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Keywords = Triassic dolomites

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19 pages, 12183 KiB  
Article
A Study on the Sedimentary Environment and Facies Model of Triassic Carbonate Rocks in the Mangeshlak Basin
by Fanyang Meng, Kaixun Zhang, Zhiping He, Miao Miao and Feng Wang
Appl. Sci. 2025, 15(14), 7788; https://doi.org/10.3390/app15147788 - 11 Jul 2025
Viewed by 268
Abstract
Based on drilling, core and seismic data, combined with the regional tectonic sedimentary evolution background, the sedimentary environment of the Triassic carbonate rocks in the Mangeshlak Basin was studied. A sedimentary facies model of this set of carbonate rocks was established. Research has [...] Read more.
Based on drilling, core and seismic data, combined with the regional tectonic sedimentary evolution background, the sedimentary environment of the Triassic carbonate rocks in the Mangeshlak Basin was studied. A sedimentary facies model of this set of carbonate rocks was established. Research has shown that the Mangeshlak Basin underwent a complete large-scale marine transgression–regression sedimentary evolution process during the Triassic. During the early to middle Triassic, seawater gradually invaded the northwest region of the basin from northwest to southeast and gradually regressed in the late Middle Triassic. In the lower part of the Triassic carbonate rocks, the primary components are developed granular limestone or dolomite with oolitic structures, interspersed with a small amount of thin mudstone, which is a good reservoir; the upper part of the Triassic is mainly composed of sedimentary mudstone and mudstone, which can form good sealings. The hill-shaped reflections of the platform edge facies, along with the high-frequency, strong-amplitude, and moderately continuous reflections within the restricted platform interior, are clearly visible on the seismic profile. These features are consistent with the sedimentary environment and lithofacies characteristics revealed by drilling data along the profile. Drilling and seismic data revealed that the sedimentary environment of the early and middle Triassic in the basin is mainly composed of shallow water platform edges and restricted platforms, as well as carbonate rock slopes and open non-marine shelves in deep water areas. A sedimentary facies model of the Triassic carbonate rock segment in the basin was established, comprising restricted platforms, platform edges, carbonate rock slopes, and non-marine shelves. Unlike the modified Wilson marginal carbonate rock platform model, the carbonate rock platform edge in the Mangeshlak Basin does not develop reef facies. Instead, it is mainly composed of oolitic beach (dam) sediments, making it the most favorable sedimentary facies zone for the Triassic reservoir development in the basin. Full article
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32 pages, 68153 KiB  
Review
Barite Deposits of Türkiye: A Review
by Zeynep Cansu, Hüseyin Öztürk and Nurullah Hanilçi
Minerals 2025, 15(7), 692; https://doi.org/10.3390/min15070692 - 28 Jun 2025
Viewed by 596
Abstract
Türkiye hosts a wide variety of barite deposits that can be broadly classified into two major groups based on their tectonic settings: magmatism-associated and passive margin-hosted deposits. The magmatism-associated deposits include Kızılcaören (F + Ba + REE + Th, Beylikova–Eskişehir), Kirazören (Bulancak–Giresun), and [...] Read more.
Türkiye hosts a wide variety of barite deposits that can be broadly classified into two major groups based on their tectonic settings: magmatism-associated and passive margin-hosted deposits. The magmatism-associated deposits include Kızılcaören (F + Ba + REE + Th, Beylikova–Eskişehir), Kirazören (Bulancak–Giresun), and Karacaören (Mesudiye–Ordu). The Kızılcaören deposit formed in relation to the emplacement of a late Oligocene carbonatitic sill, while the Kirazören and Karacaören deposits are associated with the Cretaceous Pontide magmatic arc. Passive margin-hosted deposits occur within various Paleozoic sedimentary lithologies—such as metasandstone, shale, schist, and limestone—and are found in the Taurides and the Arabian Platform. These deposits occur as either concordant or discordant veins. This barite belt extends from Şarkikaraağaç (Isparta), through Hüyük (Konya) and Alanya (Antalya), to Silifke (Mersin), Tordere (Adana), Önsen, Şekeroba (Kahramanmaraş), and Hasköy (Muş). The Paleozoic deposits represent the major barite resources of Türkiye, with an annual production of approximately 300,000 metric tons. Smaller deposits around Gazipaşa (Antalya) contain minor Pb-Zn sulfides. Mesozoic barite deposits are hosted in Triassic dolomites and are associated with Pb-Zn mineralization in the Hakkari region of the Arabian Platform. Pb and Sr isotope data indicate that the barium in these deposits was derived from ancient continental crust. The isotopic compositions of both concordant (stratabound) and discordant (vein-type) barites are generally homogeneous. In northwestern Türkiye, the Sr isotope compositions of the barite deposits align well with those of the Oligocene carbonatite host complex. The 87Sr/86Sr isotope ratio of the Kızılcaören deposit (0.706‰) is the least radiogenic among Turkish barite deposits, suggesting a mantle contribution. The Kirazören deposit in the Pontide magmatic arc follows with a slightly higher ratio (0.707‰). Triassic barites from the Hakkari region yield 87Sr/86Sr values around 0.709‰, slightly more radiogenic than coeval seawater. Paleozoic barite deposits show the most radiogenic 87Sr/86Sr values, including Aydıncık (0.718‰), Şarkikaraağaç (0.714‰), Hasköy (0.713‰), Kahramanmaraş (0.712‰), Tordere, and Hüyük (both 0.711‰), consistent with their respective host rocks. The elevated radiogenic Pb and Sr isotope values in the passive margin-hosted deposits suggest that the barium originated from deeper, barium-enriched rocks, whereas stable sulfur isotope data point to a marine sulfur source. Moreover, Sr and S isotopic signatures indicate that the Paleozoic sediment-hosted deposits formed in association with cold seeps on the seafloor, resembling modern analogs. In contrast, the Mesozoic Karakaya deposit (Hakkari) represents a typical vent-proximal, sediment-hosted deposit with no magmatic signature. Full article
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24 pages, 70177 KiB  
Article
Geology, Structure, Geochemistry, and Origin of Iron Oxide Deposits in Dehbid, Southwest Iran
by Abdorrahman Rajabi, Reza Nozaem, Sara Momenipour, Shojaedin Niroomand, Shahrokh Rajabpour, Somaye Rezaei, Pura Alfonso, Carles Canet, Ahmad Kazemi Mehrnia, Pouria Mahmoodi, Amir Mahdavi, Mansoor Kazemirad, Omid Laghari Firouzjaei and Mohammad Amini
Minerals 2025, 15(6), 590; https://doi.org/10.3390/min15060590 - 30 May 2025
Viewed by 925
Abstract
The Dehbid region, located in the southern part of the Sanandaj–Sirjan Zone (SSZ), is a significant iron oxide mining district with over 20 iron oxide deposits (IODs) and reserves of up to 50 million tons of iron oxide ores. The region features a [...] Read more.
The Dehbid region, located in the southern part of the Sanandaj–Sirjan Zone (SSZ), is a significant iron oxide mining district with over 20 iron oxide deposits (IODs) and reserves of up to 50 million tons of iron oxide ores. The region features a NW–SE oriented ductile shear zone, parallel to the Zagros thrust zone, experienced significant deformation. Detailed structural studies indicate that the iron mineralization is primarily stratiform to stratabound and hosted in late Triassic to early Jurassic silicified dolomites and schists. These ore deposits consist of lenticular iron oxide orebodies and exhibit various structures and textures, including banded, laminated, folded, disseminated, and massive forms of magnetite and hematite. The Fe2O3 content in the mineralized layers varies from 30 to 91 wt%, whereas MnO has an average of 3.9 wt%. The trace elements are generally low, except for elevated concentrations of Cu (up to 4350 ppm) and Zn (up to 3270 ppm). Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) analysis of magnetite reveals high concentrations of Mg, Al, Si, Mn, Ti, Cu, and Zn, with significant depletion of elements such as Ga, Ge, As, and Nb. This study refutes the hypothesis of vein-like or hydrothermal genesis, providing evidence for a sedimentary origin based on the trace element geochemistry of magnetite and LA-ICP-MS geochemical data. The Dehbid banded iron ores (BIOs) are thought to have formed under geodynamic conditions similar to those of BIOs in back-arc tectonic settings. The combination of anoxic conditions, submarine hydrothermal iron fluxes, and redox fluctuations is essential for the formation of these deposits, suggesting that similar iron–manganese deposits can form during the Phanerozoic under specific geodynamic and oceanographic conditions, particularly in tectonically active back-arc environments. Full article
(This article belongs to the Special Issue Mineralogy and Geochemistry of Polymetallic Ore Deposits)
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22 pages, 4345 KiB  
Article
Impact of Diverse Calcite Vein Patterns on Dissolution Characteristics of Triassic Limestone in Three Gorges Reservoir Area
by Jingyun Guo, Shouding Li, Jianming He, Zhaobin Zhang and Xiao Li
Water 2025, 17(10), 1550; https://doi.org/10.3390/w17101550 - 21 May 2025
Viewed by 421
Abstract
Carbonate rock slopes in reservoir environments are increasingly exposed to dissolution-induced deterioration due to water level fluctuations. However, the influence of internal structures—particularly calcite veins—on dissolution behavior remains inadequately understood. The acid-induced dissolution of limestone by a sulfuric acid solution leads to the [...] Read more.
Carbonate rock slopes in reservoir environments are increasingly exposed to dissolution-induced deterioration due to water level fluctuations. However, the influence of internal structures—particularly calcite veins—on dissolution behavior remains inadequately understood. The acid-induced dissolution of limestone by a sulfuric acid solution leads to the removal of soluble minerals and changes to the rock structure. Natural variation in rock structures—particularly in the presence, density, and morphology of calcite veins—can significantly affect the dissolution process and its outcomes. In this study, we obtained three types of Triassic limestone from the same host rock but with varying vein structures from the Three Gorges Reservoir area. Cylindrical rock specimens were prepared to investigate the acid-induced dissolution behavior of limestone in a sulfuric acid solution. We identified and analyzed the macrostructures on the rock specimens before and after the interaction. Additionally, SEM was employed to observe the microstructures of the specimens before and after the acid-induced dissolution, and fractal dimension analysis was conducted on the SEM images to quantify surface complexity. Furthermore, we used a focused ion beam–scanning electron microscope (FIB-SEM) with an automatic mineral identification and characterization system, as well as mineral roundness calculation, for mineral identification and analysis. Based on the experiments and analyses, we determined the following: The contact surfaces between the host rock and the calcite veins increase the dissolution areas between the limestone and the sulfuric acid solution, intensifying the dissolution reactions, enhancing the connectivity of the original microstructural planes, and generating new, highly extended dissolution fissures. The calcite veins facilitate the entry of sulfuric acid solution into the limestone, intensifying the dissolution of the edges and corners of dolomite and resulting in the gradual rounding of dolomite shapes. Quantitatively, the limestone with dense, fine calcite veins exhibited the most severe dissolution, with water absorption rates nearly twice as high as the non-veined samples (0.13% vs. 0.07%), a 2.2% reduction in fractal dimension, and a 19.53% increase in dolomite roundness with the 1 ≤ R ≤ 3 interval, indicating significantly enhanced surface complexity and mineral reshaping. In summary, the presence of more calcite veins, regardless of their width, leads to more severe rock dissolution. Full article
(This article belongs to the Special Issue Water–Rock Interaction)
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43 pages, 41722 KiB  
Article
Massive Dolomitization of Interior and Slope to Basin-Margin Facies of the Triassic Yangtze Platform Through Superposed Earth-Surface and Burial Mechanisms, Nanpanjiang Basin, South China
by Nathaniel S. Ledbetter Ferrill, Xiaowei Li, Josephine Tesauro, Madison Sears, George M. Bradley, Arianna Hilbert, Eryn Carney, Justice Saxby, Neda Mobasher, Brian M. Kelley, E. Troy Rasbury, Kathleen M. Wooton, Jason D. Kirk, John A. Luczaj and Daniel J. Lehrmann
Minerals 2025, 15(3), 324; https://doi.org/10.3390/min15030324 - 19 Mar 2025
Viewed by 825
Abstract
Triassic strata of the Yangtze Platform at Guanling contain a dolomitized interior, undolomitized margin, and partially dolomitized slope to basin margin. Dolomitized microbial laminate caps of peritidal cycles and massive dolomite with associated evaporite nodules and solution collapse breccias are consistent with penecontemporaneous [...] Read more.
Triassic strata of the Yangtze Platform at Guanling contain a dolomitized interior, undolomitized margin, and partially dolomitized slope to basin margin. Dolomitized microbial laminate caps of peritidal cycles and massive dolomite with associated evaporite nodules and solution collapse breccias are consistent with penecontemporaneous tidal flat and evaporative dolomitization in the platform interior. The preferential dolomitization of the slope and basin margin (up to 7 km basinward of the margin), dolomitization along fractures, and selective dolomitization of the matrix in slope breccia that diminishes toward the margin are interpreted to have resulted from the incursion of basin-derived fluids during burial. Integrated analysis of fluid-inclusion microthermometry, oxygen, carbon, and strontium isotopes, trace element geochemistry, U-Pb age dates of carbonate phases, and burial history support the recrystallization of interior dolomite and slope to basin-margin dolomitization by brines at high temperatures during burial. The Yangtze Platform at Guanling provides an excellent example of widespread stratiform dolomitization resulting from the superposition of multiple mechanisms, including penecontemporaneous dolomitization by evaporative seawater brines, high-temperature dolomitization of the slope and basin margin by basinal brines, and high-temperature recrystallization of dolomite by brines during burial. This study provides an example that suggests that widespread stratiform dolomite may result from superposed Earth surface and high-temperature burial dolomitization processes and provides a valuable analog for other carbonate platforms in which the margin remains undolomitized while the interior and basin margin are dolomitized. Similar mechanisms likely contributed to the widespread dolomitization of platforms across the Nanpanjiang and Sichuan basins. Full article
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33 pages, 15434 KiB  
Article
Persisting Rock-Buffered Conditions in the Upper Triassic and Lower Jurassic Dolomites of the Central Apennines (Italy) During Diagenesis, Burial, and Thrusting
by Alessio Lucca, Silvia Mittempergher, Fabrizio Balsamo, Anna Cipriani, Antonino Cilona and Fabrizio Storti
Geosciences 2025, 15(2), 35; https://doi.org/10.3390/geosciences15020035 - 22 Jan 2025
Cited by 1 | Viewed by 1409
Abstract
Basin-scale dolomitization of carbonate sequences occurs over long time spans and results from diagenesis, burial, and tectonically driven fluid fluxes. Depicting the different geological processes producing dolomitized carbonate sequences requires combining accurate field, petrographic, and geochemical analyses. Here, we investigate the dolomitization processes [...] Read more.
Basin-scale dolomitization of carbonate sequences occurs over long time spans and results from diagenesis, burial, and tectonically driven fluid fluxes. Depicting the different geological processes producing dolomitized carbonate sequences requires combining accurate field, petrographic, and geochemical analyses. Here, we investigate the dolomitization processes in carbonates of the Norian to Toarcian age exposed in the Gran Sasso Massif, Central Apennines of Italy, by integrating field observations, standard and CL petrography, carbon, oxygen, strontium and clumped isotopes, minor elements, and X-ray diffractometry. The carbonates show pervasive replacive dolomitization, and dolomite cements are observed in bed-parallel and thrust-related veins. Replacive dolomites show incomplete replacement from modified seawater in oxidizing conditions, with minimum temperatures of 40–65 °C and a 87Sr/86Sr lower than coeval seawater. The first dolomitization event started at shallow burial in the Late Triassic–Early Jurassic and was later affected by replacement at intermediate burial depths. Bedding-parallel dolomite veins crystallized due to fluid overpressures at deep burial depths in a rock-buffered system without variations in geochemistry. Fault-related dolomites cemented thrust-related fractures during compressional deformation in the Messinian–Early Pliocene from seawater modified by mixing with external fluids. Precipitation temperatures of replacive, bedding-parallel, and fault-related dolomite veins are similar. Despite the dolomite types being characterized by different textures and petrographic features, rock-buffered conditions resulted in insignificant variations of their geochemical properties. Full article
(This article belongs to the Section Sedimentology, Stratigraphy and Palaeontology)
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21 pages, 17427 KiB  
Article
Thermal History and Hydrocarbon Accumulation Stages in Majiagou Formation of Ordovician in the East-Central Ordos Basin
by Hua Tao, Junping Cui, Fanfan Zhao, Zhanli Ren, Kai Qi, Hao Liu and Shihao Su
Energies 2024, 17(17), 4435; https://doi.org/10.3390/en17174435 - 4 Sep 2024
Cited by 2 | Viewed by 1143
Abstract
The marine carbonates in the Ordovician Majiagou Formation in the Ordos Basin have significant exploration potential. Research has focused on their thermal history and hydrocarbon accumulation stages, as these are essential for guiding the exploration and development of hydrocarbons. In this paper, we [...] Read more.
The marine carbonates in the Ordovician Majiagou Formation in the Ordos Basin have significant exploration potential. Research has focused on their thermal history and hydrocarbon accumulation stages, as these are essential for guiding the exploration and development of hydrocarbons. In this paper, we study the thermal evolution history of the carbonate reservoirs of the Ordovician Majiagou Formation in the east-central Ordos Basin. Furthermore, petrographic and homogenization temperature studies of fluid inclusions were carried out to further reveal the hydrocarbon accumulation stages. The results demonstrate that the degree of thermal evolution of the Ordovician carbonate reservoirs is predominantly influenced by the deep thermal structure, exhibiting a trend of high to low values from south to north in the central region of the basin. The Fuxian area is located in the center of the Early Cretaceous thermal anomalies, with the maturity degree of the organic matter ranging from 1 to 3.2%, with a maximum value of 3.2%. The present geothermal gradient of the Ordovician Formation exhibits the characteristics of east–high and west–low, with an average of 28.6 °C/km. The average paleo-geotemperature gradient is 54.2 °C/km, the paleoheat flux is 55 mW/m2, and the maximum paleo-geotemperature reaches up to 270 °C. The thermal history recovery indicates that the Ordovician in the central part of the basin underwent three thermal evolution stages: (i) a slow warming stage before the Late Permian; (ii) a rapid warming stage from the end of the Late Permian to the end of the Early Cretaceous; (iii) a cooling stage after the Early Cretaceous, with the hydrocarbon production of hydrocarbon source rocks weakening. In the central part of the basin, the carbonate rock strata of the Majiagou Formation mainly developed asphalt inclusions, natural gas inclusions, and aqueous inclusions. The fluid inclusions can be classified into two stages. The early-stage fluid inclusions are mainly present in dissolution holes. The homogenization temperature is 110–130 °C; this coincides with the hydrocarbon charging period of 210–165 Ma, which corresponds to the end of the Triassic to the end of the Middle Jurassic. The late-stage fluid inclusions are in the dolomite vein or late calcite that filled the gypsum-model pores. The homogenization temperature is 160–170 °C; this coincides with the hydrocarbon charging period of 123–97 Ma, which corresponds to the late Early Cretaceous. Both hydrocarbon charging periods are in the rapid stratigraphic warming stage. Full article
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25 pages, 6625 KiB  
Article
Fluid Inclusion, Rare Earth Element Geochemistry, and Isotopic (O and S) Characteristics of the Ardakan Barite Deposit, Yazd Province, Iran
by Ebrahim Ansari, Farhad Ehya, Ghodratollah Rostami Paydar and Sara Maleki Kheymehsari
Minerals 2024, 14(8), 739; https://doi.org/10.3390/min14080739 - 24 Jul 2024
Viewed by 1692
Abstract
The stratabound barite mineralization occurs in the Ardakan deposit as patches and veins in the dolomites and limestones of the Middle Triassic Shotori Formation. Rare-earth element (REE) geochemistry, O and S isotopes, and fluid inclusion data were used to identify the mode of [...] Read more.
The stratabound barite mineralization occurs in the Ardakan deposit as patches and veins in the dolomites and limestones of the Middle Triassic Shotori Formation. Rare-earth element (REE) geochemistry, O and S isotopes, and fluid inclusion data were used to identify the mode of barite formation. Barite is associated with subordinate fluorite and quartz and, to a lesser extent, with sphalerite, malachite, chrysocolla, and iron and manganese oxide-hydroxides. Barite contains a very low ∑REE concentration (14.80–19.59 ppm) and is enriched in light rare-earth elements (LREEs) relative to heavy rare-earth elements (HREEs). The low ∑REE content and the Ce/La ratio (4.0–6.5) indicate a hydrothermal (terrestrial) origin of the barite. Similar to barite, the ∑REE content in fluorite is low (0.14–6.52 ppm) and suggests a sedimentary setting. The Tb/Ca versus Tb/La diagram also indicates a hydrothermal origin of fluorite. The δ34S values in the barite (+27.9 to +32.4‰) indicate that the sulfur most likely originates from evaporites and/or connate waters from the Late Precambrian to the Lower Cambrian. The δ18O values (+15.9 to +18.1‰) in the barite show that the oxygen originated either from Late Precambrian–Lower Cambrian evaporites or from basinal brines with slightly higher δ18O values than the evaporites. The salinity and homogenization temperature ranges of the aqueous fluid inclusions in barite, fluorite, and quartz (0.88–16.89 wt% NaCl equivalent and 90–270 °C, respectively) reveal that the mineralizing fluids were formed from basinal brines with the participation of heated meteoric water. From this, it is concluded that the Ardakan barite deposit was formed by the meeting of heated, ascending sulfate-bearing meteoric water and cooler, Ba-bearing connate water trapped in the overlying Middle Triassic dolomites and limestones. The Ardakan deposit belongs to the structure-related class and the unconformity-related subclass of barite deposits. Full article
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23 pages, 7739 KiB  
Article
Geochemical and Mineralogical Characteristics of Triassic Dolomites from Upper Silesia, Poland
by Katarzyna J. Stanienda-Pilecki and Rafał Jendruś
Minerals 2024, 14(4), 371; https://doi.org/10.3390/min14040371 - 31 Mar 2024
Viewed by 1470
Abstract
A detailed description of carbonate minerals of Triassic dolomites with different magnesium contents is presented in this article. Tests were carried out to determine geochemical and mineralogical characteristics. The following carbonate phases were identified: low-Mg calcite, high-Mg calcite, proto-dolomite, ordered dolomite, and huntite. [...] Read more.
A detailed description of carbonate minerals of Triassic dolomites with different magnesium contents is presented in this article. Tests were carried out to determine geochemical and mineralogical characteristics. The following carbonate phases were identified: low-Mg calcite, high-Mg calcite, proto-dolomite, ordered dolomite, and huntite. The methods used were microscopic description, X-ray diffraction (XRD), X-ray fluorescence (XRF), and electron probe microanalysis (EMPA). Samples were collected from the Tarnowice Formation, which is the lower part of the profile of Upper Muschelkalk. On the basis of the obtained results, the chemical formulae of carbonate phases were calculated. The results indicate that Mg in low-Mg calcite ranges from 0.6 to 1.2% and in high-Mg calcite from 7.47 to 10.41%. In protodolomite, it ranges from 10.96 to 11.78%. In ordered dolomite, the Mg content is 13.18% on a stoichiometric basis. Due to the reduced Mg content in the identified huntite (in the range of 13.62% to 17.76), this carbonate phase is considered de-huntite. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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18 pages, 20234 KiB  
Article
Fractal Characterization of Multiscale Fracture Network Distribution in Dolomites: Outcrop Analogue of Subsurface Reservoirs
by Ivica Pavičić, Željko Duić, Anja Vrbaški and Ivan Dragičević
Fractal Fract. 2023, 7(9), 676; https://doi.org/10.3390/fractalfract7090676 - 7 Sep 2023
Cited by 6 | Viewed by 2321
Abstract
Fractured aquifers, especially dolomites, are important hydrocarbon reservoirs and sources of thermal and groundwater in many parts of the world, especially in the Alpine-Dinaric-Carpathian region. The most dominant porosity type is fracture porosity, which acts as the preferential fluid pathway in the subsurface, [...] Read more.
Fractured aquifers, especially dolomites, are important hydrocarbon reservoirs and sources of thermal and groundwater in many parts of the world, especially in the Alpine-Dinaric-Carpathian region. The most dominant porosity type is fracture porosity, which acts as the preferential fluid pathway in the subsurface, thus strongly controlling fluid flow. Outcrops provide valuable information for the characterization of fracture networks. Dolomite rock properties and structural and diagenetic processes result in fractured systems that can be considered fractals. The fracture network was analyzed on 14 vertical outcrops in 35 digitized photographs. The values of the fractal dimensions varied slightly by the software and method used, but the trends were consistent, which confirms that all methods are valid. Small values of fractal dimension indicate the dominance of a few small or large fractures, and high values of fractal dimension result from a combination of large numbers of small fractures accompanied by a few large fractures. The mean value of the fractal dimension for analyzed fracture networks was 1.648. The results indicate that the fracture network of the Upper Triassic dolomites can be approximated by fractal distribution and can be considered a natural fractal, and values can be extrapolated to higher and lower scales (1D and 3D). Full article
(This article belongs to the Special Issue Fractal Analysis and Its Applications in Geophysical Science)
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23 pages, 9909 KiB  
Article
Phosphate Petrochronology of the Belcina REE Mineralization (Ditrău Alkaline Massif, Romania)
by Urs Klötzli, Jolanta Burda and Paul Tibuleac
Minerals 2023, 13(6), 739; https://doi.org/10.3390/min13060739 - 30 May 2023
Cited by 6 | Viewed by 2144
Abstract
A notable REE mineralization in Europe is associated with the Ditrău Alkaline Massif (DAM) in the Eastern Carpathians (Romania). It is an expression of the latest hydrothermal phase in the DAM and is found in the form of mineralized carbonate veins cross-cutting the [...] Read more.
A notable REE mineralization in Europe is associated with the Ditrău Alkaline Massif (DAM) in the Eastern Carpathians (Romania). It is an expression of the latest hydrothermal phase in the DAM and is found in the form of mineralized carbonate veins cross-cutting the complex in the NW (Jolotca region) and the SE (Belcina region) parts of the DAM. In the Belcina veins monazite-(Ce), xenotime-(Y) and apatite, together with Fe-Mg-rich carbonate, thorite, thorogummite, gedrite and plagioclase are rock-forming. Three different textural and chemical types of the monazite-(Ce) and the xenotime-(Y) document a three-stage evolution. The relative phosphate age succession (from older to younger) thereby is xnt1 > xnt2 (>)+ mnz1 + Fe2O3 + Fe-gedrite > mnz2 + Fe-dolomite (+ plagioclase) > mnz3 + xnt3 + apatite. Phosphate chemistry shows that these crystallized from hydrothermal fluids, whereby each phosphate type follows a separate evolutionary path suggesting growth from (at least) three independent and successive hydrothermal fluids. Chemistry and pathways within the DAM suggest that these hydrothermal fluids could be derived from a subsurface carbonatitic intrusion. Mnz1,2 and xnt1,2 ages are tightly clustered at 215.8 ± 0.7 Ma (Norian, Upper Triassic). The third-generation phosphate ages are younger, but are associated with large analytical uncertainties and did not deliver geologically useful ages. The mean age of ca. 216 Ma is interpreted as the timing of the Belcina REE mineralization, which together with the fluid chemistry, supports a model of the presence of a late-stage, independent carbonatitic intrusion about 10 Ma after the main igneous activity (ca. 235–225 Ma) forming the DAM, synchronous with extension-related magmatism in the region. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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22 pages, 4684 KiB  
Article
Microbialite Textures and Their Geochemical Characteristics of Middle Triassic Dolomites, Sichuan Basin, China
by Hao Wang, Ziquan Yong, Jinmin Song, Tong Lin and Yongqiang Yu
Processes 2023, 11(5), 1541; https://doi.org/10.3390/pr11051541 - 17 May 2023
Cited by 1 | Viewed by 1825
Abstract
Microbialite textures, such as microbial mats and biofilms, were observed in the Middle Triassic dolomite in the Sichuan Basin, western China, using core examination, thin section petrography, scanning electron microscopy (SEM), and geochemical analyses. The dolomite texture, consisting of fibrous and spherulitic structures, [...] Read more.
Microbialite textures, such as microbial mats and biofilms, were observed in the Middle Triassic dolomite in the Sichuan Basin, western China, using core examination, thin section petrography, scanning electron microscopy (SEM), and geochemical analyses. The dolomite texture, consisting of fibrous and spherulitic structures, is similar in morphology and size distribution to those observed in microbial culture experiments. Extracellular polymeric substances (EPS) were identified based on the occurrence of fibers forming a reticular pattern and nanometer-sized spheroids. The rare earth element (REE) and stable isotope (C, O, and Sr) compositions of the Middle Triassic dolomite were measured to determine their geochemical characteristics. Using seawater as a standard, the dolomitic microbialites (MD) exhibited significantly positive La and Eu anomalies and higher REE concentrations and (Nd/Yb)sn values than associated limestones, and these patterns are inferred to be related to initial complexation on organic ligands in the biofilm, as proposed by previous researchers. The ambient temperature during dolomite precipitation was estimated to be within the 23 °C to 50 °C range, as indicated by the δ18O values of the dolomite. This study suggests that various microbial effects can significantly affect diagenetic processes in the Middle Triassic dolomite. Full article
(This article belongs to the Special Issue Latest Advances in Petroleum Exploration and Development)
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24 pages, 13280 KiB  
Article
Sedimentological Controls on the Reservoir Characteristics of the Mid-Triassic Tredian Formation in the Salt and Trans-Indus Surghar Ranges, Pakistan: Integration of Outcrop, Petrographic, and SEM Analyses
by Kamil A. Qureshi, Mohamad Arif, Abdul Basit, Sajjad Ahmad, Hammad Tariq Janjuhah and George Kontakiotis
J. Mar. Sci. Eng. 2023, 11(5), 1019; https://doi.org/10.3390/jmse11051019 - 10 May 2023
Cited by 8 | Viewed by 3342
Abstract
The current study uses an integrated lithofacies, optical microscopy, and scanning electron microscopy (SEM) analysis to investigate the sedimentary processes, depositional architecture, and reservoir rock potential of the Tredian Formation’s (Mid-Triassic) mixed siliciclastic and carbonate succession in the Salt and Trans-Indus Ranges. The [...] Read more.
The current study uses an integrated lithofacies, optical microscopy, and scanning electron microscopy (SEM) analysis to investigate the sedimentary processes, depositional architecture, and reservoir rock potential of the Tredian Formation’s (Mid-Triassic) mixed siliciclastic and carbonate succession in the Salt and Trans-Indus Ranges. The formation has been divided litho-stratigraphically into two components: the lower Landa Member, which consists of fine-grained sandstone and shale, and the upper Khatkiara Member, which consists of coarse-grained sandstone. Based on sedimentary structures and lithology, four distinct types of lithofacies are identified. Two lithofacies representing sandstones interbedded with shale (LF1) and thick-bedded sandstone (LF2) lithofacies suggestive of fluvio-deltaic settings are among them. Another two lithofacies of thin-bedded sandstone (LF3) and dolomite (LF4) suggest a tidal flat depositional environment, correspondingly. The petrographic examination of the Tredian sandstones indicates a lithology ranging from sub-feldspathic arenite to feldspathic arenite with moderate packing. The presence of primary calcite cement, silica cement, and iron oxide/hydroxide cements were shown by the diagenetic investigation, which was supported by SEM studies. In addition, secondary cements include ferroan-dolomite, chlorite, and illite, which is linked with chemical alteration of unstable grains. The paragenetic sequence depicts the diagenetic evolution of the Tredian sandstone from early to late diagenetic phases. The reservoir quality of the LF1 and LF4 lithofacies has been destroyed by early-stage calcite cementation, but the lithofacies LF2 and LF3 have a strong reservoir potential owing to the scarcity of calcite cement, dissolution of unstable feldspar grains, and grain fracture. Full article
(This article belongs to the Special Issue Recent Advances in Sedimentology)
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15 pages, 3623 KiB  
Article
Multi-Mode Imaging of Ambient Background Noise for Karst Detection in the Limestone Area Based on Frequency-Bessel Transform
by Song Chen, Daohan Liu, Fei Cheng and Junjie Xu
Appl. Sci. 2023, 13(8), 5135; https://doi.org/10.3390/app13085135 - 20 Apr 2023
Cited by 1 | Viewed by 2010
Abstract
In response to the challenges of karst geophysical exploration in an environment with strong external interference, this paper proposes a new method, namely the frequency-Bessel transform method, for extracting multi-order dispersion curves of surface waves from background noise to characterize karst. The observation [...] Read more.
In response to the challenges of karst geophysical exploration in an environment with strong external interference, this paper proposes a new method, namely the frequency-Bessel transform method, for extracting multi-order dispersion curves of surface waves from background noise to characterize karst. The observation noise data of the Wuhan karst development area are used as an example, where the dolomitic limestone and limestone mixed with dolomite of the Jialing River Formation of the middle lower Triassic are widely developed in the observation area. The frequency-Bessel transform method involves performing a Bessel integral transformation on the cross-correlation coefficient of background noise in the frequency domain. Firstly, by synthesizing theoretical noise data and comparing it with the spatial autocorrelation method—which is currently the main method for extracting the fundamental dispersion curve of surface waves—it is verified that the frequency-Bessel transform method can extract the higher-mode dispersion curve. Then, by taking the actual measured single-point noise data as an example, the effect of applying the frequency-Bessel transform to the actual noise data is tested, and the inversion of the fine structure of the strata by the addition of higher-mode dispersion, the use of the damped least squares inversion method, and the joint inversion of fundamental and higher-mode dispersion curves are analyzed. The higher-mode dispersion curve of Rayleigh surface wave extracted by the frequency-Bessel transform is much clearer, and the 2D shear wave velocity structure profile obtained from inversion explains the karst development area, karst strip area, and thickness of the Quaternary overburden. The inferred results match with the actual borehole data. Multi-mode imaging of background noise based on the frequency-Bessel method can be applied to depict karst in complex backgrounds, and has significant potentiality in the field of ambient seismic noise tomography, providing a new idea and method for karst detection in near-surface engineering. Full article
(This article belongs to the Special Issue State-of-the-Art Earth Sciences and Geography in China)
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26 pages, 14808 KiB  
Article
Relations between Fault and Fracture Network Affecting the Lastoni di Formin Carbonate Platform (Italian Dolomites) and Its Deformation History
by Niccolò Menegoni, Riccardo Inama, Yuri Panara, Matteo Crozi and Cesare Perotti
Geosciences 2022, 12(12), 451; https://doi.org/10.3390/geosciences12120451 - 8 Dec 2022
Cited by 11 | Viewed by 3001
Abstract
In this study, we analyze the fault and fracture network of the Middle Triassic carbonate platform of the Lastoni di Formin (Italian Dolomites, Italy). The reconstruction of the deformation history is of primary importance for a full comprehension of the present structural setting [...] Read more.
In this study, we analyze the fault and fracture network of the Middle Triassic carbonate platform of the Lastoni di Formin (Italian Dolomites, Italy). The reconstruction of the deformation history is of primary importance for a full comprehension of the present structural setting of this carbonate platform. The huge dimensions of the carbonate body and superb exposure of its vertical cliffs and gently dipping top plateau make the Lastoni di Formin platform an ideal outcrop to integrate traditional fieldwork with Digital Outcrop Modelling analysis. The results of the structural studies partially confirm that the present-day fracture pattern is the result of differential compaction-induced deformation that generated WNW-ESE-trending extensional fractures and normal faults, perpendicular to the direction of progradation of the platform. Successively, extensional tectonics, likely related to the Jurassic rifting phase, led to the formation of NNW-SSE striking fractures and westward-dipping normal faults. A Neogene compressional tectonic event, characterized by N-S to NW-SE crustal shortening, deformed the platform, essentially with strike-slip structures. Full article
(This article belongs to the Section Structural Geology and Tectonics)
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