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Keywords = Z-source converters

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16 pages, 3833 KiB  
Article
Fault-Tolerant Operation of Photovoltaic Systems Using Quasi-Z-Source Boost Converters: A Hardware-in-the-Loop Validation with Typhoon HIL
by Basit Ali, Mothana S. A. Al Sunjury, Adnan Ashraf, Mohammad Meraj and Pietro Tricoli
Electronics 2025, 14(13), 2522; https://doi.org/10.3390/electronics14132522 - 21 Jun 2025
Viewed by 719
Abstract
Photovoltaic (PV) systems are prone to different types of faults, primarily electrical faults such as line-to-ground (L-G) and line-to-line (L-L) faults, which can significantly reduce system performance, efficiency, and lead to increased power losses. Moreover, mechanical damage caused by environmental stressors (such as [...] Read more.
Photovoltaic (PV) systems are prone to different types of faults, primarily electrical faults such as line-to-ground (L-G) and line-to-line (L-L) faults, which can significantly reduce system performance, efficiency, and lead to increased power losses. Moreover, mechanical damage caused by environmental stressors (such as wind, hail, or temperature variations), aging, or improper installation also contribute to system degradation. This study specifically focuses on electrical faults and proposes a method that not only enables the isolation of faulty modules but also ensures the uninterrupted operation of the remaining healthy modules and also assists in the localization of faults. Unlike benchmarked techniques-based boost converters, the Quasi-Z-Source Boost Converter (QZBC) topology offers improved voltage boosting with high gain values, reduced component stress, and enhanced reliability when the PV system is undergoing fault identification and localization algorithms. A 600-watt PV system connected with a Quasi-Z-Source Boost Converter was implemented and tested under different fault conditions using a hardware-in-the-loop (HIL) setup with Typhoon HIL. All the component values of the QZBC were calculated based on the system requirements rather than assumed, ensuring both practical feasibility and design accuracy. The experimental results show that the converter achieved an efficiency of over 96% under electrical-fault conditions, confirming the effectiveness of the quasi-Z-source boost converter in maintaining a stable power output when the PV system is undergoing fault identification and localization algorithms. The study further highlights the benefits of HIL-based testing for evaluating PV-system resilience and fault-handling capabilities in real-time conditions using a Typhoon HIL 404 environment. Full article
(This article belongs to the Special Issue Compatibility, Power Electronics and Power Engineering)
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27 pages, 12423 KiB  
Article
Voltage Control Nonlinearity in QZSDMC Fed PMSM Drive System with Grid Filtering
by Przemysław Siwek and Konrad Urbanski
Energies 2025, 18(6), 1334; https://doi.org/10.3390/en18061334 - 8 Mar 2025
Viewed by 608
Abstract
This publication investigates the control of output voltage-boosting in a Quasi-Z-Source direct matrix converter operating as part of a PMSM drive system with an RLC grid filter. The structure and control algorithms enabling regulation of the converter’s output voltage in both step-down and [...] Read more.
This publication investigates the control of output voltage-boosting in a Quasi-Z-Source direct matrix converter operating as part of a PMSM drive system with an RLC grid filter. The structure and control algorithms enabling regulation of the converter’s output voltage in both step-down and step-up modes are presented. These methods are based on the dq transformation, which provides a measurement signal for a linear PI-type controller. The article includes simulation results obtained using Matlab Simulink 2019a, which facilitated the preliminary verification of the applied structures and methods. The obtained model revealed the presence of nonlinearities in the Quasi-Z-Source voltage control system, which were subsequently confirmed through experimental verification. The system is stable but exhibits oscillatory behavior, with its parameters dependent on the amplitude of the step of the voltage gain coefficient. The voltage control system regulates the output voltage at least 10 times faster than a single period of the grid voltage sine wave. To enhance voltage control, a tunable controller with optimized parameters was proposed. The conducted studies demonstrated a 16.5% improvement in the IAE index and faster settling time for Quasi-Z-Source voltage control using the proposed controller compared to the reference controller. Full article
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13 pages, 822 KiB  
Article
Chemical Informatics Combined with Kendrick Mass Analysis to Enhance Annotation and Identify Pathways in Soybean Metabolomics
by Troy D. Wood, Erin R. Tiede, Alexandra M. Izydorczak, Kevin J. Zemaitis, Heng Ye and Henry T. Nguyen
Metabolites 2025, 15(2), 73; https://doi.org/10.3390/metabo15020073 - 24 Jan 2025
Cited by 1 | Viewed by 1082
Abstract
Background: Among abiotic stresses to agricultural crops, drought stress is the most prolific and has worldwide detrimental impacts. The soybean (Glycine max) is one of the most important sources of nutrition to both livestock and humans. Different plant introductions (PI) of [...] Read more.
Background: Among abiotic stresses to agricultural crops, drought stress is the most prolific and has worldwide detrimental impacts. The soybean (Glycine max) is one of the most important sources of nutrition to both livestock and humans. Different plant introductions (PI) of soybeans have been identified to have different drought tolerance levels. Objectives: Here, two soybean lines, Pana (drought sensitive) and PI 567731 (drought tolerant) were selected to identify chemical compounds and pathways which could be targets for metabolomic analysis induced by abiotic stress. Methods: Extracts from the two lines are analyzed by direct infusion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry. The high mass resolution and accuracy of the method allows for identification of ions from hundreds of different compounds in each cultivar. The exact m/z of these species were filtered through SoyCyc and the Human Metabolome Database to identify possible molecular formulas of the ions. Next, the exact m/z values were converted into Kendrick masses and their Kendrick mass defects (KMD) computed, which were then sorted from high to low KMD. This latter process assists in identifying many additional molecular formulas, and is noted to be particularly useful in identifying formulas whose mass difference corresponds to two hydrogen atoms. Results: In this study, more than 460 ionic formulas were identified in Pana, and more than 340 ionic formulas were identified in PI 567731, with many of these formulas reported from soybean for the first time. Conclusions: Using the SoyCyc matches, the metabolic pathways from each cultivar were compared, providing lists of molecular targets available to profile effects of abiotic stress on these soybean cultivars. Key metabolites include chlorophylls, pheophytins, mono- and diacylglycerols, cycloeucalenone, squalene, and plastoquinones and involve pathways which include the anabolism and catabolism of chlorophyll, glycolipid desaturation, and biosynthesis of phytosterols, plant sterols, and carotenoids. Full article
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25 pages, 2604 KiB  
Article
Enhancing Efficiency in Hybrid Solar–Wind–Battery Systems Using an Adaptive MPPT Controller Based on Shadow Motion Prediction
by Abdorreza Alavi Gharahbagh, Vahid Hajihashemi, Nasrin Salehi, Mahyar Moradi, José J. M. Machado and João Manuel R. S. Tavares
Appl. Sci. 2024, 14(24), 11710; https://doi.org/10.3390/app142411710 - 16 Dec 2024
Viewed by 1613
Abstract
Renewable energy sources are particularly significant in global energy production, with wind and solar being the most prevalent sources. Managing the simultaneous connection of wind and solar energy generators to the smart grid as distributed generators involves complex control and stabilization due to [...] Read more.
Renewable energy sources are particularly significant in global energy production, with wind and solar being the most prevalent sources. Managing the simultaneous connection of wind and solar energy generators to the smart grid as distributed generators involves complex control and stabilization due to their inherent uncertainties, making their management more intricate than traditional power plants. This study focuses on enhancing the speed and efficiency of the maximum power point tracking (MPPT) system in a solar power plant. A hybrid network is modeled, comprising a wind turbine with a doubly-fed induction generator (DFIG), a solar power plant with photovoltaic (PV) cells, an MPPT system, a Z-source converter, and a storage system. The proposed approach employs a motion detection-based method, utilizing image-processing techniques to optimize the MPPT of PV cells based on shadow movement patterns within the solar power plant area. This method significantly reduces the time required to reach the maximum power point (MPP), lowers the computational load of the control system by predicting shadow movements, and enhances the MPPT speed while maintaining system stability. The approach, which is suitable for relatively large solar farms, is implemented without the need for any additional sensors and relies on the system’s history. The simulation results show that the proposed approach improves the MPPT system’s efficiency and reduces the pressure on the control circuits by more than 70% in a 150,000 m2 solar farm under shaded conditions. Full article
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18 pages, 4460 KiB  
Article
Novel Quasi-Z-Source Inverter with High-Frequency AC Link of High-Proportion Renewable-Energy Power System
by Wenjuan Dong, Xingang Wang, DeLiNuEr Azan, Yuwei Wang and Lei Li
Processes 2024, 12(12), 2842; https://doi.org/10.3390/pr12122842 - 11 Dec 2024
Viewed by 983
Abstract
Z-source/quasi-z-source inverters can make up for some limitations of traditional voltage-/current-source inverters. In recent years, more and more research has been carried on z-source/quasi-z-source inverters, but most of them are unable to realize input/output galvanic isolation. The proposal of high-frequency isolated z-source/quasi-z-source inverters [...] Read more.
Z-source/quasi-z-source inverters can make up for some limitations of traditional voltage-/current-source inverters. In recent years, more and more research has been carried on z-source/quasi-z-source inverters, but most of them are unable to realize input/output galvanic isolation. The proposal of high-frequency isolated z-source/quasi-z-source inverters greatly enriches the topological family of this type of converter but places relatively high voltage stress on the capacitors. In this paper, a novel circuit topology of a quasi-z-source inverter with a high-frequency AC link of a new high-proportion power system is proposed. The operating principle and abnormal operating states, such as discontinuous-conduction mode (DCM) operation and abnormal states caused by component failures, are analyzed. The double closed-loop control strategy is analyzed and designed, and a grid-connected photovoltaic system based on the inverter is designed. The experimental results verify that the presented inverter has advantages such as high-frequency electrical isolation, bi-directional power flow, lower voltage stress on the capacitors, etc. Full article
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27 pages, 18482 KiB  
Article
Current Compensation for Faulted Grid-Connected PV Arrays Using a Modified Voltage-Fed Quasi-Z-Source Inverter
by Abdullah Abdurrahman Al-Saloli and Faris E. Alfaris
Electronics 2024, 13(21), 4312; https://doi.org/10.3390/electronics13214312 - 2 Nov 2024
Cited by 1 | Viewed by 1214
Abstract
Large-scale photovoltaic (PV) systems are being widely deployed to meet global environmental goals and renewable energy targets. Advances in PV technology have driven investment in the electric sector. However, as the size of PV arrays grows, more obstacles and challenges emerge. The primary [...] Read more.
Large-scale photovoltaic (PV) systems are being widely deployed to meet global environmental goals and renewable energy targets. Advances in PV technology have driven investment in the electric sector. However, as the size of PV arrays grows, more obstacles and challenges emerge. The primary obstacles are the occurrence of direct current (DC) faults and shading in a large array of PV panels, where any malfunction in a single panel can have a detrimental impact on the overall output power of the entire series-connected PV string and therefore the PV array. Due to the abrupt and frequent fluctuations in power, beside the low-PV systems’ moment of inertia, various technical problems may arise at the point of common coupling (PCC) of grid-connected PV generations, such as frequency and voltage stability, power efficiency, voltage sag, harmonic distortion, and other power quality factors. The majority of the suggested solutions were deficient in several crucial transient operating features and cost feasibility; therefore, this paper introduces a novel power electronic DC–DC converter that seeks to mitigate these effects by compensating for the decrease in current on the DC side of the system. The suggested solution was derived from the dual-source voltage-fed quasi-Z-source inverter (VF-qZSI), where the PV generation power can be supported by an energy storage element. This paper also presents the system architecture and the corresponding power switching control. The feasibility of the proposed method is investigated with real field data and the PSCAD simulation platform during all possible weather conditions and array faults. The results demonstrate the feasibility and capability of the proposed scheme, which contributes in suppressing the peak of the transient power-to-time variation (dP/dt) by 72% and reducing its normalized root-mean-square error by about 38%, with an AC current total harmonic distortion (THD) of only 1.04%. Full article
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15 pages, 14232 KiB  
Article
Design and Verification of Thermal Control System of Communication Satellite
by Hongzhou Huang and Changgen Bu
Aerospace 2024, 11(10), 803; https://doi.org/10.3390/aerospace11100803 - 30 Sep 2024
Cited by 2 | Viewed by 2865
Abstract
The multiple working modes, complex working conditions, frequent changes in external heat flux, and high power consumption of communication satellites all pose great difficulties to their thermal design. This paper mainly describes the design of a thermal control system for high-power communication satellites. [...] Read more.
The multiple working modes, complex working conditions, frequent changes in external heat flux, and high power consumption of communication satellites all pose great difficulties to their thermal design. This paper mainly describes the design of a thermal control system for high-power communication satellites. Firstly, new efficient heat transfer technologies and thermal control materials for spacecraft are introduced. Secondly, the structure and internal heat source of the satellite are introduced. Thirdly, the external heat fluxes are analyzed, and the position of the heat dissipation surface and extreme conditions are confirmed. Then, a thermal control system is designed around the difficulties of thermal control. With heat pipes, the temperature uniformity of +Y deck, −Y deck, and +Z deck increased by 8 °C, 9.9 °C, and 34.2 °C, respectively. Furthermore, the maximum temperature of the power controller, secondary power supply, bidirectional frequency converter, and solid discharge decreased by 32.5 °C, 22.0 °C, 14.0 °C, and 164 °C, respectively. Finally, a thermal balance test is performed. The test results show that the temperatures of the solid-state power amplifier, on-board computer, power controller, secondary power supply, and bidirectional frequency converter meet the requirements of the thermal control indices. In addition, the temperature of thermal-sensitive components such as batteries and the storage tank also meets the requirements. The thermal design scheme is reasonable and feasible, and the thermal balance test verifies the correctness of the thermal design. Full article
(This article belongs to the Section Astronautics & Space Science)
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16 pages, 6350 KiB  
Article
Design and Implementation of Peak Current Mode with PI Controller for Coupled Inductor-Based High-Gain Z-Source Converter
by Şükrü Can Özer, Bülent Dağ, Selman Demirel and Mehmet Akif Özdemir
Electronics 2024, 13(15), 2964; https://doi.org/10.3390/electronics13152964 - 26 Jul 2024
Cited by 2 | Viewed by 2091
Abstract
In this study, a peak current mode controller design and implementation is carried out for a high-gain integrated Z-Source DC–DC Converter. In this context, firstly, a small-signal dynamic modeling method for switching converters, based on volt–charge balance methodology, has been proposed and then [...] Read more.
In this study, a peak current mode controller design and implementation is carried out for a high-gain integrated Z-Source DC–DC Converter. In this context, firstly, a small-signal dynamic modeling method for switching converters, based on volt–charge balance methodology, has been proposed and then applied to the Z-Source converter. With the proposed method, the modeling procedure of the integrated complex converters with multiple operating points can be simplified. To verify the obtained model, a small-signal simulation of the converter is also performed by using the Frequency Response Estimator tool of MATLAB/Simulink. The transfer function from the control current to the output was then obtained from the developed converter model to design the current mode controller. Then, a PI (proportional–integral) controller was designed according to the obtained transfer function, and a simulation study was performed with PLECS. Finally, an experimental study was carried out and compared with the simulation study. The results of the simulation and experimental studies show that the designed control method maintains the output voltage at desired levels regardless of the changes in load conditions and input voltage, successfully. Full article
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25 pages, 6230 KiB  
Article
Improved Carrier-Based Modulation for the Single-Phase T-Type qZ Source Inverter
by Vitor Fernão Pires, Armando Cordeiro, Daniel Foito, Carlos Roncero-Clemente, Enrique Romero-Cadaval and José Fernando Silva
Electronics 2024, 13(6), 1113; https://doi.org/10.3390/electronics13061113 - 18 Mar 2024
Cited by 2 | Viewed by 1396
Abstract
The Quasi-Impedance-Source Inverter (Quasi-Z inverter) is an interesting DC-AC converter topology that can be used in applications such as fuel cells and photovoltaic generators. This topology allows for both boost capability and DC-side continuous input current. Another very interesting feature is its reliability, [...] Read more.
The Quasi-Impedance-Source Inverter (Quasi-Z inverter) is an interesting DC-AC converter topology that can be used in applications such as fuel cells and photovoltaic generators. This topology allows for both boost capability and DC-side continuous input current. Another very interesting feature is its reliability, as it limits the current when two switches on one leg are conducting simultaneously. This is due to an extra conduction state, specifically the shoot-through state. However, the shoot-through state also causes a loss of performance, increasing electromagnetic interference and harmonic distortion. To address these issues, this work proposes a modified carrier-based control method for the T-Type single-phase quasi-Z inverter. The modified carrier-based method introduces the use of two additional states to replace the standard shoot-through state. The additional states are called the upper shoot-through and the lower shoot-through. An approach to minimize the number of switches that change state during transitions will also be considered to reduce switching losses, improving the converter efficiency. The proposed modified carrier-based control strategy will be tested using computer simulations and laboratory experiments. From the obtained results, the theoretical considerations are confirmed. In fact, through the presented results, it is possible to understand important improvements that can be obtained in the THD of the output voltage and load current. In addition, it is also possible to verify that the modified carrier method also reduces the input current ripple. Full article
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14 pages, 2956 KiB  
Article
Effect of Aeration and External Carbon Source on Nitrogen Removal and Distribution Patterns of Related-Microorganisms in Horizontal Subsurface Flow Constructed Wetlands
by Hao Zhang, Rongxin Li, Yue Shi and Fuxia Pan
Water 2024, 16(5), 632; https://doi.org/10.3390/w16050632 - 21 Feb 2024
Cited by 4 | Viewed by 1912
Abstract
Nitrogen pollution of surface water is still a critical issue worldwide. In this study, a total of four treatments were conducted in horizontal subsurface flow constructed wetlands (HSSFCWs) to explore the removal rate of nitrogen in the carbon-deficient wastewater, including combination of aeration [...] Read more.
Nitrogen pollution of surface water is still a critical issue worldwide. In this study, a total of four treatments were conducted in horizontal subsurface flow constructed wetlands (HSSFCWs) to explore the removal rate of nitrogen in the carbon-deficient wastewater, including combination of aeration and external carbon source (CW_CA), external carbon source (CW_C), aeration (CW_A), and control group without aeration and carbon source (CW_CK). Results showed that the removal rates of total nitrogen (TN) in the enhanced treatments were increased compared with CW_CK. The highest removal rates of COD (66.56%), NH4+-N (73.51%), NO3-N (79.31%), and TN (76.19%) were observed in the CW_CA treatment. The bacterial community structure at the fore and rear ends of HSSFCWs was simultaneously changed in the CW_CA and CW_C treatments, respectively. The highest richness index at both the fore and rear ends of HSSFCWs was found in the CW_CA treatment. The richness and diversity indices of CW_C declined at the fore ends of HSSFCWs, but increased at the rear ends of HSSFCWs. Furthermore, the functional bacteria and genes significantly changed among different treatments. At the fore ends of HSSFCWs, the highest relative abundance of nitrifiers and absolute abundance of amoA and nxrA were obtained in CW_A, and the highest relative abundance of denitrifying bacteria and absolute abundance of nirS, nirK, nosZ were found in CW_C. However, at the rear ends of HSSFCWs, the highest relative abundance of nitrifiers and denitrifying bacteria as well as the absolute abundance of related genes were also observed in the CW_CA treatment. Overall, CW_CA improved the nitrogen removal rate by increasing the abundance of nitrogen-converting functional microbes and the genes associated with nitrification and denitrification. Full article
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16 pages, 6518 KiB  
Article
Hybrid Z-Source Circuit Breaker with Thomson Coil for MVDC
by Hyun-Seung Lee, Hyung-Wook Kang, Jae-Ho Rhee and Kun-A Lee
Energies 2024, 17(1), 69; https://doi.org/10.3390/en17010069 - 21 Dec 2023
Cited by 3 | Viewed by 1660
Abstract
Hybrid circuit breakers are the most promising circuit breakers among DC circuit breakers. Conventional hybrid circuit breakers complete fault current isolation by converting current to IGBT when fault current occurs. However, in this case, the fault current continues to increase, so the IGBT [...] Read more.
Hybrid circuit breakers are the most promising circuit breakers among DC circuit breakers. Conventional hybrid circuit breakers complete fault current isolation by converting current to IGBT when fault current occurs. However, in this case, the fault current continues to increase, so the IGBT must be large enough to withstand this current. In addition, in the case of a method of detecting and operating a fault, a delay time of up to hundreds of microseconds occurs, and in a hybrid circuit breaker, this delay time is a very large value. To solve this problem, this paper proposes a hybrid Z-source circuit breaker that operates without delay for low-impedance faults. The proposed breaker is designed to reduce stress on IGBTs and mechanical switches by generating a current zero crossing, as well as to enable the breaker to trip quickly in high-risk cases such as low-impedance fault circuits. Due to the limited environment of the laboratory, we performed 600 V fault isolation experiments. As a result of the experiment, it was confirmed that the proposed circuit breaker successfully isolated the fault within 1.6 ms. The current limiting feature of the Z-source appears to reduce stress on the IGBTs and MOVs used, and it allows for faster fault isolation. Full article
(This article belongs to the Section F: Electrical Engineering)
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22 pages, 14913 KiB  
Article
Experimentation of Multi-Input Single-Output Z-Source Isolated DC–DC Converter-Fed Grid-Connected Inverter with Sliding Mode Controller
by Kanagaraj N., Ramasamy M., Vijayakumar M. and Obaid Aldosari
Sustainability 2023, 15(24), 16875; https://doi.org/10.3390/su152416875 - 15 Dec 2023
Cited by 3 | Viewed by 1493
Abstract
Converting devices are quickly becoming the most important part of renewable energy-producing systems that are linked to the grid. Applications that are linked to the grid are the most common place to find usage for two-port power converters that are built using single-input [...] Read more.
Converting devices are quickly becoming the most important part of renewable energy-producing systems that are linked to the grid. Applications that are linked to the grid are the most common place to find usage for two-port power converters that are built using single-input and single-output (SISO) ports. The incorporation of SISO power converters into the grid-connected hybrid system results in an increase in both its size and its cost. Multiple power sources may be connected to a single DC bus by means of hybrid power systems, which make use of multi-input power converters. To combine the hybrid wind and PV system with a common DC bus, this study suggests an isolated multi-input single-output (IMISO) Z-Source converter. It has been determined that the suggested system performs well in spite of dynamic load fluctuations and shifting input voltage circumstances. The sliding mode controller (SMC) has also been used to control a single-phase five-level (SPFL) inverter. The purpose of developing the laboratory prototype model was to verify the proposed IMISO Z-source converter-fed single-phase five-level (SPFL) inverter in the context of the circumstance that is being investigated. Full article
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18 pages, 8442 KiB  
Article
Virtual Inertia Implemented by Quasi-Z-Source Power Converter for Distributed Power System
by Yitao Liu, Hongle Chen and Runqiu Fang
Energies 2023, 16(18), 6667; https://doi.org/10.3390/en16186667 - 17 Sep 2023
Cited by 4 | Viewed by 1502
Abstract
This paper proposes a novel virtual inertia control strategy for distributed power systems with high penetration of renewable energy sources. The strategy uses a quasi-Z-source power converter to emulate the inertia response of a synchronous generator by regulating the DC-link capacitor voltage in [...] Read more.
This paper proposes a novel virtual inertia control strategy for distributed power systems with high penetration of renewable energy sources. The strategy uses a quasi-Z-source power converter to emulate the inertia response of a synchronous generator by regulating the DC-link capacitor voltage in proportion to the grid frequency deviation. This paper analyzes the effect of inertia on the frequency regulation of a single-area power system and derives the parameter design method and limitations of the virtual inertia. The paper also introduces the working principle and modulation technique of the quasi-Z-source power converter and presents the virtual inertia control scheme based on a voltage-frequency controller. The paper verifies the feasibility and effectiveness of the proposed strategy through MATLAB/Simulink simulations and dSPACE semi-physical experiments. The results show that the proposed strategy can reduce the frequency deviation and rate of change of frequency (RoCoF) by 20% and 50%, respectively, under load disturbances. The paper demonstrates that the quasi-Z-source power converter can provide flexible and adjustable virtual inertia for distributed power systems without additional energy storage devices. Full article
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13 pages, 3194 KiB  
Article
Alternative Fiber-Based Paperboard Adhesion Evaluation with T- and Y-Peel Testing
by Urška Kavčič, Gregor Lavrič and Igor Karlovits
Appl. Sci. 2023, 13(17), 9779; https://doi.org/10.3390/app13179779 - 29 Aug 2023
Cited by 1 | Viewed by 1968
Abstract
Due to increased pressure on the availability of wood biomass in the EU and the regulatory attempts to lower CO2 values, where wood-based biomass plays a crucial role in carbon sequestration, the use of cellulose derived from alternative sources is gaining increased [...] Read more.
Due to increased pressure on the availability of wood biomass in the EU and the regulatory attempts to lower CO2 values, where wood-based biomass plays a crucial role in carbon sequestration, the use of cellulose derived from alternative sources is gaining increased interest in the pulp and paper industry as well as in other industries. The processing properties of alternative fiber-based packaging need to be checked in current processing operations with other types of materials and recycling workflows. For example, in the production of folding boxes, after printing other converting properties such as glueability are also of great importance. The adhesive absorption and bonding strength of materials are important as adhesive joints of packaging can interfere with the protective function. In the presented research, three different paperboards produced on a pilot scale from alternative raw material sources were tested. Two paperboards were produced from the alien invasive plants Japanese knotweed and black locust, and one from residual sawdust. The basic paperboard properties were tested regarding paperboard porosity, roughness, z-directional tensile strength, and dynamical behavior regarding liquid interaction (contact angle and liquid penetration dynamic), as water-based adhesives were used in the research. For adhesive joint strength testing, Y- and T-peel adhesion testing was performed on the joint paperboard samples, as still there is no fully standardized method for the evaluation of such fiber-based material properties. The results indicate differences in the penetration dynamics of liquids. This parameter had the highest influence on the peel adhesion strength, while porosity, roughness, and dynamic contact angle were not so significant. Regarding the two adhesive joint tests, the differences in separate materials regarding peel adhesion curves show similar results. However, the Y-peel maximum force values are higher due to the testing setup (in comparison to the T-peel test). The paperboards made from invasive plants showed adhesive joint failures which are more suitable for tamper-proof packaging due to their low surface strength and crack propagation into the fiber structure. Full article
(This article belongs to the Section Materials Science and Engineering)
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11 pages, 3747 KiB  
Article
Enhancing the Activity of Cu-MOR by Water for Oxidation of Methane to Methanol
by Xi’an Guan, Yehong Wang, Xiumei Liu, Hong Du, Xinwen Guo and Zongchao Zhang
Catalysts 2023, 13(7), 1066; https://doi.org/10.3390/catal13071066 - 3 Jul 2023
Cited by 3 | Viewed by 2048
Abstract
As clean energy, methane has huge reserves and great development potential in the future. Copper zeolites are efficient in the oxidation of methane to methanol. Water has been confirmed as a source of oxygen to regenerate the copper-zeolite active sites to enable selective [...] Read more.
As clean energy, methane has huge reserves and great development potential in the future. Copper zeolites are efficient in the oxidation of methane to methanol. Water has been confirmed as a source of oxygen to regenerate the copper-zeolite active sites to enable selective anaerobic oxidation of methane to methanol. In this work, we report that the methanol yield increased from 36 μmol/g (Cu-MOR1) to 92 μmol/g (Cu-MOR1-water) as a result of water enhancing the activity of copper ion-exchange mordenite catalyst. We show for the first time that water could convert inactive copper species into active copper species during catalyst activation. A combination of the XPS, FTIR, and NMR results indicates that water dissociates and then converts ZCuIIZ into ZCuII(OH) (where Z indicates framework O (Ofw) bonded to one isolated Al in a framework T-site, i.e., 1Al) and simultaneously produces a Brönsted acid site during catalyst activation. This finding can be used to tune the state of copper species and design highly active copper-zeolite catalysts for methane oxidation to methanol. Full article
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