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Keywords = InGaN

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13 pages, 2292 KB  
Article
Investigation on Wavelength-Dependent Light Extraction Efficiency of InGaN-Based Micro-LED Structures Using Numerical Simulations
by Chibuzo Onwukaeme and Han-Youl Ryu
Photonics 2026, 13(3), 289; https://doi.org/10.3390/photonics13030289 - 17 Mar 2026
Viewed by 347
Abstract
The external quantum efficiency (EQE) of InGaN-based LEDs typically decreases as wavelength shifts from blue to green to red. While this trend has often been attributed to the internal quantum efficiency of InGaN quantum wells (QWs), the influence of light extraction efficiency (LEE) [...] Read more.
The external quantum efficiency (EQE) of InGaN-based LEDs typically decreases as wavelength shifts from blue to green to red. While this trend has often been attributed to the internal quantum efficiency of InGaN quantum wells (QWs), the influence of light extraction efficiency (LEE) on the wavelength-dependent EQE has received less attention. In this study, we numerically investigated the LEE of blue, green, and red InGaN micro-LED structures using finite-difference time-domain simulations, including the dispersion of composite materials. We first optimized the distance between the QW and the Ag reflector for each color, then evaluated the total LEE and the LEE within a 20° collection angle as the micro-LED structure diameter varied. For diameters ranging from 2 to 6 μm, green and red micro-LEDs exhibited average LEE values that were over 10% and 20% higher than those of blue micro-LEDs, respectively. This is attributed to the decreasing refractive index of GaN and increasing reflectance of the Ag reflector as the wavelength increases. Such substantial variations in LEE among blue, green, and red InGaN micro-LEDs highlight the importance of considering wavelength-dependent LEE when interpreting measured EQE results. Full article
(This article belongs to the Special Issue Light Emitting Devices: Science and Applications)
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16 pages, 13695 KB  
Article
InGaN Laser Diode with Spin-on-Glass Isolation Fabricated by Planarization and Etch-Back Process
by Katarzyna Piotrowska-Wolińska, Szymon Grzanka, Łucja Marona, Krzysztof Gibasiewicz, Anna Kafar and Piotr Perlin
Micromachines 2026, 17(2), 142; https://doi.org/10.3390/mi17020142 - 23 Jan 2026
Viewed by 440
Abstract
We report on the fabrication and characterization of InGaN-based ridge-waveguide laser diodes employing spin-on-glass (SOG) as the insulation and planarization layer. In contrast to conventional silicon dioxide (SiO2) isolation deposited by PECVD, the SOG approach provides improved surface planarity, reduced processing [...] Read more.
We report on the fabrication and characterization of InGaN-based ridge-waveguide laser diodes employing spin-on-glass (SOG) as the insulation and planarization layer. In contrast to conventional silicon dioxide (SiO2) isolation deposited by PECVD, the SOG approach provides improved surface planarity, reduced processing complexity, and lower fabrication cost. The laser structures were grown on GaN substrates by MOCVD, with the active region consisting of In0.11Ga0.89N quantum wells. Following ridge formation and SOG deposition, an etch-back process was used to form the electrical contacts. We have demonstrated the formation of high-quality insulating surfaces with strong adhesion to the ridge sidewalls. When using a Ni protective layer, the fabricated devices exhibited favorable electrical and optical characteristics and achieved stable laser operation under both pulsed and continuous-wave conditions. These results indicate that the SOG-based insulation process represents a promising alternative for the scalable and cost-effective fabrication of InGaN laser diodes targeting advanced photonic applications. Full article
(This article belongs to the Section D1: Semiconductor Devices)
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8 pages, 1605 KB  
Communication
Saturation of Optical Gain in Green Laser Diode Structures as Functions of Excitation Density and Excitation Length
by Young Sun Jo, Seung Ryul Lee, Sung-Nam Lee and Yoon Seok Kim
Photonics 2026, 13(1), 97; https://doi.org/10.3390/photonics13010097 - 21 Jan 2026
Viewed by 233
Abstract
In this study, the optical gain characteristics of a green laser sample based on a III-Nitride InGaN single-quantum-well structure were investigated. The Green gap phenomenon, caused by bandgap fluctuations due to inhomogeneous indium composition and the quantum-confined Stark effect (QCSE), has been a [...] Read more.
In this study, the optical gain characteristics of a green laser sample based on a III-Nitride InGaN single-quantum-well structure were investigated. The Green gap phenomenon, caused by bandgap fluctuations due to inhomogeneous indium composition and the quantum-confined Stark effect (QCSE), has been a major obstacle in achieving high efficiency and high output in green-light-emitting devices. To address these issues, a sample grown on a (0001)-oriented GaN substrate with a single-quantum-well active layer was fabricated to suppress In composition non-uniformity and enhance the overlap of electron and hole wavefunctions. The optical gain behavior was analyzed using the Variable Stripe Length Method (VSLM) under various excitation densities and stripe lengths (Lcav). The results showed that as the stripe length increased, the spectral linewidth decreased and stimulated emission occurred at lower excitation densities. However, excessive cavity length led to gain saturation and a red shift in the peak wavelength due to Joule heating effects. These findings provide essential insights for determining the optimal cavity length in laser diode fabrication and are expected to serve as fundamental guidelines for improving the efficiency and output power of III-Nitride-based green laser diodes. Full article
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23 pages, 1227 KB  
Article
Quantum Theory of Polarized Superlattice Optical Response: Faithful Reproduction of Nakamura’s Blue Laser Spectra
by Pedro Pereyra and Victor G. Ibarra-Sierra
Optics 2025, 6(4), 60; https://doi.org/10.3390/opt6040060 - 20 Nov 2025
Viewed by 416
Abstract
Earlier quantum calculations of the optical response of Nakamura’s blue laser diode, assuming Kronig–Penney-like band-edge profiles, omitted the effects of charge polarization, cladding-layer asymmetry, and recombination delay times, while such simplified model reproduces the overall emission structure, underestimates the spectral width and fails [...] Read more.
Earlier quantum calculations of the optical response of Nakamura’s blue laser diode, assuming Kronig–Penney-like band-edge profiles, omitted the effects of charge polarization, cladding-layer asymmetry, and recombination delay times, while such simplified model reproduces the overall emission structure, underestimates the spectral width and fails to capture the decrease in peak intensities at higher energies. Here, we present a detailed quantum theory of polarized-asymmetric superlattices that explicitly incorporates spontaneous and piezoelectric polarization, confining-layer asymmetry, and recombination lifetimes. Local Stark fields are modeled by linear band-edge potentials, and the corresponding Schrödinger equation is solved using Airy functions within the Theory of Finite Periodic Systems. This approach enables the exact calculation of subband eigenvalues, eigenfunctions, transition probabilities and optical spectra. We show that to faithfully reproduce Nakamura’s blue laser spectra, smaller effective masses must be considered, unless unrealistically small barrier heights and widths are assumed. Furthermore, by employing the time distribution of transition probabilities, we capture the energy dependence of recombination lifetimes and their influence on peak intensities. The resulting analysis reproduces the observed spectral broadening and peak-height evolution, while also providing estimates of the magnitude of the Stark effect and mean recombination lifetimes. Full article
(This article belongs to the Section Laser Sciences and Technology)
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9 pages, 2176 KB  
Article
High Power Density X-Band GaN-on-Si HEMTs with 10.2 W/mm Used by Low Parasitic Gold-Free Ohmic Contact
by Jiale Du, Hao Lu, Bin Hou, Ling Yang, Meng Zhang, Mei Wu, Kaiwen Chen, Tianqi Pan, Yifan Chen, Hailin Liu, Qingyuan Chang, Xiaohua Ma and Yue Hao
Micromachines 2025, 16(9), 1067; https://doi.org/10.3390/mi16091067 - 22 Sep 2025
Viewed by 1211
Abstract
To enhance the RF power properties of CMOS-compatible gold-free GaN devices, this work introduces a kind of GaN-on-Si HEMT with a low parasitic regrown ohmic contact technology. Attributed to the highly doped n+ InGaN regrown layer and smooth morphology of gold-free ohmic [...] Read more.
To enhance the RF power properties of CMOS-compatible gold-free GaN devices, this work introduces a kind of GaN-on-Si HEMT with a low parasitic regrown ohmic contact technology. Attributed to the highly doped n+ InGaN regrown layer and smooth morphology of gold-free ohmic stacks, the lowest ohmic contact resistance (Rc) was presented as 0.072 Ω·mm. More importantly, low RF loss and low total dislocation density (TDD) of the Si-based GaN epitaxy were achieved by a designed two-step-graded (TSG) transition structure for the use of scaling-down devices in high-frequency applications. Finally, the fabricated GaN HEMTs on the Si substrate presented a maximum drain current (Idrain) of 1206 mA/mm, a peak transconductance (Gm) of 391 mS/mm, and a breakdown voltage (VBR) of 169 V. The outstanding material and DC performances strongly encourage a maximum output power density (Pout) of 10.2 W/mm at 8 GHz and drain voltage (Vdrain) of 50 V in active pulse mode, which, to our best knowledge, updates the highest power level for gold-free GaN devices on Si substrates. The power results reflect the reliable potential of low parasitic regrown ohmic contact technology for future large-scale CMOS-integrated circuits in RF applications. Full article
(This article belongs to the Section D:Materials and Processing)
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10 pages, 1855 KB  
Article
TCAD Design and Optimization of In0.20Ga0.80N/In0.35Ga0.65N Quantum-Dot Intermediate-Band Solar Cells
by Salaheddine Amezzoug, Haddou El Ghazi and Walid Belaid
Crystals 2025, 15(8), 693; https://doi.org/10.3390/cryst15080693 - 30 Jul 2025
Viewed by 1067
Abstract
Intermediate-band photovoltaics promise single-junction efficiencies that exceed the Shockley and Queisser limit, yet viable material platforms and device geometries remain under debate. Here, we perform comprehensive two-dimensional device-scale simulations using Silvaco Atlas TCAD to analyze p-i-n In0.20Ga0.80N solar cells [...] Read more.
Intermediate-band photovoltaics promise single-junction efficiencies that exceed the Shockley and Queisser limit, yet viable material platforms and device geometries remain under debate. Here, we perform comprehensive two-dimensional device-scale simulations using Silvaco Atlas TCAD to analyze p-i-n In0.20Ga0.80N solar cells in which the intermediate band is supplied by In0.35Ga0.65N quantum dots located inside the intrinsic layer. Quantum-dot diameters from 1 nm to 10 nm and areal densities up to 116 dots per period are evaluated under AM 1.5G, one-sun illumination at 300 K. The baseline pn junction achieves a simulated power-conversion efficiency of 33.9%. The incorporation of a single 1 nm quantum-dot layer dramatically increases efficiency to 48.1%, driven by a 35% enhancement in short-circuit current density while maintaining open-circuit voltage stability. Further increases in dot density continue to boost current but with diminishing benefit; the highest efficiency recorded, 49.4% at 116 dots, is only 1.4 percentage points above the 40-dot configuration. The improvements originate from two-step sub-band-gap absorption mediated by the quantum dots and from enhanced carrier collection in a widened depletion region. These results define a practical design window centred on approximately 1 nm dots and about 40 dots per period, balancing substantial efficiency gains with manageable structural complexity and providing concrete targets for epitaxial implementation. Full article
(This article belongs to the Section Materials for Energy Applications)
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2 pages, 138 KB  
Retraction
RETRACTED: Martínez-Revuelta et al. Numerical Study of a Solar Cell to Achieve the Highest InGaN Power Conversion Efficiency for the Whole In-Content Range. Micromachines 2022, 13, 1828
by Rubén Martínez-Revuelta, Horacio I. Solís-Cisneros, Raúl Trejo-Hernández, Madaín Pérez-Patricio, Martha L. Paniagua-Chávez, Rubén Grajales-Coutiño, Jorge L. Camas-Anzueto and Carlos A. Hernández-Gutiérrez
Micromachines 2025, 16(8), 874; https://doi.org/10.3390/mi16080874 - 29 Jul 2025
Viewed by 959
Abstract
The journal retracts the article titled “Numerical Study of a Solar Cell to Achieve the Highest InGaN Power Conversion Efficiency for the Whole In-Content Range” [...] Full article
10 pages, 895 KB  
Article
Investigation on the Carrier Dynamics in P-I-N Type Photovoltaic Devices with Different Step-Gradient Distribution of Indium Content in the Intrinsic Region
by Yifan Song, Wei Liu, Junjie Gao, Di Wang, Chengrui Yan, Bohan Shi, Linyuan Zhang, Xinnan Zhao and Zeyu Liu
Micromachines 2025, 16(7), 833; https://doi.org/10.3390/mi16070833 - 21 Jul 2025
Cited by 1 | Viewed by 710
Abstract
InGaN-based photovoltaic devices have attracted great attention due to their remarkable theoretical potential for high efficiency. In this paper, the influence of different distributions of step-gradient indium content within the intrinsic region on the photovoltaic performance of P-I-N type InGaN/GaN solar cells is [...] Read more.
InGaN-based photovoltaic devices have attracted great attention due to their remarkable theoretical potential for high efficiency. In this paper, the influence of different distributions of step-gradient indium content within the intrinsic region on the photovoltaic performance of P-I-N type InGaN/GaN solar cells is numerically investigated. Through the comprehensive analysis of carrier dynamics, it is found that for the device with the indium content decreasing stepwise from 50% at the top to 10% at the bottom in intrinsic region, the photovoltaic conversion efficiency is increased to 10.29%, which can be attributed to joint influence of enhanced photon absorption, reduced recombination rate, and optimized carrier transport process. Full article
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16 pages, 1918 KB  
Article
Optimization of InxGa1−xN P-I-N Solar Cells: Achieving 21% Efficiency Through SCAPS-1D Modeling
by Hassan Abboudi, Walid Belaid, Redouane En-nadir, Ilyass Ez-zejjari, Mohammed Zouini, Ahmed Sali and Haddou El Ghazi
Crystals 2025, 15(7), 633; https://doi.org/10.3390/cryst15070633 - 9 Jul 2025
Cited by 2 | Viewed by 1462
Abstract
This study provides an in-depth numerical simulation to optimize the structure of InGaN-based p-i-n single homojunction solar cells using SCAPS-1D software. The cell comprised a p-type In0.6Ga0.4N layer, an intrinsic i-type [...] Read more.
This study provides an in-depth numerical simulation to optimize the structure of InGaN-based p-i-n single homojunction solar cells using SCAPS-1D software. The cell comprised a p-type In0.6Ga0.4N layer, an intrinsic i-type In0.52Ga0.48N layer, and an n-type In0.48Ga0.52N layer. A systematic parametric optimization methodology was employed, involving a sequential investigation of doping concentrations, layer thicknesses, and indium composition to identify the optimal device configuration. Initial optimization of doping levels established optimal concentrations of Nd=1×1016 cm3 for the p-layer and Na=8×1017 cm3 for the n-layer. Subsequently, structural parameters were optimized through systematic variation of layer thicknesses while maintaining optimal doping concentrations. The comprehensive optimization culminated in the identification of an optimal device architecture featuring a p-type layer thickness of 0.2 μm, an intrinsic layer thickness of 0.4 μm, an n-type layer thickness of 0.06 μm, and an indium composition of x = 0.59 in the intrinsic layer. This fully optimized configuration achieved a maximum conversion efficiency (η) of 21.40%, a short-circuit current density (Jsc) of 28.2 mA/cm2, and an open-circuit voltage (Voc) of 0.874 V. The systematic optimization approach demonstrates the critical importance of simultaneous parameter optimization in achieving superior photovoltaic performance, with the final device configuration representing a 30.01% efficiency improvement compared to the baseline structure. These findings provide critical insights for improving the design and performance of InGaN-based solar cells, serving as a valuable reference for future experimental research. Full article
(This article belongs to the Section Materials for Energy Applications)
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9 pages, 1553 KB  
Communication
Orthogonally Polarized Pr:LLF Red Laser at 698 nm with Tunable Power Ratio
by Haotian Huang, Menghan Jia, Yuzhao Li, Jing Xia, Nguyentuan Anh and Yanfei Lü
Photonics 2025, 12(7), 666; https://doi.org/10.3390/photonics12070666 - 1 Jul 2025
Cited by 2 | Viewed by 650
Abstract
A continuous-wave (CW) orthogonally polarized single-wavelength red laser (OPSRL) at 698 nm with a tunable power ratio within a wide range between the two polarized components was demonstrated using two Pr3+:LiLuF4 (Pr:LLF) crystals for the first time. Through control of [...] Read more.
A continuous-wave (CW) orthogonally polarized single-wavelength red laser (OPSRL) at 698 nm with a tunable power ratio within a wide range between the two polarized components was demonstrated using two Pr3+:LiLuF4 (Pr:LLF) crystals for the first time. Through control of the waist location of the pump beam in the active media, the output power ratio of the two polarized components of the OPSRL could be adjusted. Under pumping by a 20 W, 444 nm InGaN laser diode (LD), a maximum total output power of 4.12 W was achieved with equal powers for both polarized components, corresponding to an optical conversion efficiency of 23.8% relative to the absorbed pump power. Moreover, by a type-II critical phase-matched (CPM) BBO crystal, a CW ultraviolet (UV) second-harmonic generation (SHG) at 349 nm was also obtained with a maximum output power of 723 mW. OPSRLs can penetrate deep tissues and demonstrate polarization-controlled interactions, and are used in bio-sensing and industrial cutting with minimal thermal distortion, etc. The dual-polarized capability of OPSRLs also supports multi-channel imaging and high-speed interferometry. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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22 pages, 11419 KB  
Article
A Modified Model Dielectric Function for Analyzing Optical Spectra of InGaN Nanofilms on Sapphire Substrates
by Devki N. Talwar, Hao-Hsiung Lin and Jason T. Haraldsen
Nanomaterials 2025, 15(7), 485; https://doi.org/10.3390/nano15070485 - 24 Mar 2025
Viewed by 1216
Abstract
Due to a lower InN bandgap energy Eg~0.7 eV, InxGa1xN/Sapphire epifilms are considered valuable [...] Read more.
Due to a lower InN bandgap energy Eg~0.7 eV, InxGa1xN/Sapphire epifilms are considered valuable in the development of low-dimensional heterostructure-based photonic devices. Adjusting the composition x and thickness d in epitaxially grown films has offered many possibilities of light emission across a wide spectral range, from ultraviolet through visible into near-infrared regions. Optical properties have played important roles in making semiconductor materials useful in electro-optic applications. Despite the efforts to grow InxGa1xN/Sapphire samples, no x- and d-dependent optical studies exist for ultrathin films. Many researchers have used computationally intensive methods to study the electronic band structures Ejk, and subsequently derive optical properties. By including inter-band transitions at critical points from Ejk, we have developed a semiempirical approach to comprehend the optical characteristics of InN, GaN and InxGa1xN. Refractive indices of InxGa1xN and sapphire substrate are meticulously integrated into a transfer matrix method to simulate d- and x-dependent reflectivity RE  and transmission TE spectra of nanostructured InxGa1xN/Sapphire epifilms. Analyses of RE and TE have offered accurate x-dependent shifts of energy gaps for InxGa1xN (x = 0.5, 0.7) in excellent agreement with the experimental data. Full article
(This article belongs to the Section Nanocomposite Materials)
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13 pages, 2741 KB  
Article
Quantum-Well-Embedded InGaN Quantum Dot Vertical-Cavity Surface-Emitting Laser and Its Photoelectric Performance
by Zinan Hua, Hailiang Dong, Zhigang Jia, Wei Jia, Lin Shang and Bingshe Xu
Photonics 2025, 12(3), 276; https://doi.org/10.3390/photonics12030276 - 17 Mar 2025
Cited by 1 | Viewed by 2379
Abstract
An electrically injected vertical-cavity surface-emitting laser (VCSEL) with quantum-well-embedded InGaN quantum dots (QDs) as the active region was designed. The InGaN QD size and cavity length were optimized using PICS3D simulation software to achieve a high-performance InGaN QD-embedded VCSEL. A comparative analysis between [...] Read more.
An electrically injected vertical-cavity surface-emitting laser (VCSEL) with quantum-well-embedded InGaN quantum dots (QDs) as the active region was designed. The InGaN QD size and cavity length were optimized using PICS3D simulation software to achieve a high-performance InGaN QD-embedded VCSEL. A comparative analysis between the InGaN QD VCSEL and the traditional InGaN quantum well VCSEL was conducted, and the results demonstrated that the InGaN QD VCSEL achieved higher stimulated recombination radiation and internal quantum efficiency. The threshold current was reduced to 4 mA, corresponding to a threshold current density of 5.1 kA/cm², and the output power reached 4.4 mW at an injection current of 20 mA. A stable single-longitudinal-mode output was also achieved with an output wavelength of 436 nm. The proposed novel quantum-well-embedded QD active-region VCSEL was validated through theoretical simulations, confirming its feasibility. This study provides theoretical guidance and key epitaxial structural parameters for preparing high-performance VCSEL epitaxial materials. Full article
(This article belongs to the Section Lasers, Light Sources and Sensors)
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15 pages, 8753 KB  
Article
Dielectric Passivation Treatment of InGaN MESA on Si Substrates for Red Micro-LED Application
by Hongyu Qin, Shuhan Zhang, Qian Fan, Xianfeng Ni, Li Tao and Xing Gu
Crystals 2025, 15(3), 267; https://doi.org/10.3390/cryst15030267 - 13 Mar 2025
Cited by 2 | Viewed by 2746
Abstract
The emergence of GaN-based micro-LEDs has revolutionized display technologies due to their superior brightness, energy efficiency, and thermal stability compared to traditional counterparts. However, the development of red-emitting micro-LEDs on silicon substrates (GaN-on-Si) faces significant challenges, among them including hydrogen-induced deactivation of p-GaN [...] Read more.
The emergence of GaN-based micro-LEDs has revolutionized display technologies due to their superior brightness, energy efficiency, and thermal stability compared to traditional counterparts. However, the development of red-emitting micro-LEDs on silicon substrates (GaN-on-Si) faces significant challenges, among them including hydrogen-induced deactivation of p-GaN caused by hydrogen species generated from SiH4 decomposition during SiO2 passivation layer growth, which degrades device performance. This study systematically investigates the use of high-density metal-oxide dielectric passivation layers deposited by atomic layer deposition (ALD), specifically Al2O3 and HfO2, to mitigate these effects and enhance device reliability. The passivation layers effectively suppress hydrogen diffusion and preserve p-GaN activation, ensuring improved ohmic contact formation and reduced forward voltage, which is measured by the probe station. The properties of the epitaxial layer and the cross-section morphology of the dielectric layer were characterized by photoluminescence (PL) and scanning electron microscopy (SEM), respectively. Experimental results reveal that Al2O3 exhibits superior thermal stability and lower current leakage under high-temperature annealing, while HfO2 achieves higher light-output power (LOP) and efficiency under increased current densities. Electroluminescence (EL) measurements confirm that the passivation strategy maintains the intrinsic optical properties of the epitaxial wafer with minimal impact on Wp and FWHM across varying process conditions. The findings demonstrate the efficacy of metal-oxide dielectric passivation in addressing critical challenges in InGaN red micro-LED on silicon substrate fabrication, contributing to accelerating scalable and efficient next-generation display technologies. Full article
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9 pages, 1421 KB  
Article
Electromagnetic Nanocoils Based on InGaN Nanorings
by Ziwen Yan, Peng Chen, Xianfei Zhang, Zili Xie, Xiangqian Xiu, Dunjun Chen, Hong Zhao, Yi Shi, Rong Zhang and Youdou Zheng
Nanomaterials 2025, 15(3), 245; https://doi.org/10.3390/nano15030245 - 5 Feb 2025
Viewed by 3255
Abstract
Energy issues, including energy generation, conversion, transmission and detection, are fundamental factors in all systems. In micro- and nanosystems, dealing with these energy issues requires novel nanostructures and precise technology. However, both concept and setup are not well established yet in the microsystems, [...] Read more.
Energy issues, including energy generation, conversion, transmission and detection, are fundamental factors in all systems. In micro- and nanosystems, dealing with these energy issues requires novel nanostructures and precise technology. However, both concept and setup are not well established yet in the microsystems, especially for those at the nanometer scale. Here, we demonstrate electromagnetic nanocoils with 100 nm diameters based on uniform and periodic InGaN nanoring arrays grown on patterned GaN surfaces using nanoscale selective area epitaxy (NSAE). We observed stronger photoluminescence from the periodic InGaN nanoring arrays compared to the non-uniform InGaN nanorings, which indicates good crystal quality of the InGaN nanostructure with the NSAE. Based on this kind of nanostructure, electromagnetic induction from the nanorings is detected through the rebound movement of high-energy electron diffraction patterns that are influenced by a modulated external magnetic field. Our results clearly show the generation of an inductive current and internal magnetic field in the nanorings. We anticipate this kind of nanostructure to be a potential key element for energy conversion, transfer and detection in nanosystems. For example, it could be used to fabricate microtransformers and micro- and nanosensors for electromagnetic signals. Full article
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21 pages, 7804 KB  
Article
In Situ X-Ray Study During Thermal Cycle Treatment Combined with Complementary Ex Situ Investigation of InGaN Quantum Wells
by Ewa Grzanka, Sondes Bauer, Artur Lachowski, Szymon Grzanka, Robert Czernecki, Byeongchan So, Tilo Baumbach and Mike Leszczyński
Nanomaterials 2025, 15(2), 140; https://doi.org/10.3390/nano15020140 - 17 Jan 2025
Viewed by 1686
Abstract
In situ X-ray reciprocal space mapping was performed during the interval heating and cooling of InGaN/GaN quantum wells (QWs) grown via metal–organic vapor phase epitaxy (MOVPE). Our detailed in situ X-ray analysis enabled us to track changes in the peak intensities and radial [...] Read more.
In situ X-ray reciprocal space mapping was performed during the interval heating and cooling of InGaN/GaN quantum wells (QWs) grown via metal–organic vapor phase epitaxy (MOVPE). Our detailed in situ X-ray analysis enabled us to track changes in the peak intensities and radial and angular broadenings of the reflection. By simulating the radial diffraction profiles recorded during the thermal cycle treatment, we demonstrate the presence of indium concentration distributions (ICDs) in the different QWs of the heterostructure (1. QW, bottom, 2. QW, middle, and 3. QW, upper). During the heating process, we found that the homogenization of the QWs occurred in the temperature range of 850 °C to 920 °C, manifesting in a reduction in ICDs in the QWs. Furthermore, there is a critical temperature (T = 940 °C) at which the mean value of the indium concentration starts to decrease below 15% in 1. QW, indicating the initiation of decomposition in 1. QW. Moreover, further heating up to 1000 °C results in extended diffuse scattering along the angular direction of the diffraction spot, confirming the propagation of the decomposition and the formation of trapezoidal objects, which contain voids and amorphous materials (In-Ga). Heating InGaN QWs up to T = 1000 °C led to a simultaneous decrease in the indium content and ICDs. During the cooling phase, there was no significant variation in the indium concentrations in the different QWs but rather an increase in the defect area, which contributes to the amplification of diffuse scattering. A comparison of ex situ complementary high-resolution transmission microscopy (Ex-HRTEM) measurements performed at room temperature before and after the thermal cycle treatment provides proof of the formation of four different types of defects in the QWs, which result from the decomposition of 1. QW during the heating phase. This, in turn, has strongly influenced the intensity of the photoluminescence emission spectra without any detectable shift in the emission wavelength λMQWs. Full article
(This article belongs to the Section Synthesis, Interfaces and Nanostructures)
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