Search Results (698)

Nanomaterials’ special features enable their extensive application in chemical and biochemical nanosensors for food assays; food packaging; environmental, medicinal, and pharmaceutical applications; and photoelectronics. The analytical strategies based on novel nanomaterials have proved their pivotal role and increasing interest in the assay of key food components. The choice of transducer is pivotal for promoting the performance of electrochemical sensors. Electrochemical nano-transducers provide a large active surface area, enabling improved sensitivity, specificity, fast assay, precision, accuracy, and reproducibility, over the analytical range of interest, when compared to traditional sensors. Synthetic routes encompass physical techniques in general based on top–down approaches, chemical methods mainly relying on bottom–up approaches, or green technologies. Hybrid techniques such as electrochemical pathways or photochemical reduction are also applied. Electrochemical nanocomposite sensors relying on conducting polymers are amenable to performance improvement, achieved by integrating redox mediators, conductive hydrogels, and molecular imprinting polymers. Carbon-based or metal-based nanoparticles are used in combination with ionic liquids, enhancing conductivity and electron transfer. The composites may be prepared using a plethora of combinations of carbon-based, metal-based, or organic-based nanomaterials, promoting a high electrocatalytic response, and can accommodate biorecognition elements for increased specificity. Nanomaterials can function as pivotal components in electrochemical (bio)sensors applied to food assays, aiming at the analysis of bioactives, nutrients, food additives, and contaminants. Given the broad range of transducer types, detection modes, and targeted analytes, it is important to discuss the analytical performance and applicability of such nanosensors. Full article

In this study, polysulfone-based nanocomposites with carbon black (CB) nanoparticles were fabricated to evaluate their urea-removal properties. The nanocomposites were obtained using two different methods: solution mixing and melt extrusion. These materials were evaluated using Fourier transform infrared spectroscopy (FTIR), which allowed for the identification of the corresponding functional groups within the polysulfone polymer matrix. X-ray diffraction (XRD) analysis was performed, confirming the amorphous structure of the polysulfone. The addition of modified carbon black shifted the most intense peak of the polysulfone. Thermogravimetric analysis (TGA) showed an increase in thermal stability with the addition of different concentrations of modified carbon black for solution-mixing method. Scanning electron microscopy (SEM) revealed that the melt-extrusion method presented a better dispersion of the nanoparticles, since large agglomerates were not observed. Additionally, a urea adsorption study was conducted, obtaining removal percentages of 76% and 72% for the extrusion and solution-mixing methods, respectively. It was demonstrated that the nanocomposite can be used for up to five cycles without losing urea-removal efficiency, whereas the efficiency of pure polysulfone decreases as the number of cycles increases. Finally, the hemolysis test was performed, and the nanocomposites showed less than 1% hemolysis, indicating that the material is non-hemolytic. Full article

The thermal stability of carbon fiber-reinforced plastic (CFRP) materials is constrained by the low thermal conductivity of its polymer matrix, resulting in inefficient heat dissipation, local overheating, and accelerated degradation during thermal loads. To overcome these limitations, composite materials can be modified with buckypapers—thin, densely interconnected layers of carbon nanotubes (CNTs). In this study, sixteen 8552/IM7 prepreg plies were processed with up to nine buckypapers and strategically placed at various positions. The resulting nanocomposites were evaluated for manufacturability, material properties, and thermal resistance. The findings reveal that prepreg plies provide only limited matrix material for buckypaper infiltration. Nonetheless, up to five buckypapers, corresponding to 8 wt.% CNTs, can be incorporated into the material without inducing matrix depletion defects. This integration significantly enhances the material’s thermal properties while maintaining its mechanical integrity. The nanotubes embedded in the matrix achieve an effective thermal conductivity of up to 7 W/(m·K) based on theoretical modeling. As a result, under one-sided thermal irradiation at 50 kW/m², thermo-induced damage and strength loss can be delayed by up to 20%. Therefore, thermal resistance is primarily determined by the nanotube concentration, whereas the arrangement of the buckypapers affects the material quality. Since this innovative approach enables the targeted integration of high particle fractions, it offers substantial potential for improving the safety and reliability of CFRP under thermal stress. Full article

Electroanalysis of monoamine neurotransmitters is a useful tool for monitoring relevant neurodegenerative disorders and diseases. Electroanalysis of neurotransmitters using analytical devices consisting of electrodes modified with tailored and nanostructured composite materials is an active research topic nowadays. Nano- and microstructured composite materials composed of various organic conductive polymers, metal/metal oxide nanoparticles, and carbonaceous materials enable an increase in the performance of electroanalytical sensing devices. Synergistic properties resulting from the combination of various pristine nanomaterials have enabled faster kinetics and increased overall performance. Herein, recent results related to the design and elaboration of electroanalytical sensing devices based on cost-effective and reliable nano- and microstructured composite materials for the quantification of monoamine neurotransmitters are presented. The discussion focuses on the fabrication procedures and detection strategies, highlighting the capabilities of the analytical platforms used in the determination of relevant analytes. The review aims to present the main benefits of using composite nanostructured materials in the electroanalysis of monoamine neurotransmitters. Full article

High-Bandwidth Memory (HBM) enables the bandwidth required by modern AI and high-performance computing, yet its three dimensional stack traps heat and amplifies thermo mechanical stress. We first review how conventional solutions such as heat spreaders, microchannels, high density Through-Silicon Vias (TSVs), and Mass Reflow Molded Underfill (MR MUF) underfills lower but do not eliminate the internal thermal resistance that rises sharply beyond 12layer stacks. We then synthesize recent hybrid bonding studies, showing that an optimized Cu pad density, interface characteristic, and mechanical treatments can cut junction-to-junction thermal resistance by between 22.8% and 47%, raise vertical thermal conductivity by up to three times, and shrink the stack height by more than 15%. A meta-analysis identifies design thresholds such as at least 20% Cu coverage that balances heat flow, interfacial stress, and reliability. The review next traces the chain from Coefficient of Thermal Expansion (CTE) mismatch to Cu protrusion, delamination, and warpage and classifies mitigation strategies into (i) material selection including SiCN dielectrics, nano twinned Cu, and polymer composites, (ii) process technologies such as sub-200 °C plasma-activated bonding and Chemical Mechanical Polishing (CMP) anneal co-optimization, and (iii) the structural design, including staggered stack and filleted corners. Integrating these levers suppresses stress hotspots and extends fatigue life in more than 16layer stacks. Finally, we outline a research roadmap combining a multiscale simulation with high layer prototyping to co-optimize thermal, mechanical, and electrical metrics for next-generation 20-layer HBM. Full article

This review article is devoted to the use of selenium nanoparticles (Se NPs) in plant production. The review analyzes relevant literature data for the last 10 years, considering the effect of Se NPs application on morphometric and biochemical parameters of plants. A number of actual works demonstrating the efficiency of Se NPs use in the composition of nanocomposites based on synthetic and natural polymers are considered separately. Possible mechanisms of Se NPs absorption and transport and their further activity in plant cells of agricultural crops in the context of biostimulating, biofortification, nutraceutical, and antioxidant activities of Se NPs, as well as the efficiency of Se NPs application under stress factors are discussed. The review provides data demonstrating the antibacterial and antifungal activities of Se NPs in the context of their activity against a wide range of phytopathogens. Also, we conduct a detailed comparative analysis of the relative efficiency of Se NP application with mineral Se-containing compounds (SeO₃²⁻ and SeO₄²⁻), as well as organic forms of Se (SeCys and SeMet). Full article

Bio-nanocomposites represent an advanced class of materials that combine the unique properties of nanomaterials with biopolymers, enhancing mechanical, electrical and thermal properties while ensuring biodegradability, biocompatibility and sustainability. These materials are gaining increasing attention, particularly in biomedical applications, due to their ability to interact with biological systems in ways that conventional materials cannot. Graphene and graphene oxide (GO), two of the most well-known nanocarbon-based materials, have garnered substantial interest in bio-nanocomposite research because of their extraordinary properties such as high surface area, excellent electrical conductivity, mechanical strength and biocompatibility. The integration of graphene-based nanomaterials within biopolymers, such as polysaccharides and proteins, forms a new class of bio-nanocomposites that can be tailored for a wide range of biological applications. This review explores the synthesis methods, properties and biotechnological applications of graphene-based bio-nanocomposites, with a particular focus on polysaccharide-based and protein-based composites. Emphasis is placed on the biotechnological potential of these materials, including drug delivery, tissue engineering, wound healing, antimicrobial activities and industrial food applications. Additionally, biodegradable polymers such as polylactic acid, hyaluronic acid and polyethylene glycol, which play a crucial role in biotechnological applications, will be discussed. Full article

The subject of the conducted study was primarily focused on the development of a new type of polymer blend modified with the use of nanosized fillers. The research concept involved the use of polycarbonate/polyethylene terephthalate glycol (PETG/PC) blends modified with the EBA-GMA impact modifier (ethylene–butylene–acrylonitrile copolymer) and three different types of nanofillers: montmorillonite (MMT), halloysite (HNT), and carbon nanotubes (CNT) of two types. The combination of PC, PETG, and EBA phases was used in order to achieve enhanced mechanical performance and stable processing properties. The results of the conducted study revealed that for the toughened PETG/PC/EBA blends, the impact resistance was strongly improved from the reference by 1.5 kJ/m² to 15 kJ/m². However, the results for the nanocomposites revealed that the MMT and HNT additions were limiting the impact strength. In contrast, the Charpy test results for CNT were again close to 15 kJ/m². The results of the thermal resistance measurements again revealed more favorable properties for CNT-modified PETG/PC/EBA blends. Full article

Electroactive polymers (EAPs) represent a versatile class of smart materials capable of converting electrical stimuli into mechanical motion and vice versa, positioning them as key components in the next generation of actuators and sensors. This review summarizes recent developments in both electronic and ionic EAPs, highlighting their activation mechanisms, material architectures, and multifunctional capabilities. Representative systems include dielectric elastomers, ferroelectric and conducting polymers, liquid crystal elastomers, and ionic gels. Advances in fabrication methods, such as additive manufacturing, nanocomposite engineering, and patternable electrode deposition, are discussed with emphasis on miniaturization, stretchability, and integration into soft systems. Applications span biomedical devices, wearable electronics, soft robotics, and environmental monitoring, with growing interest in platforms that combine actuation and sensing within a single structure. Finally, the review addresses critical challenges such as long-term material stability and scalability, and outlines future directions toward self-powered, AI-integrated, and sustainable EAP technologies. Full article

This research focuses on creating CuO/PANI nanocomposite films by electrodepositing copper oxide nanoparticles into a polyaniline matrix on ITO substrates. The CuO nanoparticle content was adjusted between 7% and 21%. These nanocomposites are promising for various applications, such as optoelectronic devices, gas sensors, electromagnetic interference shielding, and electrochromic devices. We utilized UV-Vis spectroscopy to examine the nanocomposites’ interaction with light, allowing us to ascertain their refractive indices and absorption coefficients. The Scherrer formula facilitated the determination of the average crystallite size, shedding light on the material’s internal structure. Tauc plots indicated a reduction in the energy-band gap from 3.36 eV to 3.12 eV as the concentration of CuO nanoparticles within the PANI matrix increased, accompanied by a rise in electrical conductivity. The incorporation of CuO nanoparticles into the polyaniline matrix appears to enhance the conjugation length of PANI chains, as evidenced by shifts in the quinoid and benzenoid ring vibrations in FTIR spectra. SEM analysis indicates that the nanocomposite films possess a relatively smooth and homogeneous surface. Additionally, FTIR and XRD analyses demonstrate an increasing degree of interaction between CuO nanoparticles and PANI chains with higher CuO concentrations. At lower concentrations, interactions were minimal. In contrast, at higher concentrations, more significant interactions were observed, which facilitated the stretching of polymer chains, improved molecular packing, and facilitated the formation of larger crystalline structures within the PANI matrix. The incorporation of CuO nanoparticles resulted in nanocomposites with electrical conductivities ranging from 1.2 to 17.0 S cm⁻¹, which are favorable for optimum performance in optoelectronic devices. These results confirm that the nanocomposite films combine pronounced crystallinity, markedly enhanced electrical conductivity, and tunable band-gap energies, positioning them as versatile candidates for next-generation optoelectronic devices. Full article

Multifunctional reinforced polymer composites provide an ideal platform for next-generation smart materials applications, enhancing matrix properties like electrical and thermal conductivity. Reinforcements are usually based on functional metal alloys, inorganic compounds, polymers, and carbon nanomaterials. The latter have drawn significant interest in developing high-performance smart composites due to their exceptional mechanical, electrical, and thermal properties. The increasing demand for highly complex functional structures has led additive manufacturing to become a reference technology for the production of smart material components. In this study, laser sintering technology was adopted to manufacture nano-graphite/nylon-12 composites with a carbon-based particle reinforcement content of up to 10% in weight. The results showed that the addition of the filler led to the fabrication of samples that reached an electrical conductivity of around 4·10⁻⁴ S/cm, in contrast to the insulating behavior of a bare polymeric matrix (i.e., lower than 10⁻¹⁰ S/cm), while maintaining a low production cost, though at the expense of mechanical performance under both tensile and bending loads. Full article

Background/Objectives: Nanocarrier particle design for treating chronic pulmonary diseases presents several challenges, including anatomical and physiological barriers. Drug-repurposing technology using monodispersed spherical silica is one of the innovative ways to deliver drugs. In the present study, the anticancer potential of combinational cisplatin/ribavirin was explored for targeted lung cancer therapeutics. Methods: Monodispersed spherical silica (80 nm) capable of diffusing into the tracheal mucus region was chosen and doped with 10 wt% superparamagnetic iron oxide nanoparticles (SPIONs). Subsequently, it was wrapped with chitosan (Chi, 0.6 wt/vol%), functionalized with 5% wt/wt cisplatin (Cp)/ribavarin (Rib) and angiotensin-converting enzyme 2 (ACE-2) (1.0 μL/mL). Formulations are based on monodispersed spherical silica or halloysite and are termed as (S/MSSiO₂/Chi/Cp/Rib) or (S/Hal/Chi/Cp/Rib), respectively. Results: X-ray diffraction (XRD) and diffuse reflectance UV-visible spectroscopy (DRS-UV-vis) analysis of S/MSSiO₂/Chi/Cp/Rib confirmed the presence of SPION nanoclusters on the silica surface (45% coverage). The wrapping of chitosan on the silica was confirmed with a Fourier transformed infrared (FTIR) stretching band at 670 cm⁻¹ and ascribed to the amide group of the polymer. The surface charge by zetasizer and saturation magnetization by vibrating sample magnetometer (VSM) were found to be −15.3 mV and 8.4 emu/g. The dialysis membrane technique was used to study the Cp and Rib release between the tumor microenvironment and normal pH ranges from 5.5 to 7.4. S/MSSiO₂/Chi formulation demonstrated pH-responsive Cp and Rib at acidic pH (5.6) and normal pH (7.4). Cp and Rib showed release of ~27% and ~17% at pH 5.6, which decreases to ~14% and ~3.2% at pH 7.4, respectively. To assess the compatibility and cytotoxic effect of our nanocomposites, the cell viability assay (MTT) was conducted on cancer lung cells A549 and normal HEK293 cells. Conclusions: The study shows that the designed nanoformulations with multifunctional capabilities are able to diffuse into the lung cells bound with dual drugs and the ACE-2 receptor. Full article

Diblock copolymers (BCP) consisting of poly(methyl methacrylate) (PMMA) and poly(1H,1H,2H,2H-perfluorodecyl methacrylate) (PsfMA) blocks are employed as templates for controlled dispersion and localization of multi-walled carbon nanotubes (MWCNT). Short MWCNT are modified with perfluoroalkyl groups to increase the compatibility between MWCNT and the semifluorinated (PsfMA) phase and to promote a defined arrangement of MWCNT in the BCP morphology. Thin BCP and BCP/MWCNT composite films are prepared by dip-coating using tetrahydrofuran as solvent with dispersed MWCNT. Atomic force microscopy, scanning and transmission electron microscopy reveal a strong tendency of the BCP to form micelle-like domains consisting of a PMMA shell and a semifluorinated PsfMA core, embedded in a soft phase, containing also semifluorinated blocks. MWCNT preferentially localized in the embedding phase outside the micelles. Perfluoroalkyl-modification leads to significant improvement in the dispersion of MWCNT, both in the polymer solution and the resulting nanocomposite film due to increased interaction of MWCNT with the semifluorinated side chains in the soft phase outside the micelle domains. As a result, reliable electrical conductivity is observed in contrast to films with non-modified MWCNT. Thus, well-dispersed, modified MWCNT provide a defined electrical conduction path at the micrometer level, which is interesting for applications in electronics and vapor sensing. Full article

Copper (Cu) nanoparticles, known for their high electrical conductivity and cost-effectiveness, have emerged as essential materials in various applications from flexible electronics to antimicrobial agents. This work focuses on the synthesis and characterization of semiconductive nanostructured films composed of polyvinyl alcohol (PVA) with embedded Cu nanoparticles. The study provides a comprehensive analysis of the structural, optical, electrical, and dielectric properties of the resulting nanocomposites. The results indicate a significant reduction in optical band gap, from 4.82 eV in pure PVA to 2.6–2.8 eV in the nanocomposites, alongside enhanced electrical conductivities reaching 1.20 S/cm for films with 5 wt.% Cu. Dielectric assessments further reveal high dielectric constants, underscoring the potential of these materials for flexible electronic applications. This work highlights the effectiveness of incorporating Cu nanoparticles into polymer matrices, paving the way for advanced materials that meet the demands of next-generation electronics. Full article

MXenes, a family of two-dimensional (2D) transition metal carbides, carbonitrides, and nitrides, have emerged as a promising class of nanomaterials for interdisciplinary applications due to their unique physiochemical properties. The large surface area, excellent electrical conductivity, superior mechanical properties, and abundant possible functional groups make this layered nanomaterial an ideal candidate for multifunctional hybrid materials for electronic applications. This review highlights recent progress in MXene-based hybrid materials, focusing on their electrical, dielectric, and electromagnetic interference (EMI) shielding properties, with an emphasis on the development of multifunctionality required for advanced electronic devices. The review explores the multifunctional nature of MXene-based polymer nanocomposites and hybrid materials, covering the coexistence of a diverse range of properties, including sensory capabilities, electromagnetic interference shielding, energy storage, and the Joule heating phenomenon. Finally, the future outlook and key challenges are summarized, offering insights to guide future research aimed at improving the performance and functionality of MXene–polymer nanocomposites. Full article