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Keywords = MSW landfill reliability

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13 pages, 1423 KB  
Article
Modeling of CH4 Emission and Assessment of Energy Potential: A Case Study of Okhla Landfill, South Delhi
by Sitansu Kumar Das, Malaya Mohanty, Satya Ranjan Samal, Sasmita Chand, Jagdeep Kumar Nayak and Kundan Samal
Methane 2026, 5(2), 18; https://doi.org/10.3390/methane5020018 - 11 Jun 2026
Viewed by 382
Abstract
Municipal solid waste (MSW) landfills are major sources of greenhouse gas (GHG) emissions, particularly methane (CH4), which possesses a significantly higher global warming potential than carbon dioxide (CO2). This study evaluates methane emission and energy recovery potential from the [...] Read more.
Municipal solid waste (MSW) landfills are major sources of greenhouse gas (GHG) emissions, particularly methane (CH4), which possesses a significantly higher global warming potential than carbon dioxide (CO2). This study evaluates methane emission and energy recovery potential from the Okhla landfill site, South Delhi, India, using the Landfill Gas Emissions Model (LandGEM). Site-specific model parameters suitable for Indian landfill conditions (k = 0.032 year−1 and L0 = 70 m3 Mg−1) were incorporated to improve prediction accuracy. The results showed that methane generation initiated in 1997 and is expected to continue until 2068. Peak methane emission of approximately 17.15 million m3 year−1 was observed in 2020 due to rapid degradation of the biodegradable organic fraction, especially food waste. The corresponding peak total landfill gas (LFG) and CO2 emissions were approximately 35.43 million m3 year−1 and 17.71 million m3 year−1, respectively. A strong correlation (R2 = 0.9557) between cumulative waste deposition and methane generation confirmed model reliability. The estimated maximum energy recovery potential was approximately 46.19 million kWh year−1. The study further discusses the applicability of the LandGEM under non-engineered landfill conditions commonly observed in developing countries. Overall, the findings emphasize the importance of methane recovery for greenhouse gas mitigation, sustainable waste management, and renewable energy generation in urban landfill systems. Full article
(This article belongs to the Special Issue 250 Years of Methane: From Discovery to Global Challenges)
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15 pages, 1299 KB  
Article
Leachate Analysis of Biodried MSW: Case Study of the CWMC Marišćina
by Anita Ptiček Siročić, Dragana Dogančić, Igor Petrović and Nikola Hrnčić
Processes 2026, 14(1), 141; https://doi.org/10.3390/pr14010141 - 31 Dec 2025
Viewed by 740
Abstract
A major factor in worldwide ecological harm is the large quantity of municipal solid waste generated because of rapid industrialization and population growth. Nowadays, there are numerous mechanical, biological, and thermal waste treatment processes that can reduce the amount of landfilled waste. A [...] Read more.
A major factor in worldwide ecological harm is the large quantity of municipal solid waste generated because of rapid industrialization and population growth. Nowadays, there are numerous mechanical, biological, and thermal waste treatment processes that can reduce the amount of landfilled waste. A variety of analytical tests are conducted to evaluate the potential risks that landfills pose to human health and the environment. Among these, laboratory leaching tests are commonly employed to assess the release of specific waste constituents that may become hazardous to the environment. Municipal solid waste (MSW) management poses significant environmental risks due to leachate contamination in bioreactor landfills, where acidic conditions (pH ≈ 5) can mobilize heavy metals. This study evaluates the reliability of leaching tests for biodried reject MSW from CWMC Marišćina, Croatia, by comparing standard EN 12457-1 and EN 12457-2 methods (L/S = 2 and 10 L/kg) with simulations of aerobic degradation using acetic acid (10 g/L) to maintain pH = 5 over 9 days. Waste composition analysis revealed plastics (35%), paper/cardboard (25%), metals (15%), and glass (10%) as dominant fractions. Although the majority of parameters determined through standard leaching tests remain below the maximum permissible limits for non-hazardous waste, simulations under acidic conditions demonstrated substantial increases in eluate concentrations between days 6 and 9: Hg (+1500%), As (+1322%), Pb (+1330%), Ni (+786%), and Cd (+267%), with TDS rising 33%. These results highlight the underestimation of risks by conventional tests, emphasizing the need for pH-dependent methods to predict in situ leachate behavior in MBO-treated waste and support improved EU landfill regulations for enhanced environmental protection. Full article
(This article belongs to the Special Issue Innovations in Solid Waste Treatment and Resource Utilization)
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19 pages, 9507 KB  
Article
Mechanical Strength of Waste Materials: A Cone Penetration Testing-Based Geotechnical Assessment for the Reclamation of Landfills
by Marek Bajda, Mariusz Lech, Katarzyna Markowska-Lech, Piotr Osiński and Eugeniusz Koda
Materials 2025, 18(9), 2130; https://doi.org/10.3390/ma18092130 - 6 May 2025
Cited by 2 | Viewed by 1488
Abstract
The stability and mechanical properties of municipal solid waste (MSW) deposits in closed landfills are critical for safe land reclamation and infrastructure development. This study employs Cone Penetration Testing (CPT) to evaluate the geotechnical parameters of aged waste at three closed landfill sites [...] Read more.
The stability and mechanical properties of municipal solid waste (MSW) deposits in closed landfills are critical for safe land reclamation and infrastructure development. This study employs Cone Penetration Testing (CPT) to evaluate the geotechnical parameters of aged waste at three closed landfill sites in central Poland. Key parameters, including shear strength, internal friction angle, density, and liquidity index, were assessed to determine slope stability and bearing capacity for future redevelopment. Due to the heterogeneous nature of MSW, CPT results were analyzed in conjunction with empirical correlations and nomograms to improve accuracy, so the parameters can be used for future numerical modeling and proposing new computational approaches for landfill body elastic and mechanical behavior predictions. The findings indicate significant variability in landfill waste mechanical properties, influenced by waste composition, decomposition stage, and compaction history. The study highlights CPT’s reliable detremination of geotechnical parameters for landfill restoration projects, particularly for infrastructure, creating the potential for green energy and sustainable development. The results contribute to improving engineering practices in landfill restoration and ensuring the long-term stability of post-closure land use. This study also contributes to obtaining reliable results on anthropogenic waste material mechanical parameters at both the material point and at the overall structural scale, benefiting future computational methods and modeling approaches for analyzing structural and geotechnical safety of such complex and demanding structures as landfills. Full article
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13 pages, 1259 KB  
Article
Energy Production from Landfill Gas: Short-Term Management
by Nuno Soares Domingues
Energies 2025, 18(8), 1974; https://doi.org/10.3390/en18081974 - 11 Apr 2025
Cited by 4 | Viewed by 2124
Abstract
An increasing lack of raw materials, resource depletion, environmental impacts and other concerns have changed the way the population faces garbage disposal and municipalities implement waste management strategies. The aggravated global rise in municipal solid waste (MSW) generation has led to a new [...] Read more.
An increasing lack of raw materials, resource depletion, environmental impacts and other concerns have changed the way the population faces garbage disposal and municipalities implement waste management strategies. The aggravated global rise in municipal solid waste (MSW) generation has led to a new stage in full development, with objectives and targets set by the European Union regarding reducing the production of MSW. The targets also include the increasing selective collection, reuse, recycling and recovery (organic and energetic) of the waste produced. At the same time, the European Union has also set caps for the greenhouse gas emissions and for increasing the use of alternative renewable energy sources. In this context, one of the sources of renewable energy that is beginning to be used to produce electricity in our country is biogas. Finally, AD promotes the development of a circular economy. The present study introduces the formalism for a computer application that simulates the technical–economic behaviour of the short-term management of biogas for the conversion of electricity, and the mathematical model is formulated as a mathematical programming problem with constraints. A simulation for a case study of short-term management is given using the real landfill data available. The case study proves the ability of the LandGEM, despite some authors’ support that the Tabasaran–Rettenberger model provided a more reliable estimate, especially when compared to actual landfill data. The present paper is a contribution to the optimisation of the management of electricity from the use of biogas, namely the second phase of the Strategic Plan for Urban Waste. In addition to complying with the legislation in force, the use of biogas to produce electricity is an added value for the concessionaires of waste treatment and final destination units, as this alternative energy source can provide not only self-sufficiency in electricity for these units but also the export of surplus energy to the National Electricity Grid, thus contributing to the self-sustaining management and energy flexibility that is intended for these infrastructures. Full article
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17 pages, 2768 KB  
Article
An Environmental Assessment of Municipal Solid Waste Management Strategies in Riyadh, Saudi Arabia: A Comparative Life Cycle Analysis
by Mohammed Almansour and Mohammad Akrami
Sustainability 2024, 16(20), 9111; https://doi.org/10.3390/su16209111 - 21 Oct 2024
Cited by 7 | Viewed by 9361
Abstract
The environmental implications of various municipal solid waste (MSW) management systems in Riyadh, Kingdom of Saudi Arabia, were analysed considering the Riyadh Green Initiative through a comprehensive Life Cycle Assessment (LCA). This study evaluates five distinct scenarios: unsanitary landfilling (Sc0), incineration (Sc1), and [...] Read more.
The environmental implications of various municipal solid waste (MSW) management systems in Riyadh, Kingdom of Saudi Arabia, were analysed considering the Riyadh Green Initiative through a comprehensive Life Cycle Assessment (LCA). This study evaluates five distinct scenarios: unsanitary landfilling (Sc0), incineration (Sc1), and a combination of technologies such as anaerobic digestion (AD) and a material recovery facility (MRF) in scenarios Sc2–Sc4. These scenarios were assessed using GaBi 9.2.1 software, employing the impact methodology outlined by CML (2001) to evaluate eight impact categories, including Global Warming and Acidification Potentials, among others. The findings indicate that scenarios incorporating the treatment of 100% of recyclable and organic waste through AD exhibited substantial environmental benefits. Additionally, Sc2 demonstrated the lowest environmental burdens across all impact categories. In contrast, Sc0 ranked the worst in all categories due to the absence of gas and leachate treatment. The results were shown to be reliable when compared qualitatively to previous studies. Furthermore, a sensitivity analysis was conducted to assess this study’s system boundaries and the impact of the MRF rate. Overall, this research provides valuable insights for optimising MSW management practices in Riyadh, aiming to reduce their environmental impacts and align with the goals of the Riyadh Green Initiative. Full article
(This article belongs to the Special Issue Sustainable Waste Management in the Context of Circular Economy)
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19 pages, 5089 KB  
Article
Analyzing MSW Landfill Failures: Stability and Reliability Evaluations from Five International Case Studies
by Filip Dodigovic, Kreso Ivandic, Anja Bek and Jasmin Jug
Geotechnics 2024, 4(3), 824-842; https://doi.org/10.3390/geotechnics4030043 - 24 Aug 2024
Cited by 3 | Viewed by 3607
Abstract
This study investigates five cases of municipal solid waste (MSW) landfill slope failures in the USA, China, Sri Lanka, and Greece, with the aim of assessing the safety margins and reliability of these slopes. The stability and reliability of the landfill slopes were [...] Read more.
This study investigates five cases of municipal solid waste (MSW) landfill slope failures in the USA, China, Sri Lanka, and Greece, with the aim of assessing the safety margins and reliability of these slopes. The stability and reliability of the landfill slopes were evaluated under both static and seismic loading conditions, using pre-failure geometries and geotechnical data, with analyses conducted in accordance with Eurocode 7, employing all three design approaches. Under static loading, the factors of safety were close to unity, and reliability indexes ranged from 1.0 to 2.8, both falling below the recommended values set by Eurocode. The landfill slopes failed to meet the stability criteria in Design Approaches 2 and 3, while in Design Approach 1, four out of five landfills met the criteria. Under seismic conditions, safety factors and reliability indexes were significantly lower than the prescribed criteria in all analyses. Sensitivity analyses revealed that in two cases, unit weight and friction angle were the dominant parameters, while cohesion was the dominant parameter in one case. The findings of this study underscore the importance of establishing minimum design requirements for MSW landfill slope stability to mitigate potential risks to public health and the environment. Full article
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13 pages, 1847 KB  
Article
Reliability of Municipal Solid Waste Landfills within the Eurocode Framework
by Filip Dodigović and Krešo Ivandić
Sustainability 2024, 16(2), 675; https://doi.org/10.3390/su16020675 - 12 Jan 2024
Cited by 1 | Viewed by 2142
Abstract
Municipal solid waste (MSW) landfill slope failures can have significant consequences for the economy, environment, and human health. One potential cause of slope failure is insufficient reliability, resulting from inadequate design. The usual practice in the design of MSW landfills involves utilizing established [...] Read more.
Municipal solid waste (MSW) landfill slope failures can have significant consequences for the economy, environment, and human health. One potential cause of slope failure is insufficient reliability, resulting from inadequate design. The usual practice in the design of MSW landfills involves utilizing established geotechnical codes, such as Eurocode 7 (EC7), to perform slope stability assessments. Considering the substantial heterogeneity of MSW relative to soil, questions arise regarding the justification of such an approach in the design of MSW landfills. This study examines the suitability of applying EC7 in MSW landfill design, analyzing the stability and reliability of landfill slopes across various heights, front slope angles, design approaches, and consequence classes. This study finds that, in most cases considered, EC7 does not ensure an adequate level of reliability for MSW landfill slopes. Therefore, it is suggested that EC7 should be complemented with specific guidelines for incorporating MSW in geotechnical analyses to achieve the desired structural reliability. Adopting this strategy will not only enhance the reliability of landfill design but also promote the development of solutions that are economically and environmentally sustainable. Full article
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18 pages, 3961 KB  
Article
Study of Modified Primary Compression Index Tests and a Regression Model for Municipal Solid Waste Considering the Temperature Effect
by Yaji Zhou, Xun Wu and Yang Yang
Appl. Sci. 2024, 14(1), 348; https://doi.org/10.3390/app14010348 - 29 Dec 2023
Cited by 3 | Viewed by 2107
Abstract
The modified primary compression index (MPCI) of municipal solid waste (MSW) is an important parameter for describing the primary consolidation settlement of MSW. It is beneficial to calculate the settlement and storage capacity of landfills accurately by calculating the MPCI of MSW correctly. [...] Read more.
The modified primary compression index (MPCI) of municipal solid waste (MSW) is an important parameter for describing the primary consolidation settlement of MSW. It is beneficial to calculate the settlement and storage capacity of landfills accurately by calculating the MPCI of MSW correctly. This article studies the primary consolidation compression characteristics and influencing factors of MSW through a consolidation experiment considering temperature control. The experimental results show that the MPCI increases with an increase in temperature, decreases with an increase in dry weight, increases with an increase in water content, and increases with an increase in organic matter content. According to the above findings, an MPCI regression fitting model was established. The reliability and accuracy of the model was validated by the experimental results of the indoor bioreactor test considering temperature control. Full article
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19 pages, 5819 KB  
Article
Effect of Material Composition on Geotechnical Properties—Study on Synthetic Municipal Solid Waste
by Vidit Singh and Taro Uchimura
Geotechnics 2023, 3(2), 397-415; https://doi.org/10.3390/geotechnics3020023 - 18 May 2023
Cited by 11 | Viewed by 4234
Abstract
The geotechnical properties of municipal solid waste (MSW) are required to design and maintain a landfill structure. Several landfill failures occurring in recent times have led to the loss of revenue and people. This study aims to investigate the impact of material composition [...] Read more.
The geotechnical properties of municipal solid waste (MSW) are required to design and maintain a landfill structure. Several landfill failures occurring in recent times have led to the loss of revenue and people. This study aims to investigate the impact of material composition on the geotechnical properties of fresh synthetic municipal solid waste (SMSW), which imitates the real waste produced in India. The study aims to understand the contribution of each material, such as paper, plastic, and organic matter, on the shear behavior of SMSW, which is essential for designing landfills and ensuring their safety and performance. A modified proctor test and a large-scale direct shear test were used to determine the unit weight and shear strength of SMSW, respectively. The synthetic waste’s unit weight and shear strength were found to be consistent with values that had already been published. The shear strength parameters of SMSW include cohesion, which was determined to be at the lower bound of the envelope, and friction angle within the envelope. Lower unit weight, less fine soil-like material, and dry material are thought to be the causes of the observed variation in the behavior of actual waste in synthetic waste. The findings of this experiment demonstrated that as the proportion of paper increases, the cohesion (C) increases, and the friction angle (Φ) decreases. Cohesion and friction angle both decrease as the proportion of plastic increases. Cohesion and friction angle both increase with an increase in the organic percentage. These findings demonstrate that each material contributes differently to the shear behavior of SMSW. Hence, the material composition’s effect should be considered while designing a landfill for improved safety and reliability. Full article
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17 pages, 3330 KB  
Article
Transient and Quasi-Steady-State Analytical Methods for Simulating a Vertical Gas Flow in a Landfill with Layered Municipal Solid Waste
by Xun Wu, Jianyong Shi, Tao Zhang, Yuping Li and Shi Shu
Mathematics 2022, 10(19), 3658; https://doi.org/10.3390/math10193658 - 6 Oct 2022
Cited by 3 | Viewed by 2211
Abstract
The exploration of gas pressure and its distribution in landfills is a principal concern for the design and management of municipal solid waste (MSW) landfills. A one-dimensional analytical model was proposed to simulate a vertical gas flow in a landfill with layered MSWs. [...] Read more.
The exploration of gas pressure and its distribution in landfills is a principal concern for the design and management of municipal solid waste (MSW) landfills. A one-dimensional analytical model was proposed to simulate a vertical gas flow in a landfill with layered MSWs. The transient analytical solution was obtained by the method of superposition and eigenfunction expansion and verified by a semi-analytical solution and numerical simulation. According to the results of a parametric analysis by the transient analytical solution, a vertical gas flow in landfills can be simplified to a quasi-steady-state flow. A quasi-steady-state analytical solution for simulating a vertical gas flow in a landfill with layered MSW is proposed. The quasi-steady-state analytical solution showed good agreement with the transient solution. Both temporal and spatial variations of the gas generation rate in MSW landfills were considered in the transient and quasi-steady-state analytical methods. A comparison between the proposed quasi-steady-state solution and the previously described steady-state solution showed that using the average gas generation rate or the gas generation rate corresponding to the average age of the MSW layer in the steady-state solution resulted in an error in the estimation of the gas pressure in landfills. The proposed solutions are reliable and can provide a reference for the design, management, and subsequent restoration of landfills. Full article
(This article belongs to the Section E: Applied Mathematics)
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20 pages, 8533 KB  
Article
Identifying and Ranking Landfill Sites for Municipal Solid Waste Management: An Integrated Remote Sensing and GIS Approach
by Bilal Aslam, Ahsen Maqsoom, Muhammad Dawar Tahir, Fahim Ullah, Muhammad Sami Ur Rehman and Mohammed Albattah
Buildings 2022, 12(5), 605; https://doi.org/10.3390/buildings12050605 - 6 May 2022
Cited by 54 | Viewed by 11058
Abstract
Disposal of municipal solid waste (MSW) is one of the significant global issues that is more evident in developing nations. One of the key methods for disposing of the MSW is locating, assessing, and planning for landfill sites. Faisalabad is one of the [...] Read more.
Disposal of municipal solid waste (MSW) is one of the significant global issues that is more evident in developing nations. One of the key methods for disposing of the MSW is locating, assessing, and planning for landfill sites. Faisalabad is one of the largest industrial cities in Pakistan. It has many sustainability challenges and planning problems, including MSW management. This study uses Faisalabad as a case study area and humbly attempts to provide a framework for identifying and ranking landfill sites and addressing MSW concerns in Faisalabad. This method can be extended and applied to similar industrial cities. The landfill sites were identified using remote sensing (RS) and geographic information system (GIS). Multiple datasets, including normalized difference vegetation, water, and built-up areas indices (NDVI, NDWI, and NDBI) and physical factors including water bodies, roads, and the population that influence the landfill site selection were used to identify, rank, and select the most suitable site. The target area was distributed into 9 Thiessen polygons and ranked based on their favorability for the development and expansion of landfill sites. 70% of the area was favorable for developing and expanding landfill sites, whereas 30% was deemed unsuitable. Polygon 6, having more vegetation, a smaller population, and built-up areas was declared the best region for developing landfill sites and expansion as per rank mean indices and standard deviation (SD) of RS and vector data. The current study provides a reliable integrated mechanism based on GIS and RS that can be implemented in similar study areas and expanded to other developing countries. Accordingly, urban planning and city management can be improved, and MSW can be managed with dexterity. Full article
(This article belongs to the Section Construction Management, and Computers & Digitization)
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29 pages, 16626 KB  
Article
Insights for Landfill Site Selection Using GIS: A Case Study in the Tanjero River Basin, Kurdistan Region, Iraq
by Arsalan Ahmed Othman, Ahmed K. Obaid, Diary Ali Mohammed Al-Manmi, Mohammad Pirouei, Sarkawt Ghazi Salar, Veraldo Liesenberg, Ahmed F. Al-Maamar, Ahmed T. Shihab, Younus I. Al-Saady and Zaid T. Al-Attar
Sustainability 2021, 13(22), 12602; https://doi.org/10.3390/su132212602 - 15 Nov 2021
Cited by 25 | Viewed by 8840
Abstract
The increasing world population and the growing quantity of solid waste have become a challenging problem facing governments and policy makers because of the scarcity of suitable sites for new landfills and the negative perception of these sites by the people. This study [...] Read more.
The increasing world population and the growing quantity of solid waste have become a challenging problem facing governments and policy makers because of the scarcity of suitable sites for new landfills and the negative perception of these sites by the people. This study aims to evaluate the performance of different Multi-Criteria Decision-Analysis (MCDA) approaches using remote sensing and Geographic Information System (GIS) data for identifying suitable landfill sites (LFSs). We evaluated the methodologies used by various investigators and selected appropriate ones as suitable sites for Municipal Solid Waste (MSW) landfill in the Tanjero River Basin (TRB) in the Iraqi Kurdistan region. We applied Boolean Overlay (BO), Weighted Sum Method (WSM), Weighted Product Method (WPM), Analytic Hierarchy Process (AHP), and Technique for Order Performance by Similarity to an Ideal Solution (TOPSIS) to allow combined use of 15 thematic layers as predictive factors (PFs). In this study, we applied the Topographic Position Index (TPI) for the first time to select MSW LFSs. Almost all methods showed reliable results and we identified eight suitable sites situated in the western part of the TRB having total area of ~18.35 km2. The best accuracy was achieved using the AHP approach. This paper emphasizes that the approach of the used method is useful for selecting LFSs in other areas, which are located in similar environments. Full article
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27 pages, 5054 KB  
Article
Coupling Fuzzy Multi-Criteria Decision-Making and Clustering Algorithm for MSW Landfill Site Selection (Case Study: Lanzhou, China)
by Jiamin Liu, Yueshi Li, Bin Xiao and Jizong Jiao
ISPRS Int. J. Geo-Inf. 2021, 10(6), 403; https://doi.org/10.3390/ijgi10060403 - 11 Jun 2021
Cited by 24 | Viewed by 5271
Abstract
The siting of Municipal Solid Waste (MSW) landfills is a complex decision process. Existing siting methods utilize expert scores to determine criteria weights, however, they ignore the uncertainty of data and criterion weights and the efficacy of results. In this study, a coupled [...] Read more.
The siting of Municipal Solid Waste (MSW) landfills is a complex decision process. Existing siting methods utilize expert scores to determine criteria weights, however, they ignore the uncertainty of data and criterion weights and the efficacy of results. In this study, a coupled fuzzy Multi-Criteria Decision-Making (MCDM) approach was employed to site landfills in Lanzhou, a semi-arid valley basin city in China, to enhance the spatial decision-making process. Primarily, 21 criteria were identified in five groups through the Delphi method at 30 m resolution, then criteria weights were obtained by DEMATEL and ANP, and the optimal fuzzy membership function was determined for each evaluation criterion. Combined with GIS spatial analysis and the clustering algorithm, candidate sites that satisfied the landfill conditions were identified, and the spatial distribution characteristics were analyzed. These sites were subsequently ranked utilizing the MOORA, WASPAS, COPRAS, and TOPSIS methods to verify the reliability of the results by conducting sensitivity analysis. This study is different from the previous research that applied the MCDM approach in that fuzzy MCDM for weighting criteria is more reliable compared to the other common methods. Full article
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13 pages, 2388 KB  
Article
New Analytical Method for Determination of Phthalates in Wastewater by on Line LC-GC-MS Using the TOTAD Interface and Fraction Collector
by Francisco J. Espinosa, Rosa M. Toledano, Juan C. Andini, Jose M. Cortés and Ana M. Vázquez
Processes 2021, 9(6), 920; https://doi.org/10.3390/pr9060920 - 24 May 2021
Cited by 9 | Viewed by 4764
Abstract
There is an increasing demand for automatic, reliable and sensitive analytical methods for determining trace levels of phthalic acid esters (PAEs) in environmental samples. While on line coupled liquid chromatography-gas chromatography (LC-GC) has been proof to be a powerful tool for trace-level analyses [...] Read more.
There is an increasing demand for automatic, reliable and sensitive analytical methods for determining trace levels of phthalic acid esters (PAEs) in environmental samples. While on line coupled liquid chromatography-gas chromatography (LC-GC) has been proof to be a powerful tool for trace-level analyses in complex matrices, the present work presents a new totally automated on line LC-GC method, using the Through Oven Transfer Adsorption Desorption (TOTAD) interface, for the analysis of four of the main phthalates, dibuthyl phthalate (DBP), diethyl phthalate (DEP), dimethyl phthalate (DMP) and diethylhexyl phthalate (DEHP), in a matrix as complex as leachate. The sample is directly injected into the LC injector valve with no sample pretreatment other than simple filtration. The LC step separates the target analytes from matrix interference. Two different LC fractions are collected in a purposely designed fraction collector and then transferred to the TOTAD interface, which concentrates the analytes, totally eliminates the solvent and transfers the analytes to the GC-MS system, where the analysis is carried out. The LOD of the method varied from 0.1 µg/L (DEHP) to 1.4 µg/L (DMP), RSD for retention time below 0.14% and for absolute peak areas below 12% and linearity from 1 µg/L to 1000 µg/L (R2 > 0.99), except in the case of DEHP (linearity from 1 to 250 µg/L, R2 = 0.94). The method was applied to the analysis of the target analytes in samples collected from a municipal solid waste (MSW) landfill in Rosario (Argentina). Full article
(This article belongs to the Special Issue Novel Technologies in Trace Elements Determination)
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