy utilization factor (EUF) and exergy efficiency of the cogeneration system were obtained. Moreover, the thermodynamic performances of the system were investigated in variable cooling/heating load and irradiation conditions. Compared with the reference system, it is indicated that the energy utilization factor (EUF) and exergy efficiency are 84.7% and 64.8%, which are improved by 11.5% and 10.3%. The proposed supercritical CO₂ CCHP system offers an effective solution for the efficient utilization of solar energy. Full article

The insufficiency of energy supply and availability remains a significant global energy challenge. This work proposes a novel approach to addressing global energy challenges by testing the supercritical property and conversion of low-temperature thermal heat into useful energy. It introduces a combined-cascade steam-to-steam trigeneration cycle integrated with vapour absorption refrigeration (VAR) and district heating systems. Energetic and exergetic techniques were applied to assess irreversibility and exergetic destruction. At a gas turbine power of 26.1 MW, energy and exergy efficiencies of 76.68% and 37.71% were achieved, respectively, while producing 17.98 MW of electricity from the steam-to-steam driven cascaded topping and bottoming plants. The cascaded plant attained an energetic efficiency of 38.45% and an exergy efficiency of 56.19%. The overall cycle efficiencies were 85.05% (energy) and 77.99% (exergy). More than 50% of the plant’s lost energy came from the combustion chamber of the gas turbine. The trigeneration system incorporated a binary NH₃–H₂O VAR system, emphasizing its significance in low-temperature energy systems. The VAR system achieved a cycle exergetic efficiency of 92.25% at a cooling capacity of 2.07 MW, utilizing recovered waste heat at 88 °C for district hot water. The recovered heat minimizes overall exergy destruction, enhancing thermal plant performance. Full article

Due to its environmental benefits, CO₂ shows great potential in refrigeration systems. However, a basic CO₂ transcritical (BCT) refrigeration system used for airconditioning in buildings might generate massive indirect carbon emissions for its low COP. In this study, a novel CO₂ transcritical/two-stage absorption (CTTA) hybrid refrigeration system is broadly investigated, and both energy efficiency and life cycle climate performance (LCCP) are specifically engaged. The theoretical model shows that optimal parameters for the generator inlet temperature (T_G2), intermediate temperature (T_m), and discharge pressure (P_c), exist to achieve maximum COP_tol. Using the LCCP method, the carbon emissions of the CTTA system are compared to six typical refrigeration systems by using refrigerants, including R134a, R1234yf and R1234ze(E) etc. The LCCP value of the CTTA system is 3768 kg CO_2e/kW, which is 53.6% less than the BCT system and equivalent to the R134a system. Moreover, its LCCP value could be 3.4% less than the R1234ze(E) system if the COP of the CO₂ subsystem is further improved. In summary, the CTTA system achieves ultra-low carbon emissions, which provides a potential alternative to air conditioning systems in buildings that can be considered alongside R1234yf and R1234ze(E) systems. Full article

This study aims to develop, evaluate, and improve a polygeneration system that combines solar and Brayton cycle technologies and focuses on the sequential integration of heat. In this configuration, the exhaust gases from the Al-Qayyarah gas turbine power plant and the parabolic trough collector (PTC) array generate steam through a high recovery steam generation process. An absorption refrigeration system also supplies the Brayton circuit with low-temperature air. This process is evaluated from a 3E perspective, which includes exergy, energy, and exergoeconomic analyses for two different configurations. These configurations are integrated solar combined cycle (ISCC) with and without absorption systems (ISCC and ISCC-ARC). In addition, a comprehensive analysis was carried out to assess the impact of critical factors on the output generated, the unit cost of the products, and the exergy and energy efficiency for each configuration. The results revealed that the power produced by the ISCC-ARC and ISCC systems is 580.6 MW and 547.4 MW, respectively. Accordingly, the total energy and exergy efficiencies for the ISCC-ARC are 51.15% and 49.4%, respectively, while for the ISCC system, they are 50.89% and 49.14%, respectively. According to the results, the total specific costs for the ISCC-ARC system increased from 69.09 $/MWh in June to 79.05 $/MWh in December. ISCC’s total specific costs also fluctuate throughout the year, from 72.56 $/MWh in June to 78.73 $/MWh in December. Full article

Well-designed passive buildings can drastically reduce building energy consumption, and optimal design of air conditioning systems is the key to achieving low operating energy consumption in near-zero energy buildings. TRNSYS was used to build the simulation model for a near-zero-energy building and its air conditioning system in Beijing. The Taguchi method was used to sort the design parameters that affect system performance according to the degree of influence and find the best combination of design parameters to optimize the system, which increased the solar fraction of the system by 4.6% and reduced the annual operating energy consumption by 7.32%. For the optimized system, a multi-objective optimization function of the life cycle costs and carbon emissions was established. By comparing the energy consumption, life cycle costs, and carbon emissions of the air conditioning system under different system configurations, optimal configuration solutions under different design target weights were obtained. It was found that using a ground source heat pump system + solar collector system had better energy-savings benefits, but the operating costs were slightly higher. The application of absorption refrigeration can reduce the system operating costs but will increase the initial investment. The best economic benefits were achieved using the ground source heat pump system + solar collector system for heating in winter and the ground source heat pump system for cooling in summer, and the best environmental benefits were obtaining using the ground source heat pump system + solar collector system for heating in winter and the ground source heat pump system + solar absorption refrigeration system in summer, which provides a reference for the optimization design and research of air conditioning systems in near-zero energy buildings. Full article