Search Results (97)

The reliability of bulk geochemical proxies for provenance analysis in heterogeneous clastic systems remains a critical yet underexplored issue. This study investigates the Lower Permian Shanxi Formation in the Southern North China Basin (SNCB) using an integrated approach combining major and trace element geochemistry, rare earth elements (REEs), and detrital zircon U–Pb geochronology. The results show that major element compositions have been significantly modified by diagenetic processes in tidal flat environments, limiting their applicability in tectonic discrimination. In contrast, immobile trace elements and REE patterns provide more robust constraints on source rock composition, suggesting predominantly felsic upper continental crustal sources. Detrital zircon age spectra reveal two dominant populations at 290–440 Ma and 1800–2500 Ma, indicating mixed provenance from the North Qinling Region (NQR) and the North China Craton (NCC). However, the application of classical discrimination diagrams is challenged by lithological heterogeneity, as the mixed presence of sandstone, sandy mudstone, and mudstone introduces compositional bias. Spatial variations among wells suggest differential contributions from continental island arc and active continental margin, likely controlled by paleogeographic configuration and sediment transport pathways. This study emphasizes the necessity of multi-proxy integration for reliable provenance reconstruction in complex sedimentary systems. Full article

Coal-bed gas well production is too low to realize a highly efficient exploitation of the #8 coal seam in the Shanxi formation in the Nalin region. Based on the reservoir characteristics, the designed poly-aromatic-grafted silicon-quantum-dot-based desorption agent (PQS) has been developed. Then, the adsorption/desorption behavior of CBM on the coal surface under the influence of this active chemical has been studied, and the synergy effect with an anionic–nonionic surfactant to desorption of CBM has also been discussed. The results show that the developed poly-aromatic-grafted silicon quantum dot, with a median size of 4.9 nm and +5.6 mV of zeta potential in neutral condition, has a significant emission peak with 470 nm at the excitation of 380 nm and 150,000 mg/L of salinity resistance, which also generates a strong adsorption capacity on the coal surface. A promoting effect to desorption of CBM for PQS nanofluid is exhibited and the Langmuir pressure is obviously increased. However, when the PQS nanofluid is synergized with an anionic–nonionic surfactant, the desorption of CBM is further improved and the wettability of the coal surface is altered from 78.2° to 84.2°. The desorption rate for this compound system reached 65.3%. It can be found that combining the quantum size, π–π stacking, π–π conjugation, and the synergy effect between PQS nanofluid and surfactant fluid with the traditional intermolecular force has a stronger capacity for promoting desorption of CBM than the conventional desorption agent. This study provides guidance for the molecular design of the desorption agent for deep coal rock and the application of silicon quantum dots. Full article

China’s stringent clean air policies have substantially reduced nitrogen oxides (NO_x) emissions, leading to a general decline in nitrogen dioxide (NO₂). However, surface ozone (O₃) pollution remains severe, creating a complex challenge due to the non-linear relationship between O₃ and its precursors. To disentangle the drivers behind these trends, this study quantifies the impacts of interannual variations in top-down constrained NO_x emissions on surface NO₂ and O₃ concentrations from 2014 to 2021 across mainland China and five national urban agglomerations. We employed the WRF-CMAQ model with a fixed-emission simulation approach, using an observationally optimized NO_x emission inventory derived from the assimilation of surface NO₂ measurements. Results reveal that NO₂ reductions were predominantly emission-driven (>80% post-2017), with declines most pronounced in winter. A strong linear consistency was found between interannual changes in top-down NO_x emissions and attributed NO₂ concentration variations, validating the methodology. In contrast, O₃ responses to NO_x reductions were spatially and seasonally heterogeneous, reflecting a non-linear photochemical regime. In major urban agglomerations (e.g., Beijing–Tianjin–Hebei (BTH), Yangtze River Delta (YRD), Pearl River Delta (PRD)), NO_x reductions post-2018 showed limited effectiveness in mitigating summertime O₃ and even increased O₃ in spring and autumn, indicating a prevalent VOC-sensitive regime where NO_x reduction can disinhibit O₃ formation. Conversely, certain provinces (e.g., Anhui, Shanxi, Jilin) exhibited O₃ decreases, suggesting a NO_x-sensitive regime. The area benefiting from NO_x reductions expanded steadily in summer after 2017 but not in other seasons. This study confirms the efficacy of NO_x-focused policies for reducing primary NO₂ pollution but highlights that mitigating persistent O₃ requires a strategic shift to synergistic, region-specific control of volatile organic compounds alongside NO_x, informed by local chemical sensitivity. Full article

The Ordos Basin hosts significant shale gas resources in China, yet its marine-continental transitional sedimentary setting causes intense reservoir heterogeneity that severely hinders accurate sweet spot identification in the Permian Shanxi Formation. This study aims to reveal the synergistic controls of lithofacies, mineralogy, and organic matter on shale gas sweet spot formation in the southern Yishan Slope of the eastern Ordos Basin. A multi-dimensional characterization approach was adopted, integrating drilling/logging data and systematic core analyses including X-ray diffraction (XRD), organic geochemical testing, porosity/permeability measurement, and on-site gas content desorption, to quantify reservoir heterogeneity across lithofacies, mineralogy, organic geochemistry, and petrophysical properties. The results show that three lithofacies associations are identified in the target interval: mud-wrapped sand, sand-mud interbedding, and sand-wrapped mud, among which sand-mud interbedding and mud-wrapped sand associations exhibit higher total organic carbon (TOC) contents and strong inter/intra-well heterogeneity. The organic matter in the reservoir is dominated by Type III kerogen, with TOC values ranging from 0.04% to 12.15%, and the Shan 2 Member shows significantly higher average TOC (2.55%) than the Shan 1 Member (1.36%). The reservoir is characterized by ultra-low porosity (average of 0.77%) and low permeability (average of 0.26 × 10⁻³ μm²), with mesopores and macropores contributing over 99% of the total pore volume and showing a significant positive correlation with gas content. Quartz (average of 34.86%) and clay minerals present strong vertical heterogeneity, with the Shan 2 Member being more heterogeneous than the Shan 1 Member due to differences in sedimentary environment evolution. A TOC threshold of 1.5% is determined for sweet spot identification in the study area, and shale gas sweet spots are synergistically controlled by high TOC abundance, moderate brittle mineral content, and 0.1–3 m thick sandy interbeds. This study enriches the theoretical understanding of marine-continental transitional shale reservoirs and provides a scientific basis for sweet spot prediction and development optimization in similar heterogeneous shale gas systems worldwide. Full article

This study examines the effects of nitrogen-planting density interactions on stalk lodging resistance mechanisms and yield formation in spring maize (Zea mays L.), aiming to establish a theoretical framework for optimizing planting configurations to achieve high and stable yields in Shanxi Province. Using the maize variety Qiangsheng 192 as the experimental material, a split-plot field experiment was conducted from 2023 to 2024. Planting density served as the main plot, with three levels: 60,000 plants ha⁻¹ (M1, 6 plants m⁻², control), 75,000 plants ha⁻¹ (M2, 7.5 plants m⁻²), and 90,000 plants ha⁻¹ (M3, 9 plants m⁻²), each replicated three times. Nitrogen application rate was the subplot, with four treatments: N0 (0 kg ha⁻¹), N1 (90 kg ha⁻¹), N2 (180 kg ha⁻¹), and N3 (270 kg ha⁻¹). At the tasseling stage, agronomic traits and mechanical properties of the stalks were investigated. The activities of Phenylalanine Ammonia-Lyase (PAL), Tyrosine Ammonia-Lyase (TAL), and Cinnamyl Alcohol Dehydrogenase (CAD) in the stalks were measured at the big trumpet stage, tasseling stage, filling stage, and maturity stages, and yield was determined. The results showed that the M2 treatment achieved the highest yield, followed by M3, while M1 (control) had the lowest yield. Under the M2N2 configuration, the yield reached 13.55 Mg ha⁻¹, the highest recorded. As planting density increased, maize growth exhibited variations: the basal internodes elongated, mechanical properties declined, and the activities of PAL, TAL, and CAD enzymes decreased. Increased nitrogen application improved basal internode quality. Correlation analysis revealed that stalk mechanical properties were positively correlated with PAL, TAL, and CAD enzyme activities, which could both reflect the quality of the stalk. In conclusion, the M2N2 configuration is an optimal combination for enhancing maize yield, improving stalk mechanical properties, and increasing enzyme activity, making it suitable for large-scale application in the dryland spring maize areas of Shanxi Province. Full article

Dissolved organic matter (DOM) in salt lake brines comprises organic compounds dissolved in high-salinity aquatic systems. With complex composition and diverse sources, DOM significantly influences biogeochemical cycles, mineral formation, and resource development in salt lakes. However, few studies have investigated the characteristics and sources of DOM in salt lake brines. In this study, a DOM sample (YC-4) from brine of Shanxi Yuncheng Salt Lake was isolated and characterized using FT-ICR-MS, nuclear magnetic resonance spectroscopy, three-dimensional fluorescence spectroscopy, and parallel factor analysis. The results demonstrate that YC-4 DOM exhibits rich chemical diversity, primarily composed of lignin/CRAM-like compounds (54.26%), tannins (16.75%) and proteins (13.43%). The predominant carbon forms in YC-4 DOM were aliphatic C-O bonded compounds (33.74%), aliphatic compounds (24.31%), and carboxylic acid compounds (23.95%). YC-4 DOM consists of five fluorescent components: marine-like humic substances, two types of humic-like substances, fulvic-like substances, and one protein-like substance. The fluorescence signature, characterized by high fluorescence index (FI 1.99), low humification index (HIX 0.66), and high biological index (BIX 1.27), collectively indicates that the DOM in Yuncheng Salt Lake brine is predominantly autochthonous, weakly humified, and highly bioavailable. This study reveals the DOM feature within the “human–environment coupled system” of Yuncheng Salt Lake. The findings provide a scientific basis for the sustainable utilization of its brine DOM resources and further enrich the theoretical system of DOM biogeochemical cycle in high-salinity lake system. Full article

Soil total carbon (TC) and total nitrogen (TN) are key indicators of soil fertility and ecosystem stability, particularly in dryland agroecosystems. However, how rotational tillage combined with straw return affects aggregate formation and aggregate-associated TC and TN stabilization remains insufficiently understood. In this study, we aimed to clarify how rotational tillage affects aggregate structure, stability, and the spatial distribution of TC and TN, thereby revealing internal processes driving nutrient stabilization in dryland farming systems. A long-term field experiment was conducted at the Shenfeng site of Shanxi Agricultural University, China, including three rotational tillage systems with straw return: T1 (two years of no tillage (NT) + one year of deep tillage (DT)), T2 (two years of conventional tillage (CT) + one year of DT), and T3 (two years of DT + one year of CT). Soil aggregates were separated into total mechanical aggregate (TMA), 0.25–2 mm MA, and 2–10 mm MA, and they were further fractionated into water-stable aggregates (WM, Wm, and Wf) for TC and TN analysis. The results showed that aggregate stability, TC, and TN were positively correlated and decreased with soil depth, indicating strong surface enrichment. TC was mainly enriched in 0.25–2 mm MA, whereas TN was concentrated in 2–10 mm MA, and water-stable macroaggregates (WM) acted as the dominant reservoirs for R_C and R_N. Relative to the 2016 baseline (CK), TC in 2022 tended to be higher under rotational tillage with straw return, while NT-containing systems better maintained TN across the 0–60 cm profile. Among the treatments, T1 provided the most balanced performance, with a higher MWD and GMD, lower D, and improved aggregate-associated TC and TN retention. These findings suggest that rotational tillage with straw return, particularly the NT–NT–DT sequence, can support aggregate stability and is associated with improved aggregate-mediated TC and TN retention in the Loess Plateau dryland winter wheat system. Full article

Currently, the formation and evolution processes of overpressure in the Upper Paleozoic tight sandstones of the Ordos Basin are not clearly understood. Taking the Shan 1 Member of the Shanxi Formation in the Yanchang area, southeastern Ordos Basin, as an example, we adopted a numerical simulation method considering pressurization effects (e.g., hydrocarbon generation and disequilibrium compaction) to quantitatively reconstruct the paleo-overpressure evolution history of target sandstone and shale layers before the end of the Early Cretaceous. We calculated two types of formation pressure changes since the Late Cretaceous tectonic uplift: the pressure reduction induced by pore rebound, temperature decrease and pressure release from potential brittle fracturing of overpressured shales, and the pressure increase in tight sandstones caused by overpressure transmission, thus clarifying the abnormal pressure evolution process of the Upper Paleozoic Shanxi Formation tight sandstones in the study area. The results show that at the end of the Early Cretaceous, the formation pressures of the target shale and sandstone layers in the study area reached their peaks, with the formation pressure coefficients of shale and sandstone being 1.41–1.59 and 1.10, respectively. During tectonic uplift since the early Late Cretaceous, temperature decrease and brittle fracture-induced pressure release caused significant declines in shale formation pressure, by 12.95–17.75 MPa and 20.00–25.24 MPa, respectively, resulting in the current shale formation pressure coefficients of 1.00–1.06. In this stage, temperature decrease and pore rebound caused sandstone formation pressure to decrease by 12.07–13.85 MPa and 16.93–17.41 MPa, respectively. Meanwhile, the overpressure transfer from two phases of hydrocarbon charging during the Late Triassic–Early Cretaceous and pressure release from shale brittle fracture during the Late Cretaceous tectonic uplift induced an increase in adjacent sandstone formation pressure, with a total pressure increase of 7.32–8.58 MPa. The combined effects of these three factors have led to the evolution of the target sandstone layer from abnormally high pressure in the late Early Cretaceous to the current abnormally low pressure. This study contributes to a deeper understanding of the formation process of underpressured gas reservoir in the Upper Paleozoic of the Ordos Basin. Full article

Mine accidents pose severe threats to worker safety and sustainable mining development in China. However, existing mine accident data in China are often scattered, unstructured, and lack systematic integration, which limits their application in safety research and practice. This study constructed a standardized structured dataset using 532 mine accident reports from official channels covering the period 2010–2025. The dataset went through four stages: data collection, standardized cleaning, structured annotation, and quality validation. It is stored in JSON Lines (JSONL) format for easy reuse. The dataset covers 27 provinces/autonomous regions/municipalities in China. Among accident levels, general accidents account for 65.6%; among accident types, roof accidents account for 20.3%. Accidents are geographically concentrated, with 11.7%, 8.3%, and 7.7% occurring in Shanxi, Gansu, and Inner Mongolia, respectively. Official data have shown an annual average decrease of 9.7% in mine accidents from 2018 to 2022, reflecting improved safety governance. This dataset addresses the gap of a full-element structured mine accident database in China, providing high-quality data for accident causation modeling, regional risk early warning, and safety policy evaluation. It also supports mine enterprises in targeted risk prevention and regulatory authorities in precise regulatory enforcement. Full article

CO₂ fracturing (CO₂-Frac) is a novel technology for coal mine gas control, which is distinct from CO₂ Enhanced Coalbed Methane, and has been applied to alleviate in situ stress concentration and to eliminate coal and gas outbursts in coal mines. However, the reasons for the greatly varying effects of CO₂-Frac application among different regions remains largely unknown, and the influence of geological structures, particularly pre-existing fracture orientations, remains poorly understood. The equipment system of phase fracturing and permeability improvement of low-permeability coalbed methane and the gas phase fracturing and permeability improvement technology are studied and analyzed, and the engineering application is carried out in the head face of Xinyuan Coal Mine. This study conducted three CO₂-Frac experiments in the Xinyuan coal mine in which borehole orientations were varied, with the primary fracture strike of coal seam #3 in the Shanxi Formation ranging from N3°E to N15°E. The characteristics of reservoir stress redistribution after CO₂-Frac and its mechanism controlled by the orientation of primary fractures were explored based on the analysis of microseismic focal mechanisms. The results showed that (1) Both the fracturing section and the buffer section determined the stress relief effect of CO₂-Frac. While the different experiments showed largely similar stress relief effects of the fracturing section, the effects of the buffer section greatly differed. (2) The microseismic events generated by the CO₂-Frac in the borehole with an N–S orientation showed a more concentrated spatial distribution, with higher proportions of tensile and dip-slip events. (3) The range of the stress relief in the buffer section of the borehole with an N–S orientation exceeded those of the other sections. Further geological analysis revealed that higher stress relief was achieved in both boreholes with a N–S orientation and a smaller angle between the borehole direction and the primary fracture orientation (angle BF). An improved numerical calculation model that integrated fracture mechanics and gas reservoir engineering was used in this study; the result showed that an improved CO₂-Frac effect was achieved under a BF angle of 0–21°, in good agreement with the field experiment results. The results of this study can help improve the effectiveness of CO₂-Frac and reduce the occurrence of coal and gas outbursts. Full article

Background: Pseudorabies virus (PRV), a critical porcine herpesvirus, induces severe diseases in both livestock and wildlife, imposing an incalculable burden and economic losses in livestock production. In this study, we investigated the evolutionary mechanisms and host adaptation strategies of the PRV gB gene through genomic alignment. The gB gene is highly conserved in PRV, and its encoded gB protein exhibits functional interchangeability across different herpesvirus species. Notably, the gB protein elicits the production of both complement-dependent and complement-independent neutralizing antibodies in animals, while also being closely associated with syncytium formation. Methods: Phylogenetic analysis and codon usage pattern analysis were performed in this study. A total of 110 gB gene sequences were analyzed, which were collected from [2011 to 2024] across the following regions: [Fujian, Shanxi, Guangxi, Guangdong, Chongqing, Henan, Shaanxi, Heilongjiang, Sichuan, Jiangsu, Jilin, Huzhou, Shandong, Hubei, Jiangxi, Beijing, Shanghai, Chengdu (China)], [Budapest, Szeged (Hungary)], [Tokyo (Japan)], [London (United Kingdom)], [Athens (Greece)], [Berlin (Germany)], and [New Jersey (United States)]. Results: The gB gene of PRV employs an evolutionary “selective optimization” strategy to maintain a dynamic balance between ensuring functional expression and evading host immune pressure, with this core trend strongly supported by its codon usage bias and mutation characteristics. First, the gene exhibits significant codon usage bias [Effective Number of Codons (ENC) = 27.94 ± 0.1528], driven primarily by natural selection rather than mere mutational pressure. Second, phylogenetic analysis shows that the second codon position of gB has the highest mutation rate (1.0586)—a feature closely linked to its antigenic variation and immune escape capabilities, further reflecting adaptive evolution against host immune pressure. Additionally, ENC-GC3 plot analysis reveals the complex regulatory mechanisms underlying codon bias formation, providing molecular evidence for the “selective optimization” strategy and clarifying PRV’s core evolutionary path to balance functional needs and immune pressure over time. Conclusions: Our study findings deepen our understanding of the evolutionary mechanisms of PRV and provide theoretical support for designing vaccines and assessing the risk of cross-species transmission. Full article

Methane (CH₄), the second-largest global greenhouse gas and a key driver of tropospheric ozone formation, critically influences climate change and air quality. As the world’s largest CH₄ emitter, China must develop targeted mitigation strategies to support its carbon peak and neutrality goals while reducing ozone pollution. Here, we analyzed the spatiotemporal evolution of provincial CH₄ emissions in China from 2000 to 2023 using spatial autocorrelation, hotspot detection, trend analysis, and K-means clustering. Our results revealed a triphasic emission trajectory—rapid growth followed by stabilization and a recent resurgence—with all provinces except Tibet showing increasing trends. The energy sector emerged as the primary contributor, particularly in Inner Mongolia, Shanxi, and Shaanxi, whereas agricultural emissions dominated in pastoral regions, such as Inner Mongolia and Sichuan, and rice-growing areas, such as Hunan and Hubei. Coastal provinces, including Shandong, Jiangsu, and Guangdong, exhibited waste disposal as their predominant CH₄ source. Based on these patterns, we classified the emission zones into four distinct typologies: coal-dominant, waste-dominant, oil-agriculture composite, and multifactorial systems, proposing tailored mitigation frameworks that integrate CH₄ and ozone co-reduction. This study provides a spatially resolved foundation for synergistic climate and air quality governance in China. Full article

Datong in Shanxi Province, known as the “Daylily Capital of China,” still primarily relies on traditional propagation by division for daylily seedling production. Although traditional seedling propagation methods are simple and low-cost, they suffer from limitations such as low propagation efficiency, which restricts large-scale production. The application of tissue culture in seedling production not only enables rapid large-scale propagation but also helps maintain desirable genetic traits through virus elimination. This study aimed to establish an efficient in vitro regeneration system for Hemerocallis citrina ‘Datong Huanghua’ through optimization of key culture stages using scape explants. The results demonstrated that during the stages of callus induction, adventitious bud differentiation, and proliferation culture, the best results were achieved using MS medium supplemented with 3 mg/L zeatin (ZT) and 0.3 mg/L α-naphthylacetic acid (NAA), yielding a callus induction rate of 83.33%, an adventitious bud differentiation rate of 83.40%, and a proliferation coefficient of 4.05. For root induction, MS medium containing 0.25 mg/L indole-3-butyric acid (IBA) and 0.25 mg/L NAA resulted in an average of 4.7 roots per plantlet with a 100% rooting rate. In addition, endogenous hormone analysis showed that lower ABA/GA₃ and ABA/ZR ratios in scape explants promoted callus formation during the induction and differentiation stages. Full article

Hydrocarbon-generation intensity (HGI) is a critical indicator for evaluating shale gas potential in source rocks. This study proposes a practical method to estimate HGI by integrating experimental pyrolysis data, EasyRo-based maturity transformation, kinetic modeling, and geological parameters. Using core samples from the Shanxi Formation in the eastern margin of the Ordos Basin, gold tube pyrolysis experiments were conducted under closed-system conditions to obtain gas yield data. The EasyRo model was applied to transform temperature to maturity, and a kinetic model was constructed to simulate hydrocarbon generation. Total organic carbon (TOC), maturity (Ro), thickness, and true density were used to calculate HGI at different depths. Spatial prediction of HGI was achieved using Kriging interpolation. Results indicate that although carbonaceous mudstones have higher TOC (14.2%) and gas yields (up to 155.84 mg/g TOC), black mudstones exhibit a 24.77% higher HGI due to greater thickness (average 67.2 m). This highlights the dominant role of formation thickness in controlling. Notably, black mudstones in the deeper western subregion exhibit greater gas-generation potential. These findings offer a robust quantitative basis for evaluating deep coal-measure shale gas resources in the Ordos Basin. Full article

The evolution of mining-induced overburden fractures (MIOFs) and their dynamic monitoring are critical for preventing roof water hazards and gas disasters in coal mines. Conventional methods often fail to provide sufficient accuracy under the thin soft–hard interbedded roof strata, necessitating advanced alternatives. Here, we address this challenge by proposing a borehole resistivity method (BRM) based on Back-Propagation Neural Network full-space inversion (BPNN-FSI). Based on the Carboniferous Taiyuan Formation in the North China Coalfield, geoelectric models of MIOFs were established for different mining stages. Finite element simulations generated apparent resistivity responses to train and validate the BPNN-FSI model. At the 9-204 working face of Dianping Coal Mine (Shanxi Province), we compared the proposed BRM based on BPNN-FSI with an empirical formula, numerical simulation, similarity physical simulation, and underground inclined drilling water-loss observations (UIDWLOs). Results demonstrate that the BRM based on BPNN-FSI achieves sub-1% error in height of MIOF (HMIOF) monitoring, with a maximum detected fracture height of 52 m—significantly outperforming conventional methods. This study validates the accuracy and robustness of BRM based on BPNN-FSI for MIOF monitoring in thin soft–hard interbedded roof strata, offering a reliable tool for roof hazard prevention and sustainable mining practices. Full article