Search Results (260)

Understanding groundwater and surface water interaction is critical for managing water resources, particularly in water-stressed and rapidly urbanizing areas, such as many parts of Africa. A survey was conducted of borehole, spring, seep and river water radon, δ²H, δ¹⁸O and field parameters in the Jukskei River catchment, Johannesburg. Average values of electrical conductivity (EC) were 274 and 411 μS·cm⁻¹ for groundwater and surface water, and similarly for radon, 37,000 and 1100 Bq·m⁻³, with a groundwater high of 196,000 Bq·m⁻³ associated with a structural lineament. High radon was a good indicator of baseflow, highest at the end of the rainy season (March) and lowest at the end of the dry season (September), with the FINIFLUX model computing groundwater inflow as 2.5–4.7 L·m⁻¹s⁻¹. High EC was a poorer indicator of baseflow, also considering the possibility of wastewater with high EC, typical in urban areas. Groundwater δ²H and δ¹⁸O values are spread widely, suggesting recharge from both normal and unusual rainfall periods. A slight shift from the local meteoric water line indicates light evaporation during recharge. Surface water δ²H and δ¹⁸O is clustered, pointing to regular groundwater input along the stream, supporting the findings from radon. Given the importance of groundwater, further study using the same parameters or additional analytes is advisable in the urban area of Johannesburg or other cities. Full article

Cold seep ecosystems harbor unique microbial communities with potential for producing secondary metabolites. However, the metabolic potential of cold seep microorganisms in the South China Sea remains under-recognized. This study employed both culture-dependent and culture-independent approaches, including 16S rRNA amplicon sequencing and metagenomics, to investigate microbial communities and their potential for secondary metabolite production in the South China Sea cold seep. The results indicate microbial composition varied little between two non-reductive sediments but differed significantly from the reductive sediment, primarily due to Planctomycetes and Actinobacteria. Predicting the Secondary Metabolism Potential using Amplicon (PSMPA) predictions revealed 115 strains encoding more than 10 biosynthetic gene clusters (BGCs), with lower BGC abundance in reductive sediment. Culture-dependent studies showed Firmicutes as the dominant cultivable phylum, with strains from shallow samples encoding fewer BGCs. Metagenomic data confirmed distinct microbial compositions and BGC distributions across sediment types, with cold seep type having a stronger influence than geographic location. Certain BGCs showed strong correlations with sediment depth, reflecting microbial adaptation to nutrient-limited environments. This study provides a comprehensive analysis of the metabolic capabilities of South China Sea cold seep microorganisms and reveals key factors influencing their secondary metabolic potential, offering valuable insights for the efficient exploration of cold seep biological resources. Full article

Earth fill dams are susceptible to internal erosion and instability when founded over cavity-prone formations such as gypsum or karstic limestone. Subsurface voids can significantly compromise dam performance, particularly under seismic loading, by altering seepage paths, raising pore pressures, and inducing structural deformation. This study examines the influence of cavity presence, location, shape, and size on the behavior of zoned earth dams. A 1:25 scale physical model was tested on a uniaxial shake table under varying seismic intensities, and seepage behavior was observed under steady-state conditions. Numerical simulations using SEEP/W and QUAKE/W in GeoStudio complemented the experimental work. Results revealed that upstream and double-cavity configurations caused the greatest deformation, including crest displacements of up to 0.030 m and upstream subsidence of ~7 cm under 0.47 g shaking. Pore pressures increased markedly near cavities, with peaks exceeding 2.7 kPa. Irregularly shaped and larger cavities further amplified these effects and led to dynamic factors of safety falling below 0.6. In contrast, downstream cavities produced minimal impact. The excellent agreement between experimental and numerical results validates the modeling approach. Overall, the findings highlight that cavity geometry and location are critical determinants of dam safety under both static and seismic conditions. Full article

The paper presents the geochemical characteristics of 26 selected oil seeps, more than half of which are remnants of old oil wells. The samples were collected from three tectonic units: the Magura, Silesian, and Skole units in the Polish part of the Carpathians. The analyzed seeps are mainly located on outcrops of Inoceramian beds within the Magura nappe, the Krosno Beds and Transition Beds in the Silesian nappe, as well as the Menilite Beds of the Skole unit. The study primarily focused on genetic characteristics, which were used to correlate the seeps with the oils from the deposits of these tectonic units and to assess the degree of secondary alterations. All hydrocarbon seeps were analyzed in terms of their location on surface cross-sections, and attempts were made to assign them features based on the classification proposed in 1952, which takes into account the tectonic characteristics of the regions where the seeps were identified. In the general genetic characterization, these seeps did not show significant differences, suggesting a similar source of supply as the crude oils. Among the analyzed seeps, three genetic groups were distinguished. For correlation purposes, information from published materials on crude oils and their genetic characteristics was used. Of the five classification types described in the literature, only two could be assigned to those occurring in the Carpathians. Considering the tectonic structure and the location of the seeps (based on surface cross-sections), it has been determined that most of the analyzed seeps are the result of migration along faults connecting source rocks or, less frequently, deformed deep accumulations with the surface. Full article

Türkiye hosts a wide variety of barite deposits that can be broadly classified into two major groups based on their tectonic settings: magmatism-associated and passive margin-hosted deposits. The magmatism-associated deposits include Kızılcaören (F + Ba + REE + Th, Beylikova–Eskişehir), Kirazören (Bulancak–Giresun), and Karacaören (Mesudiye–Ordu). The Kızılcaören deposit formed in relation to the emplacement of a late Oligocene carbonatitic sill, while the Kirazören and Karacaören deposits are associated with the Cretaceous Pontide magmatic arc. Passive margin-hosted deposits occur within various Paleozoic sedimentary lithologies—such as metasandstone, shale, schist, and limestone—and are found in the Taurides and the Arabian Platform. These deposits occur as either concordant or discordant veins. This barite belt extends from Şarkikaraağaç (Isparta), through Hüyük (Konya) and Alanya (Antalya), to Silifke (Mersin), Tordere (Adana), Önsen, Şekeroba (Kahramanmaraş), and Hasköy (Muş). The Paleozoic deposits represent the major barite resources of Türkiye, with an annual production of approximately 300,000 metric tons. Smaller deposits around Gazipaşa (Antalya) contain minor Pb-Zn sulfides. Mesozoic barite deposits are hosted in Triassic dolomites and are associated with Pb-Zn mineralization in the Hakkari region of the Arabian Platform. Pb and Sr isotope data indicate that the barium in these deposits was derived from ancient continental crust. The isotopic compositions of both concordant (stratabound) and discordant (vein-type) barites are generally homogeneous. In northwestern Türkiye, the Sr isotope compositions of the barite deposits align well with those of the Oligocene carbonatite host complex. The ⁸⁷Sr/⁸⁶Sr isotope ratio of the Kızılcaören deposit (0.706‰) is the least radiogenic among Turkish barite deposits, suggesting a mantle contribution. The Kirazören deposit in the Pontide magmatic arc follows with a slightly higher ratio (0.707‰). Triassic barites from the Hakkari region yield ⁸⁷Sr/⁸⁶Sr values around 0.709‰, slightly more radiogenic than coeval seawater. Paleozoic barite deposits show the most radiogenic ⁸⁷Sr/⁸⁶Sr values, including Aydıncık (0.718‰), Şarkikaraağaç (0.714‰), Hasköy (0.713‰), Kahramanmaraş (0.712‰), Tordere, and Hüyük (both 0.711‰), consistent with their respective host rocks. The elevated radiogenic Pb and Sr isotope values in the passive margin-hosted deposits suggest that the barium originated from deeper, barium-enriched rocks, whereas stable sulfur isotope data point to a marine sulfur source. Moreover, Sr and S isotopic signatures indicate that the Paleozoic sediment-hosted deposits formed in association with cold seeps on the seafloor, resembling modern analogs. In contrast, the Mesozoic Karakaya deposit (Hakkari) represents a typical vent-proximal, sediment-hosted deposit with no magmatic signature. Full article

Colloidal silica can seep through calcareous sand in the subgrade, forming colloidal-silica-cemented sand with self-sensing ability—that is, it is sensitive to stress changes caused by vehicle loading. Its self-sensing sensitivity is higher than that of traditional Portland-cement-based self-sensing materials. The self-sensing mechanism is attributed to the ionic conductive network formed by seawater. However, a change in tidal water level causes an unsaturated state, and foundation deformation leads to cracking of the roadbed. The effect of unsaturation and cracking on self-sensing remains unclear, and they have not been studied in the previous literature. The aim of this paper is to study the self-sensing ability of subgrades formed via colloidal-silica-cemented sand under unsaturated and cracked states, as well as to explore the underlying mechanisms. Specimens with different degrees of saturation and different levels of joint roughness in precracks were prepared; then, the self-sensing ability was tested using the four-electrode method for each specimen under cyclic stress loading. NMR (nuclear magnetic resonance) and an unsaturated triaxial apparatus were also used to investigate the underlying mechanisms. This paper discovers that (1) either unsaturation or crack alone can increase self-sensing, but their self-sensing sensitivities are on the same order; (2) under the coupled effect of unsaturation and cracking, the self-sensing sensitivity increases by one order of magnitude, which is higher than when only unsaturation or cracking exists; and (3) the joint roughness of precracks does not affect self-sensing in the saturated state, but it affects self-sensing dramatically in the unsaturated state. The NMR test demonstrated the conductive ionic water within nanopores, which forms the conductive network for self-sensing. Unsaturation causes suction-induced shrinkage based on the unsaturated triaxial apparatus, while unsaturation increases self-sensing sensitivity, indicating that shrinkage is accompanied by self-sensing improvement. This paper provides the effects of unsaturation and cracking on the self-sensing capabilities of colloidal-silica-cemented sand, and the findings can contribute to the knowledge of subgrades formed via colloidal-silica-cemented sand for stress-sensing under traffic loading. Full article

Soil pollution at airports is a critical environmental issue that affects not only the local ecology but also the health of people living near these infrastructures. The main causes of pollution include the use of chemical products such as de-icing agents, fuels, and lubricants, as well as waste from aircraft and ground vehicles. These substances often seep into the soil, leading to the accumulation of toxic elements. However, due to security reasons, there is a great scarcity of real data on the impact of airport operations on ecosystems and the role trees could play in pollutant limitation. Thus, the aim of this study was to determine whether airport operations have toxic effects on soils within and around Macedonia Airport, Thessaloniki, Northern Greece, by determining the concentrations of potentially toxic elements (Cu, Ni, Pb, Mn, Fe, Co, Cr, Cd, and Zn) in soil samples taken within the airport and near the airport. Furthermore, this study aimed to investigate the effect of the canopies of forest species on the accumulation of toxic metals in the soil inside the airport and in the peripheral zone. The results show that, overall, no important pollution was detected in the soil of the Thessaloniki Airport, Northern Greece, both inside and outside the airport area. Some differences were observed in the content of toxic metals studied between the samples taken inside and outside the airport, and some effects of tree canopy were noted. However, all values were lower than the defined permissible limits according to international standards (except for iron). It is important, however, to perform regular re-checking of soil quality with new samples in order to prevent soil contamination and mitigate any contamination found. Full article

This study investigates rainfall-induced slope instability in fine-grained clayey soils through a probabilistic and sensitivity analysis framework that integrates spatial variability. Moving beyond traditional deterministic methods, Monte Carlo simulations were employed to quantify uncertainty in geotechnical parameters—unit weight, cohesion, and friction angle—modeled as random fields with a 1 m spatial resolution. This approach realistically captures natural soil heterogeneity and its influence on slope behavior during rainfall events. Transient seepage and slope stability analyses were performed using SEEP/W and SLOPE/W, respectively, with the Spencer method ensuring full equilibrium. This study examined how slope height, inclination, rainfall intensity and duration, and soil properties affect the factor of safety (FS). The results showed that higher rainfall intensity and longer durations significantly increase failure risk. For example, under 9 mm/h rainfall for 48 h, slopes taller than 10 m at 45° inclination exhibited failure probabilities over 30%. At 20 m, FS dropped to 0.68 with a 100% probability of failure. Sensitivity analysis confirmed cohesion and friction angle as key stabilizing factors, though their impact diminishes with infiltration. A dataset of 9984 slope scenarios was generated, supporting future machine learning applications for risk assessment and climate-resilient slope design. Full article

The reduction in the stability of rock slopes due to rainfall is a significant issue in tropical regions. Unsaturated soil, commonly found on hill slopes, provides higher shear strength compared to saturated soil due to matric suction. Soil moisture plays a crucial role in determining slope stability during rainfall events, yet it is often overlooked in geotechnical engineering projects. This study integrates both steady-state and transient analyses to examine how rainfall intensity affects the stability of a rock slope near a tunnel portal. Transient seepage analysis was conducted using SEEP/W to simulate changes in pore water pressure (PWP) resulting from rainfall infiltration under historical and future precipitation conditions. The analysis considers medium (SSP245) and worst-case (SSP585) climate change scenarios as per Coupled Model Intercomparison Project Phase 6 (CMIP6). The findings underscore the significant impact of rainfall-induced infiltration on slope stability and highlight the importance of incorporating soil moisture dynamics in slope stability assessments. The safety factor, initially 1.54 before accounting for rainfall effects, decreases to 1.34 when the effects of rainfall are included. Full article

Geochemical and isotopic analysis of bitumen lining potsherds from the al-Qusur monastery (second half of the 7th c. CE and the middle of the 9th c. CE), at the central part of Failaka Island (Kuwait Bay), confirms the presence of two distinct compositional categories that can be matched to contemporary sources from two different areas of Iran: the Kermanshah province on one side, and the Khuzestan–Fars–Busher provinces on the other side. Potsherds comprise different types: TORP-S amphorae, TORP-C amphorae, SPORC storage jar, turquoise alkaline-glazed jar (TURQ.T), and CREAC jar. There is no relationship between the type of potsherd and the origin of bitumen. The bitumen coating SPORC jar, first identified as a kind of juice strainer to filter the «garum-like juice», was examined in greater details to try to identify traces of fish sauce mentioned in the Arabic kitchen books as ‘murri’, and quite similar to the Roman garum. The mineralogical analysis exhibits the classical minerals of archaeological mixtures (quartz, calcite, dolomite) and no halite. Hydrocarbons, alcohols, and methyl esters show a typical biodegraded bitumen signature but no fatty acids and terpenoids. It seems that the bitumen matrix has not adsorbed any molecules from the presumed «garum» filtered in the basin. Full article

Deep-sea chemosynthetic ecosystems, including cold seeps and hydrothermal vents, are widely spread in global oceans. Campylobacterota are important primary producers in deep-sea hydrothermal vents and serve as a vital food source for local invertebrates. However, the nutrients that these bacteria can provide to their hosts are unclear. To date, research on Campylobacterota in cold seeps is very limited. Consequently, little is known about the biological features and ecological potential of Campylobacterota in cold seeps. In the present work, we examined the diversity, growth, metabolic characteristics, and nutrient production of Campylobacterota in a deep-sea cold seep. Over 1000 Campylobacterota ASVs, especially autotrophic Sulfurovum and Sulfurimonas, were identified. By optimizing the culture medium, 9 Sulfurovum and Sulfurimonas strains were isolated, including three potentially novel species. Two novel species were characterized and found to exhibit unique morphological features. These two novel strains possessed complete reverse tricarboxylic acid pathways. One novel strain, FCS5, was a psychrotolerant autotroph with denitrification and phosphorus-removing capacity. FCS5 could grow in the absence of vitamins. Consistently, metabolomics and transcriptome analyses indicated that FCS5 produced multiple vitamins, which regulated the expressions of a large number of genes associated with carbon fixation and multiple-nutrient synthesis. Besides vitamins, autotrophic Campylobacterota also produced abundant free amino acids, fatty acids (short-chain, medium, and long-chain), and proteins. This study indicates that the cold seep abounds with Campylobacterota, which are capable of providing various nutrients for the chemosynthetic ecosystem. In addition, these bacteria may have wide applications, such as in wastewater treatment and carbon emission reduction. Full article

The Cape Floristic Region (CFR) boasts rich biodiversity but faces threats from invasive species and land-use changes. Fynbos wetland vegetation within the CFR is under-mapped despite its crucial role in supporting biodiversity and maintaining hydrological cycles. This study assessed the potential of UAV VIS-NIR data, gathered during Spring and Summer, to identify the spectral characteristics of eleven Fynbos wetland species in a seep wetland. Spectral distances derived from reflectance data revealed distinct spectral clustering of plant species, highlighting which species could be distinguished from each other. UAV data also captured differences in reflectance across spectral bands for both dates. Spectral statistics indicated that certain species could be more accurately classified in Spring than in Summer, and vice versa. These findings underscore the efficacy of UAV multispectral data in analyzing the reflectance patterns of fynbos wetland species. Additionally, the sensitivity of UAV multispectral data to foliar pigment composition across different seasonal stages was confirmed. Lastly, species classification results demonstrated that a random forest classifier is well suited, with relative producer and user accuracies aligning with the derived spectral distances. The results highlight the potential of UAV imagery for monitoring these endemic species and creating opportunities for scalable mapping of Fynbos seep wetlands. Full article

Well leakage is a recurring hazard in drilling operations that can lead to significant loss of drilling fluids and serious consequences when drilling fluids seep into the formation. Increasing drilling depths correspond to elevated formation temperatures and pressures, which place stringent demands on leakage control materials. In this study, a high-pressure- and high-temperature-resistant branched resin, poly-BDEB, was synthesized using 2,2-bis(4-hydroxyphenyl)propane diepoxyglycidyl ether and epoxy crack adhesive B. The properties of the branched resin poly-BDEB were characterized. Leakage control performance of the branched resin poly-BDEB was evaluated through single-stage and multi-stage crack plugging experiments to determine its effectiveness. The results show that poly-BDEB maintains structural stability under pressures of up to 198.33 MPa. Poly-BDEB has a stable structure and will not be thermally decomposed at 352.25 °C. These properties demonstrate poly-BDEB’s excellent pressure and temperature resistance. The density of branched resin poly-BDEB is 1.07 g/cm³. When its concentration in the drilling fluid reaches 24% (8%A + 8%B + 8%C), it still maintains good sedimentation stability. Poly-BDEB can effectively plug single-stage and multi-stage fractures ranging from 1 to 3 mm in width. Unlike conventional leakage circulation materials (LCMs), poly-BDEB features a branched molecular structure that improves its mechanical strength, thermal stability, and bridging efficiency in fractures. This study can provide technical support for leakage control in deep and ultra-deep wells during drilling. Full article

Genomic adaptations of parasitic crustaceans in deep-sea extreme environments are poorly understood. This study presents the first genome survey of Pleurocryptella shinkai, a bopyrid isopod parasitizing deep-sea squat lobsters, using Illumina sequencing. The genome size was estimated to be 1.06 Gb via a K-mer analysis, smaller than its free-living relatives. The repeat content and heterozygosity were 66.31% and 1.14%, respectively, indicating a complex genome. The draft genome assembly yielded 0.93 Gb of scaffolds with an N50 length of 989 bp, and a complete mitochondrial genome of 14,711 bp was obtained. Phylogenetic analyses of 13 mitochondrial protein-coding genes confirmed the monophyly of Bopyridae, supporting Pleurocryptella as the most primitive genus within the group and the key role of deep sea in the origin and diversification of bopyrids. A mitochondrial gene variation analysis identified NAD2 and NAD4 as promising DNA markers for a population genetic study of P. shinkai. Twenty-four positively selected sites across COX1, NAD2, and NAD4 genes in P. shinkai explained the genetic basis of its adaptive evolution at the mitochondrial level. These findings provide valuable genomic resources for deep-sea parasitic crustaceans and establish a foundation for further high-quality genome assembly and adaptive mechanism studies of P. shinkai. Full article

The Mesoproterozoic alkaline Grønnedal-Íka complex (1325 ± 6 Ma) is intruded into old Archean gneissic bedrock between Ikka Fjord and Kangilinnguit (Grønnedal) by Arsuk Fjord in Southwestern Greenland. This 8 × 2.8 km oval-shaped complex constitutes the oldest part of the Gardar Province, representing a failed continental rift across southern Greenland. It comprises outer rings of mainly nepheline syenites with a central plug of Fe- and Ca-rich carbonatites. Here, we present petrological data on the syenites and carbonatites combined with geochemical modelling of groundwater percolating through the Grønnedal-Íka complex and the secondary minerals and fluid chemistry arising from these fluid–rock reactions. The results show that modelling using input data of (1) meteoric water in a closed system with respect to atmospheric CO₂ can (2) dissolve the primary minerals of the syenites and carbonatites and (3) simulate the fluid chemistry of the natural sodium carbonate springs of 3–4 °C and pH 10–11 seeping up through fractures at the bottom of Ikka Fjord, which (4) leads to the deposition of nearly a thousand tufa columns of the cold carbonate mineral ikaite (CaCO₃•6H₂O). Our results thereby support the geochemical relationship between fluid–rock reactions inside the Grønnedal-Íka alkaline complex and the precipitation of ikaite in the shape of submarine tufa columns in Ikka Fjord. The modelling indicates that the groundwater itself can be supersaturated with respect to ikaite and provide the seed crystals that lead to the columnar growth of ikaite up to 20 m tall in the seawater of Ikka Fjord. Full article