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19 pages, 4538 KiB  
Article
Structural Optimization of Numerical Simulation for Spherical Grid-Structured Microporous Aeration Reactor
by Yipeng Liu, Hui Nie, Yangjiaming He, Yinkang Xu, Jiale Sun, Nan Chen, Saihua Huang, Hao Chen and Dongfeng Li
Water 2025, 17(15), 2302; https://doi.org/10.3390/w17152302 (registering DOI) - 2 Aug 2025
Abstract
As the core equipment for efficient wastewater treatment, the internal structure of microporous aeration bioreactors directly determines the mass transfer efficiency and treatment performance. Based on Computational Fluid Dynamics (CFD) technology, this study explores the optimization mechanism of a Spherical Grid-Structured on the [...] Read more.
As the core equipment for efficient wastewater treatment, the internal structure of microporous aeration bioreactors directly determines the mass transfer efficiency and treatment performance. Based on Computational Fluid Dynamics (CFD) technology, this study explores the optimization mechanism of a Spherical Grid-Structured on the internal flow field of the reactor through a 3D numerical simulation system, aiming to improve the aeration efficiency and resource utilization. This study used a combination of experimental and numerical simulations to compare and analyze different configurations of the Spherical Grid-Structure. The simulation results show that the optimal equilibrium of the flow field inside the reactor is achieved when the diameter of the grid sphere is 2980 mm: the average flow velocity is increased by 22%, the uniformity of the pressure distribution is improved by 25%, and the peak turbulent kinetic energy is increased by 30%. Based on the Kalman vortex street theory, the periodic vortex induced by the grid structure refines the bubble size to 50–80 microns, improves the oxygen transfer efficiency by 20%, increases the spatial distribution uniformity of bubbles by 35%, and significantly reduces the dead zone volume from 28% to 16.8%, which is a decrease of 40%. This study reveals the quantitative relationship between the structural parameters of the grid and the flow field characteristics through a pure numerical simulation, which provides a theoretical basis and quantifiable optimization scheme for the structural design of the microporous aeration bioreactor, which is of great significance in promoting the development of low-energy and high-efficiency wastewater treatment technology. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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18 pages, 5178 KiB  
Article
Quantification of Suspended Sediment Concentration Using Laboratory Experimental Data and Machine Learning Model
by Sathvik Reddy Nookala, Jennifer G. Duan, Kun Qi, Jason Pacheco and Sen He
Water 2025, 17(15), 2301; https://doi.org/10.3390/w17152301 (registering DOI) - 2 Aug 2025
Abstract
Monitoring sediment concentration in water bodies is crucial for assessing water quality, ecosystems, and environmental health. However, physical sampling and sensor-based approaches are labor-intensive and unsuitable for large-scale, continuous monitoring. This study employs machine learning models to estimate suspended sediment concentration using images [...] Read more.
Monitoring sediment concentration in water bodies is crucial for assessing water quality, ecosystems, and environmental health. However, physical sampling and sensor-based approaches are labor-intensive and unsuitable for large-scale, continuous monitoring. This study employs machine learning models to estimate suspended sediment concentration using images captured in natural light, named RGB, and near-infrared (NIR) conditions. A controlled dataset of approximately 1300 images with SSC values ranging from 1000 mg/L to 150,000 mg/L was developed, incorporating temperature, time of image capture, and solar irradiance as additional features. Random forest regression and gradient boosting regression were trained on mean RGB values, red reflectance, time of captured, and temperature for natural light images, achieving up to 72.96% accuracy within a 30% relative error. In contrast, NIR images leveraged gray-level co-occurrence matrix texture features and temperature, reaching 83.08% accuracy. Comparative analysis showed that ensemble models outperformed deep learning models like Convolutional Neural Networks and Multi-Layer Perceptrons, which struggled with high-dimensional feature extraction. These findings suggest that using machine learning models and RGB and NIR imagery offers a scalable, non-invasive, and cost-effective way of sediment monitoring in support of water quality assessment and environmental management. Full article
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30 pages, 1130 KiB  
Review
Beyond the Backbone: A Quantitative Review of Deep-Learning Architectures for Tropical Cyclone Track Forecasting
by He Huang, Difei Deng, Liang Hu, Yawen Chen and Nan Sun
Remote Sens. 2025, 17(15), 2675; https://doi.org/10.3390/rs17152675 (registering DOI) - 2 Aug 2025
Abstract
Accurate forecasting of tropical cyclone (TC) tracks is critical for disaster preparedness and risk mitigation. While traditional numerical weather prediction (NWP) systems have long served as the backbone of operational forecasting, they face limitations in computational cost and sensitivity to initial conditions. In [...] Read more.
Accurate forecasting of tropical cyclone (TC) tracks is critical for disaster preparedness and risk mitigation. While traditional numerical weather prediction (NWP) systems have long served as the backbone of operational forecasting, they face limitations in computational cost and sensitivity to initial conditions. In recent years, deep learning (DL) has emerged as a promising alternative, offering data-driven modeling capabilities for capturing nonlinear spatiotemporal patterns. This paper presents a comprehensive review of DL-based approaches for TC track forecasting. We categorize all DL-based TC tracking models according to the architecture, including recurrent neural networks (RNNs), convolutional neural networks (CNNs), Transformers, graph neural networks (GNNs), generative models, and Fourier-based operators. To enable rigorous performance comparison, we introduce a Unified Geodesic Distance Error (UGDE) metric that standardizes evaluation across diverse studies and lead times. Based on this metric, we conduct a critical comparison of state-of-the-art models and identify key insights into their relative strengths, limitations, and suitable application scenarios. Building on this framework, we conduct a critical cross-model analysis that reveals key trends, performance disparities, and architectural tradeoffs. Our analysis also highlights several persistent challenges, such as long-term forecast degradation, limited physical integration, and generalization to extreme events, pointing toward future directions for developing more robust and operationally viable DL models for TC track forecasting. To support reproducibility and facilitate standardized evaluation, we release an open-source UGDE conversion tool on GitHub. Full article
(This article belongs to the Section AI Remote Sensing)
21 pages, 7537 KiB  
Article
Variable Step-Size FxLMS Algorithm Based on Cooperative Coupling of Double Nonlinear Functions
by Jialong Wang, Jian Liao, Lin He, Xiaopeng Tan and Zongbin Chen
Symmetry 2025, 17(8), 1222; https://doi.org/10.3390/sym17081222 (registering DOI) - 2 Aug 2025
Abstract
Based on the principle of symmetry, we propose a variable step-size FxLMS algorithm with double nonlinear functions cooperative coupling (DNVSS-FxLMS), aiming to optimize the contradiction between convergence rate and steady-state error in the active pressure pulsation control system of hydraulic systems. The algorithm [...] Read more.
Based on the principle of symmetry, we propose a variable step-size FxLMS algorithm with double nonlinear functions cooperative coupling (DNVSS-FxLMS), aiming to optimize the contradiction between convergence rate and steady-state error in the active pressure pulsation control system of hydraulic systems. The algorithm innovatively couples two types of nonlinear mechanisms (rational-fractional and exponential-function-based), constructing a refined error-step mapping relationship to achieve a balance between rapid convergence and low steady-state error. Simulation experiments were conducted considering the complex time-varying operating environment of a simulation-based hydraulic system. The results demonstrate that, when the system undergoes unstable random changes, the DNVSS-FxLMS algorithm converges at least twice as fast as traditional and existing variable step size algorithms, while reducing steady-state error by 2–5 dB. The proposed DNVSS-FxLMS algorithm exhibits significant advantages in convergence rate, steady-state error reduction, and tracking capability, providing a highly efficient and robust solution for real-time active control of hydraulic system pressure pulsation under complex operating conditions. Full article
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22 pages, 2498 KiB  
Article
SceEmoNet: A Sentiment Analysis Model with Scene Construction Capability
by Yi Liang, Dongfang Han, Zhenzhen He, Bo Kong and Shuanglin Wen
Appl. Sci. 2025, 15(15), 8588; https://doi.org/10.3390/app15158588 (registering DOI) - 2 Aug 2025
Abstract
How do humans analyze the sentiments embedded in text? When attempting to analyze a text, humans construct a “scene” in their minds through imagination based on the text, generating a vague image. They then synthesize the text and the mental image to derive [...] Read more.
How do humans analyze the sentiments embedded in text? When attempting to analyze a text, humans construct a “scene” in their minds through imagination based on the text, generating a vague image. They then synthesize the text and the mental image to derive the final analysis result. However, current sentiment analysis models lack such imagination; they can only analyze based on existing information in the text, which limits their classification accuracy. To address this issue, we propose the SceEmoNet model. This model endows text classification models with imagination through Stable diffusion, enabling the model to generate corresponding visual scenes from input text, thus introducing a new modality of visual information. We then use the Contrastive Language-Image Pre-training (CLIP) model, a multimodal feature extraction model, to extract aligned features from different modalities, preventing significant feature differences caused by data heterogeneity. Finally, we fuse information from different modalities using late fusion to obtain the final classification result. Experiments on six datasets with different classification tasks show improvements of 9.57%, 3.87%, 3.63%, 3.14%, 0.77%, and 0.28%, respectively. Additionally, we set up experiments to deeply analyze the model’s advantages and limitations, providing a new technical path for follow-up research. Full article
(This article belongs to the Special Issue Advanced Technologies and Applications of Emotion Recognition)
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24 pages, 1964 KiB  
Article
Data-Driven Symmetry and Asymmetry Investigation of Vehicle Emissions Using Machine Learning: A Case Study in Spain
by Fei Wu, Jinfu Zhu, Hufang Yang, Xiang He and Qiao Peng
Symmetry 2025, 17(8), 1223; https://doi.org/10.3390/sym17081223 (registering DOI) - 2 Aug 2025
Abstract
Understanding vehicle emissions is essential for developing effective carbon reduction strategies in the transport sector. Conventional emission models often assume homogeneity and linearity, overlooking real-world asymmetries that arise from variations in vehicle design and powertrain configurations. This study explores how machine learning and [...] Read more.
Understanding vehicle emissions is essential for developing effective carbon reduction strategies in the transport sector. Conventional emission models often assume homogeneity and linearity, overlooking real-world asymmetries that arise from variations in vehicle design and powertrain configurations. This study explores how machine learning and explainable AI techniques can effectively capture both symmetric and asymmetric emission patterns across different vehicle types, thereby contributing to more sustainable transport planning. Addressing a key gap in the existing literature, the study poses the following question: how do structural and behavioral factors contribute to asymmetric emission responses in internal combustion engine vehicles compared to new energy vehicles? Utilizing a large-scale Spanish vehicle registration dataset, the analysis classifies vehicles by powertrain type and applies five supervised learning algorithms to predict CO2 emissions. SHapley Additive exPlanations (SHAPs) are employed to identify nonlinear and threshold-based relationships between emissions and vehicle characteristics such as fuel consumption, weight, and height. Among the models tested, the Random Forest algorithm achieves the highest predictive accuracy. The findings reveal critical asymmetries in emission behavior, particularly among hybrid vehicles, which challenge the assumption of uniform policy applicability. This study provides both methodological innovation and practical insights for symmetry-aware emission modeling, offering support for more targeted eco-design and policy decisions that align with long-term sustainability goals. Full article
(This article belongs to the Section Engineering and Materials)
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16 pages, 1541 KiB  
Article
Economic Dispatch Strategy for Power Grids Considering Waste Heat Utilization in High-Energy-Consuming Enterprises
by Lei Zhou, Ping He, Siru Wang, Cailian Ma, Yiming Zhou, Can Cai and Hongbo Zou
Processes 2025, 13(8), 2450; https://doi.org/10.3390/pr13082450 (registering DOI) - 2 Aug 2025
Abstract
Under the construction background of carbon peak and carbon neutrality, high-energy-consuming enterprises, represented by the electrolytic aluminum industry, have become important carriers for energy conservation and emission reduction. These enterprises are characterized by significant energy consumption and high carbon emissions, greatly impacting the [...] Read more.
Under the construction background of carbon peak and carbon neutrality, high-energy-consuming enterprises, represented by the electrolytic aluminum industry, have become important carriers for energy conservation and emission reduction. These enterprises are characterized by significant energy consumption and high carbon emissions, greatly impacting the economic and environmental benefits of regional power grids. Existing research often focuses on grid revenue, leaving high-energy-consuming enterprises in a passive regulatory position. To address this, this paper constructs an economic dispatch strategy for power grids that considers waste heat utilization in high-energy-consuming enterprises. A typical representative, electrolytic aluminum load and its waste heat utilization model, for the entire production process of high-energy-consuming loads, is established. Using a tiered carbon trading calculation formula, a low-carbon production scheme for high-energy-consuming enterprises is developed. On the grid side, considering local load levels, the uncertainty of wind power output, and the energy demands of aluminum production, a robust day-ahead economic dispatch model is established. Case analysis based on the modified IEEE-30 node system demonstrates that the proposed method balances economic efficiency and low-carbon performance while reducing the conservatism of traditional optimization approaches. Full article
(This article belongs to the Section Energy Systems)
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19 pages, 3154 KiB  
Article
Optimizing the Operation of Local Energy Communities Based on Two-Stage Scheduling
by Ping He, Lei Zhou, Jingwen Wang, Zhuo Yang, Guozhao Lv, Can Cai and Hongbo Zou
Processes 2025, 13(8), 2449; https://doi.org/10.3390/pr13082449 (registering DOI) - 2 Aug 2025
Abstract
Flexible energy sources such as electric vehicles and the battery energy storage systems of intelligent distribution systems can provide system-wide auxiliary services such as frequency regulation for power systems. This paper proposes an optimal method for operating the local energy community that is [...] Read more.
Flexible energy sources such as electric vehicles and the battery energy storage systems of intelligent distribution systems can provide system-wide auxiliary services such as frequency regulation for power systems. This paper proposes an optimal method for operating the local energy community that is based on two-stage scheduling. Firstly, the basic concepts of the local energy community and flexible service are introduced in detail. Taking LEC as the reserve unit of artificial frequency recovery, an energy information interaction model among LEC, balance service providers, and the power grid is established. Then, a two-stage scheduling framework is proposed to ensure the rationality and economy of community energy scheduling. In the first stage, day-ahead scheduling uses the energy community management center to predict the up/down flexibility capacity that LEC can provide by adjusting the BESS control parameters. In the second stage, real-time scheduling aims at maximizing community profits and scheduling LEC based on the allocation and activation of standby flexibility determined in real time. Finally, the correctness of the two-stage scheduling framework is verified through a case study. The results show that the control parameters used in the day-ahead stage can significantly affect the real-time profitability of LEC, and that LEC benefits more in the case of low BESS utilization than in the case of high BESS utilization and non-participation in frequency recovery reserve. Full article
(This article belongs to the Section Energy Systems)
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17 pages, 3061 KiB  
Article
Model-Agnostic Meta-Learning in Predicting Tunneling-Induced Surface Ground Deformation
by Wei He, Guan-Bin Chen, Wenlian Qian, Wen-Li Chen, Liang Tang and Xiangxun Kong
Symmetry 2025, 17(8), 1220; https://doi.org/10.3390/sym17081220 (registering DOI) - 2 Aug 2025
Abstract
The present investigation presents the field measurement and prediction of tunneling-induced surface ground settlement in Tianjin Metro Line 7, China. The cross-section of a metro tunnel exhibits circular symmetry, thereby making it suitable for tunneling with a circular shield machine. The ground surface [...] Read more.
The present investigation presents the field measurement and prediction of tunneling-induced surface ground settlement in Tianjin Metro Line 7, China. The cross-section of a metro tunnel exhibits circular symmetry, thereby making it suitable for tunneling with a circular shield machine. The ground surface may deform during the tunneling stage. In the early stage of tunneling, few measurement data can be collected. To obtain a better usable prediction model, two kinds of neural networks according to the model-agnostic meta-learning (MAML) scheme are presented. One kind of deep learning strategy is a combination of the Back-Propagation Neural Network (BPNN) and the MAML model, named MAML-BPNN. The other prediction model is a mixture of the MAML model and the Long Short-Term Memory (LSTM) model, named MAML-LSTM. Founded on several measurement datasets, the prediction models of the MAML-BPNN and MAML-LSTM are successfully trained. The results show the present models possess good prediction ability for tunneling-induced surface ground settlement. Based on the coefficient of determination, the prediction result using MAML-LSTM is superior to that of MAML-BPNN by 0.1. Full article
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20 pages, 3657 KiB  
Article
Numerical Study of Chemo–Mechanical Coupling Behavior of Concrete
by Feng Guo, Weijie He, Longlong Tu and Huiming Hou
Buildings 2025, 15(15), 2725; https://doi.org/10.3390/buildings15152725 (registering DOI) - 1 Aug 2025
Abstract
Subsurface mass concrete infrastructure—including immersed tunnels, dams, and nuclear waste containment systems—frequently faces calcium-leaching risks from prolonged groundwater exposure. An anisotropic stress-leaching damage model incorporating microcrack propagation is developed for underground concrete’s chemo–mechanical coupling. This model investigates stress-induced anisotropy in concrete through the [...] Read more.
Subsurface mass concrete infrastructure—including immersed tunnels, dams, and nuclear waste containment systems—frequently faces calcium-leaching risks from prolonged groundwater exposure. An anisotropic stress-leaching damage model incorporating microcrack propagation is developed for underground concrete’s chemo–mechanical coupling. This model investigates stress-induced anisotropy in concrete through the evolution of oriented microcrack networks. The model incorporates nonlinear anisotropic plastic strain from coupled chemical–mechanical damage. Unlike conventional concrete rheology, this model characterizes chemical creep through stress-chemical coupled damage mechanics. The numerical model is incorporated within COMSOL Multiphysics to perform coupled multiphysics simulations. A close match is observed between the numerical predictions and experimental findings. Under high stress loads, calcium leaching and mechanical stress exhibit significant coupling effects. Regarding concrete durability, chemical degradation has a more pronounced effect on concrete’s stiffness and strength reduction compared with stress-generated microcracking. Full article
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16 pages, 3043 KiB  
Article
Experimental Investigations on Sustainable Dual-Biomass-Based Composite Phase Change Materials for Energy-Efficient Building Applications
by Zhiwei Sun, Wei Wen, Jiayu Wu, Jingjing Shao, Wei Cai, Xiaodong Wen, Chaoen Li, Haijin Guo, Yin Tang, Meng Wang, Dongjing Liu and Yang He
Materials 2025, 18(15), 3632; https://doi.org/10.3390/ma18153632 (registering DOI) - 1 Aug 2025
Abstract
The incorporation of phase change material (PCM) can enhance wall thermal performance and indoor thermal comfort, but practical applications still face challenges related to high costs and potential leakage issues. In this study, a novel dual-biomass-based shape-stabilized PCM (Bio-SSPCM) was proposed, wherein waste [...] Read more.
The incorporation of phase change material (PCM) can enhance wall thermal performance and indoor thermal comfort, but practical applications still face challenges related to high costs and potential leakage issues. In this study, a novel dual-biomass-based shape-stabilized PCM (Bio-SSPCM) was proposed, wherein waste cooking fat and waste reed straw were, respectively, incorporated as the PCM substance and supporting material. The waste fat (lard) consisted of both saturated and unsaturated fatty acid glycerides, exhibiting a melting point about 21.2–41.1 °C and a melting enthalpy value of 40 J/g. Reed straw was carbonized to form a sustainable porous biochar supporting matrix, which was used for the vacuum adsorption of waste fat. The results demonstrate that the as-prepared dual-Bio-SSPCM exhibited excellent thermal performance, characterized by a latent heat capacity of 25.4 J/g. With the addition of 4 wt% of expanded graphite (EG), the thermal conductivity of the composite PCM reached 1.132 W/(m·K), which was 5.4 times higher than that of the primary lard. The thermal properties of the Bio-SSPCM were characterized using an analog T-history method. The results demonstrated that the dual-Bio-SSPCM exhibited exceptional and rapid heat storage and exothermic capabilities. The dual-Bio-SSPCM, prepared from waste cooking fat and reed straw, can be considered as environmentally friendly construction material for energy storage in line with the principles of the circular economy. Full article
(This article belongs to the Special Issue Eco-Friendly Intelligent Infrastructures Materials)
25 pages, 7503 KiB  
Article
A Diagnostic Framework for Decoupling Multi-Source Vibrations in Complex Machinery: An Improved OTPA Application on a Combine Harvester Chassis
by Haiyang Wang, Zhong Tang, Liyun Lao, Honglei Zhang, Jiabao Gu and Qi He
Appl. Sci. 2025, 15(15), 8581; https://doi.org/10.3390/app15158581 (registering DOI) - 1 Aug 2025
Abstract
Complex mechanical systems, such as agricultural combine harvesters, are subjected to dynamic excitations from multiple coupled sources, compromising structural integrity and operational reliability. Disentangling these vibrations to identify dominant sources and quantify their transmission paths remains a significant engineering challenge. This study proposes [...] Read more.
Complex mechanical systems, such as agricultural combine harvesters, are subjected to dynamic excitations from multiple coupled sources, compromising structural integrity and operational reliability. Disentangling these vibrations to identify dominant sources and quantify their transmission paths remains a significant engineering challenge. This study proposes a robust diagnostic framework to address this issue. We employed a multi-condition vibration test with sequential source activation and an improved Operational Transfer Path Analysis (OTPA) method. Applied to a harvester chassis, the results revealed that vibration energy is predominantly concentrated in the 0–200 Hz frequency band. Path contribution analysis quantified that the “cutting header → conveyor trough → hydraulic cylinder → chassis frame” path is the most critical contributor to vertical vibration, with a vibration acceleration level of 117.6 dB. Further analysis identified the engine (29.3 Hz) as the primary source for vertical vibration, while lateral vibration was mainly attributed to a coupled resonance between the threshing cylinder (58 Hz) and the engine’s second-order harmonic. This study’s theoretical contribution lies in validating a powerful methodology for vibration source apportionment in complex systems. Practically, the findings provide direct, actionable insights for targeted structural optimization and vibration suppression. Full article
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11 pages, 5112 KiB  
Article
Fabrication of a Porous TiNi3 Intermetallic Compound to Enhance Anti-Corrosion Performance in 1 M KOH
by Zhenli He, Yue Qiu, Yuehui He, Qian Zhao, Zhonghe Wang and Yao Jiang
Metals 2025, 15(8), 865; https://doi.org/10.3390/met15080865 (registering DOI) - 1 Aug 2025
Abstract
Porous intermetallic compounds have the properties of porous materials as well as a combination of covalent and metallic bonds, and they exhibit high porosity, structural stability, and corrosion resistance. In this work, a porous TiNi3 intermetallic compound was fabricated through reactive synthesis [...] Read more.
Porous intermetallic compounds have the properties of porous materials as well as a combination of covalent and metallic bonds, and they exhibit high porosity, structural stability, and corrosion resistance. In this work, a porous TiNi3 intermetallic compound was fabricated through reactive synthesis of elemental powders. Next, detailed studies of its phase composition and pore structure characteristics at different sintering temperatures, as well as its corrosion behavior against an alkaline environment, were carried out. The results show that the as-prepared porous TiNi3 intermetallic compound has abundant pore structures, with an open porosity of 56.5%, which can be attributed to a combination of the bridging effects of initial powder particles and the Kirkendall effect occurring during the sintering process. In 1 M KOH solution, a higher positive corrosion potential (−0.979 VSCE) and a lower corrosion current density (1.18 × 10−4 A∙cm−2) were exhibited by the porous TiNi3 intermetallic compound, compared to the porous Ni, reducing the thermodynamic corrosion tendency and the corrosion rate. The corresponding corrosion process is controlled by the charge transfer process, and the increased charge transfer resistance value (713.9 Ω⋅cm2) of TiNi3 makes it more difficult to charge-transfer than porous Ni (204.5 Ω⋅cm2), thus decreasing the rate of electrode reaction. The formation of a more stable passive film with the incorporation of Ti contributes to this improved corrosion resistance performance. Full article
(This article belongs to the Special Issue Advanced Ti-Based Alloys and Ti-Based Materials)
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20 pages, 4427 KiB  
Article
Mechanistic Insights into m-Cresol Adsorption on Functional Resins: Surface Chemistry and Adsorption Behavior
by Yali Wang, Zhenrui Wang, Zile Liu, Xiyue He and Zequan Zeng
Materials 2025, 18(15), 3628; https://doi.org/10.3390/ma18153628 (registering DOI) - 1 Aug 2025
Abstract
The removal of high-concentration m-cresol from industrial wastewater remains a significant challenge due to its toxicity and persistence. In this study, a commercially available functionalized resin with a high BET surface area (1439 m2 g−1) and hierarchical pore structure was [...] Read more.
The removal of high-concentration m-cresol from industrial wastewater remains a significant challenge due to its toxicity and persistence. In this study, a commercially available functionalized resin with a high BET surface area (1439 m2 g−1) and hierarchical pore structure was employed for the adsorption of pure m-cresol at an initial concentration of 20 g L−1, representative of coal-based industrial effluents. Comprehensive characterization confirmed the presence of oxygen-rich functional groups, amorphous polymeric structure, and uniform surface morphology conducive to adsorption. Batch experiments were conducted to evaluate the effects of resin dosage, contact time, temperature, and equilibrium concentration. Under optimized conditions (0.15 g resin, 60 °C), a maximum adsorption capacity of 556.3 mg g−1 and removal efficiency of 71% were achieved. Kinetic analysis revealed that the pseudo-second-order model best described the adsorption process (R2 > 0.99). Isotherm data fit the Langmuir model most closely (R2 = 0.9953), yielding a monolayer capacity of 833.3 mg g−1. Thermodynamic analysis showed that adsorption was spontaneous (ΔG° < 0), endothermic (ΔH° = 7.553 kJ mol−1), and accompanied by increased entropy (ΔS° = 29.90 J mol−1 K−1). The good agreement with the PSO model is indicative of chemisorption, as supported by other lines of evidence, including thermodynamic parameters (e.g., positive ΔH° and ΔS°), surface functional group characteristics, and molecular interactions. The adsorption mechanism was elucidated through comprehensive modeling of adsorption kinetics, isotherms, and thermodynamics, combined with detailed physicochemical characterization of the resin prior to adsorption, reinforcing the mechanistic understanding of m-cresol–resin interactions. Full article
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18 pages, 8099 KiB  
Article
Machine Learning-Based Recursive Prediction and Application of Green’s Function of Water-Wave Radiation and Diffraction
by Minmin Zheng, Xinsheng Fan, Chuanqing Li, Jianpeng Li, Duolun He and Renchuan Zhu
J. Mar. Sci. Eng. 2025, 13(8), 1488; https://doi.org/10.3390/jmse13081488 (registering DOI) - 1 Aug 2025
Abstract
The frequency-domain free-surface Green’s function method is widely used in solving ship hydrodynamic problems, with its core challenge lying in the computation of the Green’s function and its partial derivatives. This study analyzes the relationship between the free-surface Green’s function and its derivatives, [...] Read more.
The frequency-domain free-surface Green’s function method is widely used in solving ship hydrodynamic problems, with its core challenge lying in the computation of the Green’s function and its partial derivatives. This study analyzes the relationship between the free-surface Green’s function and its derivatives, proposing a machine learning-based recursive prediction method termed the pulsating source recursive prediction method. The accuracy and efficiency of this method under various parameter settings are investigated, and its application to the hydrodynamic calculations of container ship S175 and a bulk carrier is demonstrated. Results show that the predicted Green’s function achieves an accuracy of 3–6 decimals, with computational efficiency surpassing numerical methods and matching analytical approaches. The hydrodynamic results are reliable, confirming the method’s practical value. Full article
(This article belongs to the Special Issue Advancements in Marine Hydrodynamics and Structural Optimization)
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