Search Results (16)

Inspired by the phenomenology of high-critical-temperature superconducting cuprates, we investigate the effect of an anisotropic scattering rate on the magnetoresistance of a metal, relying on Chambers’ solution to the Boltzmann equation. We find that if the scattering rate is enhanced near points of the Fermi surface with a locally higher density of states, an extended regime is found where the magnetoresistance varies linearly with the magnetic field. We then apply our results to fit the experimental magnetoresistance of La_1.6−xNd_0.4Sr_xCuO₄ and speculate about the possible source of anisotropic scattering. Full article

To investigate proposed ferromagnetic fluctuations in the so-called single-layer Bi-2201 and La-214 high-T_c cuprates, we performed magnetization and electrical resistivity measurements using single-layer Tl-2201 cuprates Tl₂Ba₂CuO_6+δ and La-214 La_2−xSr_xCuO₄ in the heavily overdoped regime. Magnetization of Tl₂Ba₂CuO_6+δ and La_2−xSr_xCuO₄ exhibited the tendency to be saturated in high magnetic fields at low temperatures, suggesting the precursor behavior toward the formation of a ferromagnetic order. It was found that the power of temperature n obtained from the temperature dependence of the electrical resistivity is ~4/3 and ~5/3 for Bi-2201 and La_2−xSr_xCuO₄, respectively, and is ~4/3 at high temperatures and ~5/3 at low temperatures in Tl₂Ba₂CuO_6+δ. These results suggest that two- and three-dimensional ferromagnetic fluctuations exist in Bi-2201 and La_2−xSr_xCuO₄, respectively. In Tl₂Ba₂CuO_6+δ, it is suggested that the dimension of ferromagnetic fluctuations is two at high temperatures and three at low temperatures, respectively. The dimensionality of ferromagnetic fluctuations is understood in terms of the dimensionality of the crystal structure and the bonding of atoms in the blocking layer. Full article

The fabrication of trilayer superconductor-insulator-superconductor (SIS) Josephson junctions with high-temperature superconductor (HTS) electrodes requires atomically perfect interfaces. Therefore, despite great interest and efforts, this remained a challenge for over three decades. Here, we report the discovery of a new family of metastable materials, La_2−xSr_xZnO₄ (LSZO), synthesized by atomic-layer-by-layer molecular beam epitaxy (ALL-MBE). We show that LSZO is insulating and epitaxially compatible with an HTS compound, La_2−xSr_xCuO₄ (LSCO). Since the “parent” compound La₂ZnO₄ (LZO) is easier to grow, here we focus on this material as our insulating layer. Growing LZO at very low temperatures to reduce cation interdiffusion makes LSCO/LZO interfaces atomically sharp. We show that in LSCO/LZO/LSCO trilayers, the superconducting properties of the LSCO electrodes remain undiminished, unlike in previous attempts with insulator barriers made of other materials. This opens prospects to produce high-quality HTS tunnel junctions. Full article

Focused ion beam (FIB) milling is a mask-free lithography technique that allows the precise shaping of 3D materials on the micron and sub-micron scale. The recent discovery of electronic nematicity in La_2−xSr_xCuO₄ (LSCO) thin films triggered the search for the same phenomenon in bulk LSCO crystals. With this motivation, we have systematically explored FIB patterning of bulk LSCO crystals into micro-devices suitable for longitudinal and transverse resistivity measurements. We found that several detrimental factors can affect the result, ultimately compromising the possibility of effectively using FIB milling to fabricate sub-micrometer LSCO devices, especially in the underdoped regime. Full article

First-principles calculations for underdoped La_2−xSr_xCuO₄ (LSCO) have revealed a Fermi surface consisting of spin-triplet (KS) particles at the antinodal Fermi-pockets and spin-singlet (SS) particles at the nodal Fermi-arcs in the presence of AF local order. By performing a unique method of calculating the electronic-spin state of overdoped LSCO and by measurement of the spin-correlation length by neutron inelastic scattering, the origin of the phase-diagram, including the pseudogap phase in the high temperature superconductor, Sr-doped copper-oxide LSCO, has been elucidated. We have theoretically solved the long-term problem as to why the angle-resolved photoemission spectroscopy (ARPES) has not been able to observe Fermi pockets in the Fermi surface of LSCO. As a result, we show that the pseudogap region is bounded below the characteristic temperature T*(x) and above the superconducting transition temperature T_c(x) in the T vs. x phase diagram, where both the AF order and the KS particles in the Fermi pockets vanish at T*(x), whilst KS particles contribute to d-wave superconductivity below T_c. We also show that the relationship T*(x_c) = T_c(x_c) holds at x_c = 0.30, which is consistent with ARPES experiments. At T*(x), a phase transition occurs from the pseudogap phase to an unusual metallic phase in which only the SS particles exist. Full article

C-axis trilayer cuprate Josephson junctions are essential for basic science and digital circuit applications of high-temperature superconductors. We present a method for probing the interface perfection in La_2−xSr_xCuO₄ (LSCO)-LaSrAlO₄ (LSAO)-La_2−xSr_xCuO₄ trilayer junctions. A series of LSCO-LSAO superlattices with atomically smooth surfaces and sharp interfaces were grown by the atomic-layer-by-layer molecular beam epitaxy (ALL-MBE) technique. We have systematically varied the thickness of LSCO and LSAO layers with monolayer precision. By studying the mutual inductance and electrical transport in these superlattices, we detect the non-superconducting (“dead”) layers at the interfaces and quantify their thicknesses. Our results indicate that two optimally doped LSCO monolayers just above and below the one monolayer LSAO barrier are no longer superconducting, rendering the actual barrier thickness of five monolayers. Next, we have shown that introducing a protective highly-overdoped LSCO layer reduces the thickness of dead layers by one or two monolayers. Full article

We present methods to create devices that utilize the high-temperature superconductor La_2-xSr_xCuO₄ grown by atomic layer-by-layer molecular beam epitaxy (ALL-MBE). The ALL-MBE synthesis technique provides atomically precise interfaces necessary for the tunnel junctions, Josephson junctions, and dyon detection devices that will be considered. A series of microfabrication processing steps using established techniques are given for each device, and their details are discussed. These procedures are easily extended to generate more complex designs and could be suitable for a wider variety of materials. Full article

Atomic layer-by-layer molecular beam epitaxy (ALL-MBE) combined with ozone is one of the best methods to fabricate single-crystal thin films of complex oxides. Cuprate such as La_2−xSr_xCuO₄ (LSCO) is a representative complex-oxide high-temperature superconductor (HTS) material. Our group utilizes this method to produce high-quality single-crystal HTS films with atomically smooth surfaces and interfaces. In addition, ALL-MBE enables us to engineer multilayer heterostructures with atomic precision. This allows the fabrication of tunnel junctions, various nanostructures, and other HTS devices of interest for superconducting electronics. We have synthesized over three thousand LSCO thin films in the past two decades. These films’ structural and electronic properties have been studied and characterized by various methods. Here, we distill the extensive experience we accumulated into a step-by-step protocol to fabricate atomically perfect LSCO films. The recipe includes substrate preparation, ozone generation and distillation, source calibration, the in situ monitoring of the film synthesis, post-growth annealing, and ex situ characterization. It discloses a reproducible way to fabricate single-crystal LSCO films for basic research and HTS electronic applications. Full article

In La₂-_xSr_xCuO₄ (LSCO), a prototype high-temperature superconductor (HTS) cuprate, a nonzero transverse voltage is observed in zero magnetic fields. This is important since it points to the breaking of the rotational symmetry in the electron fluid, the so-called electronic nematicity, presumably intrinsic to LSCO (and other cuprates). An alternative explanation is that it arises from extrinsic factors such as the film’s inhomogeneity or some experimental artifacts. We confront this hypothesis with published and new experimental data, focusing on the most direct and sensitive probe—the angle-resolved measurements of transverse resistivity (ARTR). The aggregate experimental evidence overwhelmingly refutes the extrinsic scenarios and points to an exciting new effect—intrinsic electronic nematicity. Full article

Cu-content La_1−xSr_xNi_1−yCu_yO_3−δ perovskites with A-site strontium doping have been tuned as cobalt-free cathode materials for high-performance anode-supported SOFCs, working at an intermediate-temperature range. All obtained oxides belong to the R-3c trigonal system, and phase transitions from the R-3c space group to a Pm-3m simple perovskite have been observed by HT-XRD studies. The substitution of lanthanum with strontium lowers the phase transition temperature, while increasing the thermal expansion coefficient (TEC) and oxygen non-stoichiometry δ of the studied materials. The thermal expansion is anisotropic, and TEC values are similar to commonly used solid electrolytes (e.g., 14.1 × 10⁻⁶ K⁻¹ for La_0.95Sr_0.05Ni_0.5Cu_0.5O_3−δ). The oxygen content of investigated compounds has been determined as a function of temperature. All studied materials are chemically compatible with GDC-10 but react with LSGM and 8YSZ electrolytes. The anode-supported SOFC with a La_0.95Sr_0.05Ni_0.5Cu_0.5O_3−δ cathode presents an excellent power density of 445 mW·cm⁻² at 650 °C in humidified H₂. The results indicate that La_1−xSr_xNi_1−yCu_yO_3−δ perovskites with strontium doping at the A-site can be qualified as promising cathode candidates for anode-supported SOFCs, yielding promising electrochemical performance in the intermediate-temperature range. Full article

The nano-size effects of high-T_c cuprate superconductor La_2−xSr_xCuO₄ with x = 0.20 are investigated using X-ray diffractometry, Transmission electron microscopy, and muon-spin relaxation (μSR). It is investigated whether an increase in the bond distance of Cu and O atoms in the conducting layer compared to those of the bulk state might affect its physical and magnetic properties. The μSR measurements revealed the slowing down of Cu spin fluctuations in La_2−xSr_xCuO₄ nanoparticles, indicating the development of a magnetic correlation at low temperatures. The magnetic correlation strengthens as the particle size reduces. This significantly differs from those observed in the bulk form, which show a superconducting state below T_c. It is indicated that reducing the particle size of La_2−xSr_xCuO₄ down to nanometer size causes the appearance of magnetism. The magnetism enhances with decreasing particle size. Full article

In 1986 Bednorz and Műller discovered high temperature superconductivity in copper oxides by chemically doping holes into La₂CuO₄ (LCO), the antiferromagnetic insulator. Despite intense experimental and theoretical research during the past 34 years, no general consensus on the electronic-spin structures and the origin of pseudogap has been obtained. In this circumstance, we performed a first-principles calculation of underdoped cuprate superconductors La_2-xSr_xCuO₄ (LSCO) within the meta-generalized gradient approximation of the density functional theory. Our calculations clarify first the important role of the anti Jahn-Teller (JT) effect, the backward deformation against the JT distortion in La₂CuO₄ by doping extra holes. The resulting electronic structure agrees with the two-component theory provided by the tight-binding model of Kamimura and Suwa (K-S), which has been also used to elucidate the d-wave superconductivity. Our first-principles calculation thus justifies the K-S model and demonstrates advanced understanding of cuprates. For example, the remarkable feature of our calculations is the appearance of the spin-polarized band with a nearly flat-band character, showing the peaky nature in the density of states at the Fermi level. Full article

We used an electronic phase separation approach to interpret the scaling between the low-temperature superfluid density average ${\rho }_{\mathrm{sc}}\left(0\right)$ and the superconducting critical temperature $T_{\mathrm{c}}$ on overdoped La ${}_{2-x}$ Sr ${}_x$ CuO ${}_4$ films. Guided by the observed nematic and incommensurate charge ordering (CO), we performed simulations with a free energy that reproduces charge domains with wavelength ${\lambda }_{CO}$ and provides a scale to local superconducting interactions. Under these conditions a complex order parameter with amplitude ${\mathsf{\Delta }}_d\left(r_i\right)$ and phase $\theta \left(r_i\right)$ may develop at a domain i. We assumed that these domains are coupled by Josephson energy $E_{\mathrm{J}}\left(r_{ij}\right)$ , proportional to the local superfluid density ${\rho }_{\mathrm{sc}}\left(r_{ij}\right)$ . Long-range order occured when the average $E_{\mathrm{J}}\left(T_{\mathrm{c}}\right)$ is $\sim k_{\mathrm{B}}{T}_{\mathrm{c}}$ . The linear ${\rho }_{sc}\left(0\right)$ vs. $T_{\mathrm{c}}$ relation was satisfied whenever CO was present, even with almost vanishing charge amplitudes. Full article

Ionic liquids have recently been used as means of modulating the charge carrier properties of cuprates. The mechanism behind it, however, is still a matter of debate. In this paper we report experiments on ionic liquid gated ultrathin La_2−xSr_xCuO₄ films. Our results show that the electrostatic part of gating has limited influence in the conductance of the cuprate in the gate voltage range of 0 to $-2$ V. A non-electrostatic mechanism takes over for gate voltages below $-2$ V. This mechanism most likely changes the oxygen concentration of the film. The results presented are in line with previous X-ray based studies on ionic liquid gating induced oxygenation of the cuprate materials YBa₂Cu₃O_7−x and La_2−xSr_xCuO₄. Full article

Perovskite oxides La_1−xSr_xCo_1−yFe_yO_3–δ (LSCF) have been extensively investigated and developed as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFCs) due to mixed ionic–electronic conductivity and high electrooxygen reduction activity for oxygen reduction. Recent literature investigations show that cathode performances can be improved by metal surface modification or B-site substitution on LSCF. Although the specific reaction mechanism needs to be further investigated, the promoting effect of metal species in enhancing oxygen surface exchange and oxygen bulk diffusion is well recognized. To our knowledge, no previous reviews dealing with the effect of metal promotion on the cathodic performances of LSCF materials have been reported. In the present review, recent progresses on metal (Pd, Pt, Ag, Cu, Zn, Ni) promotion of LSCF are discussed focusing on two main aspects, the different synthesis approaches used (infiltration, deposition, solid state reaction, one pot citrate method) and the effects of metal promotion on structural properties, oxygen vacancies content and cathodic performances. The novelty of the work lies in the fact that the metal promotion at the B-site is discussed in detail, pointing at the effects produced by two different approaches, the LSCF surface modification by the metal or the metal ion substitution at the B-site of the perovskite. Moreover, for the first time in a review article, the importance of the combined effects of oxygen dissociation rate and interfacial oxygen transfer rate between the metal phase and the cathode phase is addressed for metal-promoted LSCF and compared with the un-promoted oxides. Perspectives on new research directions are shortly given in the conclusion. Full article