Search Results (325)

In recent years, recovering precious and base metals such as silver and copper from end-of-life products has become a fundamental factor in the sustainable development of many countries. This not only supports environmental goals but is also a profitable economic activity. Therefore, in this study, we investigate the recovery of silver and copper from an end-of-life photovoltaic panel powder using an alternative leaching system containing sulfuric acid and ferric sulfate instead of nitric acid-based leaching systems, which are susceptible to producing hazardous gases such as NO_x. To obtain this goal, a series of experiments were designed with the Central Composite Design (CCD) approach using Response Surface Methodology (RSM) to evaluate the effect of reagent concentrations on the leaching rate. The leaching results showed that high recovery rates of silver (>85%) and copper (>96%) were achieved at room temperature using a solution containing only 0.2 M sulfuric acid and 0.15 M ferric sulfate. Analysis of variance was applied to the leaching data for silver and copper recovery, resulting in two statistical models that predict the leaching efficiency based on reagent concentrations. Results indicate that the models are statistically significant due to their high R² (0.9988 and 0.9911 for Ag and Cu, respectively) and the low p-value of 0.0043 and 0.0003 for Ag and Cu, respectively. The models were optimized to maximize the dissolution of silver and copper using Design Expert software. Full article

The internal combustion process in a boiler in power plants has a direct impact on boiler efficiency and NOx generation. The objective of this study is to propose an intelligent deep learning modeling and multi-objective optimization approach that considers NOx emission concentration and boiler thermal efficiency simultaneously for boiler combustion in power plants. Firstly, a hybrid deep learning model, namely, convolutional neural network–bidirectional gated recurrent unit (CNN-BiGRU), is employed to predict the concentration of NOx emissions and the boiler thermal efficiency. Then, based on the hybrid deep prediction model, variables such as primary and secondary airflow rates are considered as controllable variables. A single-objective optimization model based on an improved flow direction algorithm (IFDA) and a multi-objective optimization model based on NSGA-II are developed. For multi-objective optimization using NSGA-II, the average NOx emission concentration is reduced by 5.01%, and the average thermal efficiency is increased by 0.32%. The objective functions are to minimize the boiler thermal efficiency and the concentration of NOx emissions. Comparative analysis of the experiments shows that the NSGA-II algorithm can provide a Pareto optimal front based on the requirements, resulting in better results than single-objective optimization. The effectiveness of the NSGA-II algorithm is demonstrated, and the obtained results provide reference values for the low-carbon and environmentally friendly operation of coal-fired boilers in power plants. Full article

Hydrogen is a promising zero-carbon fuel for internal combustion engines; however, the geometric optimization of injectors for low-pressure direct-injection (LPDI) systems under lean-burn conditions remains underexplored. This study presents a high-fidelity optimization framework that couples a validated computational fluid dynamics (CFD) combustion model with a surrogate-assisted multi-objective genetic algorithm (MOGA). The CFD model was validated using particle image velocimetry (PIV) data from non-reacting flow experiments conducted in an optically accessible research engine developed by Sandia National Laboratories, ensuring accurate prediction of in-cylinder flow structures. The optimization focused on two critical geometric parameters: injector hole count and injection angle. Partial indicated mean effective pressure (pIMEP) and in-cylinder NO_x emissions were selected as conflicting objectives to balance performance and emissions. Adaptive mesh refinement (AMR) was employed to resolve transient in-cylinder flow and combustion dynamics with high spatial accuracy. Among 22 evaluated configurations including both capped and uncapped designs, the injector featuring three holes at a 15.24° injection angle outperformed the baseline, delivering improved mixture uniformity, reduced knock tendency, and lower NO_x emissions. These results demonstrate the potential of geometry-based optimization for advancing hydrogen-fueled LPDI engines toward cleaner and more efficient combustion strategies. Full article

Environmental comfort and air pollution are among the most important indicators for assessing the population’s quality of life in urban agglomerations. This study aims to explore long-term memory in air pollution time series by analyzing the dynamics of the Hurst exponent and evaluating the predictability index. This type of statistical pre-forecast analysis is essential for developing accurate forecasting models for such time series. The effectiveness of air quality monitoring systems largely depends on the precision of these forecasts. The Ekibastuz coal-mining center, which houses one of the largest coal-fired power stations in Kazakhstan and the world, with a capacity of about 4000 MW, was chosen as an example for the study. Data for the period from 1 March 2023 to 31 December 2024 were collected and analyzed at the Ekibastuz coal-fired power station. During the specified period, 14 indicators (67,527 observations) were collected at 10 min intervals, including mass concentrations of CO, NO, NO₂, SO₂, PM_2.5, and PM₁₀, as well as current mass consumption of CO, NO, NO₂, SO₂, dust, and NO_x. The detrended fluctuation analysis of a time series of air pollution indicators was used to calculate the Hurst exponent and identify long-term memory. Changes in the Hurst exponent in regards to dynamics were also investigated, and a predictability index was calculated to monitor emissions of pollutants in the air. Long-term memory is recorded in the structure of all the time series of air pollution indicators. Dynamic analysis of the Hurst exponent confirmed persistent time series characteristics, with an average Hurst exponent of about 0.7. Identifying the time series plots for which the Hurst exponent is falling (analysis of the indicator of dynamics), along with the predictability index, is a sign of an increase in the influence of random factors on the time series. This is a sign of changes in the dynamics of the pollutant release concentrations and may indicate possible excess emissions that need to be controlled. Calculating the dynamic changes in the Hurst exponent for the emission time series made it possible to identify two distinct clusters corresponding to periods of persistence and randomness in the operation of the coal-fired power station. The study shows that evaluating the predictability index helps fine-tune the parameters of time series forecasting models, which is crucial for developing reliable air pollution monitoring systems. The results obtained in this study allow us to conclude that the method of trended fluctuation analysis can be the basis for creating an indicator of the level of air pollution, which allows us to quickly respond to possible deviations from the established standards. Environmental services can use the results to build reliable monitoring systems for air pollution from coal combustion emissions, especially near populated areas. Full article

This study combines convolutional neural network (CNN) recognition technology, Greenwich engineering software, and statistical yearbook methods to evaluate rural solar, wind, and biomass energy resources in pilot cities in China, respectively. The CNN method enables the rapid identification of the available roof area, and Greenwich software provides wind resource simulation with local terrain adaptability. The results show that the capacity of photovoltaic power generation reaches approximately 15.63 GW, the potential of wind power is 458.3 MW, and the equivalent of agricultural waste is 433,900 tons of standard coal. The city is rich in wind, solar, and biomass resources. By optimizing the hybrid power generation system through genetic algorithms, wind energy, solar energy, biomass energy, and coal power are combined to balance the annual electricity demand in rural areas. The energy trends under different demand growth rates were predicted through the LEAP model, revealing that in the clean coal scenario of carbon capture (WSBC-CCS), clean coal power and renewable energy will dominate by 2030. Carbon dioxide emissions will peak in 2024 and return to the 2020 level between 2028 and 2029. Under the scenario of pure renewable energy (H_WSB), SO₂/NO_x will be reduced by 23–25%, and carbon dioxide emissions will approach zero. This study evaluates the renewable energy potential, power system capacity optimization, and carbon emission characteristics of pilot cities at a macro scale. Future work should further analyze the impact mechanisms of data sensitivity on these assessment results. Full article

This study creates and tests a machine learning model that can predict fuel use and emissions (NO_x, CO₂, CO, HC, PN) from a marine internal combustion engine when it is running normally. The model learned from data collected from conventional diesel fuel experiments. Subsequently, we evaluated its ability to transfer by employing the parameters associated with waste cooking oil (WCO) biodiesel and its 60/40 diesel mixture. The machine learning model demonstrated exceptional proficiency in forecasting diesel mode (R² > 0.95), effectively encapsulating both long-term trends and short-term fluctuations in fuel consumption and emissions across various load regimes. Upon the incorporation of WCO data, the model maintained its capacity to identify trends; however, it persistently overestimated emissions of CO, HC, and PN. This discrepancy arose primarily from the differing chemical composition of the fuel, particularly in terms of oxygen content and density. A significant correlation existed between indicators of incomplete combustion and the utilization of fuel. Nonetheless, NO_x exhibited an inverse relationship with indicators of combustion efficiency. The findings indicate that the model possesses the capability to estimate emissions in real time, requiring only a modest amount of additional training to operate effectively with alternative fuels. This approach significantly diminishes the necessity for prolonged experimental endeavors, rendering it an invaluable asset for the formulation of fuel strategies and initiatives aimed at mitigating carbon emissions in maritime operations. Full article

In this study, water residue obtained from Salvia desoleana Atzei et Picci steam distillation was evaluated for its antioxidant activity in vitro using different experimental models. In particular, the study evaluated the antiradical and antioxidant activity of Salvia desoleana extracts using CUPRAC, FRAP, DPPH^•, and ABTS^•+ assays; and tested ROS scavenging activity in Caco-2 cell cultures. Phenolic compounds were identified by (HR) LC-ESI-QTOF MS/MS and quantified with HPLC-PDA. Furthermore, Keap1-Nrf2, iNOS, and NOX enzymes involved in oxidative stress and antioxidant defences were the targets of molecular docking on key polyphenols. Hydroxycinnamic acids and flavonoids are the most important classes of compounds detected in the extracts. Among these compounds, the most significant was rosmarinic acid, followed by caffeic acid, luteolin glucuronide, and methyl rosmarinate. Although all extracts have shown encouraging results, the ethanolic extract solubilised with water (SEtOHA) was the one with the highest hydroxycinnamic acid content and total phenol content (518.64 ± 5.82 mg/g dw and 106.02 ± 6.02 mg GAE/g dw), as well as the highest antioxidant and antiradical activity. The extracts have shown anti-inflammatory activity by inhibiting NO release in LPS-stimulated Caco-2 cells. Finally, the in silico evaluation against the three selected enzymes showed interesting results for both numerical affinity ranking and predicted ligand binding models. The outcome of this study suggests this by-product as a possible ally in counteracting oxidative stress, as established by its favourable antioxidant compound profile, thus suggesting an interesting future application as a nutraceutical. Full article

Challenges associated with the homogeneous charge combustion ignition (HCCI) concept include combustion phasing control and a narrow operating window. To address the HCCI engine developmental needs, chemical kinetic solvers have been recently included in the commercial engine simulation toolchains like GT-Suite v2024 upward. This study investigates the feasibility of ammonia (NH₃) and hydrogen (H₂) as dual fuels in homogenous charge compression ignition (HCCI) engines, leveraging chemical kinetics modeling via GT-Suite software v2024. A validated baseline model was adapted with NH₃/H₂ injectors and simulated across varying blending ratios (BR), compression ratios (CR), air–fuel equivalence ratios (ER), and engine speeds. Results reveal that adding 10% H₂ to NH₃ significantly improves ignition. Optimal performance was observed at a CR of 20 and a lean mixture, achieving higher indicated thermal efficiency (about 40%), while keeping the intrinsic advantages of zero-carbon fuel. However, NOx emissions increased with higher ER due to elevated combustion temperatures. The study emphasizes the trade-offs between efficiency and NOx emissions under tested conditions. Finally, despite the single-zone model limitations in neglecting thermal stratification, this study shows that kinetic modeling has great potential for effectively predicting trends in HCCI, thereby demonstrating the promise of NH₃/H₂ blends in HCCI engines for cleaner and efficient combustion, paving the way for advanced dual-fuel combustion concepts. Full article

This review article provides a comprehensive analysis of the recent advancements in combustion science and engineering, focusing on the application of machine learning and genetic algorithms from 2015 to 2024. The study examines the integration of computational methods, including computational fluid dynamics, neural networks, and genetic algorithms, with various fuel types such as biodiesel, biomass, coal, gasoline, hydrogen, and natural gas. A systematic search in the Scopus database identified relevant articles, which were categorized based on fuel types and computational methodologies. The analysis covers key areas such as combustion modelling and simulation, engine applications, alternative fuels, pollutant control, and industrial combustion systems. This review highlights the growing role of machine learning and genetic algorithms in enhancing combustion efficiency, reducing emissions, and optimizing energy production, providing insights into the current state of the art and future trends in this critical field. The study further examines the geographical distribution of research, noting significant contributions from Canada, China, France, Germany, India, Iran, Japan, Malaysia, Pakistan, Saudi Arabia, the United Kingdom, and the United States, alongside other international contributions. A total of 165 peer-reviewed articles were analyzed, covering a range of combustion scenarios and fuel types. The most frequently applied methods include artificial neural networks (ANNs), support vector machines (SVMs), and random forests (RFs) for predictive modeling, as well as genetic algorithms (GAs) for system optimization. ANN-based models achieved high accuracy in predicting NO_x emissions and flame speed, with some studies reporting mean absolute errors below 5%. GA methods demonstrated effectiveness in fuel blend optimization and geometry design, achieving emission reductions of up to 30% in experimental setups. This review also highlights persistent challenges such as data availability, model generalization, and reproducibility, and proposes future directions toward more interpretable and standardized applications of ML/GA in combustion science. Full article

This study proposes a data-driven optimization framework to enhance emission control performance in diesel engine selective catalytic reduction (SCR) systems under transient operating conditions. A one-dimensional SCR model was constructed in GT-Power, and simulation datasets were generated using experimentally measured inputs from the World Harmonized Transient Cycle (WHTC), with representative emission responses obtained by varying fixed ammonia-to-NOx (A/N) ratios. Building on these datasets, a hybrid prediction model combining Long Short-Term Memory (LSTM) networks and multi-head attention mechanisms was developed to accurately forecast SCR outlet NH₃ leakage and NOx emissions. The model exhibited high predictive accuracy, achieving R² values exceeding 0.977 and low RMSE across training, validation, and test sets. Based on the model predictions, a constrained dynamic multi-objective optimization strategy was implemented to adaptively adjust ammonia dosing, aiming to simultaneously minimize NH₃ leakage and NOx emissions. The optimized NH₃ injection profiles were validated through reapplication in the GT-Power simulation environment. Compared to the baseline fixed-ratio control strategy, the proposed approach reduced NH₃ leakage and NOx emissions by 34.40% and 11.15%, respectively, as determined for the transient segment of the WHTC cycle. These results demonstrate the effectiveness of integrating physics-based simulation, deep learning prediction, and dynamic optimization for improving aftertreatment adaptability and emission compliance in real-world diesel engine applications. All reported values are based on a single simulated WHTC cycle without statistical uncertainty analysis. Full article

Light-duty trucks (LDTs) are often used to tow trailers. Towing increases the load on the engine, and this additional load can affect exhaust emissions. Although heavy-duty towing impacts are widely studied, data on LDT towing impacts is sparse. In this study, portable emissions measurement systems (PEMSs) were used to measure in-use emissions from three common LDTs during towing and non-towing operations. Emission rates were characterized by operating modes defined in the Environmental Protection Agency’s (EPA’s) MOVES (MOtor Vehicle Emissions Simulator) model. The measured emission rates were compared to the default rates used by MOVES, revealing similar overall trends. However, discrepancies between measured rates and MOVES predictions, especially at high speed and high operating modes, indicate a need for refinement in emissions modeling for LDTs under towing operations. Results highlight a general trend of increased CO₂, CO, HC, and NOx when towing a trailer compared to non-towing operations across nearly all operating modes, with distinct CO and HC increases in the higher operating modes. Although emissions were observed to be notably higher in a handful of scenarios, results also indicate that three similar LDTs can have distinctly different emission profiles. Full article

Firstly, this study investigates the spatiotemporal distribution characteristics of the ozone (O₃) pollution in Liaoyuan City using monitoring data from 2015 to 2024. Then, three machine learning models (ML)—random forest (RF), support vector machine (SVM), and artificial neural network (ANN)—are employed to quantify the influence of meteorological and non-meteorological factors on O₃ concentrations. Finally, the HYSPLIT clustering method and CMAQ model are utilized to analyze inter-regional transport characteristics, identifying the causes of O₃ pollution. The results indicate that O₃ pollution in Liaoyuan exhibits a distinct seasonal pattern, with the highest concentrations found in spring and summer, peaking in the afternoon. Among the three ML models, the random forest model demonstrates the best predictive performance (R² = 0.9043). Feature importance identifies NO₂ as the primary driving factor, followed by meteorological conditions in the second quarter and land surface characteristics. Furthermore, regional transport significantly contributes to O₃ pollution, with approximately 80% of air mass trajectories in heavily polluted episodes originating from adjacent industrial areas and the sea. The combined effects of transboundary precursors and O₃ transport with local emissions and meteorological conditions further increase the O₃ pollution level. This study highlights the need to strengthen coordinated NO_X and VOCs emission reductions and enhance regional joint prevention and control strategies in China. Full article

Energy and mobility are currently powered by conventional fuels, and for the specific case of spark ignition (SI) engines, gasoline is dominant. Converting these power-units to hydrogen is an efficient and cost-effective choice for achieving zero-carbon emissions. The use of this alternative fuel can be combined with a circular-economy approach that gives new life to the existing fleet of engines and minimizes the need for added components. In this context, the current work scrutinizes specific aspects of converting a small-size passenger car to hydrogen fueling. The approach combined measurements performed with gasoline and predictive 0D/1D models for correctly including fuel chemistry effects; the experimental data were used for calibration purposes. One particular aspect of H₂ is that it results in lower volumetric efficiency compared to gasoline, and therefore boosting requirements can feature significant changes. The results of the 0D/1D simulations show that one of the main conclusions is that only stoichiometric operation would ensure the reference peak power level; lean fueling featured relative air–fuel ratios too low for ensuring the minimum value of 2 that would allow mitigating NO_x formation. Top speed could be instead feasible in lean conditions, with the same gearbox, but with an extension of the engine speed operating range to 7000 rpm compared to the 3700 rpm reference point with gasoline. Full article

It is important to predict air pollutant emissions from coal-fired power plants using real-time technological parameters to improve environmental efficiency. Since the relationship between emissions and parameters is nonlinear, machine learning models are needed to forecast emissions under various boiler operating modes. This study develops and tests Deep Sparse Transformer Networks for predicting pollutant time series, accounting for long-term dependencies. Data were collected from a 4000 MW coal-fired power plant in Ekibastuz, Kazakhstan, covering 67,527 records for 14 indicators at 10 min intervals. Fractal R/S analysis confirmed long-term memory in SO₂, PM_2.5, and NO_x series, guiding window length selection. The results show that the model achieves slightly better accuracy for SO₂ (R² 0.95–0.38), while NO_x and PM_2.5 have similar dynamics (R² 0.93–0.26). However, accuracy drops notably after 12 points, making the model best suited for short-term forecasts. These findings support environmental monitoring services and help optimize plant parameters, contributing to lower emissions and advancing carbon neutrality goals. Full article

Tillage is one of the most energy-intensive operations in crop production, leading to high fuel consumption and the emission of harmful gases such as CO₂ and NO_x. This study was conducted under real field conditions to explore how soil parameters influence variations in fuel use and exhaust emissions. A machine learning approach based on the XGBoost algorithm was applied to develop predictive models for CO₂ concentrations in exhaust gases and specific fuel consumption. The CO₂ prediction model achieved an accuracy exceeding 80%, while the model for fuel consumption reached over 65%. Although not optimized for high precision, these models offer a valuable basis for preliminary assessments and highlight the potential of data-driven approaches for improving energy efficiency and environmental sustainability in agricultural mechanization. Full article